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By M. Kung, D. Schwegler-Berry, V. Castranova, D. Lewis, H. Abrons

Pulmonary responses to coal mine dust exposure were investigated by analysis of bronchoalveolar lavage specimens from non-smoking coal miners (n-12, mean age-43 ± 2 years, mean underground exposure-17 ± 2 years) and from non-smoking normal volunteers (n-18, mean age-43 ± 2 years). Spirometric and diffusion capacity indices were monitored as part of a physical exam. Lavage was performed in a subsegment of the right middle lobe by instillation of 200 ml of warmed saline solution in 50 ml aliquots and recovery by gentle suction. Specimens were centrifuged at 500g for 5 minutes at 2°C. Total and differential cell counts were recorded. Secretion of oxidants measured by chemiluminescence, surface morphology (spreading and ruffling), and lymphocyte parameters were determined. Lavage fluid was analyzed for the presence and quantity of acute phase reactants and immunoglobulins. Pulmonary function measurements as well as recovered lavage volume, total lavagable cells, and differential cell counts were similar in both miners and controls. Both resting and phorbol myristate acetate-stimulated chemiluminescence were also similar in miners and controls. In contrast, particle-stimulated chemiluminescence was significantly decreased in the alveolar macrophages from the miners (48% of control values). Morphometric analysis of scanning electron micrographs indicate that phagocyte surface spreading was similar in miners and controls. However, surface ruffling was 127% greater in the miners compared to controls. Lymphocyte subpopulations were similar in miners and controls. Protein analysis of the lavage fluid revealed lower total protein content in the lavage fluid of miners. However, the concentration of albumin, IgG, and IgA were similar in miners and controls. We conclude that most indices were normal in underground miners working under the current dust standard of 2 mg/m3. The decrease in particlestimulated chemiluminescence and the increase in surface ruffling in miners may suggest the beginnings of particle overload and activation of the macrophages. In addition, a decrease in total protein was noted in lavage fluid from miners.

Jan 1, 1991

Development of the Boleo Process Flow Sheet and the Direct Solvent Extraction (DSX) Circuit for Cobalt and Zinc Recovery The metallurgical process designed to treat the El Boleo Cu-Co-Zn-Mn ore involves a sulphuric acid leach in seawater under oxidative and then reductive conditions to maximise metal extraction. Copper and cobalt are recovered as cathodes by electrowinning, zinc and manganese as zinc sulphate monohydrate and high quality manganese carbonate, respectively, by precipitation after a number of separation and purification stages. One of the key purification stages of the Boleo metallurgical process is the CSIRO DSX circuit. The DSX circuit was developed using the synergistic solvent extraction (SSX) technology. Initially, a synthetic solution was studied, and by adding 0.4 M LIX63 to 0.5 M Versatic 10 in Shellsol D70, large synergistic shifts were obtained for cobalt (?pH50 4.24) and zinc (?pH50 1.62). After a single contact, the separation factor of metals over manganese reached over 6,000 for cobalt and over 380 for zinc, indicating excellent separation of cobalt and good separation of zinc from manganese, magnesium and calcium. The SSX system was further optimised with the modified synthetic pilot plant solution. The extraction of cobalt and Zn after a single contact was 93 per cent and 70 per cent, respectively, while the Mn concentration in the loaded organic solution was only 0.28 g/L. A proof of principle pilot plant operation was conducted in 2004 and a demonstration pilot plant for final engineering design in 2006 with outstanding performance of the DSX circuit. For the demonstration pilot plant, the overall recovery of cobalt and zinc exceeded 99 per cent with a raffinate containing only 4 mg/L Zn and 1 mg/L Co. The DSX organic system showed no sign of degradation during the pilot plant operation, indicating good chemical stability under the anticipated commercial operating conditions. The DSX circuit will be implemented in the future Boleo processing plant.

