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By Roger J. Araujo

A photochromic material is one which undergoes a change of color when exposed to light and reverts to its original color when the light is removed. Review articles carrying extensive bibliographies have been written by Brown and Shaw (1) and by Schwab and Bertelson (2). Organics. Schwab and Bertelson divide the reactions in different organic photochromic materials into some half-dozen categories; Windsor (3) reduces these to the following three main classes of general interest, based on how they work. 1. Stereoisomers. Absorption of light breaks one of the chemical bonds in a. ring molecule, thus allowing the molecule to unwind and form a different geometrical arrangement. The reverse process is a reforming of the bond. Examples of this class are the spiropyrans and the anils. 2. Dyes. A triphenyl methane dye, for example, is oxidized by energetic light; the absorption characteristics of the positive ion so formed are different from those of the original electrically neutral benzene rings. 3. Triplet States. In the class of polynuclear aromatic hydrocarbons, ground-state molecules are excited first to a singlet state by irradiation, and then go, via the lowest triplet state, to an excited triplet state. Visible light is absorbed in the triplet-triplet transition.

Jan 1, 1970

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

Recycling has become an important part of the lithium-ion battery (LIB) life cycle due to the growing demand for energy storage in applications like electric vehicles and renewable energy. Recycling spent LIBs provides a secondary source for strategically scarce metals, like lithium and cobalt, helping to reduce the environmental impact of LIBs. Organic acids have been proven to be effective lixiviants with the benefit of reduced environmental impacts, amongst which citric acid has shown to exhibit similar extraction performance when compared to mineral acids. Leaching LCO and NMC batteries with 1.5M citric acid and 2 vol.% H2O2 at 95°C, 20 g/L for 20 minutes achieved 93% Al, 90% Co, 96% Li, 94% Mn and 94% Ni dissolution. The strong chelating property of citric acid affects the separation of the metals, providing unique extraction opportunities. The first extraction uses 12 vol.% D2EHPA at a pH of 2.5 and O/A ratio of 2 to separate 96.4% Mn and 100% Al from the PLS in two counter-current stages. Stripping the loaded organic with 1.25M citric acid at an A/O ratio of 3 allows for up to 91% stripping of the manganese in a single stage. The second extraction then separates 96.5% Li from the PLS in three counter-current stages using 20 vol.% D2EHPA at a pH 5.5 and O/A ratio of 5. The raffinate remaining after the second separation contains 48.4 wt.% Co and 50.3 wt.% Ni. Keywords: Hydrometallurgy, lithium-ion batteries, metal recycling, citric acid, solvent extraction

Jan 1, 2020

By L. A. Readdy

Pilot Hole "X" was drilled to test the formations through which the ventilation shaft for the proposed U.S.B.M. demonstration oil shale mine will be drilled. The history of the drilling of Pilot Hole "XI' is presented. This historical summary provides the details of method used during the drilling of this hole. Problems encountered during drilling are discussed. The quantities of drilling mud and other materials used to drill the hole are documented.

Jan 1, 1977

By M. P. Ahola

This U.S. Bureau of Mines report presents an overview of the use of three unique numerical modeling methods to analyze cutter roof problems in underground coal mines. Cutter roof failures are common in coal mines where the immediate roof is comprised of thin laminae exposed to highly biaxial tectonic stress fields. The predominant mechanism for failure is assumed to be excessive shear stress at the entry corners exceeding the shear strength of the rock. Early work in this area utilized the finite-element method and then the boundary-element method to analyze several cutter roof control measures. Various stress control measures were simulated to estimate their respective effects on reducing the high levels of shear stress at the entry corners. More recent studies made use of the discrete-element method. This method was used to take the analyses beyond the elastic continuum limits to simulate the propagation of a shear fracture and subsequent redistribution of stress within the mine roof. A simple roof bolt model was implemented to show the benefits of bolting to increase the resistance to shearing and separation along horizontal bedding planes and maintain roof stability.

