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By A L. Withy

This paper is intended as a review from a planner's viewpoint, of the relationship between town and country planning, a primarily government activity, and the minerals industry, which, with the exception of coal, is a largely private enterprise activity. The paper first considers the nature of the system of planning in New Zealand, and the objectives sought by planners in relation to minerals are discussed. The reasons why these objectives are not generally being achieved are investigated. A final section deals with the gap between objectives and achievement, and suggests a number of ways in which this gap may be narrowed.

Jan 1, 1976

The following data cover a phase in the systematic testing of gold deposits which does not appear to have been specificalIy investigated.In boring either secondary or primary deposits, gold, by virtue of its high specific gravity, will tend to migrate downward, below the driving shoe or bit, and thus cause misinterpretation of value unless final recovery Can be effected after the hole has been bottomed.Unlike fortuitous and non-recurrent errors, due to, say, running ground, "pile driving" or rock fractures, systematic error due to migration may be unpredict.able from operating data alone, and, therefore, result in serious miscalculation of the weighted average upon which the engineer's recommendation is based.Applied to diamond drilling, loss by downward migration appears to have been largely responsible for distrust of sludge assays in the past. On the other hand, although modern practice rightly trends towards an integration of both core and sludge samples in borehole valuation, the possibility of systematic loss must be investigated when using combination graphs such as those of Longyear, Moehlman and WeIler. If the sludge value is incorrect the combination graphs will serve solely to stultify the core valuation.It appears to be axiomatic that: 1. With full core, sludge assays are of minor import.2. With recovery above 90%, differentjal grinding, of the high grade sections may have occurred, and this c!ln be corrected only by the us.e of cOJ;rect sludge valuation.3. With core recovery less than, say, 70%, no accurate valuation is possible without integrating the sludge assay.4. With less than, say, 10% core recovery, the sludge assay affords the sole basis of evaluating a borehole which may have cost many hundreds of pounds.The conditions demanded for reliable sludge valuation have, in practice, been restricted to high quantitative recovery and return of nearly 90% of the drill water. It is submitted, however, that the following additional knowledge is required:1. The nature of gold distribution in the ore.2. The lifting power of the return water column, which can be gauged by the maximum quartz particle, provided that the degree of "hindrance" can be determined.3. That all gold has been cleared from the bottom of the borehole immediately after it has passed through the orebody.The three cases discussed hereunder are offered not only as proof of the thesis, but also in the hope of promoting discussion on the interpretation of borehole values and on methods for saving free gold in the sludge. The fact that two of them cover alluvial boringand the third diamond drilling has resulted in this attempt to reduce the behaviour of free gold to a basis common to all types of boring.

Jan 1, 1950

By Flavio Rojos-Tapia, Oscar Pereira-Cerda, Samuel Sánchez-Pino, Samuel Sánchez-Baquedano

"Pneumatic flotation was introduced to the Chilean Copper Mining Industry in 1993 by Ingeniería de Minerales S.A. (IDM). The technology is based on the designs of Dr. Rainer Imhof from Germany, who is the designer of several different types of pneumatic flotation cells, already sold through his Company Maelgwyn Mineral Service Limited (MMH). The company is represented by Ingenieria de Minerales S.A. (IDM) in South America.Pneumatic flotation, has been used in tough industrial applications .It has been successfully used for metallic ores such as copper sulphide and oxide minerals, copper slag, silica and silicates from iron magnetic preconcentrate (reverse flotation) and gold. It has also provided promising results when applied to molybdenum flotation. The latest applications, with ultrafine molybdenum particles in operating plants, is showing the V and G Cell (end model designed) as a real technological alternative to conventional flotation., The G Cell is an extremely high speed flotation machine with high selectivity which introduces the possibility of producing a final molybdenum concentrate with only one stage of cleaning. This is a completely new development in molybdenum flotation in the industrial circuit which has the potential to dramatically reduce the circulating load in the cleaning circuit. As a consequence the capital costs of future Molybdenum plants may also be reduced. The suitability of the G Cell will have to be determined on a case by case basis but it provides the metallurgist with an alternate flowsheet for consideration.The good performance of the G Cell can be explained by the high gas hold-up and very effective micro-turbulence which helps improve the attachment of solid particles to the bubbles. This technology may change our traditional concept of residence time in flotation. Additionally, the rotation phenomena introduced in the vessel of the G Cell ,creates radial separation forces which are critical to achieving a more rapid separation of the target minerals from the tailing. This results in a much reduced residence time requirement in the flotation machine. Some benefits associated with the use of the new G Cell are: less energy consumption, less maintenance costs, simple and reliable circuit to operate and a small area required for installing the circuits.As a result of the industrial experience in the Chile, the pneumatic flotation type G Cell can be regarded as a technology which must be considered as a replacement technology for the rougher and cleaner stages for fine particle flotation."

