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By C. A. Petch

Abstract - The High Lake polymetallic deposit is located in the northern Slave province, 40 km south of Coronation Gulf, Nunavut. The main zone, the AB zone, hosts an estimated resource of 3.56 Mt grading 5.0% copper, 1.1% zinc, 0.06% lead, 1.7 g/t gold, and 18.2 g/t silver. Archean felsic metavolcanic and metavolcaniclastic rocks are the dominant rock type and are associated with lesser mafic metavolcanic and carbonate-rich metasedimentary rocks. The sequence strikes north-northeast, dips steeply to the west, and is truncated to the west by a large granodioritic intrusion. The mineralization at the AB zone is comprised of massive and stringer chalcopyrite-sphalerite-pyrrhotitepyrite± galena. At the core of the mineralized zone, intensely chlorite-altered rocks are locally metamorphosed to form distinctive zones of anthophyllite-magnetite-cordierite-altered rock. Peripheral to the mineralized core, alteration consists of sericitization, silicification, and weaker chloritization. Primary morphology and facing direction of the zone are difficult to interpret in part due to poor primary metal zonation of the deposit. However, the irregular shape of the mineralized zone and the erratic zones of zinc enrichment at the fringes are consistent with the interpretation that the zone was formed by the replacement of a porous volcaniclastic pile.

Jan 1, 2004

By Prakash Venkatesan, Mehmet Ali Recai Ӧnal, Shaik Saida, Veerendra Singh, Chenna Rao Borra, Manish Kumar Kar

A laboratory-scale investigation of the effect of milling operation and catalyst addition ( K2CO3) on the partial reduction of low-grade pyrolusite ore pellets was carried out using coke as a reductant. Thermogravimetric analysis was used to understand the correlation between milling and catalyst addition parameters with the reduction temperatures. DTG analysis of pyrolusite pellet reduction showed three distinctive peaks associated with a three-step reduction mechanism (i.e., MnO2→ Mn2O3→Mn3O4→MnO). The results showed that the grinding and addition of the catalyst have a significant effect on lowering the MnO2 reduction temperature independently. But maximum reduction temperature drop is obtained when combining grinding and catalyst addition in this work. By 3 h milling and 10 wt% catalyst addition, the reduction temperatures were reduced by more than 200 °C compared to the raw ore pellets. These results obtained from the DTG analysis were further supported by XRD analysis of the reduced samples.

Dec 20, 2022

By W. G. Willson, Y. L. Li, P. D. Rao, D. E. Walsh

The combination of high moisture and low heating value has restricted most low-rank coal (LRC) usage worldwide to mine-mouth power generation. The objective of this study was to subject two Alaska low-rank coals to hydrothermal drying to enhance their marketability in the Pacific Rim markets and to evaluate the chemical and physical properties of the dried products as a function of process conditions. Coals from Usibelli Coal Mine and the Beluga coalfield have a heating value of approximately 18.5 MJ/kg and contain about 28% moisture. Hydrothermal treatment (at 275° to 325° C) of lump coal, from the Usibelli Coal Mine and the Beluga coalfield, enhanced the heating value of the material, on an equilibrium moisture basis, from 18.5 MJ/kg to nearly 27.8 MJ/kg. The product coal, with a high heating value and only 0.2% S, is an environmentally-acceptable premium fuel; additionally, with the Hardgrove grindability index of the coal greatly improved, its value is even further enhanced. An increase in hydrothermal drying temperature promotes vesiculation of resinite. Also, ulminite reflectance increased to 0.92%, and ulminite was subjected to widespread vesiculation; this resulted in a coke-like structure indicative that the material went through the fluid stage.

Jan 1, 1993

By Angel Neira, César Espejo, Wilson Bardales

A pesar de los importantes recursos que contiene el yacimiento, las bajas recuperaciones (alrededor del 40 %) obtenidas en pruebas metalúrgicas hacían inviable el proyecto El Toro, motivo por el cual se formó un equipo multidisciplinario con la misión de maximizar la recuperación. El equipo logró caracterizar detalladamente litologías, alteraciones, mineralización y contaminantes, así como definir las unidades geometalúrgicas (UGM), que permitieron la realización de más de 6 000 pruebas, gracias a las que se logró identificar las variables significativas que favorecen la recuperación, así como conocer las características físicas del mineral. El resultado de este trabajo de investigación incrementó significativamente la recuperación (se superaron valores del 70%) y permitió que el proyecto pase a su fase operativa con un horizonte de 8 años.