Jan 1, 1991

By Andrew Fletcher

AS good health is the most important asset in life, the development of healthful conditions should be the one common meeting ground of agreement between management and labor. Health should not be a subject to be pulled apart, shoved around, or bargained about. Differences of opinion may exist in the procedure and techniques employed in approaching the goal of maintaining the health of workmen, and in the method of increasing the ultimate profit of the employer by improved working and living conditions. Such matters are doubtless appropriate subjects for discussions between the interested parties, but techniques are only tools. If an employer fails to remedy a hazard or a menace which contributes to poor working condlions, this constitutes a legitimate grievance. It should not be necessary, however, nor is it desirable that fundamentals of health maintenance become matters of collective bargaining, any more than should the principles of management and engineering. I have been especially concerned during the last few months with the propaganda in collective bargaining negotiations throughout the country for including in union contracts a given number of days of sick leave with pay. We all

Jan 1, 1946

By Edwin R. Phelps

Good morning ladies and gentlemen - today I am in an enviable position for two basic reasons - No. 1, since I am first on the program, the audience should start out awake because those that partied too much last night are still asleep, but in their room, not here. No. 2, since copper, iron, and mining technology are not competitive, the veracity of my statements will not be questioned. Most such meetings I attend are based on the subject of energy and the coal industry does have competition from oil, gas, hydro, and nuclear. However, to counteract this advantage I am the usual engineer with a limited vocabulary by schooling, and the remaining vocabulary almost completely eliminated due to the presence of ladies. In relation to the past of the coal industry, we have not only suffered the competition of other energy sources mentioned before, but in addition have in the last 25 to 30 years been required to meet the demands of a vastly changing market. To explain this statement, I am sure many of you can remember 30 to 40 years back when most homes were heated by coal furnaces or stoves and shudder to recall the shoveling of coal into the fire and the carrying out of ashes with the attendent manual labor dust. Now this space heating portion of our sales has almost become non-existant due to an almost universal switch from coal to natural gas, oil, and electric heating. Actual figures show a decrease from 119 million to less than 28 million tons per year in less than a twenty year span. Also, most of you can remember the coal burning steam locomotives and the tremendous volume of coal they consumed and then the very rapid change to the diesel-electric locomotives, incorporating improved large diesel engines driving D C generators and electric drive motors, which resulted in cheaper motive power. This change over was so complete that the annual tonnage of coal dropped from 125 million to less than 2 million tons in 15 years. 'Actually, now it requires some considerable interrogation and traveling to find a locomotive still operating on steam.

Jan 1, 1968

By Robert L. Marovelli

The major mining health and safety problems of concern to United States Government and private industry researchers in 1981 included the difficulty experienced by longwall operators in complying with the Federal 2 .0-mg/m3 respirable dust standard, the accident rate associated with falls of ground and materials handling hazards, and the upsurge in the incidence of disasters after the steady decline in recent years. Although the many mines and manufacturing companies involved in the research projects to be described are not specifically identified, it is important to note their significant involvement. This is not by way of acknowledgement, but rather to establish that these projects, using mostly Federal funds, represent close cooperation between the U.S. Government and the mining industry. The ongoing work to be described on the development of critical longwall dust control technology is a classic example of Government-industry participation through the phases of problem identification, planning, cost-sharing, and implement at ion.

Jan 1, 1982

By S. Kawatra, K. Lewandowski

Heap leaching efficiency is reduced by poor solution flow characteristics (channeling and ponding), which result from fines migration. Agglomeration of the ore can immobilize fines, but copper leaching requires an acid-resistant binder to stabilize the agglomerates. Until now, there has not been a satisfactory way to evaluate whether a binder was effective, other than squeezing a handful to see if it “feels right”. We have developed procedures to quantitatively determine whether a binder gives good performance in an acidic solution, and have identified several binders that will be suitable for copper heap leaching.

