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By Lauri Pesonen

"Although electrical energy use at copper smelters is typically about 15-20% of operational costs, it is something which is not very often analyzed and discussed at a detail level in technical papers and presentations. This paper aims to list different equipment configurations per smelter area and estimate their electrical energy consumptions versus unit of material processed. In addition chosen smelting technology and oxygen enrichment rates affect the overall electricity consumption and therefore some overall guidance is provided for efficiency gains.INTRODUCTION In principle, processing plants, such as copper smelters, require electrical and chemical energy together with some degree of human input to process input materials into desirable output form like metallic copper. From the standpoint of metallurgical plant designers, the thermodynamics of smelting, when it comes to releasing and conserving thermal energy, is sufficiently understood and frequently discussed in the literature in detail, but judging from the quantity of publications, the way how we exactly utilize electrical energy is not. This article is meant to illustrate how electrical energy consumption is distributed among different process units and equipment types at copper smelters using various smelting technologies. In general, typically about 15-20% of operational costs are related to electricity and at locations with high electricity prices the potential savings can be quite significant for the overall profitability of the plant operations. In today’s tight profit margin environment any potential savings are more than welcome. The purpose here is not to promote any certain copper smelting technology, but to open a discussion on how and where we use electrical energy, and how the overall energy use could be lowered with the implementation of newest electric power saving designs and solutions. Using the principles outlined in this article, it should be fairly easy and straightforward to replicate the calculations and even improve them wherever it is seen necessary for the greater benefit for us all in this industry"

Jan 1, 2017

By K. R. Barnard, K. D. Marte, T. V. Gamarano

"The first commercial scale application of CSIRO’s direct solvent extraction (DSX) technology has been in operation at the Boleo project in Mexico since December, 2015. In this application, DSX is a synergistic solvent extraction system consisting of the extractants LIX 63 and Versatic 10 for recovery of cobalt and zinc from a solution background of manganese, magnesium, and calcium. Key operating parameters such as metal extraction, phase disengagement and extractant stability are summarized and discussed in this paper.INTRODUCTION Commissioning of the Boleo processing plant, located on Mexico’s Baja peninsula, began with the copper circuit starting in late 2014, with first copper cathode production achieved in January, 2015. The cobalt and zinc circuits began commissioning in December, 2015 with first zinc sulphate monohydrate (ZSM) and cobalt cathode production achieved in February and April, 2016 respectively. The Boleo project flow sheet and development has been described in detail in previous publications (Dreisinger, et al. 2005; Dreisinger, Baxter, & Molnar, 2006; Dreisinger, et al. 2008; Dreisinger, et al. 2009) and is summarized schematically in Figure 1. Boleo is a mixed oxide/sulphide Cu-Co-Zn-Mn high clay deposit that is processed in a whole ore, atmospheric, oxidative and reductive, sulphuric acid/seawater leach. Copper is recovered as cathode by conventional solvent extraction and electrowinning. Cobalt and zinc are recovered, from a solution background of manganese, magnesium, and calcium, by CSIRO’s synergistic solvent extraction technology Direct Solvent Extraction (DSX). Cobalt and zinc are bulk stripped from the DSX circuit and then further purified by phosphinic acid solvent extraction to produce zinc sulphate monohydrate granules via spray dried granulation and cobalt cathode rounds via divided cell electrowinning."

Jan 1, 2017

By G. J. McTeer, D. L. Verhelst, D. J. Rioux

Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. Since 1997, KIVCETTM flash smelting technology has been utilized for the treatment of zinc plant residues and lead concentrates. Trail Operations’ furnace uses four water-cooled jackets for bullion tapping. This paper provides an overview of KIVCET bullion tapping for the past 16 years, and discusses successes and challenges encountered with respect to operations, training and monitoring.

