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By T. Hidayat, D. Shishin, V. Prostakova, M. Shevchenko

The chemical compositions of copper feed streams are becoming increasingly complex following the growing demand for metals and corresponding shortages of primary sources. The optimisation of process conditions requires an accurate description of phase equilibria and thermodynamics. Integrated experimental and thermodynamic modelling research program on the characterisation of the complex, multi-component, multi-phase gas-slag-matte-speiss-metal-solids Cu2O-PbO-ZnO-Al2O3- CaO-MgO-FeO-Fe2O3-SiO2-S-(As-Bi-Ni-Sb-Sn-Ag-Au) system is being carried out to support companies undertaking the pyrometallurgical primary production and recycling of copper. The experiments involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of equilibrium phase compositions with quantitative microanalytical techniques, including electron probe X- ray microanalysis and Laser Ablation ICP-MS. The thermodynamic modelling is undertaken using FactSage computer package with advanced thermodynamic solution models. The continuing development of research methodologies has resulted in significant advances in research outcomes. Implementation of the results of these fundamental studies involves an ongoing collaboration of researchers and industry technologists. An overview of recent progress in research, implementation and applications in industrial practice are given in the paper. INTRODUCTION Rapidly developing technologies increase the demand for various metals in number and volumes. Modern technological devices such as mobile phones, computers, other electronic devices, have dozens of metals—all those metals have to be a) produced and b) recycled. The fast transition in mobility from fossil energy delivered through combustion to renewable energy first stored in bakeries and delivered through electric engines introduce a significant change in the metal demand in terms of both type and volume of metals. Pyrometallurgy is playing a key role in supporting these changes in our industrialised society.

Jan 1, 2019

By A. J. Smethurst, S. B. Hearn, S. Boskovic

"The problem of crud in solvent extraction is well known and can be a major handicap and operational issue. Colloidal silica can cause a number of problems including interfering with flocculation, initiating crud formation in solvent extraction (SX), decreasing SX extraction kinetics and increasing SX phase disengagement times. Flocculation can be utilized to remove some of the troublesome particulates but colloidal silica does not flocculate well and presents a different problem requiring innovative chemistry to solve. Coagulants can assist by facilitating the removal of this colloidal silica by promoting the agglomeration of the particles to a size which can be more readily settled or flocculated in solid/liquid separations. This is achieved when the coagulants bind to the surfaces, displacing water and destabilizing the colloids, whereupon they bind to each other which facilitate their amenability to conventional flocculation.INTRODUCTIONSilicate minerals are abundant in the upper layers of the Earth’s crust, and there are few mineral deposits without significant levels of gangue silicates. Silicate minerals include the pure silicas, such as quartz and other silicate containing minerals such as clays, chlorites, feldspars, as well a vast number of less common silicates.During the acid leaching of ores, two types of fine silica particles are released in solution from the dissolution of the host mineral. The first consists of partly depleted silicates, and the second is colloidal silica, which forms in solution. It is this second type which has the potential to cause crud formation as well as poor solution clarities, slow filter rates and excessive flocculant usage (Figure1)."

Jan 1, 2016

By M. L. Jeremic

"The syngenetic and epigenetic mechanics of sedimentation and deformation of coal seams resulted in various types of internal structure, as listed below:TYPE I-massive structure with evenly distributed coal constituencies of integrated mechanical properties.TYPE II-broad-banded structure, with bright and dull coal bands of differential mechanical properties.TYPE III-heterogeneous structure, with sheared coal bands and partings of sectional mechanical properties.TYPE IV-contortional structure, with refolded coal layers and deteriorated mechanical properties.TYPE V-porous structure of orogenically crushed and pulverized coal, with disintegrated mechanical properties.The study suggests criteria for the estimation of coal seam internal structure (gamma-gamma density log and cracks density log), which might be related to the evaluation of strata stability and coal mineability.IntroductionIt is common knowledge that coal seams have various internal structures due to different syngenetic and epigenetic events. Investigations of the internal structure of coal seams have been carried out in the coal fields of Western Canada, as follows: geological field studies of coal-bearing strata;?,geophysical borehole surveying studies;?,geological borehole logging and crack density;?,underground phenomenological studies of mine structure;?,chemical coal analysis; and?,mechanical testing of coal samples.These investigations eliminated a large number of criteria previously established for the estimation of coal seam internal structure and indicated that, from an engineering point of view, only two of them are sufficient:(I) density of seam profile (inferred from gamma-gamma log);(2) density of crack s (inferred from geological log).On the basis of these criteria, five main structural types of coal seams have been classified, which might be related to mechanics of deformation and ' failure of mine structures."

