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By J. Bensabat, B. Figueiredo, A. Niemi, J. Rutqvist, C. F. Tsang

"A hydro-mechanical model was developed to study the interaction between mechanical deformation and fluid flow in the fault zones during CO2 injection and storage at the Heletz site which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The potential reservoir for CO2 storage at the Heletz site consists of three sand layers separated by lowpermeability shale layers. The potential consequences caused by fault reactivation, focusing on the shortterm integrity of CO2 storage, are evaluated. The difference in the results obtained by considering the three-layer as an equivalent layer storage formation is analyzed.INTRODUCTIONLarge-scale storage of CO2 in deep underground reservoirs may cause considerable pore-pressure perturbation as well as flux migration and concern has been raised over whether shear slip displacements may be induced in nearby faults, as a consequence of their reactivation. A state-of-the-art review can be found in Rutqvist (2012), which describes the various possible effects resulting from CO2 injection into a deep sedimentary basin, including those involved in reservoir stress–strain changes, micro-seismicity, caprock sealing performance, and potential fault reactivation. Moreover, several studies have recently shown how CO2 injection may produce seismic events both on major faults (i.e., large faults with large initial shear offset) (Cappa & Rutqvist, 2011a, b, 2012), and on minor faults that might have gone undetected during the site characterization, e.g., faults less than 1 km long and without detected initial offset (Mazzoldi et al., 2012).The present paper is concerned with the Heletz formation which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The Heletz site located at the southern Mediterranean coastal plain of Israel and the structure is an anticline fold with a crest of about 4 km by 2 km. The structure is gently dipping to the east, truncated by a pinch-out line to the west and subdivided into a number of blocks by transversal normal faults with small displacements. The water table is located at 300 m below the land surface. An areal sketch of the site with the elevation of the caprock and the location of the borehole that has been chosen for the CO2 injection experiment is presented in Figure 1."

Jan 1, 2015

By Fredrik Sarvell, Leo-Ville Miettinen, Veli-Matti Uotinen

"Abstract The continued concentration of building activities in cramped areas of city centres means more underground construction and facilities. Demand to minimize execution time and any kind of disturbance to business, general traffic, people and nearby technical structures is increasing. To answer these challenges foundation business has to develop schedule-wise and technically reliable deep excavation and foundation solutions in vulnerable surroundings and challenging soil conditions.Drilled pipe pile wall – RD-pile wall – is a combination of Ruukki drilled steel pipe piles and interlocking sections. Individual RD piles, typical diameters between 219 mm to 610 mm, are connected to each other with interlocks welded to the piles on the automated welding line at the workshop. The matching dimensions of the drilling system and interlocking sections allow the installation of RD piles through stones and boulders and even into the bedrock, if necessary, in a single operation. Installation is done by a down-the-hole hammer (DTH) using the centric drilling system and oversized ring bits or a drilling system consisting of a pilot bit and reamer wings.RD-pile walls have been used as permanent and temporary retaining walls for different kinds of demanding excavations and structures, such as bridge foundation, as quay wall and as sealing structure in rehabilitation of an existing dam. Rigidity and watertightness of the lower end of the RDpile wall is being researched as well as fire design issues examined. One of the most fascinating RDpile wall solution is to utilize the wall as a permanent underground basement wall. Reliable and rigid connection to bedrock decreases the bending moment and deflection of the wall and good fire resistance in addition to large variety of pile dimensions and steel grades gives possibilities to design and execute a cost-efficient basement wall and foundations without temporary retaining wall works. 1. IntroductionIn northern Scandinavian soil conditions, installation of sheet pile walls, or even secant pile walls, is often problematic due to the existence of hard and large boulders in the overburden, and especially when the retaining wall structure should penetrate to or into the hard bedrock. On the other hand, an efficient and reliable piling technique suitable for the demanding soil conditions described above, percussion drilling, has been developed since the 1960’s, and especially from the mid-1990’s, when the concentric drilling method with the ring bit and pilot was introduced. A new retaining wall application, the RD pile wall was developed by combining that drilling method with the widely used retaining wall solution based on steel pipe piles and welded interlocks (a pipe pile wall normally installed with vibratory or impact hammers)."