Jan 1, 2015

By J. C. Marchand, M. A. Berube

"L'objectif principal recherché lors du broyage d 'un minerai est de libérer adéquatement ses valeurs utiles en vue de leur concentration ultérieure. La pratique courante consiste à tenter d'obtenir un produit de broyage d'une granulométrie constante. Malheureusement, les propriétés texturales des minéraux utiles varient naturellement dans un gisement et une telle stratégie n'entraine pas toujours pour ces minéraux un degré de libération constant. Pour un rendement optimal du procédé de concentration, cette variable très importante doit donc être périodiquement vérifiée.Jusqu'à maintenant, la plupart des études de libération des minerais se font en examinant des sections polies de particules du minerai broyé. Le GRAAIM a récemment assemblé un système modulaire d'analyse d'images qui servira en grande partie à des mesures automatiques du degré de libération des minéraux. Le système s'avère relativement peu coûteux comparativement à la plupart des analyseurs de texture conventionnels si l'on considère que plusieurs de ses composantes, par exemple le miniordinateur, sont utilisées à une foule d'autres applications, et il permet de plus une grande souplesse d'utilisation puisque l'on a qu'à construire des algorithmes de mesure et de calcul en fonction de l'objectif recherché. Des programmes particuliers permettant des études automatiques de libération sur des sections polies de particules ont ainsi été élaborés. Ils permettent également des mesures de teneurs et de distributions granulométriques apparentes des particules. Des résultats obtenus dans le cas de minerais de fer sont brièvement présentés afin d'illustrer la technique."

Jan 1, 1983

By T. S. Heah, S. T. Bishop

"The Lorraine property is located in the northern Intermontane Belt, north-central British Columbia. The property is underlain by intrusive rocks of the Duckling Creek Syenite Complex, an Early Jurassic, alkaline phase of the Late Triassic-Early Cretaceous Hogem Batholith. Two significant zones of copper-gold mineralization have been explored to date; the Main zone (historical Upper and Lower deposits) and the recently discovered Extension zone. A combined geological resource was estimated in 1975 for the Main zone deposits at 10 million tonnes averaging 0.7% Cu, and from 0.1 g/t Au to 0.34 g/t Au. The Extension zone, still at an exploration stage, is estimated to be considerably smaller than the Main zone.Copper-gold mineralization at Lorraine Mountain exhibits characteristics suggestive of both magmatic and hydrothermal origins, and may be related to orthomagmatic-hydrothermal fluid flow contemporaneous with magmatism and development of migmatitic fabrics. A depth greater than the depth of formation of classical porphyries may explain many of the variations displayed by mineralization at Lorraine. These characteristics distinguish Lorraine from other members of the alkalic suite of porphyry Cu-Au deposits in the Canadian Cordillera.IntroductionThe Lorraine prospect is located in the Omineca Mountains, at the headwaters of Duckling Creek, 56 km northwest of Germansen Landing (Fig. 1). The property is centred at latitude 55°55'N, longitude l25°26'W on NTS mapsheet 93N/14W. The area is typified by mountains of moderate relief, with elevations ranging from 1150 m in the valleys to peaks of 2000 m. Valleys are U-shaped and blanketed by glacial till which give way to steep, talus covered slopes and sharp ridges. Outcrop is generally limited to elevations above 1600 m (Fig. 2)."

Jan 1, 1995

By S. Noh, T. K. Kim, B. O. Lee

Future nuclear reactor systems such as a sodium-cooled fast reactor are being designed under severe conditions in terms of operating temperature and irradiation fluence compared to current commercial reactors. For realization of such systems, it is necessary to develop an advanced structural material having both high strength and irradiation resistance at high temperatures. Oxide dispersion strengthened (ODS) steel is considered as one of the most promising structural material because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. Several advanced ODS steels were designed and fabricated by a mechanical alloying, hot isostatic pressing and hot extrusion processes. This study focuses on the effects of heat treatment parameters during the fabrication process parameters on the microstructures of ODS steels for future nuclear system applications.