Jan 1, 1982

By Karl J. C. Harries

"The following is an outline or check sheet of some things that might be looked at when considering the concept of a royalty or royalty provisions. It is not intended as a guide to what is right or wrong (that is for the parties to decide). It does not replace the discussions in this work and is not intended to be a complete or exhaustive compilation of matters to be considered. It presumes that you are familiar with the basic concepts of royalties and has been included as an aide memoire only. Use it as such, with caution and common sense, and amend it to suit your needs. Remember also that brevity can result in inaccuracy or imprecision. This is a danger in many points below.The section references are for the sections where the matter is the main subject of the section – see the index for other sections.Royalty TypesNet Proceeds [§§ 5.8.; 11.4.]• No accepted or understood meaning within industry.• Literal meaning, if not defined, would imply “net operating profit”.• Often defined as net profit with revenue base of proceeds from sale of product.• Should not be used without detailed and clear definition. Net Operating Profit [§§ 5.8.; 11.4. – referred to only]• Net profit without recoupment of pre-production expenditures.• Revenue base: usually proceeds from sale of product.• Operating costs deductible.• Some reserves may be permitted.• Recoupment of some post-production capital expenditures may be permitted.• Not often seen as basis for royalties in Canada."

Jan 1, 2003

By H. Stocker, C. E. Makepeace

"This paper presents the statistical analyses of several sets of data acquired in several programs of sampling of radon daughters in uranium mines. The measurements were taken over periods of days or weeks for given locations or location occupations within these mines. Because the sampling applies to specific intervals of time and specific locations, a method is suggested f or the eventual application of a monitoring program which would be suitable on an annual basis for these locations. The present data and analyses thereof are not justifiably applicable to a monitoring regimen on an annualbasis, without a number of additional assumptions.The aim of the present analyses of concentration measurements is the determination of the minimum number of measurements required to achieve an annual radon daughter exposure estimate, for individual workers, having an error no greater than 50% at the 95% confidence level. The criterion of accuracy is taken from a statement in the American National Standard, Radiation Protection in Uranium Mines (ANSI NI3.8-I973), and is currently used, in somewhat modified form, as a guide to uranium mining licensees in Canada. Uncertainties associated with occupancy time are ignored in the present analysis. IntroductionOne of the principal aims of any scheme of radiation protection is that of improving the accuracy of exposure estimation for workers. The example presented here is from the area of radon daughter exposure estimation for uranium miners. The conventional means of estimating workers' exposures is grab sampling of radon daughter concentrations combined with occupancy time weighting in the various work and travel locations. Uncertainties exist in each of these components, and in an environment of highly variable radon daughter concentrations (such as an active uranium mine) one is always uncertain as to the representativeness of the grab sample (compared to the average concentration) unless a sophisticated monitoring scheme has been implemented based on previous experience in such an environment.Improvements in the accuracy and precision of employee radon daughter exposure records depend, primarily, on three factors;"

Jan 1, 1980

By Robert B. Parsons

"Ontario and Quebec taxpayers will have to dig deeper into their pockets to pay more tax, according to budget papers tabled in these provinces in May 1993. Individuals will be hardest hit, but corporations will also have to ante up in the face of higher rates, reduced deductions, and new taxes.Up, up, and away...Somewhere in the bleak picture of the 1993 Quebec and Ontario budgets, there is a bit of good news for the mining industry.Careful scrutiny reveals:• Ontario will correct a capital tax provision which inadvertently penalizes flow through share issuers;• Quebec's flow-through incentives will be extended to December 31, 1995; and • both Quebec and Ontario will allow deductions for mine site reclamation payments.The industry may also find some comfort in the fact that Ontario's new corporate minimum tax will be profit-based (unlike the federal minimum tax), so that non-producers should not face a liability for this tax. There is some concern though, about Quebec's announcement that the refundable credit mechanism in the Mining Duties Act will be reviewed."