Sep 20, 2019

By R. I. Jaffee, J. G. Dunleavy, W. Hodge, H. R. Ogden

Early in 1946, at the instigation of the U. S. Army Signal Corps, the authors made an extensive survey of the available literature covering high-strength, high-conductivity alloys. For the purposes of the Signal Corps, the minimum tensile strength to be considered was 150,000 psi, together with at least 50 pct IACS conductivity. No single alloy was found to be in production, or mentioned in the literature, which had this combination of properties. The constitution diagram for the iron-copper alloys is not well established in the respect to the two-liquid region. Fig I, taken from the 1939 Ed. of the ASM Metals Handbook, shows a two-liquid system existing above the liquidus temperature, but disconnected from it. Although Ruer and Fickl and Ruer and Goerensz definitely established the fact that two liquid layers could occur in the system, Ruer3 was not convinced that the line of immiscibility was closed in the center. Maddocks and Claussen4 found no liquid immiscibility at temperatures up to 157oOC in alloys containing almost no carbon. Although the diagram would indicate age hardening of the copper-iron alloys is possible, Hanson and Fords found that little hardening effect could be obtained. However, Gordon and Cohen6 reported that the response is better if the quenching is very efficient. Although iron has a potent effect on the conductivity of copper, Hanson and Fords have shown that, when hot-rolled copper-iron alloys are aged at 1200°F, the electrical conductivity decreases sharply with iron contents up to 0.2 pct Fe, and then levels off at conductivities between 60 to 70 pct IACS with compositions to 2.1 pct Fe. They also found that aging did not increase the tensile strength, although increasing iron content gave a moderate improvement in strength. High-strength copper-iron alloys, usually containing about 60 pct iron, had been reported by Smith and Palmer.7 They found that an alloy containing 56.4 pct copper, 0.21 pct magnesium, balance iron, would give a maximum tensile strength of 170,000 psi and an electrical conductivity of slightly over 35 pct IACS. The alloy could also be processed to have I50,000 psi tensile strength, and about 41 pct I.\CS conductivity. Decreasing the iron content increased the electrical conductivity, but the long mushy range during freezing of the alloy containing 10 to 20 pct iron made the production of good castings difficult. In spite of the difficulty encountered by Smith and Palmer with alloys of around 20 pct iron, it was decided to make a rather complete investigation of this type of alloy. As a result of this investigation, a method of alloying and fabricating copper alloys containing 10 to 15 pct iron was developed

Jan 1, 1949

By C. E. Reistle

The generation of steam for drilling operations has visually been accomplished in the past by the use of portable locomotive-type boilers without the aid of auxiliary equipment or advanced for economizing fuel or water consumption. This has been due primarily to the fact that the steam-generating plant of a drilling well must necessarily be of temporary and portable design, and the amount of steam generated has not been considered sufficient to justify the additional expense necessary to obtain more economical operation. However, with the constantly increasing depth to which oil wells are being drilled and the use of larger and heavier equipment, the steam requirements have reached a point where equipment and methods that were previously considered as applicable only to permanent plant installation can be and are being used to a decided advantage by the more progressive operators. As an example of the present-day requirements and the rapidly increasing steam consumption in rotary drilling, a comparison between the requirements during the intensive drilling period in the Seminole end Oklahoma City fields of Oklahoma is of interest. In the Seminole field. There the approximate depth of rotary drilling was 3,500 feet, the general practice was to use three 85 to 90 or 100 horsepower A. P. I. code boilers operating at a working pressure of 175 to 200 pounds per square inch. The fuel end water consumption was approximately 450 to 500 thousand cubic feet of gas and 700 to 750 barrels of water per day. In the Oklahoma City field, where the average drilling depth is approximately 6,500 feet, the general practice is to use either four 100 or 116 horsepower or three 123 horsepower A.P.I. code boilers, operating at a pressure of 250 pounds per square inch. The fuel and water consumption varies from 550 to 750 thousand cubic feet of gas and from 1,000 to 1,500 barrels of water per day.

