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By Harry R. Nicholls

As part of the pre- and post - shot mine examination at Project GNOME , acceleration data were recorded underground from a series of chemical explosive shots . The cube root of the charge weight was used to scale acceleration and distance because charge weight was not constant . Regression analysis of particle acceleration - distance data gave the following propagation equation : A W1 /3 = 5.10 x 105 ( R / W¹ / 3 ) −2 .43 The quantity A W1 /3 is scaled particle acceleration expressed in g's - lbs¹ / 3 , and R/W1 /3 is scaled distance expressed in ft / lbs¹ /3 Data obtained from the nuclear explosion were scaled and fall within one standard deviation of the calculated propagation law for the smaller shots . Cube root scaling laws were adequate to group acceleration data from explosive charges varying by a factor of more than 1 x 10 in charge weight and over shot - to - gage distances varying from 100 to 46,000 feet . Data obtained from a series of small tests provided sufficient data from which reliable predictions of acceleration could be made for the large nuclear explosion .

Jan 1, 1964

By Manlapig E. V

ABSTRACT- I Results are given for a series of tests in which a 300 mm pilot-scale Jameson cell has been used in copper recleaner flotation, and for the flotation of a lead rougher feed. the results indicate that the production rate of solids, at the same superficial air velocity Jg, is higher than in conventional columns. Thus in the copper recleaner application, the pulling rate reached 14 gm/cm2/min compared with between two and three for an operating column, while in the lead cleaner application the comparable figures were 12 - 14 gm/cm2/min for the Jameson cell vs 8 - 9 gm/cm2/min for a test column. A froth crowder was used to increase the air superficial velocity Jg in the Jameson cell in the copper recleaner, while holding the collection mechanism and pulp feed rates constant. The recovery increased from 50 per cent to over 90 per cent, suggesting that recovery is controlled mainly by the froth conditions, rather than the particle-bubble interactions in the Downcomer.

Jan 1, 1991

By Dinuzzo P, Wychie J, Desoe C

The Selwyn Gold-Copper Mine is located 150 km southeast of Mount Isa within Proterozoic units of the Mount Isa inlier (Figure 1). Mineralization in the mine area is associated with strongly sheared ironstones and iron rich schists at the base of the mid- Proterozoic Staveley Formation. The ironstone horizons outcrop as a series of dominant ridges over a 10 km strike. Economic gold-copper mineralization has been defined in 4 separate zones within a 3.5 km length of the outcropping ridges. A current combined geological resource for the deposits is 5.3 million tonnes of 5.0 g/t Au and 2.02 Cu. Weathering of the deposits has resulted in a pronounced vertical zonation of mineralogy, especially copper, within the ore zones. This has produced 3 separate ore types which require different treatment techniques. The categorization is based on copper content and zones are termed leached (surface), oxide and sulfide. Ore removed from the pits will be mainly leached and oxidized with minor sulfide near the pits final depths, while the underground ore will be from the sulfide zone with minor oxide in some areas.