Jan 1, 1993

Agenda ?Trends in Wireless Technology ?Success and Opportunities ?Improving plants efficiency ?Improving plants reliability ?Improving plants safety and security ?Wireless Ecosystem ?Lessons Learnt / Recommendations Why Wireless? ?Lower cost (no wiring cost) ?Flexibility (no wire) ?Standards-compliant wireless devices major factor enabling growth:?Standard WLAN (IEEE 802.11)?Wireless field I/Os (IEEE 802.11, ISA100.11 and WirelessHART) ??Wireless adoption will become a milestone that will rival the introduction of Fieldbus and the distributed control system (DCS) in its importance.? ARC Advisory Group

May 1, 2009

By Steve Scott

Green Economy Toyota Prius Hybrid contains about 50 kg of copper. All-electric cars have about 100 kg of copper. From where will all the copper come? Wind turbines have 1 metric ton of copper China is building 221 cities of 1 million people by 2025 (13 cities per year from 2008) = 10 New Yorks. The Greater Toronto Area has 5.6 million people, so a new GTA every 22 weeks!

May 1, 2013

By Peter A. Bevan

"In massive and semi-massive deposits, it is essential to take samples continuously for specific gravity determination as well as for assays of the various metals of interest. Failure to use specific gravity in mixed deposits of high density contrast will result in incorrect determinations of the average grade.Graphs and linear equations of specific gravity against the grade of one metal are not considered accurate enough in a multi-mineral deposit, but appear to be very satisfactory in a theoretical one-sulphide/gangue mix. Specific gravities based on base-metal values only in massive sulphide deposits will result in underestimating the effect of low grade areas on the average grade and also cause a reduction in the calculated tonnage.IntroductionBy definition, a base-metal assay is the percentage of metal by weight contained in a sample, whether it be a soil or silt sample, a grab, chip or channel sample, or a section of diamond drill core.In those cases where there is a series of contiguous samples, say in diamond-drill core, the average grade may be required of the various assays that are above a desired or required cutoff grade.Internal low grade or waste can be included if the assays one side or the other are used to ""carry"" the lower grade material and the resulting average grade is above the cut-off grade. To determine the average grade, the individual assays are ""weighted"" by multiplying these values by their respective lengths, adding up the cumulative assay times length and dividing by the total length. This method is essentially a weighting by volume, because the core diameter is constant and is common to all the samples being considered for estimating the average grade . If some of the core samples have much higher specific gravities than others, and the specific gravities are not used in the weighting process, the resultant average grade will be over-estimated or underestimated, depending on the grade of the heavier sections. When core assays of approximately the same specific gravity or weight are averaged by length, the error in the weighted estimation of the average grade is negligible."

Jan 1, 1993

By J. R. Shouldice

"IntroductionREEFS of Silurian age are recognized in southwestern Ontario, both in outcrop and from subsurface information. This paper deals with the so-called 'pinnacle' reefs which are known only in the subsurface. For the purpose of this paper, the pinnacle reefs are arbitrarily defined as those structures having a height of over 250 feet and a length of less than two miles. This definition eliminates numerous mounds and other broader, more subdued, structures of less certain origin, found in subsurface beds.The term 'pinnacle reef' is perhaps unfortunate, but it is in common usage in Ontario and is used elsewhere for different types of reefs. A new name is justified by the unusual environment and structure of the Ontario reefs, but it is unlikely that any other term would gain acceptance. Rather than propose a new term which would be ignored or result in further confusion and misuse, the name 'pinnacle', as defined above, is used in this paper.Pinnacle reefs have been found over a fairly large part of southwestern Ontario. The known reefs of this type parallel the southeast edge of lake Huron and •follow the strike of the structure contours which circle the Michigan basin (see Figure 1). In total, twenty-five such reefs have been discovered in southwestern Ontario."