Jan 1, 1930

By D. J. Carney, J. Chipman, N. J. Grant

G. A. Moore—The tin-fusion method has been a very favorable possibility for many years. The authors apparently have settled the question that delayed the method for a long time by showing that no hydrogen is absorbed in the tin. This, of course, is very important. I want to make a few remarks concerning the absolute accuracy of analysis, which must be the final basis for deciding among the various methods. From the figures in the paper, there seems to be some remaining slight discrepancy on the actual amount of hydrogen present in various samples which may be presumed essentially identical. (This is of the order of the precision of individual analyses but appears in averaged results.) From the analyst's viewpoint, the tally of hydrogen content can be regarded as occurring in three portions. First is a large portion which comes off easily and automatically during sample storage and later on heating in the apparatus. This is fairly easily analyzed. Second is an item which may be either positive or negative in the tally sheet. In warm or hot evolution, this is a portion which, in practice, can never be re-

Jan 1, 1951

By L. Douglas Smoot

This research program was a theoretical and experimental study to improve understanding of the mechanisms of flame extinguishment in methane-coal dust-air-suppressant mixtures. This final report is a summary of work conducted during this grant, sponsored by the Bureau of Mines. Work under this new grant closely followed a recently completed contract for the Bureau of Mines that was conducted at this laboratory, and results of the earlier contract are also summarized in this report, as required in the grant work statement. The experimental effort was concentrated on supplementing the limited data available to describe laminar flames in methane-coal-air-suppressant mixtures. The theoretical effort was devoted to developing a comprehensive model that could be used to explain and extrapolate the experimental data. Selected for study were the following flames: Methane-air; methane-air plus KHCO , KNO3, K C204, KBr, Al203 or Monnex; methane-coal dust-air; coal dust-air with size, volatiles content, and concentration as variables, and coal dust-air plus KHCO3, KN03, KBr, NaCl or CaC03.

Jan 1, 1978

By C. R. Hayward

THE CHAIRMAN (ALBERT SAUVEUR, Boston, Mass.).-I am sure we are indebted to Prof: Hayward for his addition to our knowledge of the influence of sulphur on steel. As he has said in this paper, sulphur has had many defenders in recent years. It seems to me, however, that, while it may be old school to believe in the detrimental action of sulphur, it is not yet old school to believe in segregation; that while it may be that 0.1 per cent. of sulphur has no very great effect on the physical properties of steel, a ladle analysis of 0.1 per cent. of sulphur may readily result in 0.2 or 0.3 per cent. sulphur being present in the segregated portion of the ingot, and that, it seems to me, might be a rather serious matter. J. S. UNGER, Pittsburgh, Pa.-Prof. Hayward has presented the results of an investigation along a line to which I have devoted considerable time and attention, and I am particularly pleased to note that his results are in accord with my own and further tend to prove the fact that the old, established prejudice against sulphur is based more on belief than actual facts. I have felt for years that tooo much stress was placed on the harmful influence of certain elements in steel such as sulphur, phosphorus, copper, etc., but it has only been within recent years that efforts have been made to, establish the truth. Practically all the investigations made to date have proven that these elements within reasonable limits are harmless and, in fact, that for certain purposes the addition of these elements is beneficial. In referring to copper, J. E. Stead, Vice-President of the British Iron and Steel Institute, said at their last meeting: "Even today one comes across steel specifications in which copper is barred, which can only be regarded as ail indication of ignorance, if not stupidity, of those who prescribe the composition of steel, for it has been long ago proved that copper in steel, instead of being an evil, is quite harmless, and is sometimes distinctly beneficial." Sulphur owes its evil name to the early days of the manufacture of steel. Chemical analyses were crude, and failure due to either poor raw materials or metallurgical treatment were many. Sulphur being a comparatively easy element to determine with reasonable accuracy, particular attention was called to the amount of sulphur, and the failure was attributed to it, without giving any consideration to other causes. A pre-