Jan 1, 1989

By Masatsugu Morimitsu, Tian Zhang

"This paper presents a novel anode for oxygen evolution in acidic aqueous solutions to produce non-ferrous metals by electrowinning. The method to prepare the anode was thermal decomposition of a precursor solution, and the obtained anode consisted of Ru02-based oxide catalytic layers formed on a titanium substrate, in which the catalytic layer contains nano-oxide particles as the active component. The oxygen evolution potential was lower than amorphous lr02-Ta20s coated titanium anodes so that the cell voltage of electrowinning was further reduced with the amorphous Ru02-based electrode.IntroductionElectrowinning (EW) is used to produce high purity of non-ferrous metals, and the primary metal production of copper, zinc, nickel, and cobalt by EW consumes huge electric energy worldwide, which tends to increase with increasing demand of such metals. The reduction of electric energy consumption is a significant issue for electrowinning industry, which means that the cell voltage reduction is needed to realize more energy-efficient EW processes. Another issue is also indicated from environmental perspectives; i.e., an improvement in EW plant environment by eliminating hazardous byproducts and wastes. Such byproducts and wastes include lead oxide, manganese oxide, and acid mist.We have been developing the anodes for energy-efficient and environmentally friendly electrowinning processes [ 1-11]. The development has been successfully done with the invention of the smart anode, MSA TM (Morimitsu Smart Anode) [ 1-5], which has low polarization for the main reaction and high polarization for the side reaction, in which the main reaction is oxygen or chlorine evolution, while the side reaction is the anodic deposition of each or both of lead oxide, manganese oxide, and cobalt oxide. The anode consists of a valve metal substrate coated with amorphous or less crystalline oxide catalytic layers. One of the typical examples of such oxides is amorphous lr02-Ta20s, and the substrate is normally titanium plate or mesh. The most important point of the oxide is that the amorphization or less crystallinity induce the increase in the active surface area only to the main reaction, not to the side reaction, thereby the polarization of the main reaction being reduced.In this paper, we present the smart anode consisting of RuO2-based catalyst formed on titanium substrates for oxygen evolution in electrowinning. The preparation, characterization, and polarization behaviors of the anodes are shown, and the cell voltage data for zinc or copper electrowinning using the anodes are also presented."

Jan 1, 2012

By Zoran M. Stevic, Mirjana M. Rajcic-Vujasinovic, Zvonimir D. Stankovic

"Covellite is one of the most important copper sulfide minerals. Its behavior during the anodic polarization, as well as its rest potential in various solutions are of importance for flotation processes and also define the mechanism of electrochemical extraction of copper from sulfide minerals.Measurements of the rest potential have been performed in water solutions in presence of different cations and anions. The existence of the Nernst type dependence of the rest potential on the activity of some of the investigated ions was established. The biggest influence on the rest potential of covellite exhibits the change of activities of the ions forming the crystal lattice of investigated mineral, i.e. Cu(II) and S(II). The dependence of the rest potential of covellite on logarithm of Cu(II) activity has a shape of a strait line with a positive slope of 60 mV, while when concentration of S(II) anions increases ten times, the rest potential of covellite decreases about 120 mV. The first dependence was established in acid medium, while the second was registered in alkali one.Different electrochemical techniques have been used for the investigation of the behavior of covellite during anodic polarization. In the basis of all these measurements is a three electrode system consisted of: 1) working electrode made of the sample of natural covellite from the Bor mine (Eastern Serbia, Yugoslavia); 2) reference electrode (saturated calomel electrode) and 3) counter electrode (flat platinum). Electrolyte solutions used in these investigations are of the same kind as those used in the rest potential measurements. Sulfate and chloride solutions, as well as the mixed sulfate/chloride solutions, are the most perspective from the application point of view.Cyclic voltammetry has been the first used method that confirmed the formation of passive layer on the electrode surface during anodic polarization. Elementary data about the reaction mechanism have been obtained too. More detailed data needed for more precise conclusions about the mechanism and rate of the anodic process on covellite have been obtained by galvanostatic method. It was established that the essential difference exists between the reaction mechanism in sulfate and chloride solutions. Also, the difference is exhibited in the nature of reaction product directly connected with the passivation of the electrode surface. Chronopotentiometric investigations have been performed in sulfate, nitrate, chloride perchlorate and mixed sulfate/chloride solutions applying different current densities. The shape of obtained curves indicate if there was a surface passivation and how intensive it was."