Jan 1, 1955

By J. H. Shillabeer

"Rational exploration requires the prior selection of areas possessing excellent geological potential and minimum hazards to commercial development . Within an over-all strategy of grass-roots exploration, two procedures for selecting areas for (i) coal and (ii) metals exploration are described. The procedures explicitly balance infrastructure requirements and environmental concerns for areas of geological merit not alienated in parks and reserves. Through consensus, priorities are attached to those areas meriting closer scrutiny and field reconnaissance.IntroductionMining companies need to know that having made a potentially economic discovery, they will be allowed to develop it with minimum delay and at reasonable cost. The environment for exploration in British Columbia is complex and recent experience suggests that conditions are not becoming any easier. Conflicts over land use issues, preservation and economic development are common. The high cost of exploration requires that the risks should be offset where possible by: (i) carefully selecting the areas in which to work (ii) conducting operations in a responsible manner, and (iii) working cooperatively with the community of interests. This paper concerns the first action: prior selection of areas.To aid exploration planning at Suncor, a procedure was developed to grade those areas of the province possessing favourable geology according to the ease with which a mine might be developed . This had to be done within the constraints of the company's over-all approach to exploration. This emphasizes ""grass-roots"" exploration of self-generated projects in British Columbia. In addition, having selected a favourable belt of rocks, it is intended to persevere there while steadily adding to the accumulated data base and local experience. Hence, it is intended to concentrate on an area. This implies a long-term commitment to an area which in turn increases the importance of the original selection.Suncor's search is directed to finding base and precious metals in intrusive and volcanic environments, and export quality coal."

Jan 1, 1985

By Rodnei Graça, Jorge Silva Bettencourt, Lena Virgínia Soares Monteiro, Baruch Spiro, Tolentino Flávio De Oliveira

Abstract - The Vazante Mine is located in the Vazante District, the largest zinc district in Brazil. The Vazante deposit consists dominantly of an unusual willemitic ore. Small sulfide bodies are tectonically imbricated with the willemitic ore, within the Vazante shear zone. Structural styles of deformation and petrographic and isotopic evidence indicate that willemitic mineralization and deformation occurred synchronously during the Neo-Proterozoic. Various generations of hydrothermal veins and hydraulic breccias may pre-date, accompany and overprint the mineralization. Ore-formation temperatures are deduced from stable isotope geothermometry and mineral chemistry of both sulfide bodies and willemitic ore. Temperatures during the main stage of mineralization range from 206°C to 294°C (willemitic ore) and 317°C (sulfides), and reflect the prevailing metamorphic conditions within the shear zone. The fluid from which the gangue minerals of the sulfide bodies precipitated (at 250°C) had an oxygen isotopic average value of ?18O = +19.4‰. This value appears to reflect the interaction of metamorphic fluid with the carbonate rocks of the Vazante formation. At 250°C, the fluid in equilibrium with the vein mineral phases and willemitic ore assemblage exhibits a uniform oxygen isotopic composition, with an average value of ?18O = +11.5‰. The positive linear covariance of ?18O and ?13C ratios of the carbonates is most likely due to the mixing of metamorphic and meteoric fluids. The ?34S values of sulfides indicate a direct crustal origin for the sulfur. It is suggested that the sulfur is largely derived from pre-existing sulfide bodies and has been transported by metamorphic fluids. The willemitic ore may have originated from the precipitation of metal in sulfur- poor fluids under oxidized conditions, within the Vazante shear zone.

Jan 1, 1999

By R. W. Lawrence, A. Bruynesteyn

"Pre-oxidation of refractory pyritic concentrates by biological leaching to enhance the recovery of gold and silver in cyan ideation has been investigated. The results of laboratory tests on three concentrates are presented. In all cases substantial increases in precious metal recoveries were obtained following the pre-treatment. For one concentrate, gold recovery of 81% was achieved following an 87% oxidation of pyrite, compared with 24% recovery by direct cyanidation of non-oxidized concentrate. Gold and silver recoveries from the other concentrates were increased from the range 60-78% to over 90% and from 80-86% to over 98% respectively. Operating parameters are discussed and methods of maintaining high oxidation rates are evaluated. Methods of employing this pre-oxidation technique in commercial practice are described.IntroductionMany of the gold and silver deposits now being developed contain precious metals finely disseminated in sulphide minerals such as pyrite. These ore s often present considerable resistance to metal recovery. The ease with which gold may be extracted is usually related to grain size and its manner of distribution within the host mineral. In many cases, a significant percentage of the gold may occur in submicroscopic form, or in solid solution with pyrite, so that even very fine grinding fail s to liberate the metal for recovery by cyanide leaching. Such ores are often termed refractory. Even in cases where liberation by fine grinding is practicable, high cyanide and lime consumption may be experienced due to the presence of specific sulphide minerals, and poor metal recovery may result.Pre-oxidation methods for refractory ore s and concentrates are commonly used to improve precious metal recoveries. Roasting, for example, as a pre-treatment to cyanidation, removes harmful constituents by oxidation or volatilization, and liberates gold from pyrite. In some cases, however, this method of pre-oxidation can result in poorer metal recovery, particularly of silver, due to fusion and the formation of clinker, and the formation of compounds which consume cyanide in the subsequent metal recovery stage. Difficulties in compliance with environmental pollution regulations may also be encountered."