Jan 1, 2008

By N. Z. Fotoyi

Keywords: MgO-MgR2O3 refractory, SO2-containing gases, chemical attack The reaction mechanisms occurring when MgO-MgR2O3 refractories are exposed to SO2-containing gas atmospheres were examined. The study examined the characteristic structures of magnesite-chrome, chrome-magnesite and magnesite refractories exposed to SO2-O2 gas mixture at temperatures of 700°C to 1350°C. The phase characterization was conducted with scanning electron microscopy (SEM) and powder X-ray diffractometry (XRD). The results show that the physical characteristics of the refractory matrix along the grain boundaries are important refractory features during chemical attack from SO2-containing gas. Upon heating in SO2-containing gas, the changes in phase-chemical compositions and accompanying grain growth causes loosening of the structure and the pore volume promotes gas diffusion. The chemical reactions that occur form stable sulfate compounds identified as MgSO4, CaSO4 and CaMg3(SO4)4, and lead to disintegration of various phase structures and consequently erosion of the refractory. In conclusion, the reaction mechanisms in MgO-MgR2O3 refractories exposed to SO2-containing gases progress through a combination of structural disintegration and chemical attack.

Jan 1, 2011

By Mark Tsirlin

Kinetics of the initial oxidation stages of diffusive silicide coatings on 8 molybdenum and niobium at 1100 - 1700 and under the pressure of 400 and 1330 Pa has been studied using methods of gravimetry and gas phase analysis of oxygen, as well as by SEK, XRD and EDMA methods. The first oxidation stage described by asymptotic equation in case of NbSi coating changed over to the stage described by parabolic equation. The asymptotic law was shown to depend on non - stationary conditions on the oxide layer boundaries. Interconnection between silicides and quartz structures, on the one hand, and peculiarities of oxidation kinetics, on the other, is [discussed. The possibility of estimation oxygen atom jump frequency in quartz and fractions of oxygen reacting with metal and with silicon proceeding from the analysis of the kinetic data was ascertained. Conditions of oxidation kine- tics transfer from asymptotic (or parabolic) stage to a non - protective "linear" stage, associated with volatile ~roduct formation, are also discussed.

Jan 1, 1995

By Gerhard Derge, J. Warren Stewart

Extrusion processes are used in the commercial production of a wide variety of products, as indicated by the review presented a few years ago by D. K. Crampton.' Most writers have confined themselves to a general description of the equipment and products and the engineering aspects of the process. The few studies that have dealt with the metallurgical side of extrusion have been concerned primarily with an examination of the mode of flow of the metal during extrusion. This has been accomplished by the use of composite billets, by scribing grids on symmetrical sections of billets and observing the change of dimensions in the gridwork, or by examining microstructures in extruded sections.2"8 Ariotlier limitation of these original studies is that they were confined to the extrusion of very simple shapes, usually rods having a diameter of about one-fourth that of the billet. Tin is particularly well suited to the extrusion of collapsible tubes and similar shapes in which the extruded section is very small in comparison to the diameter of the billet or slug. In modern production, impact extrusion methods are generally employed, therefore the thickness of the slug is small compared to its diameter. Under these conditions the process differs considerably from the processes that have been most fully described in the literature, and it is known that the quality of the product is very sensitive to slight variations in any one of the many variable factors involved, such as coinposition and structure of the alloy, rate of extrusion, temperature, shape of punch and die. An exhaustive examination of all of the above-mentioned problems promises to produce so many data that it seems advisable to initiate the reports at this time, even though all of the factors outlined have not been examined fully, and to confine this paper to a description of the apparatus and method. Only tin and its alloys with small amounts of copper have been considered. These are the alloys most commonly used in this country for the production of the type of articles already described.