Jan 1, 2003

By B Belle

Dust sampling is pivotal in estimating the ‘dose’ of dust exposure and in deriving dose-response curves in epidemiological studies. Over the last half century, gravimetric sampling has been the fundamental means for dust exposure monitoring using recognised respirable size-selective standards. In Australia, a gravimetric sampling technique has been followed since 1983 using the Higgins-Dewell (HD) type cyclones (AS2985). The re-emergence of ‘Black Lung’ or Coal Workers Pneumoconiosis (CWP) in Queensland, Australia has re-kindled the need for better understanding of personal dust monitoring, compliance determination, accuracy, timeliness of sampling results and dust control systems. Reporting dust levels in real time empowers miners and operators to take immediate action to avoid being exposed to excessive airborne dust. Two decades of intensive research in the USA has led to the introduction of gravimetric based continuous personal dust monitors (CPDMs) called PDM3700 as compliance tools. The new real-time mass based sensor is a continuous mass based dust monitor using the Tapered Element Oscillating Microbalance (TEOM) principle and is regarded as significantly superior to the current gravimetric sampling methodology.Recently the overall respirable dust standard in USA coalmines has been reduced from the historic 2.0 to 1.5 mg/m3. This paper provides the results of a comparative pairwise study of an existing gravimetric sampler and the PDM3700 carried out in 3 different Australian underground mines. The field results consistently suggest that there is a significant ‘measurement bias’ between the current gravimetric HD sampler and the PDM3700 monitor operated using a similar HD type cyclone. The results show that the currently used cyclone measurements are approximately 59 per cent higher than the ‘auditable’ PDM3700 monitor data at the current compliance limit of 3 mg/m3. Based on a review of the extensive data collected, the differences can in part be attributed to the aerosol size selectivity of the samplers with the current gravimetric sampler used in mines, collecting more larger sized particles (D90 of 15 µm). This finding has significant consequences for historic exposure results and their use in medical surveillance programs, as well as the current approach to non-compliance determination.CITATION:Belle, B, 2017. Pairwise evaluation of PDM3700 and traditional gravimetric sampler for personal dust exposure assessment, in Proceedings Australian Mine Vent Conference 2017, pp 87–92 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By M. J. Spendlove, P. P. Zapponi

"INTRODUCTION In carbothermic processes for the production of magnesium, magnesium oxide is reduced by carbon according to the following equation:(1) MgO + C = Mg(g) + CO.The reaction is virtually complete at temperatures above 2,000° C. but reverses rapidly at somewhat lower temperatures. To produce magnesium by this reaction, therefore, it is necessary to cool the gas very rapidly to a temperature at which the rate of the reverse reaction becomes negligible. Several media for quenching the gas have been proposed, among which are hydrogen, natural gas, liquid hydrocarbons, and molten metals of low melting point.The results of a preliminary investigation on the use of molten lead as the quenching medium are summarized in this report. The work was done in 1941, when the threat of war made it imperative to investigate every process that offered possibilities for rapid expansion of domestic production of magnesium. Although the results were encouraging, other processes appeared to offer better prospects for immediate wartime development, so the work was not continued. Shortly before the investigation was completed, several patents on the use of low-melting metals for absorption of magnesium vapors appeared, 4/"

Jun 1, 1947

By Chang Wei, Fan Zhang, Zhigan Deng, Minting Li, Cunxiong Li, Gang Fan, Xingbin Li

Marmatite is an important resource of zinc, which exist in forms of high iron and high indium. In order to recycle the valuable metal from these ores, the testwork of simultaneous leaching on neutral residue mixed with zinc concentrate of high iron and high indium has been conducted. The primary objectives are to leach the zinc and indium remaining in the neutral leach residue as ferrite using acid, and to reduce the ferric iron in solution to the ferrous by zinc concentrate, thereby extracting the zinc and indium in the zinc concentrate. The results indicated that in the following conditions, mass ratio of neutral residue to zinc concentrate of 1:0.25, particle size of 74-58 μm, initial sulfuric acid concentration of 150 g/L, liquid to solid ratio of 8 L/kg, temperature of 90°C, reaction time of 4h, the leaching efficiency of zinc and indium were over 95%, nearly 90% Fe was Ferrous in the leaching solution. This process effectively extracted zinc and indium and converted Fe3+ into Fe2+ in solution, and simplified the traditional process of reduction after leaching.