Jan 1, 1983

By O. A. Ojo, D. L. Chen, N. Zhou, J. Q. Zhang, A. K. Khan

Dual phase (DP) steels are designed to consist of hard martensite dispersed in a relatively soft ferrite matrix, which offers a favorable combination of high strength with good deformability. Fiber laser welding (FLW) is becoming increasingly important for joining advanced materials due to its flexibility and deep penetration. In this study, the microstructure of a dual phase steel, DP980, welded by FLW technique was carefully analysed. Gleeble thermo-mechanical simulation coupled with analytical transmission electron microscopy (TEM) revealed that the FLW process produced significant microstructural changes in a narrow heat affected zone (HAZ) and fusion zone (FZ), which can result in dramatic changes in mechanical properties. This is reflected in the micro-hardness profile obtained across the welded material. The salient phase transitions induced by the FLW, including the formation of new martensite grains in the upper-critical HAZ and FZ, are discussed.

Jan 1, 2014

By C. Dodds, R. S. Ferrari-John, The University of Nottingham, G. Dimitrakis, J. Katrib, A. R. Batchelor

"Sorting technologies have the potential to reduce energy use in comminution by rejecting uneconomic ore before feed material enters the mill. However, a major challenge for sorting porphyry copper ores is providing a basis of discrimination between valuable and non-valuable fragments, due to their complex mineralogies and textural features. Microwave heating in combination with infra-red detection (MW-IR) has been shown to provide upgraded feedstock for certain ores at bench scale. Selective heating of copper sulphide minerals compared to the gangue leads to an increased thermal response for valuable fragments, providing the basis for sorting.Rapid scale up of MW-IR from bench scale to a 100 t/h continuous pilot plant facility has been facilitated by the design of microwave choking structures to allow continuous operation at industrially meaningful throughputs, whilst meeting health and safety and electromagnetic compliance standards, and the integration of materials handling with electromagnetic systems.Laboratory batch testing on a pilot scale microwave system has been undertaken to investigate the thermal response of copper ores under industrial conditions, at microwave energy inputs up to 1 kWh/t. These results provided the operating window and recommended test conditions for the continuous pilot plant. Sortability curves predicted in the laboratory are in good agreement with separations achieved during continuous pilot plant operations. The potential microwave sortability of a number of ores has been studied, allowing informed decisions to be made about potential ore candidates based on mineralogy. Future development of the technology will be underpinned by the creation and validation of scale up concepts for 1000 t/h operations. Understanding the value proposition for individual sites/applications will be central to unlocking the potential economic and environmental benefits of microwave sorting."

Jan 1, 2016

By D. S. Harries, R. I. L. Guthrie

"The use and development of scientific disciplines involved in heat transfer technology, related in general to steel masses and in particular to batch annealing, is demonstrated.The measurable benefits of cooperation are tabled; on industry's side, this includes a 10 to 20 per cent decrease in annealing time, and a corresponding higher productivity potential. The returned benefits to the academic engineer include the development and refinement of new computer algorithms related to heat transfer mechanisms.IntroductionThe object of this discussion is not really to describe an improvement in the batch annealing operation, but to use the project as an example of joint work between industry and the academic field. Both parties have derived a number of substantial benefits. These benefits will be listed, of course, but the batch anneal project will be used just as a typical example of cooperation. Why it happened will be explained, what actually happened will be described and finally some thoughts about areas in the field of heat transfer, where cooperation will continue in the future, will be highlighted. The paper will close with a message.Industry OverviewAt the outset, perhaps it should be understood that, in general, the Research Department at Dofasco believes that the universities and their staff are not destined for the problem-solving role in industry. Its opinion is that the university staff is best suited to the gathering and dissemination of knowledge. There are other more professional problem solvers for industry, including the steel industries' own individual investigation groups. Dofasco, therefore, looks to its academics for consultation. It benefits by bouncing ideas off them, and through rubbing shoulders with them in such a way that their knowledge can be tapped, and thus establish more effective scientific routes. In addition, the younger and brighter engineer s can broaden their scope through the intellectual contact with experts. The university professors can, it is believed, benefit through closer contacts with result-orientated research. They can also develop an appreciation of the fiscal control necessary for industrial investigations, without government subsidies, grants, etc., and with massive overheads."