Jan 4, 1917

By G Caddy, M Middleton, S Kerec, R Keil, J Tsalapatis

Arrium’s OneSteel Whyalla Steelworks in South Australia is a fully integrated plant which operates a single blast furnace. The key operational objective has been to maintain high process availability and stability while maximising the process efficiency and the produced hot metal quality. All ferrous raw material input feeds are sourced exclusively from company iron ore deposits in the nearby Middleback Ranges. The Whyalla blast furnace has mostly operated using a combination of a high percentage of pellet feed, produced in Whyalla, together with screened lump ore.The unique ironmaking challenge has always been to extract the maximum value from the ferrous burden feed available locally. In earlier times, high-grade hematite lump ore was available for both screened lump ore and pellet production. Blast furnace trials from acid to fluxed pellet feed commenced in 1977. The furnace pellet feed has been wholly fluxed since 1981. Many pellet/lump ore feed mixes and significant pellet chemistry composition design changes have been made over the years. These changes have been aimed at best balancing the ferrous burden availability/cost and the optimum reducibility/high temperature melting behaviour of the charged ferrous feed within the blast furnace. In more recent times since 2007, the Whyalla blast furnace operation has transitioned from a hematite based pellet feed to a magnetite based pellet feed while there is an ongoing contest dealing with diminishing absolute quality/increased variability raw material feed inputs.The paper will detail key elements of the Whyalla blast furnace operational philosophy with regards to ferrous feed use and process optimisation. The blast furnace ferrous feed design considerations will be discussed, together with the test work performed, the operational and slag design transition strategies employed and the process results achieved.CITATION:Tsalapatis, J, Middleton, M, Keil, R, Kerec, S and Caddy, G, 2015. The use and optimisation of ferrous feed at the Whyalla Blast Furnace, in Proceedings Iron Ore 2015, pp 377–384 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

[1.1. The provisions of this code are minimum provisions and are designed to minimize hazards to life and property in and about underground coal mines where electrical equipment and circuits installed used. They indicate the Steps necessary in the selection, installation, operation, inspection, and maintenance of electrical equipment and circuits to obtain proper safeguards in reducing electric shock, fire, explosion and other hazards. Surface as well as underground installations were considered in formulating the code and, unless otherwise stated, each provision applies equal to both underground and surface installations. This code does not apply to buildings and installations not directly connected with mining operations, nor does apply to strip-mining operations.]

Jan 1, 1952

By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

This study presents a viable approach for recovery of precious metals such as gold (Au), silver (Ag), palladium (Pd), and base metals, including copper (Cu), nickel (Ni), cobalt (Co), lead (Pb) and zinc (Zn) from waste printed circuit boards (WPCBs) via iodine-iodide leaching and precipitation. The behaviours of dissolution and precipitation of precious and base metals during iodine-iodide leaching and precipitation processes were discussed. Sodium hydroxide (NaOH) was used to remove base metal impurities exist in the pregnant leach solution under alkaline conditions. Precious metals remained in the resulting solution from NaOH precipitation were recovered by reduction using ascorbic acid (L-AA) solution. Results show that under optimum leaching conditions, almost all (> 99%) of Au was dissolved in an iodine-iodide solution when the dissolution efficiencies of other precious metals (Ag, Pd) and base metals, besides calcium (leaching of 25%) were less than 1 and 6%, respectively. The study revealed that more than 95% of Cu, Ni, Pb, Zn, Fe and Mn were initially removed from the pregnant leach solution at pH of 9.3 with addition of 0.1 M NaOH. Then 99.8% Au, 81.7% Ag and 74% Pd were precipitated from the obtained solution after NaOH precipitation while L-AA dose was 0.6 ml/ml at the condition. It can be concluded that the precious and base metals could be recovered selectively and economically from WPCBs via iodine-iodide leaching followed by precipitation using NaOH and L-AA.