Jan 1, 2014

By T. Johnson

Hydrometallurgical processes can be exceptionally corrosive. This is particularly true in acid leaching processes for copper, cobalt, nickel and rare earth elements. In the last five years, several large hydromet plants have been built in North America (Vale - Long Harbour, Baja Mining ? El Boleo and MolyCorp - Mountain Pass). Hundreds of storage tanks, extraction vessels and electrowinning cells along with miles of piping were designed and fabricated to withstand the aggressive environments inherent in these processes. One key element all three projects had in common was the extensive use of FRP in equipment design. As a material of construction, FRP provided equal if not improved durability relative to alternative corrosion resistant alloys at a considerably lower cost. This paper will highlight the extensive use of FRP in these three world scale projects and why it was chosen for each process.

Jan 1, 2013

As in other countries, gold mining inNew Zealand has been cyclic in character. Looking at these cycles may provide insights as to what may occur in the future and that is the basis for this study.   New Zealand has experienced four gold mining cycles. The first began in 1857, peaked in 1866 and terminated in 1890. This cycle was characterised by alluvial gold mining by individuals and small groups. This is referred to as the Labour Led cycle. The second cycle began in 1890 and reached its peak in 1906 and terminated in 1929. This cycle was characterised by the use of dredges in alluvial gold mining and was also the peak of hard rock mining. This cycle is referred to as the Technology Led Cycle. The third cycle peaked in 1940. This cycle was far less significant than the previous cycles, arising out of the depression when the unemployed embarked on small scale alluvial mining. This overprinted the continuing decline that occurred after 1906. This cycle is here referred to as the Depression Overprint Cycle.   The fourth cycle began in 1984 when production began to climb rapidly from a very low base. The growth in production was spurred by rising gold prices in the early 1980s resulting in relatively low grade gold-bearing alluvial ground becoming economic. But in the 1990s, production from the new hardrock mines in Coromandel and Otago has overshadowed alluvial production. This cycle is here referred to as the Price Led cycle.   What are the future prospects for gold in New Zealand? Although there are many factors involved, this will be largely determined by two factors; firstly, continued access to prospective gold-bearing properties, and secondly, the price of gold. Based on these factors, three future industry scenarios have been developed. The first of these is industry collapse, in which access to prospective property is constrained and prices mayor may not weaken. The second is industry consolidation, in which the available ground is accumulated by a small number of large companies who can use economies of scale to weather price fluctuations. The third scenario is industry growth, in which access to prospective ground is constrained in environmentally sensitive areas but is otherwise relatively unconstrained. Efficient companies are allowed to work in a policy and economic framework that allows them to make a major contribution to the economy.   While the industry cannot control these critical factors, a good knowledge of the positive role gold mining could play in the future economy may provide a framework by which the access issue, in particular, may be addressed from a balanced perspective.

Jan 1, 1994

By Vladimir I. Ryaboy, Konstantin M. Asonchik

"At flotation of sulfide-barite ores of one of deposits sulfide and barite concentrates are obtained. In sulfide cycle potassium xantogenate as a collector in consumption of 200 g/ton, methylisobutylcarbinol (MIBC) as a foaming agent in consumption of 30 g/ton and also liquid glass are used. In barite cycle tall oil as fatty acid collector in consumption up to 400 g/ton is used.Sulfide concentrate represents mainly gold- and silver-containing pyrite. The contents of gold makes not less than 10 g per ton, silver - not less than 278 g/t. Barite concentrate contains up to 86% of barite.Factory is working in water recirculation conditions. Owing to that in barite cycle fatty acid collector is used, technological water from tailing repository contains fatty acids soap up to 25 mg/l. Before submission into sulfide cycle this water is conditioned with active carbon to delete the main part of fatty acid collector. The active carbon consumption makes 0,4-0,5 kg per 1m3 of water or 1,5-2 kg per ton of ore. The above mentioned consumption of active carbon improves reducing of contents of fatty acid collector from the initial concentration of 25-30 mg/l to 4 mg/l. At concentration 4 mg/l fatty acid collector does not render negative influence on flotation index in sulfide cycle. At the absence of active carbon pollution of sulfide concentrate and its irrevocable lost are observed."