Sep 13, 2010

By Fernanda Mitke Maria de Lacerda Rocha Hoppe R

O objetivo deste trabalho foi avaliar a capacidade da máquina de tração Instron em conjunto com um forno acoplado em sua estrutura (especialmente desenvolvido para este fim) para a obtenção das curvas tensão versus deformação do aço 22MnB5 nas temperaturas usualmente empregadas no processo de estampagem a quente. Adicionalmente, teve como objetivo avaliar a influência da temperatura nas propriedades mecânicas do aço para estampagem a quente. De posse dos dados experimentais de tensão e deformação foram realizadas tentativas de ajuste aos modelos constitutivos Voce–Kocks e Hollomon para as diferentes temperaturas. Os resultados demonstraram que o conjunto Instron-forno foi capaz de entregar resultados com repetibilidade, permitindo assim o ajuste dos dados ao modelo de Voce-Kocks na maior parte dos casos.

Oct 30, 2017

By Bodo Peinemann

For more than 35 years Lurgi has been providing its fluid bed roasters on a world­wide basis. The current total annual capaci­ty of the 250 Lurgi roasters approaches 26 million mt of sulphide minerals, including gold-bearing flotation pyrite concentrates. While the stationary fluid bed has been uti­lized for roasting exclusively, Lurgi has now commercially introduced its Circulating Fluid Bed (CFB) technology for gold roasting in a successful effort to maximize gold re­covery.

Jan 1, 1990

By John P. Cosgro

The increasing use of internal furnace-boilers for power-plants at mines (doubtless due to the facility with which they may be installed by reason of their portability; the fact that they require no masonry setting, cast-iron fronts, buck-stays, etc., and practically no foundation; and the successful maintenance of their claim to equal and even superior economy, as compared with boilers of other types1) warrants this description of a method of remedying an injury which may occur, to such a furnace, even though it satisfies the requirements of the formula adopted by the U. S. Board of Supervising Inspectors of Steam Vessels.2 I refer to the sagging and deformation which may result from overloading the boilers for a considerable period—say, several days. This is sometimes unavoidable under the exacting conditions of continuous day-and-night service, and (in spite of all rules and precautions) the occasional careless or unskillful work of attendants. Such a trouble is by no means unknown on shipboard, where this type of boiler is so largely employed.

Jan 1, 1906

By R. D. Pehlke, J. F. Elliott

The equilibrium pressure of nitrogen gas over pure silicon metal and silicon nitride has been measured in the temperature range 1400° to 1700°C. From the experimental data, the standard free energies and enthalpies of formation of Si3N4(a) have been calculated as functions of temperature over the above temperature range. Utilizing data in the literature and the results of this investigation, the specific heat, molar enthalpy, molar entropy, standard enthalpy of fornation, and standard free energy of fornation are estimated for the temperature range 298° to 1400°C. THE high-temperature thermodynamic properties of many metallic nitrides are not well established at present. This is a serious deficiency because nitrogen and nitride-forming metals are important alloying additions to steels, and knowledge of the interaction between nitrogen and these elements is essential to a better understanding of the behavior of steels. Metallic nitrides also are used as refractory materials. Consequently, the investigation reported here was undertaken to provide more complete information on the standard entropy and free energy of formation of silicon nitride. The experimental technique provided a direct measurement of the equilibrium pressure of nitrogen gas in the range of 1413 to 1700°C for the reaction: 3 Si(1) + 2N2 (g) = Si3N4 (a) [ 1 ] and below 1413oC for the reaction: 3Si(c) + 2N2(g) = Si3N4(a) [2] APPARATUS The experimental system consisted of a crucible assembly, a reaction chamber, and a gas supply and vacuum system. The Crucible Assembly which contained the equilibration specimen and molybdenum radiation shields with a susceptor for induction heating is shown in Fig. 1. Two covered, high-purity alumina crucibles, one nested within the other, contained the susceptor, shields and specimen. Central openings in the upper shield and crucible covers permitted on optical pyrometer to be sighted into the central cavity of the specimen. The specimen itself was a 5/8 OD by 1-in.