Mar 1, 2018

By E. Snyders

The upgrading process of an inferior grade of zircon to a superior opacifier for ceramic applications was investigated. A calcining process in the presence of mineralizers was used to produce the product in a conventional muffle furnace. A pre-milled inferior grade zircon concentrate, with a relatively high iron and alumina content generally not suitable for high quality ceramic applications, was used in this study. The influence of the upgrading process on the opacifying properties of the zircon material was compared to that of commercially available prime grade zircon opacifier products currently being produced in South Africa. The influence of a calcining step in the presence of mineralizers with regard to the milling characteristics of the treated zircon material was also evaluated in this study. The morphology of the treated and untreated zircon opacifier samples were investigated by SEM micrographs and the colours of zircon samples were characterized on the grounds of the Commission Internationale de l`Eclairage (CIE) standard procedure (CIE L* a* b* measurements) after application on a bisque ceramic tile. It was found that the treatment improved both the milling as well as the opacifying properties of the treated inferior grade zircon concentrate and renders it equivalent to or better than prime grade zircon opacacifiers currently produced. Keywords: ZrSiO4; opacifier; colour; milling; calcining.

Jan 1, 2005

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012

By Lawrence Addicks

THrough the courtesy of Dr. James Douglas I am permitted to give a summary of some of the results obtained in leaching slimes tailings in a series of experiments conducted under my direction at Douglas, Ariz., during the past year. While the test run for which the data are given deals with a particular case, much of the work is general in its application and may therefore be of interest. This work was done upon the ores of the Burro Mountain Copper CO. A description of the geology of the district will be found in the paper by R. E. Somers published in this volume, p. 604. The mineral is pyrite and chalcocite very finely disseminated throughout the gangue and a characteristic of all the ores is the large amount of alumina present. A representative analysis of the particular ore under consideration would be about as follows: Cu, per cent..................... 2.35 S, per cent...................... 3.0 Ag, ounces per ton.............. 0.05 CaO, per cent.................. 0.5 Au............................ None K2O, per cent.................... 4.0 Fe, per cent..................... 1.50 SiO², per cent.................... 70.0 Alz²O³, per cent....................13.OO The leaching of the ore direct was early dismissed from consideration for the following reasons: 1. The ore would have to be quite finely crushed to liberate the mineral for leaching; concentrating after crushing would cost but a few cents a ton; and a higher total reeovery would result from leaching tailings rather than ore. 2. Rough concentration would yield a suitable material for roasting to make sulphur dioxide or sulphuric acid in connection with the leaching scheme. 3. Such a program put the question of cost vs. recovery on a basis where flotation and discarding of tailings were directly comparable. Concentrating experiments already available indicated that the tail-

Jan 1, 1916

By A. Fisher

The use of thermal integrity testing to verify the quality of deep foundations has increased significantly in the UK and other world markets over the last 5 years. The introduction of distributed fibre optic sensing to this field has broadened the range of applications in which it can be deployed and the types of foundations which can be tested. This paper presents how fibre optic sensing technology can be successfully deployed in the construction environment the range of foundation techniques to which it can be applied. Alongside developments in the practical aspects of thermal testing, progress has been made in establishing assessment criteria which can be used to evaluate the results. This paper presents recent examples of comparative studies on foundations which include both thermal integrity testing, cross hole sonic logging and intrusive coring. The use of distributed strain measurement during pile load testing presents an alternative means to verify the assessment criteria used for integrity testing. This new approach can achieve comparable results to foundation exhumation or intrusive investigation and at a fraction of the cost. This paper presents the findings of several such studies, highlighting the benefits and opportunities for future improvement of the method.