Jan 1, 2016

By C. W. Whitten

Solis from an abandoned Pb battery processing facility were characterized prior to the selection of the extraction technique. Reflected light microscopy and electron beam methods were used to locate Pb-bearing phases and to quantify the compositions of the phases. It was found that the soils are composed primarily of quartz and feldspars with minor amounts of iron and titanium oxides. Lead is primarily present as an oxide or sulfate that is associated with the silicate minerals. Specific phases identified were PbO; Pb02; cerrusite, PbCO3; angleslte, PbSO4; galena, PbS; and magnetoplumbite, 2PbO3Fe2O3; or plumboferrite PbO2Fe2O3?

Jan 1, 1989

By Raymond A. Bradbury

The first diesel-powered Scooptram has now been in service for 21/2 yr at the I-C mine of Martin County Coal Corp. It has become the workhorse of the operation, being used around the clock many days. The fleet of nine 20-ton capacity Teletrams used behind three Jeffrey Heliminers now have more than 1 1/2-yr experience in the Coalburg mine. They have been exposed to some difficult conditions which, include steep grades, water, mud, and rutted roadways. These units have proven to he both rugged and powerful. The safety components and shutdown systems make these haulage units very safe for underground coal mines. A clean-burning engine, a satisfactory exhaust conditioning system, and good ventilation are the keys to maintaining a safe and healthful atmosphere for the underground operators and other employees.

Jan 1, 1976

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by the Bureau of Mines at its bauxite project in saline and Pulaski Counties, Ark., has been given in Report of Investigations 4251. The factual data obtained during the project are reported in a series of Reports of Investigation beginning with No. 4251, of which this is the eleventh. The-data are accompanied by maps showing the location of holes drilled and the deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township map. The description of each halt township is followed by a description of each deposit developed in that halt township. The 14 halt-township maps and 77 detail maps of the bauxite deposits in this series at reports give the locations and numbers of all the holes drilled on the project, except the deep holes drilled to test the geophysical anomalies. The locations of those holes show on figure 13 in volume 1. The descriptions of the deposits developed are followed by complete detailed logs of the drill holes. Many of the widely spaced exploratory holes did not discover bauxite of minable thickness and grade. The pertinent information obtained tram the widely spaced exploratory drill holes has been summarized and tabulated, and a table for each halt township is given with the discussion of that area.

Jan 1, 1948

By Howard A. Meyerhoff

IN western Argentina, in the Province of Mendoza and the Territory of Neuquén, there is a series of solid bitumen deposits which are claimed to be the most extensive in the world. In a linear belt 500 km (311 miles) long, roughly paralleling the axis of the Andes but occupying a variety of positions with respect to the orogenic structures, more than 100 outcrops have been reported. Approximately 70 of these have been prospected, and some mining has been planned or attempted for about half this number. Limited tonnage, high sulphur content, inaccessibility, labor shortages, and disastrous fires have taken a heavy toll among these operations, and in 1947, only 4 deposits were being actively mined, but 8 more were being explored and developed with a view to placing them in production. Inasmuch as these deposits are currently yielding a substantial fraction of Argentina's limited domestic supply of solid fuels, a brief account of the deposits and of the small industry based upon them will provide a commentary on Argentina's fuel problem. CHARACTER OF SOLID BITUMENS The solid bitumens of Mendoza and Neuquén are petroleum derivatives, as is indicated by the following ultimate analysis: [CONSTITUENTS PER CENT Hydrogen6.8 Carbon82.4 Nit.rogenI.6 Oxygen2.7 Sulphur2.2 Ash4.3 100.0] In physical appearance they bear a close resemblance to coal and are commonly called carbón. Their specific gravity has an extreme range of 1.10 to 1.777 in 36 samples weighed, but the average is between 1.14 and 1.24. The material is black, lustrous to dull, with blocky to sub-conchoidal fracture. Though brittle, the purest material is softer than anthracite and exhibits slightly more cohesion. This bituminous material is generally known as asfaltita or asphaltite, but definitive chemical studies indicate that the term asphaltite or grahamite can be applied correctly only to the exceptionally pure material of the Auca Mahuida district in Neuquén. Some other name should be used for the chemically variable bitumens found in all other districts, and the designation "asphaltitic pyrobitumen" has been proposed by Carlos A. S. Piscione.1 At the present time these bitumens, are finding favor as solid fuel and as a gas-producing medium. They yield heat values of 8650 to 9750 cal,2 or 14,500 to 16,750 Btu per pound, and in consequence of their excellent heating qualities and the scarcity of imported coal, they are marketed as far away as Buenos Aires at a price of go to 95 pesos, or approximately $22 to 23, per metric ton. In burning, the material swells and decomposes into solid, fluid, and gaseous fractions which burn violently though nonexplosively. Its combustibility has been responsible for disasters and virtually complete destruction at Mina La Esperanza and Mina Santa Marta, and for minor mishaps elsewhere, as at Mina Escondida in August 1947.