Jan 1, 2003

By L. L. Wyman

THE exact nature of the changes that take place in the iron-nickel alloys, giving rise to the interesting and useful expansion alloys in the Invar range, has yet to be fully understood. Similarly, the ternary iron-nickel-cobalt alloys, which also possess such commercially useful expansion characteristics, 1,2 are concerned with transformations that appear to be identical with those found in the parent iron-nickel alloys. The investigations on iron-nickel alloys in the range 26 to 29 per cent Ni have been reported by several authors" wherein it is shown that there are factors other than temperature, such as stress and grain size, which play an important part in determining the temperature at which the low-temperature transformation takes place. It will be shown in this paper that the ternary iron-nickel-cobalt alloys having nickel contents comparable to the alloys mentioned above behave in a parallel manner. The alloys in the range of 26 to 31 per cent Ni and 16 to 21 per cent Co have a coefficient of expansion of about 4.0 X 10-1 per degree Centi-grade, and the alloys in this range of composition find considerable application in making glass-to-metal seals, because these expansion properties so well match commercial glasses. The behavior of these alloys is not a simple matter, for it has been observed in alloys of 28.5 per cent Ni and 18.5 Co that severe working can cause the appearance of a second phase having a needlelike structure similar to the martensite structure in carbon steels. Fig. 1 shows the change brought about in an alloy of this composition when a strip of this material was cut with tin shears. This second phase has been identified as the body-centered cubic alpha phase, and it is the purpose of this paper to describe the results of some of the preliminary investigations in the study of the changes involved in these alloys.

Jan 1, 1939

By J. Härkki, R. Hiltunen

The Akanvaara intrusion (surface area 50-55 km2) in Savukoski, Northern Finland, hosts 23 distinct monocumulate layers of small euhedral chromite crystals enclosed in a silicate matrix. These chromitite layers have been divided into four groups; UC (upper chromitite), ULC (uppermost lower chromitite) LC (lower chromitite) and LLC (lowermost lower chromitite). The driving force for investigating the Akanvaara chromites and their reduction behaviour originated from their very low MgO content and relatively low Al2O3 content, giving them a unique quality which based on thermodynamics should facilitate the reduction. Another interesting feature is the high amount of V2O3 present especially in the upper chromitite. The chromites included in this study are from the UC and ULC layers (24.9 and 22.7 per cent Cr2O3 respectively). To obtain a better understanding of the reduction behaviour of Akanvaara samples in comparison to MgO-bearing chromitites, Kemi chromite from the ferrochrome works in Tornio, Finland, was included in the study as a reference sample. The reduction experiments were isothermal in a temperature range of 1000-1400°C in CO atmosphere. Experiments were also conducted with coke addition in pellets and briquettes in CO/Ar/H2 atmospheres. The results of the reduction experiments complemented with microanalytical research indicate that the Akanvaara chromites do reduce to a higher degree than the Kemi chromite. Although the aim was to characterize the mechanisms of reduction focusing on gas-solid reactions, the nature and amount of the gangue minerals was such that a considerable amount of slag phase was formed, which affected the reduction mechanisms extensively. The structural features together with low MgO and high FeO content in both Akanvaara chromites are important factors resulting in better reducibility than in the Kemi chromite.

