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By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By T. F. Bamber

The South Nottinghamshire Area has not been greatly troubled by spontaneous combustion until the last few years, during which the Blackshale Seam has been developed and exploited. The problem was first encountered at a colliery which was heavily preoccupied with a major reconstruction scheme, and with the sudden appearance of a completely new hazard both men and management had to adapt themselves very quickly to meet the situation. The paper contributed to the Symposium by the South Nottinghamshire Area illustrates the problems by reference to actual incidents, and shows how the lessons learned from them have been applied to the shaping of future policy on the avoidance and treatment of spontaneous combustion.

May 23, 1905

By T Atkinson, A Cobb, R AJIington

Risk management is concerned with the whole spectrum of financial, geological, engineering, legal, governmental, social and occasionally ethnic issues, concerned with mining projects. The inherent risks in mining operations are well publicised, but new issues and hazards arrive on the scene and lake precedence, but the older risks still remain, while insurance cover may not he ‘full cover’ in the future. It has long been recognised that quantitative approaches to risk analysis can play a major role, but although these methods are capable of considerable theoretical precision, the lack of sound risk input data and experienced personnel limits the usefulness of theoretical analysis. It can, however, greatly assist in comparing cases, in identifying areas of risk and help in the investment decision process. Its major contribution to a mining project is that it imposes an investigative discipline that also assists in improving the quantitative approach to risk analysis and hence risk management. Risk analysis and risk management also requires sound common sense and major inputs from experienced geologists, mining, mechanical, electrical and mineral processing engineers. The Engineering Council, in 1992, issued a ten point code of professional practice entitled ‘Engineers and Risk Issues’ (The Engineering Council. 1992), covering our professional responsibilities, the law, our conduct, the need for a systematic approach to risk issues, the use of professional judgement, communications, risk management, evaluation of risk, our professional development in this field and the encouragement of public awareness of risk issues. This is a specific area of training perhaps long neglected by our industry and academic institutions (Atkinson. 1983).

Jan 5, 1996

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By A. H. G. Mitchell

Gold-poor and gold-rich porphyry and epithermal gold-silver deposits of Caenozoic and Cretaceous age in the western Pacific and central and eastern Europe are confined to predominantly andesitic continental margins and island arcs. The arc volcanic rocks overlie a complex non-oceanic basement of stacked nappes, the uppermost of which is often ophiolitic. The emplacement of ophiolite triggered a reversal of tectonic polarity, subduction and arc magmatism. Andesitic volcanism and the formation of a strato-volcano were followed by the ascent of magma and porphyry copper mineralisation. Regional propylitic alteration came from convecting, predominantly meteoric fluids. Magmatic degassing caused advanced argillic alteration. This is commonly unmineralised in perched water tables, but may sometimes host high sulphidation gold or enargite gold at deeper levels within the propylitic zone. The onset of extensional stress after the andesitic volcanism allowed meteoric water to circulate to depths of 5 km or more, with consequent cooling of an ascending magma body at depth and the development of low sulphidation epithermal gold mineralisation near and immediately above the sub-volcanic basement surface. All andesitic arcs are mineralised. Regional controls on their ore potential include the level of erosion and geological features in the basement that focus the ascent of fluids. Differences between the mineralisation of the European and the western Pacific arcs may reflect the presence of older, more granitic basements in many of the European arcs.

Jan 12, 1992

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By M. A. Bussell, G. S. Camm

The study included lode zones at Wheal Pendarves, South Crofty and Rosevale tin mines. Fluid inclusion-containing microfractures are a common feature of the granites and typically show a preferred orientation over quite a large area. The close proximity of a dominant vein or fault controls their density and orientation. They are important pathways for fluids and provide a marker for palaeo-fluid flow. Overprinting provides a reliable representation of the evolution of the hydrothermal fluids in a vein system from early magmatic fluids to late-stage meteoric and basinal brine input. Measurement of microfracture orientation allows estimation of the regional stress regime during a specific hydrothermal event. Since micro- and macro-structures can generally be reliably correlated, these studies assist in modelling the detailed development of complex vein systems. Microfracture density is a good measure of palaeo-permeability, with implications for control of wallrock alteration. The determination of the location and density of microfractures can assist the mine geologist in identifying the location of potentially economic vein structures where macroscopic markers are absent