Jan 1, 2007

By W. A. Heitbrink, J. D. Ashley, R. E. Gresh, J. A. Organiscak, A. B. Cecala

Many different types of mobile equipment used in surface coal mining utilize enclosed cabs to protect equipment operators. The overburden removal process is extremely dusty and can cause excessive exposure to respirable dust, especially crystalline silica. After equipment is used for years, many components of the enclosure deteriorate and its effectiveness is greatly reduced. This report discusses a cooperative research study performed on an Ingersoll Rand DM45E surface drill, retrofitted with a new Sigma pressurization and filtration system. Respirable dust concentrations were substantially reduced from 0.64 mg/m3 during pre-testing to 0.05 mg/m3 during post-testing with the new system, representing a 92% reduction in dust levels in the drill cab. This new system appears to be a very well-built and sturdy device, well-suited for the mining industry.

Jan 1, 2002

By Ramon Santos Corrêa

Com a descoberta de poços de petróleo cada vez mais profundos, as tolerâncias das propriedades mecânicas dos tubos de aço utilizados para este fim estão mais restritas. Somando-se a isso, o mercado pressiona por redução de custos e agregação de valor nos produtos ofertados. Por outro lado, a maturidade de interconexão alcançada pelos sistemas industriais, permitiu a disponibilização de dados mais precisos dos processos e a utilização de ferramentas computacionais avançadas de análise e modelagem de dados. Este trabalho tem como objetivo prever as propriedades mecânicas dos tubos após o processo de revenimento, a partir da composição química do aço, parâmetros dimensionais dos tubos e parâmetros do processo. O acompanhamento on-line da tendência das propriedades mecânicas permitiu uma operação preventiva no forno de revenimento, possibilitando a redução do lead time do processo, visto o tempo médio de 2 dias para o recebimento dos resultados do laboratório. A definição pela utilização das Redes Neurais Artificiais se baseou em trabalhos relacionados ao tema e casos de sucesso aplicados na indústria. Observou-se que os resultados obtidos a partir dos modelos obtiveram índices de assertividade superiores aos de outras técnicas utilizadas para este fim. Além disso, foi possível a criação de um único modelo para cada propriedade mecânica considerando todas as famílias de aço produzidas na Vallourec, facilitando os processos de calibração e sustentabilidade dos modelos.

Aug 16, 2017

By Daniel S. Witkowsky

The Pollution Prevention Act of 1990 provides few specifics to assist the non-fuel mining and mineral processing industries of the United States in achieving pollution prevention (P2) compliance. The U.S. Bureau of Mines (USBM) recognizes the absence of specific information to reduce pollution impacts from mining and mineral processing of hardrock and industrial minerals. Therefore, the USBM has prepared this publication to help reduce or eliminate environmental pollution and to assure the viability of these segments of the domestic mining industry. This report includes worksheets designed to help operators of mining and milling facilities to establish a P2 program. The report can also be used by citizen and environmental groups, State and local governments, and academia to gain an understanding of P2 as it relates to mining and mineral processing.

Jan 1, 1995

By C. H. Hopper

DIAMOND drills have played an important part in the development of mines for many years. Recently. they have also entered the production field arid the use of diamond drills m the primary breaking of ores has become a big branch of the industry. The writer has estimated roughly that the total diamond drilling in Canada during 1942 was 5,625,000 feet, of which 2,250,000 feet, or 40 per cent, was for blast-holes. This accounts for 6,750,000 tons of ore broken, using the conservative factor of 3 tons per foot of hole. Many consider that the use of diamond drills for blast-holes is the most important advance in mine practice of the past decade, and the industry owes a great deal to the staff of Noranda Mines, Limited, for the pioneering they have done in the development of long-hole mining methods and for publishing their results. A great many mines have followed Noranda's lead. At the Waite-Amulet, Aldermac, Flin Flon, Canadian Malartic, Hoyle, and Matachewan Consolidated mines, most of the ore is broken by long-hole blasting. While the mines were developing new methods, the diamond-drill industry was developing mechanically-set bits and better machines. Through the effective use o smaller, cheaper diamonds, as well as more efficient setting, bit costs per foot are only one-half what they were ten years ago. Few people realize that a diamond bit is relatively inexpensive. The common EXT coring bit, for example, contains some 200 small diamonds, weighing altogether about 2.70 carats which, at $3.40 per carat, cost $9.20. After use, the equivalent of about 100 of these diamonds may be recovered. Therefore the true cost of the bit is only $7.00, made up of $4.60, the cost of the diamonds lost, $2.00 for setting, and $0.40 tax. The trend in machines has been toward specialization for the different classes of rock in blast-hole work. Light, high-speed machines have been developed for soft ores and higher powered machines for hard ores.