Jan 1, 2004

By P. Karimi, A. Akcil, A. Amini, H. Abdollahi

"In this study, cyanidation experiments were carried out on a massive sulfide ore sample, whose grades of the precious metals gold and silver were found to be 4.2 g/t and 311.9 g/t, respectively. Other elements in the ore were arsenic with average grade of 1,751.6 g/t; antimony, 619.7 g/t; zinc, 781.4 g/t; copper, 454.6 g/t; lead, 101.8 g/t; mercury, 324.3 g/t; and bismuth, 0.6 g/t. The first objective of test work focused on determining the best conditions for extracting gold from the ore, ground to less than 75 microns. Different influential parameters such as particle size fraction, cyanide concentration, pH and leaching time were investigated. The optimum parameters were found to be particle size fraction of less than 25 microns, cyanide concentration of 2,000 mg/L, pH of 11 and cyanidation time of 24 hours. In these optimum conditions, the highest gold and silver leaching efficiencies were 76.88 and 59.63 percent, respectively. In addition, roasting as pretreatment at a temperature of 700°C over a period of two hours was evaluated. Cyanidation testing of the roasted ore in the optimum conditions found increases in the gold and silver leaching efficiencies to 85.97 and 67.57 percent, respectively. Moreover, antimony extraction rose to 43.10 percent, from 23.73 percent without roasting.IntroductionGenerally, gold ores can be classified as “free milling” or “refractory,” depending on how they respond to cyanide leaching (La Brooy et al., 1994; Celep et al., 2009). While high gold recoveries (> 90 percent) from free-milling gold ores can be readily achieved, refractory gold ores are often characterized by low gold recoveries (50-80 percent) within a conventional cyanide leaching process (Rubisov et al., 1996; Adams, 2005; Celep et al., 2009). The presence of preg-robber components such as carbonaceous matter, sulfide minerals and aluminosilicate can further decrease gold and silver dissolution rates and recoveries. With the negative effect of the presence of preg-robbers, gold dissolution is considerably diminished in solutions with high cyanide concentration (Tan et al., 2005). In such refractory gold ores, gold particles may sometimes be occluded or included in the sulfide minerals, and pretreatment becomes necessary to break down the mineral structure to liberate gold for subsequent recovery. These ores are usually pretreated with an oxidizing process, after which gold and silver can be recovered by a standard cyanidation process. The main oxidizing processes available for refractory gold ores are roasting (LaBrooy et al., 1994; Angelidis and Kydros, 1995; Li et al., 2009; Karimi et al., 2010; Kyle et al., 2012), biological oxidation (Lawrence and Bruynesteyn, 1983; Komnitsas and Pooley, 1990, 1991; Deng and Liao, 2002; Ciftci and Akcil, 2010, 2013) and pressure oxidation (Mason, 1990; Murthy et al., 1992; Qingcui et al., 2009). In addition, ultra-fine grinding is being used in some plants for the liberation of gold and silver particles that are interlocked in the sulfide or silicate minerals (Celep et al., 2011)"

Jan 1, 2015

By G. R. Lane, A. Vermeulen, S. van de Venter, S. Bhoowanpursadh

Over the past two years Anglo Platinum made use of the specialist skills of Cyest Corporation to develop a Mine Optimization Tool (MOT) to enhance the current suite of in house mine planning tools and processes. The application was built in a multidimensional modelling environment developed by Cyest called CarbonL. This has allowed complex modelling that is transparent to the business users and therefore is not prone to the ?black box? approach that generally exists with these types of complex tools. The purpose of the MOT is to have an integrated software tool that can schedule production activities by half level for a shaft complex, while at the same time integrating the economics concomitant with that schedule. The tool allows the user to configure all activities relevant to the selected mining method, define the mine design parameters and geological parameters, define scheduling rules and then schedule all activities. This allows the user to test various production strategies and schedules very quickly and easily in terms of shaft value, costs and revenue profiles, labour complement and production ramp up so as to determine the option that best fits the overall strategy. This allows assessments of multiple scenarios in a relatively short period of time, after which only the best option is taken forward for graphic design and scheduling. This paper discusses briefly the rationale behind the Mine Optimisation Tool and the underlying workings of the modules that comprise the tool. It also covers the life cycle of this tool from the original prototype through to the final Mine Optimisation Tool software and discusses the positioning of the final tool.

Jan 1, 2007

By J. E. Sepulveda, R. Morrow

"The Linear Wear Theory provides a reliable framework for the assessment of grinding media performance at full scale. This theory can be applied for analyzing grinding media consumption rates in any given grinding operation as well as the evaluation of alternative grinding media products, based on actual operational data, correcting for conditions like ore hardness, feed and product sizes, mill power and circuit throughput; all of them unrelated to the grinding media intrinsic quality attributes. A series of Moly-Cop Tools 3.0 applications have been developed to facilitate the calculations involved. Moly-Cop Tools 3.0 is available, free of charge, to all interested parties through the corresponding author.INTRODUCTION Mineral grinding circuit operators recognize the significance of grinding media (balls) consumption on the cost structure of any full scale grinding facility. The effective cost associated with this essential consumable depends on two factors: delivered price and durability (quality) of the grinding media. When evaluating alternative grinding media varieties, there is a well accepted evaluation criterion by which a given media type is considered to be “cost-effective” when its unit application cost – normally expressed in $/ton of ore ground – is shown to be lower than that of a nominal reference condition: Grinding Media Cost = Ball Price x Ball Consumption (1) ($ /ton ground) ($/ton balls) (ton balls/ton ground) Under this criterion, an alternative, higher-price grinding media product could be “cost-effective” if its associated consumption rate is sufficiently lower than the reference media, enough to yield a lower grinding cost, as dictated by Equation 1. For the proper application of the above criterion, evaluators must rely on representative indicators of grinding media quality, ideally independent of most mill operating conditions. In each particular case, ball price is always a known component; however, it is not so evident how media performance (quality) differences amongst alternative product types could be assessed with a reasonable degree of accuracy and precision."