Aug 1, 1996

By C R. Ferrari

Residual subsidence is generally accepted as being about 5% of the total subsidence occurring within 12 months of all mining finishing. This paper looks at five case studies from different parts of the country, in various mining settings within a depth range of 430m to 760m. From a single seam single panel working to working the eleventh seam, all are within the concealed coalfield, similar to today's mining. The monitoring of subsidence continued for many years once the mining had finished and the results obtained are at considerable variance from the accepted norm. Subsidence has been found to carry on for up to eleven years after mining has ended, within a range of 8% to 45% of total subsidence. A highly significant factor was that subsidence, as a whole, was generally much more than predicted. The residual subsidence aspect has to he viewed in this context and in order to debate the subject at length, the causes of residual subsidence have to be balanced against the apparent inability to accurately predict subsidence. The results from the case studies were similar, even though the mining settings differed considerably. Subsidence of around 10% to 20% continued for several years after mining had ceased.

Jan 7, 1997

By W. R. Chambers

A wide variety of mining conditions exists within the South Midlands Area and across this range of conditions more than one half of the mines are highly susceptible to spontaneous combustion. Two thick seams in which the greatest risk exists are described and illustrated. The different heatings which take place are categorized by the locations at which they occur in the mines: additional special cases not easily categorized by location are discussed separately. The discussion for each category of heating follows the pattern of: (i) the reasons why it occurs; (ii) when it arises the means by which it is fought, and (iii) the preventive measures taken in an attempt to avoid its occurrence. Relatively new factors which may affect the incidence of heatings are highlighted and suggestions are made which may assist in reducing the number of incidents in the Area. A new method of continuous sampling, analysis and recording is described and mention made of an original method of interpreting carbon monoxide results with the aid of the computer. The first results from this work show that an early warning is given of an adverse change in trend several weeks earlier than with the present methods. Lastly, suggestions are made about the direction in which research might proceed to assist in reducing the special hazards created by several features inherent in the present methods of mining.

May 23, 1905

By L. J. Cabri, J. M. D. Wilson, R Lastra

An image analysis program can search for gold minerals in polished sections by scanning about 100 x 100 back-scattered electron images at a magnification of x400, allowing gold grains as small as 1 micrometre in diameter to be detected. Typically, a c.15 h overnight search of a product smaller than 45 micrometres will scan c.1 500 000 particles, providing data that are not easily obtained through manual operation of an optical microscope. The program locates grains of the correct brightness, acquires gold X-rays from them by wavelength-dispersive spectrometry, filters the data to remove artefacts and record the images and stage locations for subsequent retrieval. At the end of the run, the program allows the operator to verify and identify the grains found. Industrial studies at Canmet have included determining the nature of gold in cyanidation tailings, checking the mineralogy and size of gold grains in samples from an Indonesian Cu-Au concentrator and locating and measuring gold liberation and grain sizes in an ore

Jun 21, 1905

By M. A. Leosson, S. H. Bottrell, R. J. Newton

Sylvite at Boulby is mined 1 140 m beneath the sea and the mine suffers from the influx of water. This is of two kinds: persistent flows originating in the Sherwood Sandstone aquifer and entering the evaporite sequence through fractures in the intervening mudstone, and impersistent flows which are transient in nature and of uncertain origin. Water from the overlying sandstone has become enriched with NaCl and large amounts of KCl and some Mg and Br have been added by interaction with the evaporites. Waters from the transient flows are isotopically distinct from those in the Sherwood Sandstone, being enriched in H and O. They are also saturated with respect to halite and sylvite, but have higher K/Na than the persistent flows and are much more enriched in Mg and Br

Jun 18, 1905

By I. L. Whyte

apparent density and drag coefficient of porous ores on

Apr 1, 1995

A study of the thermodynamic properties of magnesium chloride ammines was carried out with the ultimate objective that the thermal decomposition of the hexammine MgCl2.6NH3 may prove successful on a commercial scale for the manufacture of anhydrous magnesium chloride, which is required for the efficient electrolytic production of magnesium. The experimental data are presented in the form of an equilibrium diagram that aids the understanding of the conditions associated with the thermal decomposition of ammines