Jan 1, 1982

By J. D. Galloways

The northern part of the P. G. E. railway traverses and opens up that part of the province known as the Cariboo district, comprising the Cariboo and Quesnel Mining Divisions, which are a part of the Northeastern Mineral Survey District. Williams lake, a divisional point on the P. G. E. is near the southern boundary of the Quesnel Division and from this point the railway runs northerly to Quesnel, its present terminus. From Quesnel the railway is projected and partially constructed to Prince George on the Canadian National railway; therefore its general trend is northerly through the heart of the Cariboo district. Early History There is no need to outline at any length the early history of mining in the Cariboo. It is sufficient to say that the great gold rush to the Cariboo, in the early sixties, was practically the commencement of mining in British Columbia. These early placer mining operations centred around the old towns of Quesnel Forks, Keithley Creek, Barkerville and Van Winkle, the latter now called Stanley. Many millions of dollars of placer gold have been taken out and the end of production is not in sight yet. The maximum yearly production was reached about 1863, after which there was a gradual decline in output. During the war years production was at a very low figure but a steady, even if small, increase has occurred in the last three years and prospects are encouraging for a much greater output.

Jan 1, 1925

By J. W. Reynolds

This paper describes the function of the research and development department of a large mining organization and the benefits which can be derived over the years. Examples are given of work done in rock drilling, ventilation, noise control and the development of backfill stowing machinery.

Jan 1, 1970

By Robert B. Parsons

"Canadian income tax legislation contains a number of provisions which serve to facilitate the structuring of business arrangements, including mineral resource ventures. These rules are often fairly complex and not easily understood. This article attempts to explain in plain and understandable language the mechanics and benefits of one of the more frequently encountered provisions, the ""Section 85 election"".IntroductionThe Canadian resource industries are probably singled out for more special attention under this country's tax legislation than any other industry. This special treatment is, of course, not always welcomed by the industry, such as where unnecessarily restrictive taxation is perceived to exist or where agonizingly complex tax legislation must be dealt with. On the other hand, certain provisions in the tax legislation treat the industry in a relatively favourable manner, including a number of rules which, in recognition of the high risk and capital requirements of the resource sector, serve to facilitate the structuring of resource ventures."

Jan 1, 1984

By K. D. Eng, W. T. Tierney

"During the past century, the development of vehicular transportation has benefitted tremendously from the performance improvement in engines in a situation where low-cost, plentiful fuel supplies were the order of the day. Engine advances were enhanced by and also dictated fuel modification to better adapt the energy source to the power plant.In discussing the several aspects of the change in approach from ""an engine and its fuel to a fuel and its engine"", the authors touch on the following areas:1. Description of an engine concept that provides the needed flexibility in fuel appetite at good efficiency to cope with future requirement s.2. The constraints placed on liquid fuel resource energy utilization efficiency by special engine-required fuel properties and the fuel efficiency of the various engine types available.3. Future vehicle engine fuel sources. This review will put into perspective the problem associated with the net energy available from future fuel sources under extensive research and development at present.4. A brief review of test data to show that fuel-tolerant and fuel-efficient engines are viable and that, in a fuel-resource-limited future, they can be a ""light at the end of the tunnel.""The Texaco Controlled Combustion System (TCCS)The TCCS is a unique means for stratified charge operation of an internal combustion engine in such a manner as to eliminate the requirement for octane or cetane number specification for the fuel. Octane rating is an empirical engine test method that evaluates a gasoline's resistance to spontaneous ignition or ""knock."" Cetane is based on a different engine test, which determines a diesel fuel's ease of spontaneous ignition . High cetane number enhances cold starting and permits high-speed diesel engine operation. As one would expect, the fuels in current use cover a band when the two values, octane and cetane, are plotted against each other."

Jan 1, 1982