Jan 1, 2014

By Leonard Obert

[Tng occasional. rock noises in a nice caured by brc,*ing and ripping of the back, settling, and other cailscr, are well-known tc~ a11 mining en- gineers. These noises oftcn prececte certnin tpes of rock failure as such are used to e certain event a; w:,rnlngs. Senides t5ese audible rock noisee t'nere are, l?o\;evpr, even Iprger nw.iber of' s;Lba.J^;li5le rock mis~s, which must; be piclcell UT with sole type of vi-urr,tion rnicroyhoce and qli- fied in order tnnt :hey n;ny e heard. It v:zs s~v;,yestec" Ir, an evlier ? ,I a.ldible noises Ifureau of I.lines s~zb:ic;et.iod that n stud:r of t!ler;c! *- t mig!!t be useful ir. de temining roc^ movemrnt 3 preceding failure.]

Jan 1, 1941

By F. L. Wideman

This paper is one of a series on mining methods being published by the Bureau of Mines. It describes briefly mining practices at the Sunrise iron mine of the Colorado Fuel & Iron Corp., Platte County, Wyo. The Sunrise mine is in the Hartville iron district in east-central Wyoming (fig. 1). The district covers part of the Hartville Mountains, a region of moderate relief in which erosional features have been formed by the dissection of a low plateau. Altitudes vary from 4,300 feet along the North Platte River to 6,000 feet in the uplift. The climate is semiarid, with hot summers and winter temperatures below zero for short periods. Grasses, cacti, yucca, and low desert shrubs grow at lower elevations. Cottonwood and boxelder trees and willows grow along permanent streams; juniper and coniferous trees are confined to the higher elevations.

Jan 1, 1956

By Floyd Kelley

THE literature of the last decade is rich with information relating to the cause and means of control of grain growth in pure metals, but is deficient concerning the role diffusion plays in grain growth, although during this period many new products that depend on diffusion for their properties and success have been developed. Among these are cementation products, produced by calorizing, chromizing, and carbonizing, or by mixing, pressing, and sintering powdered metals such as Syke's iron-molybdenum die material, Genelite, and Elcon Metal (copper, tungsten) etc. This is a fertile field for new developments, but before it can be util-ized to the fullest extent there must be a thorough investigation of the processes by which diffusion and grain growth take place. Grain growth plays no small part in the process and certainly the physical properties of these products depend largely on the grain size and state of equilibrium produced. The field of investigation does not end here, but may be extended to the effect of diffusion on impurities, segregations and dendrites in the broad field of ferrous and non-ferrous metallurgy. A number of years ago the author investigated several of these cases and noted, with striking regularity, the pronounced effect of diffusion in promoting recrystallization and grain growth. An example of this phenomenon is given in his paper on chromizing1 which contained photomicrographs of large radial or columnar crystals produced by diffusion of chromium in the solid state. Another manifestation of this effect was discussed by Austen,2 who showed the part hydrogen plays in the decarburization of steel and the effect of diffusion upon the grain structure.

Jan 1, 1928

By M. S. Safarzadeh

Over the last fifty years, the treatment of enargite concentrates has not received much attention primarily because of the availability of other clean concentrates suitable for processing with existing smelting and/or leaching technologies. As traditional copper ores have become scarcer, copper-arsenic ore deposits have garnered more interest. Arsenic release is a significant concern during the treatment of enargite by pyro or hydrometallurgical methods. Enargite is also very refractive in standard leaching procedures. Thus, economical treatment options for enargite concentrates are needed. Preliminary experiments have shown that the acid-bake leach process could be adapted and used for the treatment of enargite concentrates. In this study, low-temperature (100-400 ºC) sulfuric acid baking of an enargite concentrate followed by water-leaching has been evaluated. The results indicate the thermal transformation of enargite to copper sulfate during sulfuric acid baking, with most of the arsenic being released from the concentrate into the gas phase for baking at 400 ºC. The condition for maximum copper extraction (~100%) from the concentrate was found to be 400 ºC, sulfuric acid amount of 0.5 mL/g of concentrate, and 2 h baking time. Part of the arsenic was captured in the form of arsenopyrite (FeAsS). XRD analysis proved the presence of some arsenic in the form of claudetite (As2O3) in the baked concentrate. Acid baking of pure enargite behaved in similar fashion.