Jan 1, 1960

By Kim B. Shedd

An initial evaluation of the flow of cobalt-containing materials in the United States was prepared. The following aspects of materials flow were included: cobalt released as a result of mining and processing other metals and minerals; scrap generation and subsequent recycling or cobalt recovery; and cobalt losses resulting from the generation of wastes, dissipative uses, and disposal of used products. Where possible, estimates were made to quantify the amount of cobalt lost from the materials flow. More than 2,000 metric tons (mt) of cobalt are released annually from mining and mineral processing in the United States, including 480 mt of cobalt in coal produced in the United States. Metallurgical industries examined in this study have well-established recycling or cobalt recovery practices. The petroleum industry recycles spent catalysts, and some chemical catalysts are also recycled. Losses generated during cobalt chemical and powder processing were estimated at 50 to 80 mt of cobalt annually. Losses from alloy processing and the manufacture of parts and products were estimated to be 360 mt. These industrial losses are greatly outweighed by an estimated 2,780 mt of cobalt' consumed in the United States each year to make products that will ultimately be disposed of.

Jan 1, 1992

By C. E. Armantrout, H. Kato, M. I. Copeland, M. Krug

The investigation of the nickel - gadolinium phase diagram was undertaken to determine the alloying behavior of these two metals . The data from meltingpoint determinations , thermal analyses , metallographic examinations , and X- ray diffraction analyses revealed a phase diagram with three eutectic points and seven intermetallic compounds . Very limited solubility of the phases in each other was observed . The five phases , Ni Gd , Ni , Gd , Ni Gd , Ni, Gd , and NiGd¸ , melted incongruently at about 1,300 ° , 1,270 ° , 1,180 ° , 1,070 ° , and 775 ° C , respectively . Ni Gd and NiGd melted congruently at approximately 1,550 ° and 980 ° C , respectively . Four of the compounds were determined to crystallize in the hexagonal system : Ni Gd , Ni Gd , Ni , Gd , and Ni Gd . Ni Gd was determined to be cubic and NiGd , orthorhombic . The crystal system of NiGd was not determined . The eutectic points occurred at 13 , 67 , and 85 wt pct gadolinium , and the isotherms at 1,290 ° , 890 ° , and 700 ° C , respectively .

Jan 1, 1964

By D. Crone, T. Watts

"The Lindsley project was a program of deep drilling to test the contact down-dip from two nickel-copper deposits, one uneconomical and the other mined out. The role of Borehole Pulse EM(PEM) was to detect the higher grade, more massive sulphide zones if they were missed by a drillhole, and to help determine geometry if the zones were intersected. Two problems appeared as the PEM survey progressed: (1) conductivity-thickness as measured by the PEM did not always relate to economic sulphides as determined by the market; (2) a pattern of unusual PEM anomalies was obtained that indicated something odd and big, but the cause was unknown. A large fold structure subsequently was indicated by a program of deepening previous holes, the third of which intersected high-grade mineralization below 1280 m. Falconbridge is in the process of shaft sinking and underground exploration.IntroductionThe Falconbridge Lindsley property is on the south rim of the Sudbury basin, 8 Ian north of downtown Sudbury. The original property was acquired by a prospector named James Stobie, who, in early August 1885, staked a showing that later became the Mount Nickel mine (Fig. I). On August 10 Stobie staked another property that would become the Little Stobie mine, and at the end of the same month he staked the main Stobie orebody.In 1888, the ground immediately west of the MOlU1t Nickel find was staked. This ground contained the Blezard deposit (Fig. 1) which was put into production in 1889 and was eventually acquired by Inco. Down-dip from the Blezard workings, on Falconbridge ground, is located the upper Lindsley No. 1 deposit which was drilled off by Falconbridge in the 1940s to 1950s. A decision to go underground on the Lindsley No.1 mineralization was made in 1969, but the project was cancelled in 1971 because of declining nickel prices. The shaft was stopped at 95 m, and the headframe and hoist were sold. Further surface exploration drilling in the 1970s discovered the deeper Lindsley No. 2 zone, but as it had grades similar to those of the No. 1 zone, it too was considered uneconomic."