Jan 1, 1943

By E. D. Attanasi, M. W. Bultman

Most statistical measures of mineral exploration continued downward in 1986. Prospects in 1987, however, appear to have brightened for exploration as the overall economic health of the mineral industry improved. The Society of Economic Geologists (SEG) survey of US and Canadian firms documents the marked decline in US mineral exploration since the early 1980's. From 1981 through 1986, the total exploration expenditure by US firms declined by more than 73% (Fig. 1). Exploration expenditures by US firms declined by 66%%. US based professional exploration staffs were slashed by 70% (Fig. 2). Also, many firms have written off some reserves because of weak markets or have not delineated new reserves to replace production. The Canadian government reported that between 1981 and 1986 Canadian molybdenum re¬serves had declined by 30%, lead and zinc reserves by 20%, and nickel and copper reserves by 15%. The SEG survey also shows the immediate impact of the decline in the dollar on US exploration expenditures abroad. Between 1981 and 1986 the share of the exploration dollar spent by US firms outside of the country declined by nearly one-half and exploration acreage abroad declined by 69%. The downward trend of the last six years may finally be near the end as a leaner and more efficient minerals industry starts to gear up for a period of increased activity. An industry survey reported to Mine Development Bimonthly (Metals Economics Group) indicates that mining firms were expected to increase exploration expenditures in 1987 by at least 10% above 1986 levels. Worldwide expenditures for 1987 by companies covered by the report were expected to top $800 million. It is the first time since 1984 that an increase in exploration expenditures was expected. Also, the US Bureau of Land Management reported a 30% increase in new mining claims for fiscal year 1987 over fiscal year 1986. The bulk of the increase in claims was in states having intense gold exploration, particularly Washington and Oregon. Much of the optimism is undoubtedly due to the increases in metal prices that occurred in 1987. Some of these increases include gold, average price up about 20%; copper, average price up 24%; aluminum, average price up 26%; and nickel, average spot price up 20%. The SEG survey shows precious and base metals accounting for 89% of the exploration expenditures in the US in 1986, up 52% from 1981. The US Bureau of Mines estimates that 80% of US exploration activity in 1986 was directed entirely at gold (1986 Minerals Yearbook). Worldwide exploration plans indicate the continued dominance of gold exploration. New programs were announced for Ghana, Malaysia, and Indonesia. Major new exploration programs were also launched for lead-zinc sulfides in Morocco, platinum and palladium in northwest Brazil, rare earth minerals in Greenland, diamonds in Indonesia, and heavy minerals off-shore Australia. Significant gold discoveries were made at Angels Camp in Oregon; South Africa, near Potchestroom; India, in the Chitradgra district; Northern Ireland near Mt. Speerin; Chile, San Cris-