Jan 1, 2015

By J R. Barber, B. E. Rogers, R. Fukuzawa

Mercury is sometimes present in non-ferrous ores including gold, zinc, copper and lead. The selection and use of appropriate mercury abatement technology is critical for preventing its release to the environment during ore processing and to protect workers from mercury exposure. This paper presents a general decision-making process for mercury abatement technology selection for major emission sources in the gold industry. Mercury abatement can be accomplished through making process changes and/or by adding a process step to an existing system (i.e. "end-of-pipe control"). Advantages and limitations of the technologies along with waste / by-product management options are discussed through case studies of current operating mercury abatement systems.

Jan 1, 2015

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By P. E. Cavanagh

"The Davis tube test has been used for many years as a laboratory method for determining the magnetic iron re-coverable from a magnetite iron orebody. This paper de-scribes a method for determining the recoverable iron from ores of the Labrador Trough type, with the usua1 flow sheet utilizing spirals followed by magnetic separation.The mechanical structure of a metamorphosed iron ore, resulting from recrystallization over long periods of time, is the basis for the laboratory method developed. Similarities between the structures of such recrystallized ores and the structure of annealed and recrystallized steel are noted.A laboratory technique to determine the size of the different grains of gangue and iron ore minerals is de-scribed and the application of this information to arrive at recommended grinding techniques and flow sheets is demonstrated. The use of the method to determine recoverable iron in such ores is compared to actual iron recovery in the pilot-plant and commercial concentrations of the same ore.The use of a specified lower limit of recoverable iron as determined by this method, in order to design open-pit limits, achieves practical results when compared to designing a pit based on an arbitrary lower limit of total soluble iron. The Ungava Iron Ore deposits are used in giving an example of the resulting pit design changes."

Jan 1, 1968

By Lawrence Devon Smith

"What is Due Diligence?Within the mining industry the term “due diligence” is used to describe a detailed data review, generally in connection with the purchase or sale of a mineral property, the approval of a large capital expenditure, or the borrowing of a large sum of money.The term originates in the requirement of the board of directors of a corporation to “act honestly and in good faith ... and exercise the care, diligence, and skill that a reasonably prudent person would exercise in comparable circumstances” (OBCA, 1994). Furthermore, the law assumes that a corporation (or its board) will have exercised due diligence in the acquisition of an asset and, therefore, knowingly (in the absence of fraud or deceit) will have taken on the liabilities and obligations associated with the asset (Nelson, 1994). This is the familiar “Buyer Beware”.Directors are liable for their decisions except “if the director relies in good faith upon financial statements of the corporation represented … by an officer of the corporation or in a written report of the auditor, or a report of a lawyer, accountant, engineer, appraiser, or other person whose profession lends credibility to a statement made by any such person.” (OBCA, 1994).Hence the importance of reports prepared by professionals. They provide confirmation that the directors have exercised due diligence in the performance of their duties. For this reason these reports are referred to as due diligence studies"

Jan 1, 1997

By Lawrence Devon Smith

"Within the mining industry the term “due diligence” is used to describe a detailed data review, generally in connection with the purchase or sale of a mineral property, the approval of a large capital expenditure, or the borrowing of a large sum of money.The term originates in the requirement of the board of directors of a corporation to “act honestly and in good faith and exercise the care, diligence, and skill that a reasonably prudent person would exercise in comparable circumstances” (OBCA, 1994). Furthermore, the law assumes that a corporation (or its board) will have exercised due diligence in the acquisition of an asset and, therefore, knowingly (in the absence of fraud or deceit) will have taken on the liabilities and obligations associated with the asset (Nelson, 1994). This is the familiar “Buyer Beware”.Directors are liable for their decisions except “if the director relies in good faith up on financial statements of the corporation represented by an officer of the corporation or in a written report of the auditor, or a report of a lawyer, accountant, engineer, appraiser, or other person whose profession lends credibility to a statement made by any such person.”(OBCA, 1994).Hence the importance of reports prepared by professionals. They provide confirmation that the directors have exercised due diligence in the performance of their duties. For this reason these reports are referred to as due diligence studies."