Jan 1, 1947

By J. A. Sweet, T. BACHMANN, G. E. Sandoval, T. M. Hauyon, F. A. Contreras

In many respects a porphyry copper ore concentrator plant can be considered as a simple system. Chalcopyrite typically liberates well at relatively coarse sizes, and even low grade ores are amenable to upgrading 20 to 30 times to produce concentrate grades in excess of 25 % in very simple Rougher- Regrind-Cleaner+Scavenger flotation circuits. The flotation response of chalcopyrite has been well characterised in many fundamental and applied research studies and the conditions necessary to depress pyrite and other floating gangue species are well understood. But what happens to the particle surfaces when you have a 50 km pipeline between the grinding circuit and the flotation plant? How does the seasonal variation in water quality affect your ability to control pulp chemistry? What impact does the relative concentration of the different sulphide species have on their separability? Why do two plants that receive nominally the same ore produce consistently different results? And most importantly, what do you need to do to improve the performance of both plants? To answer these and other questions, a focussed sampling and analysis programme was carried out at the Las Tórtolas flotation plants in 2018 and 2019. The work included full down-the-bank sampling, hot floats, the use of radioactive tracers for determining residence time distribution profiles, gas dispersion measurements, detailed mineralogy by size across the circuits and multiple regrind surveys. This comprehensive study was augmented by analysis of historical mineralogy, geometallurgy and operating data using modern data science techniques, and has provided the foundation for current and future optimisation initiatives. Some of the findings and their implementation will be presented in this paper. Keywords: Circuit optimization, Residence time, Gas dispersion, Pulp chemistry

Jan 1, 2020

By B E. Hall, J Poniewierski, A J. Hills

Following a review of life-of-asset work at MMG’s Rosebery mine in which a proposal to increase production from 0.8 Mt/a to 1.2 Mt/a was mooted, questions were raised as to the seemingly arbitrary reasoning for the production increase. They included: Did the proposal actually add value? Was the production rate from the mine sustainable? Was it the best identifiable value-adding configuration?A multiple scenario analysis study commenced to model how various cut-off grade values against mill throughput, along with associated capital expenditure, would impact on the potential value of the operation. This was carried out utilising the ‘hill of value’ approach promoted by AMC Consultants.The traditional approach to these studies uses a constant cut-off value (NSR – net smelter return) for the whole mine analysis. This was thought to potentially introduce a large amount of variability to the model as different ore types were thought to have different processing costs and different underground lenses were thought to have different mining costs. With the aim of developing a consistent value measure that would be comparable between the lenses, an alternative measure was suggested for all ore block values in this model, irrespective of lens location.The new measure used was a mine variable value (MVV). This allowed for the variable factors of final metal concentrate production to be removed from the ore value. From a mining point this was the haulage distance from ore source to run-of-mine (ROM). For the mill it was the amount of reagents required, varying based on grade together with the amount of power required for crushing, grinding and tailings handling.From the initial run of the model, preliminary results lead to a conclusion of increased value being gained by either increasing cut-off grade or increased mill throughput rate. The validity of the result was tested using alternative price scenarios, which although changed the absolute value achieved did not significantly change the identified value-adding strategies. The realisation of these value increases identified are however contingent on higher sustainable development rates being able to be achieved mine-wide, higher backfilling rates being able to be achieved and overcoming recognised ventilation constraints. Further detailed studies are being put in place to identify the practicality of overcoming these recognised constraints and achieving the higher-value strategies identified.The ongoing objective of the hill of value model built is to keep the model alive as a life-of-asset planning tool and to continue refining the foundation data, such that various mining strategies can be analysed with increased confidence.CITATION:Hills, A J, Hall, B E and Poniewierski, J, 2014. Mining scenario analysis and mine variable value, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 111–118 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By W. A. Krivsky, R. Schuhmann