Oct 1, 2022

By E. W. Geist, W. J. Bronkala

PRINCIPLES OF MAGNETIC SEPARATION The application of magnetic separators relies on the different behavior of individual mineral particles under the influence of magnetic forces. When exposed to a magnetic field, all materials are affected in some way. According to whether materials are attracted or repelled by the magnetic field, they are designated paramagnetic or diamagnetic, respectively. Paramagnetic materials are attracted along lines of magnetic force from points of lower magnetic field intensity to points of higher magnetic field intensity. The very strong response of some materials to a magnetic field is sometimes designated ferromagnetic and the particles attracted frequently retain magnetic properties after the applied magnetic field is removed. Diamagnetic materials are repelled along the lines of magnetic force from points of high magnetic intensity to points of lower field intensity. Only limited commercial use of diamagnetic effects has been made. For practical applications, the paramagnetic groupings are: 1. Strongly magnetic (ferromagnetic) 2. Magnetic 3. Weakly Magnetic 4. Non-magnetic The limits of these groupings are not well defined and will vary in some mineral species. Only a few minerals are ferromagnetic (magnetite is an example) and arbitrarily some investigators have selected 10,000 gauss, or 1 Telsa, as the dividing line between low and high intensity magnetic fields. I. S. Wells has developed a table indicating the magnetic intensity required to separate a selected grouping of minerals which is shown in Table 1 on page 2. A similar table has been developed by Carpco Inc. of Jacksonville, Florida in conjunction with the use of its high tension separators. This table, Table 2 on page 3 shows other minerals grouped in the broader categories cited above. Magnetic separation methods are used either to separate valuable minerals from nonmagnetic waste or magnetic impurities or other valuable magnetic minerals from bulk nonmagnetic values. Magnetically susceptible mineral particles occur as either individually discrete particles,

Jan 1, 1986

By Lawrence Addicks

(San Francisco Meeting, September, 1915) THROUGH the courtesy of Dr. James Douglas I am permitted to give, a summary of some of the results obtained in leaching slimes tailings in a series of experiments conducted under my direction at Douglas, Ariz.. during the past year. While the test run for which the data are given deals with a particular case, much of the work is general in its application and may therefore be of interest. This work was done upon the ores of the Burro Mountain Copper Co. A description of the geology of the district will be-found in the paper by R. E. Somers published in the May, 1915, Bulletin of the Institute. The mineral is pyrite and chalcocite very finely disseminated throughout the gangue and a characteristic of all the ores is the large amount of alumina present. A representative analysis of the particular ore under consideration would be about as follows: Cu, per cent 2.35 S, percent 3.0 Ag, ounces per ton 0.05 CaO, per cent 0.5 Au None K202, per cent 4.0 Fe, per cent 1.5 SiO2, per cent 70.0 A120,, per cent 13.0 The leaching of the ore direct was early dismissed from consideration for the following reasons: 1. The ore would have to be quite finely crushed to liberate the mineral for leaching; concentrating after crushing would cost but a few cents a ton; and a higher total recovery would result from leaching tailings rather than ore. 2. Rough concentration would yield a suitable material for roasting to make sulphur dioxide or sulphuric acid in connection with the leaching scheme. 3. Such a program put the question of cost vs. recovery on a basis where flotation and discarding of tailings were directly comparable.

Jan 8, 1915

By G. P. Chatterjee

HARDNESS is one of the most common properties of metals and alloys but is one of the most difficult to define or express in terms of the fundamental units. In the Brinell or Vicker's hardness test, the hardness number N is defined as N = L/A where L is the load in kilograms and A is the area in mm'. This does not necessarily imply that a pressure of N kilograms per mm2 actually acts on the specimen.' It is essential that for a true comparison of hardness values the angle of indentation be kept constant,' a which is not done in the Brinell test. For this and other reasons, the Brinell hardness value is not based on a satisfactory physical concept.' The concept of hardness based on the work done per unit volume of indentation3-6 offers a simple and scientific definition. An attempt has been made here to develop this concept (at constant angle) and to compare the values so obtained with the Bhn for different metals and alloys. In Fig. 1 a vertical load L is applied to a compara- tively hard ball of diameter D creating an indentation of diameter 6 and depth h on the specimen S. The work done, W, is then given by W = So Ldh. [I] Since L is not independent of h, Honda and Takahasip and Matsumura" assumed different functions leading to equations which do not apply equallye to a wide variety of metals and alloys. A better relation is obtained from Meyer's Law L = ad" [2] where A and n are constants depending on the nature of the material but independent of the ball diameter D. From Fig. 1 it is obvious that h = R(l — cosq) and d = 2R sin 8.

Jan 1, 1957

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971