Jan 1, 1996

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a' very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948

By Alessandro Navarra, Amir Arash Rafiei, Kristian Waters

Mathematical programming (MP) is fundamental to systems engineering and operations management, but has not been widely adopted by mineral processors. The current paper presents an interdisciplinary approach, using MP to incorporate basic notions of mass balancing into an optimization framework. The optimization is typically related to economic profitability. Two- and three-product formulas are extended to give formal descriptions of alternate modes of operation, and a global representation of the concentrator. At this global level, the framework may assist plant managers to make tactical decisions based on incoming feed data. The MP framework is demonstrated through sample calculations describing a lead-zinc concentrator.

Jan 1, 2015

By H S. Ellis

Flow studies have been conducted on nickel-water suspensions in a 1in.-diam., 42-ft.-long transparent lab-oratory pipeline at concentrations of up to 25 per cent, by volume, and slurry velocities of up to 15 ft/sec. The average size of the nickel powder was approximately 150 mesh (106J.L). Three flow regime were noted. At the highest velocities, i.e., above 10 ft/;sec., where the concentration distribution through the vertical diameter was most uniform, pressure gradients could be correlated with the Durand-Condolios equation (7,8). An intermediate region, i.e., from 7 ft/sec. to10 ft/sec., could be distinguished, the lower velocity limit being that at which nickel particles began to deposit. This region was also marked by decreasing pressure gradients, for a given concentration, as the velocity was reduced. The upper velocity limit in this region was also uniquely defined in that the friction factor for any nickel concentration was the same as that for water. In the third regime, below about 7 ft/sec

Jan 1, 1963

By D. Pacey

"This paper reviews the installation, start-up, and operation of a comprehensive monitoring and targeting management technique in which all plant utilities (i.e., electricity, natural gas, compressed air, and water) are managed as controllable resources in the same way that raw materials, mined ore, personnel and capital are managed.The essential elements of monitoring and targeting (M&T) include:•gathering in a systematic, disciplined way the utility information by energy account centres;•closely monitoring the utilities used in each centre and comparing them with production on a common time base (e.g., kWh/ton per day);•bench marking and target setting to pro-vide attainable energy reduction goals which can be further refined as they are achieved; and•establishing an implementation plant that may provide efficiency enhancing benefits to various operating areas within the plant.The M&T system will reduce utility consumption per unit of production on a continuing basis.This would translate into sustained operating cost and waste. M&T will also provide better information for assessing the plant operation and progressively implementing further enhancements."

Jan 1, 1997

By D. P. McDonald

"IntroductionTHE PURPOSE of this paper is to present .a summary of the evidence given before the Petroleum and Natural Gas Conservation Board in support of applications to it for permits to export natural gas from Alberta.I will attempt to be objective in my statements, despite the fact that my main interest in the hearings before the Board was to advance the interests of my own clients, the Westcoast Transmission Company, Limited.The hearing of the export applications •commenced before the Board in January, 1950, with the .application of the Westcoast Transmission Company. Joint hearings were commenced in September, 1950, and completed on December 14th, 1951. The Board heard evidence in support of six applications for export, one application to build a gathering system in Alberta, and three interveners, the .latter being the City of Calgary, the local gas companies, .and the coal interests, including both operators of coal mines and the Unions.The evidence comprised better than 8,400 pages, over two million words, and occupied 92 days before the Board.The Interest in Natural GasThe natural gas industry is one of the newer industries. It is not yet twenty years •old. In the United States, the expansion •of pipeline facilities has been phenomenal in the last fifteen years, and particularly in the last three years, when a total of over two billion dollars was invested in pipeline facilities. There are approximately 250,000 miles of gas transmission pipelines in the United States at this time, with additional lines constantly being pressed."