Jan 1, 1940

By Gerhard Derge, J. Warren Stewart

Extrusion processes are used in the commercial production of a wide variety of products, as indicated by the review presented a few years ago by D. K. Crampton.' Most writers have confined themselves to a general description of the equipment and products and the engineering aspects of the process. The few studies that have dealt with the metallurgical side of extrusion have been concerned primarily with an examination of the mode of flow of the metal during extrusion. This has been accomplished by the use of composite billets, by scribing grids on symmetrical sections of billets and observing the change of dimensions in the gridwork, or by examining microstructures in extruded sections.2"8 Ariotlier limitation of these original studies is that they were confined to the extrusion of very simple shapes, usually rods having a diameter of about one-fourth that of the billet. Tin is particularly well suited to the extrusion of collapsible tubes and similar shapes in which the extruded section is very small in comparison to the diameter of the billet or slug. In modern production, impact extrusion methods are generally employed, therefore the thickness of the slug is small compared to its diameter. Under these conditions the process differs considerably from the processes that have been most fully described in the literature, and it is known that the quality of the product is very sensitive to slight variations in any one of the many variable factors involved, such as coinposition and structure of the alloy, rate of extrusion, temperature, shape of punch and die. An exhaustive examination of all of the above-mentioned problems promises to produce so many data that it seems advisable to initiate the reports at this time, even though all of the factors outlined have not been examined fully, and to confine this paper to a description of the apparatus and method. Only tin and its alloys with small amounts of copper have been considered. These are the alloys most commonly used in this country for the production of the type of articles already described.

Jan 1, 1940

By A. J. Petrina

"At Craigmont Mines Limited, Merritt, B.C., tests were begun in March, 1965 to evaluate the use of shotcrete as a method of ground support m development headings; previously, ail drifts had. required support, which was accomplished mainly by timber and occasionally by the use of rockbolts. The tests demonstrated conclusively the effectiveness of shotcrete for supporting Craigmont's ground. Gradually, the use of timber for ground support was virtually eliminated in favour of shotcrete. This paper describes the equipment used, the operation of the equipment, pertinent cast data and opera ting details. Also discussed are other uses developed for the shot-creting equipment, the use of reinforcing bar rockbolts, and a method used at Craigmont for lining long vertical ore passes with steel plate and concrete as part of the raising cycle."

Jan 1, 1968

A comprehensive review of ore pass records, from ten Quebec underground mines, indicated some of the limitations of available design tools to predict the occurrence of ore pass interlocking hang-ups in metal mines. The Distinct Element Method was used to perform a series of numerical experiments in order to investigate the influence of ore pass geometry, rock fragments shape and size distribution on material flow in an ore pass. Guidelines have been developed to help limit the occurrence of interlocking hang-ups in an ore pass. The proposed guidelines were evaluated with respect to field observations. Ein kompletter Bericht der Erzrollezeichnungen, von 10 Quebec unterirdischen Gruben, hat einige der Beschränkungen der vorhandenen Designwerkzeuge angezeigt, um das Auftreten Erzrolle der blockierenhang-ups in den Metallgruben genau vorauszusagen. Eine Reihe numerische Experimente mit der eindeutigen Element-Methode, wurden aufgenommen, um den Einfluss von Erzrollegeometrie, Partikelform nachzuforschen und Felsenkorngrößenverteilungen auf Materialfluss in ein Erz überschreiten. Dieses hat zu die Entwicklung der Richtlinien geführt deren Implementierung das Auftreten der blockierenhang-ups in eine Erzrolle begrenzen sollte. Die vorgeschlagenen Richtlinien wurden in Bezug auf Labor- und Feldbeobachtungen ausgewertet. Une revue de la performance actuelle des cheminées à minerai dans 10 mines souterraines du Québec a indiqué les limites des outils de conception servant à dimensionner les cheminées pour minimiser le nombre d’accrochages par enchevêtrement rocheux. Des séries de modélisations numériques, utilisant la méthode des éléments distincts, ont été réalisées afin d’évaluer l’influence de la géométrie des cheminées, de la forme des fragments rocheux et de la distribution granulométrique sur l’écoulement du matériel dans les cheminées. Cet exercice a permis de développer des lignes directrices pour le dimensionnement des cheminées afin de limiter l’occurrence d’accrochage par enchevêtrement rocheux. Les lignes directrices proposées ont été évaluées en fonction des observations effectuées sur le terrain.