Jan 1, 2012

By George J. Karcas, Raimo Kuusisto, Pertti Pekkala

Ongoing Outokumpu development in Solvent Extraction and Electrowinning Technology, involving all aspects of process chemistry, equipment and control, extends over a period of close to 30 years. The development in SX started with molybdenum and rhenium, continued with zinc, manganese, cobalt and nickel and is now focusing on copper. The OutoCompact VSF? SX concept, which has been recently introduced, is a honed version of earlier VSF? technology. The Outokumpu VSF? ("Vertical Smooth Flow") SX package includes the DOP ("Dispersion Overflow Pump") units, the Spirok Mixers, the OutoCompact Settlers including their DDG ("Dispersion Depletor Gate") fences and tank farm equipment such as the LOS ("Loaded Organic Scrubbing") tank as well as the CEP ("Copper Electrolyte Purifying") tank. Although the VSF? SX package can be implemented according to several optional lay-outs, the so-called Track version has lately been introduced to the advantage of new plants. The new OutoCompact SX technology decreases the footprint of future VSF? plants. The lay-out, including plant size flexibility, have further been improved by Outokumpu?s new OutoReverse settler technology. Two of several SX plants currently under construction rely on reverse settlers in order to maximize their performance. The Outokumpu EW technology includes process know-how as well as proprietary equipment. The copper EW package consists of permanent stainless steel cathodes based on wax-less technology and lead anodes utilising polymer concrete cells with the double contact bus bar system and ventilation hoods fitted for efficient mist control. The lifting of cell hoods, as well as cathode washing, is done by the cathode pulling crane. Proper electrolyte flows and matching current density further ensure high productivity of LME grade copper cathodes.

Jan 1, 2005

By Richard Snyder

Secretariat of the Coal Mining and Mining Executive Committees' of the National Safety Council (NSC) and Manager of the memberships to both Mining Sections; Senior Consulting Safety Engineer, NSC; member of several committees for consensus Standards of the American National Standards Institute (ANSI); a Certified Safety Professional (CSP) of the Board of Certified Safety Professionals of the Americas, Inc. and a chief proctor for CSP testing and certification procedures, et al. It appears that the tunneling trade is merging into its own renaissance for the decade of the 1970s', and most likely on past the year 2001. Federal interest in underground excavation, and more specifically, rapid excavation expertise has been on the upswing since the latter part of the 1960's, mainly due to the pressing national needs for more raw materials based on the rise for material goods and the projective gloom of possible power shortages. On the pure tunneling side the national needs encompass, in the mainstream of priorities, rapid transportation and water supply excavation as the two top contenders. For instance, the estimates for tunnel mileage for the period 1968-1975 are:(1) Subways---85 miles Urban Highways--- 123 miles Intercity Highways---210 miles Water Supply Routes---528 miles at a total of 946 miles of tunnels. The estimated cumulative underground excavation demand in dollar amounts for the period 1970-1989 are:(1) Construction Oriented Demand--- $35 billions Mining Oriented Demand---$34 billions (which includes the coal-oriented demand on the order of 26 billions.

Jan 1, 1997

By J. D. Nye, I. A. Farr, W. J. D. Stone

"A unique deposit of barite exists near Brookfield, Nova Scotia. The crystals are extremely fine and the whole deposit virtually free of heavy metals. The deposit size was not large enough for conventional uses, such as the production of barium carbonate and drilling mud. In an effort to obtain maximum utilization, a program was begun to determine if U.S.P.-grade pharmaceutical barium sulphate for X-ray diagnosis could be produced. Early work was sufficiently encouraging to institute a development program under the federal Program for Advancement of Industrial Technology. This has been very successfully completed. Canadian and U.S. process patents have been issued, clinical trials have been successful, a production plant has been designed and the plant’s production sold. The processing plant will include magnetic separation for the removal of iron minerals, fine grinding by paddle milling to minus one micron and acid leaching. The process is unique in that at no time is the barium taken into solution.Information is given on the deposit, process, markets, use, plant capital and operating costs, and projected profits. The initial production plant will have an annual capacity of 2,000 tons per year of end product. Capital cost is $850,000 and annual turnover more than $1.5 million. As this capacity only represents approximately 15% of the North American market, rapid plant expansion is foreseen."