Jan 1, 1952

By A. M. L. Cushing, S. Kelebek

Presently, adsorption is one of the effective methods of removing toxic contaminants from waste waters. The contaminants from metal mining industrial operations include an effluent water containing various types of heavy metal species at concentrations beyond the maximum allowable limits, which are 0.5 ppm and 0.3 ppm for nickel and copper species, respectively. Adsorption behavior of copper ions pre-chelated with diethylenetriamine (DETA) and triethylenetetramine (TETA) onto natural bentonite and peat has been investigated. Both natural bentonite and peat was found to be capable of removing these copper-polyamine complexes from aqueous solutions relevant to process water effluents. However, the adsorption capacity of bentonite was significantly higher than that of peat. Two models were used to study the adsorption kinetics: a pseudo-first-order rate expression and a pseudo-second-order rate expression. For both adsorbents, the data conformed best to the pseudo-second-order rate expression. Representation of the experimental data through adsorption models was also investigated. Out of the four cases considered, namely, Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms, it was found that for both bentonite and peat, the copper polyamine adsorption data conformed best to the Dubinin-Radushkevich adsorption model. The Langmuir model also represents the bentonite-copper polyamine adsorption system reasonably well as the second best case, suggesting that the amount adsorbed on bentonite might be a monolayer with strong affinity.

Jan 1, 2015

By E. Y. Carlson

"IN A SHORT PAPER it is impossible to do much more than to list the industrial minerals found in Saskatchewan and to give a brief description of the activity associated with each. I will not attempt to discuss the geology. It is sufficient to say that the settled part of the Province is covered by glacial drift which varies in thickness from a few feet to several hundreds of feet, and that this has hindered the search over much of the Province.CLAYA notable exception to this is the Cypress Hills area in the southwest corner which did not suffer any glacial action and where we find some of the large exposures of Cretaceous clays. In this area, the majority of the deposits are of stone-ware clays which are •an excellent raw material for such products as face brick and sewer pipe. Although the clay cannot be transported over any great distance it is used extensively in Alberta and Saskatchewan in the production of these products."

Jan 1, 1959

By N. Campbell, W. T. Orvine

The metalliferous deposits of British Columbia are largely confined to that portion of the Cordilleran province lying west of the Rocky Mountain trench. Massive sulphides in the coastal area carry important copper •values together with lead and zinc and are composed mainly of pyrite which replaces schists or shear zones. The massive sulphide ore of the interior, on the other hand, contains lead and zinc with little copper. Pyrrhotite rather than pyrite is... the dominant metallic and deposition took place through selective replacement of sedimentary beds.

Jan 1, 1960

By L G. White

During 1958, prospecting parties working for the Mackenzie Syndicate in the Flat River area of the Mackenzie mountains, Northwest Territories, identified tungsten mineralization and located the property now being developed by the Canada Tungsten Mining Corporation Ltd. Scheelite mineralization, associated with pyrrhotite and minor chalcopyrite, occurs in lime silicate skarn replacement zones within a limestone-chert-argillite series intruded by granitic dykes originating from the ? main batholithic mass underlying the sedimentary beds. The results of surface outcrop sampling and 15,000 feet of grid-pattern diamond drilling have been combined to outline an orebody estimated to contain 1.32 million tons, grading 2.51 per cent WO after applying a 10 per cent dilution factor for mining purposes. T HE property of Canada Tungsten Mining Corporation Ltd. is located in the upper Flat River area of the Mackenzie mountains, Northwest Territories. Skarn-type replacement deposits containing scheelite mineralization are .situated between elevations of 4,500 and 5,500 feet above sea level along the east flank of the mountain range forming the boundary between the Yukon Territory and the Northwest Territories. The nearest supply center for the area is Watson Lake, Yukon Territory, located at Milepost 635 on the Alaska Highway.

Jan 1, 1963