Jan 1, 1992

"An atmospheric process for the synthesis of scorodite(DMSP®)has beendeveloped,in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. Under optimum conditions, the synthesized scorodite (FeAsO4?2H2O) was well crystallizedand the crystals were faceted; the particle sizes were as large as 15 to 20 µm. In thisstudy, iron (II) sulfate heptahydrate (FeSO4·7H2O), arsenic (V) acid (60mass%H3AsO4) solution, and distilled water were used to prepare the original experimental solution (700 ml), in which the contents of Fe(II) and As(V) were 55.9 g/L and 50.0 g/L, respectively. The effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas injectionrate, temperature, and the initial pH of the solution, on the size and shape of the scorodite particles wereinvestigated. From the experimental results, the changes in the shape of the scorodite particles wereclarified for each synthesis condition.INTRODUCTIONDOWA has developed a processfor synthesizing well-crystallized scorodite (FeAsO4•2H2O). Theprocess is named andtrademarked as DMSP® (Fujita et al., 2008; Fujita et al., 2008; Fujita et al., 2009; Fujita et al., 2009; Fujita et al., 2009, Kubo et al., 2010). In this process, oxygen gas is injectedinto a sulfuric acid solution containing large amountsof As(V) and Fe(II). Facetedscorodite crystals as large as 15–20 µm weregeneratedthrough the pre-formation of a gel-like precursor. However, it is known that the synthesized scorodite particles become smaller and more aggregatedwhen the synthesis conditionsdeviate from the optimumconditions.In this study, the effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas flowrate, temperature, and initial pH of the solution, on the size and shape of the scorodite particles were investigated. The experimental resultsclarified the changes in the shape of the scorodite particles for each synthesis condition."

Jan 1, 2016

The variety and sources of sampling errors have been studied since the late 1800s, but the pioneering work of Pierre Gy in the 1950s provided insights into sampling as an error generating process. Total sampling variance is a measure of the total sampling error, but disaggregating the variance into its component parts is problematical. Ten sources of error and error generating processes have been identified, some of which can be eliminated through rigorous application of the principle of correct sampling. Others can only be minimized but never eliminated. Three principal questions relating to the appropriate mass of a sample, the fragment size of the sample and the size of the associated error are addressed. These questions relate principally to the Fundamental Error (FE), the only error that can be estimated before the sampling event. Aspects of constitutional and distributional heterogeneity are examined, as are the essential components of Gy?s formula including the shape factor (?), the granulometric factor (g), the mineralogical composition factor (c), and the liberation factor, l. Applications of Gy?s equation to the problems of sampling in the minerals industry are explained using real-life examples. The approach to sampling taken by Pierre Gy provides an excellent inferential relationship between the mass of material to be sampled, the size of the fragments being sampled, and the relative variance of the sampling error. It also provides solutions for three of the main problems associated with the Theory of Sampling.

Jan 1, 2007

By Ana Luiza Chaves de Oliveira

Com o avanço do conceito de sustentabilidade e as novas legislações ambientais, percebemos um crescente aumento da responsabilidade ambiental. As empresas cada vez mais investem em coletas seletivas, tratamento dos resíduos, etc., buscando minimizar os impactos ambientais, preservar os recursos naturais e assegurar a sustentabilidade. Tendo como objetivo apresentar uma solução integrada para a reciclagem e reaproveitamento dos resíduos refratários após o uso. Este trabalho propôs a produção de três classes de argamassas secas e úmidas através da utilização de reciclados. Foram realizadas quatro etapas (identificação visual das matérias-primas, cominuição, formulação/produção e acompanhamento durante a estocagem). Procurando avaliar o potencial dos reciclados o acompanhamento será realizado através da variação reológica e da determinação da força ligante após a fabricação e durante a estocagem (período de 12 meses). Os resultados evidenciaram que há potencial de reaproveitamento dos reciclados tanto na produção de argamassas secas e quanto úmidas sem que ocorra perda de suas propriedades reológicas, químicas e termo-mecânicas.