Jun 13, 1905

By J. Crummy, I. K. Anderson, A. J. Hall, R. S. Haszeldine

Bedrock gold mineralisation has been located in association with an extensive float train 25 km west of known alluvial gold. It is in the form of open, matrix-supported breccias comprising pyritic quartz/sericite clasts in a vuggy, cherty chalcedonic and crystalline quartz matrix. Fluid inclusions in pyritic clasts indicate trapping temperatures for gold mineralising hydrothermal fluid of 170-240 degrees C. This mineralisation could represent the upper part of a feeder zone to an exhalative hydrothermal system. It is possible that other high-level feeder zones could be preserved elsewhere in the area. Deep weathering of such a system could provide a source for the alluvial gold localities near Helmsdale. It is suggested that east and central Sutherland presents good prospects for exhalative epithermal gold mineralisation and the associated feeder zones

Jun 19, 1905

By T. Ogasawara, J. P. Barbosa, A. J. Monhemius, F. T. Da Silvia

A thermodynamic analysis of the sulphation of rare-earth phosphates and the water-leaching of rare-earth sulphates was used to guide experimental work on the sulphation and leaching of concentrates from Pitinga. It was concluded that the sulphuric acid digestion of xenotime is technically feasible and could be used industrially to produce yttrium and other rare-earth oxides. Yttrium extractions of more than 90% were obtained by digestion at 503 K for 4 h at an acid:concentrate ratio of 2:1 with particle size -0.053 mm. The apparent activation energy at temperatures less than 473 K, as determined from the Arrhenius plot, was 11.0 kJ/mol, indicating that the reaction is controlled by the diffusion of the reactants or products through the sulphate layer

Jun 19, 1905

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By A. Sutherland Strachan

Before regulations governing the work on the mines, it was not uncommon in the Rand for a miner to die within a period of 2-3 years as the result of exposure to dust. This paper considers mine and tunnel conditions promoting silicosis and measures to avoid dust exposure in the Rand, South Africa.The relationship between blasting and lung lesions is explored. Evidence is presented that improved working conditions and lowered dust levels reduce the incidence of silicosis.

Jan 1, 1947

By S K. Das

An intensive investigation into modern roof support technology, including hy draulic and control systems, has been carried out against the perspective of global development and support behaviour on longwall faces across the Indian sub-continent. The wide ranging study examined various types and designs of modern supports used in seams of varying thickness and inclination where caving and stowing were practised. Consideration has been given to structural analysis, support resistance, the various forces acting over and on the powered supports and to support compatibility. The examination of the phy sical parameters has been allied to field experience and, together, have led to the formulation of standard designs for both the powered support structure and structural systems. A realistic mathematical model has been formulated for calculating the capacity of roof support requirements resulting from the actual behaviour of the immediate roof stratum. As a result of the work, it should be possible to readily select the most appropriate type of support sy stem for the conditions and longwall mining method that is to be employed.

Jan 4, 1997

By C. C. Harris

The use of Alyavdin's equation Y(x,t) = 1-e(-bt) for describing the effect of grinding time on size distribution is discussed. The equation transforms into linear form by expressing it as log-log reciprocal (1 - Y) versus log t. For plotting, specially divided grids are available; Rosin-Rammler or Weibull charts may be used. The data of Herbst and Fuerstenau are especially useful for illustrating the Alyavdin-Weibull chart in two applications: (1) presenting data (which are relatively unaffected by experimental scatter) and comparing them with theoretical predictions, and (2) as a test for the zero-order kinetics production hypothesis. The chart based on the Alyavdin-Weibull equation is suggested as a useful aid in the analysis of kinetic data (/ versus f), though not as a procedure in its own right. Proposed applications are (1) displaying data with excellent clarity, since it avoids the kind of congestion inherent in some other plotting methods, and (2) as a test for assumed kinetic relationships. Sometimes, equation 1 describes the data quite closely, and in these cases the parameter values appear to be related to certain operating conditions.

Dec 1, 1971

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971