Jan 5, 1988

By S. Sun

The equilibrium distribution of Cu, Fe and Ni between Cu-Ni-Fe mattes and Pt alloy was measured as functions of the sulphur partial pressure (pS2), oxygen partial pressure (pO2),temperature and Fe content of the matte. The distribution ratios of Cu, Fe and Ni between matte and alloy were independent of oxygen pressure when the pS2was fixed at 2.5x10-5atm and pO2was varied between 10-15and 10-12atm. The distribution ratio of Cu, Fe and Ni increased as the sulphur partial pressure increased. The Cu and Ni distribution ratios decreased with increasing temperature and the Fe distribution ratio increased slightly over the temperature range of1350?1500°C. For mattes where the proportions of Cu and Ni were kept constant, the distribution ratio of Cu increased as the Fe content in the matte increased. The Fe and Ni distribution appeared to be independent of the iron content in the matte and had a value of 1.2 and 1.6 respectively. The activity of Cu, Fe, Ni in the matte was calculated using a regular solution model for solid Pt-Fe-Ni-Cu alloy. The activity coefficient of Cu, Fe and Ni decreased as pO2and pS2increased.The activity coefficients also appeared to be independent of the Fe content and temperature over the range of 36 to 54 wt% iron and 1350 to 1500°C respectively. Keywords: activity, alloy, matte, thermodynamics

Jan 1, 2004

By R. W. Lawrence

A method by which it is possible at an oxidation potential below 680 mV SHE to achieve quantitative conversion of sulphide sulphur to elemental sulphur instead of sulphate in a biological leach of chalcopyrite and bornite has been investigated. The process chemistry, biological phenomena and process flowsheet options are discussed. Several copper concentrates have been evaluated and have been found to be amenable to th process. Results to study the progression of chalcopyrite decomposition during the leach are presented and mineralogical factors affecting the requirement for silver addition are discussed. A chloride addition method for improving silver recovery is described. The results of a small scale continuous leach test have demonstrated that continuous operation can be carried out with high copper extraction and stoichiometric conversion of sulphide sulphur to elemental sulphur.

Jan 1, 1985

By H. Verakis, M. A. Hockenberry, A. C. Smith, J. H. Rowland III

Four different types of fire suppression systems were evaluated in large-scale fire experiments to study the effect of air velocity on their effectiveness in extinguishing conveyor belt fires. The four different types of suppression system were water sprinkler, deluge-type water spray and two different dry chemical fire suppression systems. The large-scale fire tests were conducted with 1.8-m- (72-in.)-wide fire-resistant rubber belt that met the Mine Safety and Health Administration flame resistant requirement specified in Title 30, Code of Federal Regulations, Part 18, section 18.65 (also known as the 2G Flame Test). Each fire suppression system was tested at air velocities of 152 - 168 m (500–550 ft) per minute (mpm) and 411 - 457 mpm (1,350 - 1,500 fpm). Two tests were conducted at both air velocities for each fire suppression system. Both of the water-based fire suppression systems were able to suppress the fire to the point that a miner could extinguish it with a fire extinguisher. However, the amount of water needed to suppress the fire to the point where a miner could walk up to and extinguish any smoldering belting was greater than the current MSHA regulations required. MSHA regulations only require 10 minutes of water supply for a suppression system. In the test setup, neither of these systems would have suppressed the fire had the water been turned off to the system after 10 minutes. The dry chemical suppression systems produced mixed results. Dry chemical suppression system A did not suppress the conveyor belt fire at either air velocity. Dry chemical system B suppressed the fire at 152 mpm (500 fpm) air velocity, but produced mixed results at the higher air velocity. Details are presented on the large-scale fire test setup, arrangement of the fire suppression systems and conclusions regarding the effect of air velocity on fire suppression system design and performance.

Jan 1, 2010

By L. C. IlsLey, M. W. Von Bernewitz

"Introduction.Several hundred thousand open lights are daily carried in coal mines of the United States, each lamp being a menace to life and property through fire or explosion. They have been responsible for many disasters in the past, and will be again. Flame safety lamps have been available for over a hundred years, but during the last ten years safe and practical electric lamps have been perfected. These have eliminated many of the flame safety lamps, and in a few mines have replaced open flame lamps. But there are still more than twice as many open lamps as electric lamps in our mines, and the open lamps should be discarded in favor of an approved type of electric lamp. There are several electric miners' lamps which have been approved by the Bureau of Mines for safety and efficiency, give good light, and are easily maintained and carried, some flame safety lamps will always be used, hut mostly for detecting gas; although they might be supplanted if some simple, reliable, and cheap gas detector were developed.Explosion Hazards from Open Lights.An open light and gas*** constitute a vicious hazard; while if there be coal dust present in the vicinity the consequences are multiplied many times. An open light and black blasting powder also constitute an explosion hazard, vividly attested by several serious disasters."