Jan 1, 1962

By Hongchun Lou, Yan Zhang, Xianjun Lu

"The potential of Fe(NO3)3 modified attapulgite was assessed for the adsorption of phosphorous removal from aqueous solutions. Natural attapulgite was modified by Fe(NO3)3, and thus the composite adsorption materials could be obtained. Also phosphorous adsorption characterization on the iron-coated attapulgite was investigated in this research. Taken overall the results suggested that phosphorous adsorption capacity could be improved markedly by adopting ferric modified-attapulgite. The optimum phosphorous adsorption were developed in the experimental conditions of the solid-to-liquid Ratio 1g/L, the initial phosphorous concentration 5 mol•L-1, reaction time 120 min, temperature 25 ? and pH=4.0, the removal efficiency is 92.28% for the modified attapulgite. In comparison of batch experimental results of phosphorous adsorption onto natural and iron-coated attapulgite, it has provided much more likely the same change trend. On the other hand, the outcomes of this analysis indicated that ferric modified adsorbent was notably influenced by adsorption element over natural attapulgite. The Freundlich isotherm adequately described the adsorption course of phosphorous onto ferric modified-attapulgite with the correlation coefficient R2 goodness of fit of 0.9690."

Jan 1, 2014

Tectonic subsidence plots have been calculated for well, extrapolated-well and significant off-well (seismically-based) locations in the Vulcan Sub-basin and adjacent highs (western Timor Sea). The subsidence curves have been normalized to a common datum, the distinctive "near top Permian" marker, and corrected for sediment compaction, palaeobathymetry, eustatic sea-level change and loading effects.Four principal phases of post-Permian basin development are recognised and quantitatively described by integrating the results of the sub-sidence analysis into the regional (e.g. recent Ocean Drilling Program-derived) framework of the tectonic evolution of the North West Shelf. They are1. the Triassic-mid Jurassic Westralian Superbasin intracratonic phase,2. the late Jurassic-early Cretaceous North West Shelf rift phase,3. the mid Cretaceous-Palaeogene North West Shelf subsidence phase, and4. the Neogene-present Timor collision phase. Rapid Triassic tectonic subsidence occurred in an intracratonic setting, possibly subsequent to aborted late Palaeozoic rifting. Intracratonic sub-sidence mechanisms such as deep crustal metamorphism and/or intrustion and regional tectonic compression are invoked in addition to any post-rift thermal subsidence which may have occurred.