Aug 17, 2017

By Léo Daiki Shinomiya

O planejamento de cenários é uma ferramenta empregada como um mecanismo competitivo que entrega uma visão para um futuro passível de acontecer, baseado em fatos atuais e históricos. Adaptado para ser aplicado a resíduos industriais, este método de planejamento de cenários pode ser descrito em oito etapas. Neste trabalho é apresentada a 1ª etapa, que mostra o uso de pesos e critérios para definir as aplicações mais adequadas para a Lama Vermelha a partir de uma infraestrutura disponível localmente. A Lama Vermelha é gerada em larga escala pela indústria do Alumínio, somente no estado do Pará são gerados 5,4 milhões de toneladas anualmente, que impacta diretamente nos custos desta indústria em função de seu tratamento e estocagem. Os resultados guiam definições para as aplicações mais adequadas para a Lama vermelha, sendo destacado o emprego na fabricação de cerâmica vermelha e na produção do cimento.

Aug 17, 2017

By Otto W. Nuttli

THE magnetic method of prospecting is well suited to determination of faulting in the basement rock. In addition to establishing the horizontal position of the fault, it often furnishes valuable information concerning the depth and amount of faulting. Consider a simple case of a vertical fault, represented in cross-section in Fig. 1. Let A A' represent the plane of observation (ordinarily the surface of the earth), and BB'B"B"' the upper surface of the basement. Assume that the sedimentary rocks are nonmagnetic, so that the magnetic susceptibility of the material above the basement is zero. Let k indicate the susceptibility of the basement rock, c the density contrast between it and the neighboring sedimentary rocks, and the amount of vertical displacement. Fig. 1 shows the material, indicated by cross- hatching, which gives rise to the magnetic anomaly. In most cases it can be assumed that is small compared to the thickness of the sedimentary rocks. The semi-infinite, rectangular slab of rock of susceptibility k, density contrast , and thickness t may then be replaced by a semi-infinite sheet CC' of mass t per unit area at depth 2 (the mean depth of the slab). Nettleton 1 states that this approximation results in an error of less than 2 pct for the computed gravitational field intensity when t is as great as 2/2 and decreases rapidly for smaller values of t. By a theorem of Poisson, the magnetic field intensity can be determined readily from the gravitational field. The theorem states that W = (I/) • (U/i) i1 [1] where W is the magnetic potential associated with the structure, I is the intensity of magnetization which is assumed to have the direction of the inducing field, ? is the constant of gravitation, the density contrast, U the gravitational potential associated with the structure, i the direction of the inducing magnetic field, and i1 a unit vector in that direction. The multiplication indicated in Eq. 1 is

Jan 1, 1956

By Sidney Katell

Covering the period from January 1961 through December 1961, this report is a continuation of the series that began with the publication of Information Circular 7516 in October 1949. It is also the third report in the series to be prepared as a cooperative effort by the Bureau of Mines and the American Association of Cost Engineers. The cooperative agreement between the two groups provides for the publication of an annual cost bibliography with the work load involved in the preparation shared equally. The abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related facilities, came from the following sources: 1. A.A.C.E. Bulletin. 2. Bureau of Mines Information Circulars. 3. Bureau of Mines Reports of Investigation. 4. Chemical Engineering. 5. Chemical Engineering Progress. 6. Chemical Week. 7. Coal Age. 8. Coal Utilization. 9. Cost Engineering. 10. Industrial and Engineering Chemistry. 11. Nucleonics 12. Oil and Gas Journal. 13. Petroleum Engineer for Management. 14. Petroleum Refiner. 15. World Oil.

Jan 1, 1962

By R. Benito

This paper describes the development of a life-of-mine schedule (LOM) for one of the world's largest known sedimentary copper-cobalt districts located in the Katanga Province, Democratic Republic of Congo (DRC). A particular feature of the Tenke Fungurume LOM schedule is the considerable number of pits/phases for scheduling, each competing to provide the best ore available to a capacity-constrained process facility. This paper discusses the LOM scheduling objectives and constraints, data preprocessing steps such as ore binning, block aggregation and clustering analysis as a scheduling aid, the mine scheduling approach and results and conclusions. Mining Engineering, 2011, Vol. 63, No. 8, pp. 39-47. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By Tignor E. M.