Jan 1, 1924

By Dharmil S. Patel, Zoyav S. Benyaminov, Cassandra A. Wetzel

Rehabilitation of the Henry Hudson Bridge is nearing completion, connecting Spuyten Duyvil in the Bronx to Inwood Hill in Manhattan, New York. Constructed in 1936, the Henry Hudson Bridge spans 840 feet over the Hudson River. Challenging geotechnical aspects of this Project required a team of innovators to overcome. Rehabilitation of the existing bridge involved the replacement of sixteen bent pedestal substructures, two abutment pilasters and installation of new deep foundations at the skewbacks. However, the Bridge, roadways, adjacent Metro-North Railroad (MNR) structures and New York City (NYC) Parks land were to remain open to the public for use, with minimal disturbance. In addition to physical constraints, geologic site conditions varied widely across both sides of the River, with varying bedrock quality and depth, greatly impacting the proposed design and construction. Extensive analysis of bedrock conditions was conducted to locate areas of potential wedge failure. The implementation of anchors was used to reinforce rock stability where pedestals and pilasters were replaced. This paper describes several challenging technical and natural aspects overcome in the rehabilitation of the Henry Hudson bridge foundations, including varying geologic site conditions, access restrictions, construction limitations, project specifications and design requirements.

Sep 8, 2021

By Marco Locatelli

En este trabajo se evalúa, como una alternativa sostenible para minería subterránea, el reemplazo de agregados por el uso de material de desmonte de mina (zarandeado o chancado) en la elaboración de shotcrete, sin que se afecten parámetros de ingeniería ni factores de seguridad. Los procesos para probar la viabilidad de esta iniciativa partieron de los análisis granulométricos de humedad, absorción y peso específico del agregado. Se procedió a la evaluación del concreto en estado fresco y endurecido, con pruebas de slump, pruebas de rebote y ensayos de compresión simple.

Sep 20, 2019

By Leykam Chris J., Jacobs Scott. A.

"Construction of the New NY Bridge over the Hudson River 25 miles north of New York City is one of the largest civil infrastructure projects presently underway in the United States (formerly Tappan Zee Hudson River Crossing). The $3.14 billion Design-Build contract is also the largest ever awarded by the state of New York using an Alternative Project Delivery method, and the first major public project to use Design-Build. The new 3.1 mile long bridge will replace the existing Governor Malcolm Wilson Tappan Zee Bridge with a modern twin crossing featuring: Iconic side by side cable stay main spans; significant deck widths accommodating eight lanes of regular traffic, wide shoulders, and a shared use pedestrian and bike path; foundation with excess capacity to fully support a future rail bridge; more than 1,000 large diameter pipe piles driven in deep glacial deposits; drilled shafts installed through steep blast-rock slopes on the east shore landings. Geotechnical challenges included varied bedrock and glacial till surfaces with steep slopes and depths in excess of 750 ft.The purpose of this paper is to highlight major features of the New NY Bridge project with specific focus on the design and construction of the foundations supporting the approach and main span structures from abutment to abutment, provide background on alternative project delivery in NY, as well as provide an overview of the design-build process as it was applied to foundation delivery.The 3.1 mile Governor Malcolm Wilson Tappan Zee Bridge was constructed across the Hudson River connecting Nyack and Tarrytown (Rockland and Westchester Counties). Construction started in March 1952 and was completed in 1955 for a cost of $81 million. The seven lane crossing first opened to traffic on December 15, 1955 and coincided with the opening of a 28 mile segment of highway I-87 / I-287 between Suffern NY and Yonkers NY. The bridge is part of the extensive 574 mile New York State Thruway road system owned and operated by the New York State Thruway Authority (NYSTA)."

Jan 1, 2016