Jan 1, 1990

By Arnulf Muan, Egil Aukrust

Activities of COO in the three solid solution series COO-MgO, COO-MnO, and COO-"FeO" have been determined at 1200°C by equilibrating oxide samples with a metal phase (cobalt or a Co-Fe alloy) in atmospheres of known oxygen activities. The systems COO-MgO and COO-MnO are ideal, within limits of experimental error, whereas the system COO-"FeO" shows a slight positive deviation from ideality at the temperature of this investigation. KNOWLEDGE of activities of oxide components in solid solutions is necessary for the calculation of the cation distribution among coexisting oxide phases in many important metallurgical, ceramic, and geochemical systems. Very few activity-composition curves are available for such systems at the present time. A start on the prodigious job of obtaining such data has been made by studies of solid solutions with simple sodium chloride type structure containing NiO or "FeO" as a component.1-3 The present paper describes similar studies for solid solutions with sodium chloride type structure containing COO as a component. For the systems COO-MgO and COO-MnO, the activity solid solution is determined by the equation Here po and are the oxygen activities of the gas phase in equilibrium with the phase assemblages metallic cobalt plus oxide solid solution, and metallic cobalt plus pure COO, respectively. In the system CoO-"Fe07', the metal phase is a Co-Fe alloy rather than pure cobalt. In this case the activity of COO in the oxide solid solution is calculated from the equation where a& is the activity of cobalt in the metal phase. Because the system Co-Fe is close to ideal4 and the metal phase appearing in the present work contains less iron than cobalt even at the lowest COO concentrations of the oxide phases used may be set equal to N . Hence, Eq. [2] becomes The value of Nc, can be estimated from the relative stabilities of the oxides COO (see below) and I) EXPERIMENTAL METHOD Two different but closely related procedures were used in the present investigation to determine the activity-composition curves. In one method, the oxide solid solutions were equilibrated against

Jan 1, 1963

By P D. "Takis" Katsabanis

The phenomenon of sympathetic detonations in blastholes is investigated by comparing experimental observations and numerical modelling results. Numerical modelling using the TDL computer code and Forest Fire decomposition rates for commercial explosives has shown the importance of blasthole diameter, impedance of the stemming and host rock. Comparison with experimental observations has also shown that sympathetic detonations cannot always be treated as shock to detonation transition. Examination of previous results which have been obtained from calibrated low amplitude shock experiments reveal that there is an ignition threshold prior to the detonation threshold. The difference between the two thresholds is more pronounced in the case of air bubble sensitized products. The ignition threshold can be very important under the confinement provided by the blasthole and the conditions of application. It also correlates well with the pressures expected at the gap distances of interest in the practical application. It is suggested that critical energies are used as the criterion for cross initiation in blastholes. Practical suggestions based on the numerical calculations and experiments based on these calculations are also given and discussed.

Jan 1, 1991

By S H. Li, H Z. Gu, A Huang

High aluminium steel is a promising advanced steel known for its exception properties and holds significant economic and strategic importance. However, the CaO-Al2O3-SiO2 based slag with high alumina content reacts vigorously with alumina refractories during the smelting process at high temperature, seriously affecting the safe and efficient production of furnaces and resulting in the formation of Al2O3-MgO non-metallic inclusions within the molten steel. This is a bottleneck problem for high-quality steel refining, and the key reaction path during the corrosion remains unclear. The dissolution reaction mechanism of alumina refractories in high alumina CaO-Al2O3-SiO2 slags under a weak static magnetic field was investigated in this work, using high temperature laser confocal microscopy and in situ radiation spectroscopy techniques. The results indicate that the interaction between the high alumina slags and the alumina refractories is governed by free radical reactions. The dissolution of alumina forms AlO and AlO2 radicals. The reaction rate increases with the C/S ratio of the slag due to its low polymerisation. The reaction between non-bridging oxygen and AlO2 free radicals accelerates the generation of AlO and O2ꞏ- radicals. The reaction layer composed of calcium aluminate is formed through the recombination of AlO, Caꞏ+ and O2ꞏ- radicals. The weak static magnetic field induces the Zeeman splitting of free radical pairs and intersystem crossing occurs, promoting the formation of triplet free radical pairs through the hyper-fine coupling effect. The reaction can be significantly inhibited as the triplet free radical pair does not meet Pauli’s incompatibility principle. This discovery perfects the structure theory of molten slags with radicals and provides supplement to the design of the highly slag-resistant refractories, and provides the theoretical basis for the development of external field protection technologies for high-quality steel refining.

Jun 19, 2024