The Brenneman oil field in Grant District, Hancock County, W. VA., was selected for study by Bureau of Mines engineers because it was typical of many of the smaller petroleum reservoirs in the Appalachian region. In 1906, E. W. Marland & Co. discovered the Brenneman field by drilling a well that readied the oil-bearing .Berea sandstone at a depth of 750 feet and initially produced 200 barrels of oil a day. Most of the oil-productive area (348 acres) of the field was developed in a comparatively short time, and the initial daily production rates of some of the wells were as high as 1,000 barrels of oil a day. Although the field was a prolific producer of oil for several years, it was abandoned in 1923 when the production rate was less than 1,000 barrels of oil a year and 705,000 barrels of oil had been produced. Secondary-recovery operations were started in the Brenneman field in 1927 after useable old wells had been repaired and unsatisfactory wells had been plugged; drilling of new wells was started in 1929. The peak of the redevelopment program was reached in 1942 when 92 oil-producing wells and 26 injection wells were in use; both air And mixtures of air and natural gas were used for injection purposes. It is estimated that approximately 357,000 barrels of oil, equivalent to 1,030 barrels per acre, 105 barrels per acre-foot, 8.5 percent of the total pore volume, or 11.9 percent of the original oil in place will be produced as a result of gas-injection secondary-recovery operations. Engineers of the Bureau of Mines Petroleum Field Office, Franklin, Pa., are studying secondary-recovery projects in the Appalachian region as a part, of the Bureau's secondary recovery research and are reporting these studies so that others: can profit by the experience gained from the operations. In common with most of the other Appalachian oil fields, there was no natural water drive in the Brenneman field. The estimated oil saturation in the Brenneman reservoir at the end of economic gas-injection operation indicates that additional oil might be recovered economically by water flooding and that a pilot flood would be warranted.

Jan 1, 1950

Flotation Research on Cassiterite of Tailings

Sep 13, 2010

By A K. Bhatnagar, S Saha, P Dixit, A K. Mukherjee, P Patra

TATA Steel’s R&D Division at Jamshedpur has developed a slime beneficiation process to recover iron values from iron ore slime. This process recovers iron ore concentrate containing 2.2 per cent alumina from a feed containing 7–10 per cent alumina. The reject generated from beneficiation of iron ore slime is treated as waste as the iron content in the reject is below 45 per cent. Effective utilisation of this waste is required for making the iron ore slime beneficiation process a zero-waste technology. In this connection several studies were made towards utilisation of slime waste. One of these studies revealed that slime waste can be used as a soil conditioner. Slime waste contains particles of size less than 10 micron and when these particles are mixed with soil in definite proportions, the porosity and the permeability of the mixture goes down. As a result, the water holding capacity (WHC) improves. This concept was evaluated through a series of tests at greenhouse level to optimise the soil to slime ratio. Finally, a pilot scale field trial was carried out over a period of three months using paddy rice as the crop. Three separate plots with compositions of: soil + organic matter comprising Farmyard Manure (FYM), (ii) soil and slime waste (2:1) + organic matter (FYM), and (iii) soil and slime waste (2:1) + organic matter (FYM) + Nitrogen, Phosphorus and Potassium (NPK) fertiliser were used for the pilot trial. The results showed a 20 per cent increase in the productivity of paddy rice for plot (ii) as compared to plot (i). This was due to the beneficial effect of slime waste in the soil. The addition of inorganic fertiliser such as NPK in the ratio of (4:2:1) further enhanced the productivity of paddy rice.

Sep 18, 2023

By R. D. Brown

This Bureau of Mines report describes a new methodology for identifying and sorting scrap metals using two modern portable instruments: a thermoelectric sorter and a hand-held emission spectroscope. The method, tested on a 27-sample stainless steel and superalloy array, makes it possible to group and/or identify a typical mixture of high-value metal scrap in two or three steps, whereas as many as seven or eight steps are needed to perform the same separations using chemical spot tests. A portable fluorescent X-ray analyzer identified 19 of the 27 alloys in the sample array by name or type; these alloys are included in the microprocessor memory. The remaining alloys were identified by using the analyzer in its elemental analysis mode and comparing the results wit.h alloy specification chemistry.

Jan 1, 1984