Jan 1, 1980

By R. D. Auten

This paper is primarily a report on the process of using oolitic aragonite, as received from Marconi& Ocean Industries, Ltd. without further processing, for a major portion of the raw feed to a rotary kiln producing cement clinker. Oolitic aragonite is a high purity calcium carbonate material, dust free, with the appearance of a course, white sand. It is farmed when under the right conditions of temperature ocean currents, and ocean floor topography. The calcium carbonate will precipitate into small spherical particles on the ocean floor. These oceanic conditions are correct to cause precipitation of the calcium carbonate near Ocean Cay in the Bahama Island chain. The present growing deposit near Ocean Cay is in the billions of tons and is mined by a relatively shallow-operation hydraulic dredge. The aragonite thus formed is en orthorhombic crystaline form of calcium carbonate with a specific gravity of approximately 2.9. At a temperature of 505°C. (940F), the aragonite converts to the hexagonal crystal of calcite with a specific gravity of 2.6 to 2.7. This change in specific gravity weakens the structure of the particles but the individual pieces are still fairly hard. When the material is then calcined at 900°C (1650°F), the particles retain their shape but become soft and will break up under finger pressure.

Jan 1, 1978

By C. A. Young, J. D. Miller

The surface chemistry of the calcite/oleate flotation system was examined by in-situ FT-NIR/IRS. Spectra of combination and overtone bands of aliphatic stretching vibrations revealed gauche/trans conformational changes that occurred solely as a function of temperature. The conformational changes were attributed to the simple "melting" behavior associated with phase transitions. It was concluded that chemisorbed oleate at calcite surfaces is gel-like at temperatures below 22oC, resembles a coagel between 22oC and 31oC, and becomes micelle-like at temperatures above 31oC. By comparison, chemisorbed oleate at fluorite surfaces also undergoes these phase transitions but is additionally dependent on adsorption density. The conformational changes were observed at high chemisorption densities (> 2.0x10-10 mol/cm2) and attributed to molecular forces, primarily van der Waal's interactive forces, among neighboring chemisorbed oleate molecules. Similar analysis of in-situ FT-NIR/IRS spectra of surface-precipitated calcium dioleate at calcite surfaces did not exhibit this behavior thereby confirming that surface-precipitated calcium dioleate remains in an all-trans conformation. The results help explain why surface polymerization is not observed at calcite surfaces but is observed at fluorite surfaces.

Jan 1, 2002

By J Kelly, C Kelsey

The Autogenous Kelsey Axial Displacement (KAD) mill is essentially a short retention time centrifugal mill, designed to effectively harness extraordinarily high concentrations of input energy for efficient particle size reduction. The mill which has an operating duty band extending from primary to ultra-fine also has the unique capacity to generate fine and ultra-fine products from single stage size reductions of either coarse or fine mineral feeds, in both wet or dry operating modes. This paper covers developments following a recent optimisation programme which confirmed that mill shell speed and the velocity differential between the shell and the rotating internal disc assembly tips could be optimised in relation to specific energy for a given feed rate and feed size providing the product size remains constant. Subsequent test-work further demonstrated the versatility of the mill with duties ranging from the removal of surface contamination associated with heavy mineral concentrate particles to the production of premium ultra-fine talc, from a single stage of size reduction. Open circuit grinding of a rougher gravity concentrate to liberate gold ahead of leaching also highlighted the scope for the application of low cost KAD milling for a range of hydrometallurgical feed preparation duties, which involve fine and ultra-fine grinding.CITATION:Kelly, J and Kelsey, C, 2013. Advanced media-free fine and ultra-fine grinding - The Kelsey axial displacement mill, in Proceedings MetPlant 2013 , pp 152-161 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013