Jan 1, 2003

By F. Halverson

"The theory of flocculation usually is in a state of flux, involves many diverse phenomena, and is complex and sometimes contradictory in details. Instead of attempting a general discourse, I shall discuss selected observations made at our Stamford Laboratories, which impinge on theoretical aspects in two somewhat distinct areas of flocculation. Since some of you many not be familiar with flocculation, and :.n order that we all attach the same meaning to the jargon used, I first would like to review briefly a generalized picture of what goes on.Assume we have a suspension of particles in water, with a distribution in the sizes of particles. The surfaces of the particles interact to some extent with the water--· tending to alter the extent of hydration, may generate some ion exchange, all being somewhat variable with time--developing a surface condition which is very complex in details. We refer to this suspension as the ""substrate.""In the usual situation, if the suspension is allowed to stand quietly, the large particles settle out first, with somewhat smaller particles settling more slowly, and then there is a portion of very fine material which takes a long time or doesn't settle out at all. This resistance to settling t~ the very fine particles results from many factors, but all relate back to the size and density of the particles, to their surface properties, and to the other components in the aqueous suspending medium."

Jan 1, 1978

By Larissa Gomes Simão

Compósitos à base de diboreto de titânio (TiB2) e nitreto de alumínio (AlN) vêm demonstrando propriedades interessantes quando comparados aos seus materiais de origem. Um exemplo é a melhor relação entre resistência mecânica e tenacidade. Propriedades como dureza a quente e tenacidade à fratura são de extrema relevância para a análise de compósitos cerâmicos destinados a aplicações termomecânicas. No entanto, para determiná-las com confiabilidade há a necessidade de uma superfície rigorosamente preparada. Tal preparação torna-se extremamente dispendiosa pelas técnicas metalográficas convencionais. O presente trabalho tem como objetivo registrar uma rota de preparação que viabilize uma superfície livre de irregularidades e resquícios oriundos do processo de sinterização. Possibilitando, desta forma, a realização de ensaios de dureza Vickers e tenacidade à fratura com maior confiabilidade, e ainda, uma análise microestrutural que revele características da matriz e fase dispersa presentes no compósito.

Aug 16, 2017

By L. F. Elkins

Water coming into wells with bottom water present in the Fosterton field, when their oil recovery was only 0.1 to 1.5 per cent of oil in place below the lowest perforation, confirms lack of shale barriers to vertical flow which also are not apparent in cores and electric logy. Low contrast of vertical and horizontal permeability, high mobility ratio betweerz oil and water zone and pos.rible rate effects due to gravity Combine to prevent easy analysis of water invasion pattern and efficiency by analogy or intuition. Theoretical analysis of performance including these factors using a new direct nurnerical .solution of potential distribution in a network led to unanticapted indications that water would under-run the entire oil reservoir with low volumetric coverage if supplied through natural influx or peripheral water injecfion below the oil-water contact. An unusual pattern of water injection is to he adopted in this recently unitized pool to provide more uniform water flooding in that two-thirds of the oil reservoir not underlain by bottom wafer. INTRODUCTION The Fosterton field, Southwestern Saskatchewan, Canada, was discovered in Jan., 1952. It produces at a depth of 3,100 ft from a pinch-out of the Roseray sand at the Lower Cretaceous-Jurassic unconformity. The field, covering 2,500 acres, contains 54 wells on 40-acre spacing. Development was essentially complete in June, 1954, but significant production did not start until May, 1955, when a pipeline outlet became available. Within one year rapid in- creases in gas-oil ratio and early encroachment of water created operating problems in the down-structure eastern half of the field and raised serious questions about reservoir performance and ultimate recovery. This paper describes the unusual behavior of water encroachment—on both well and reservoir bases—and the analyses made to interpret it. The field was unitized July 1, 1958, for water flooding. A somewhat unconventional

Fire-clay blocks lining the combustion chambers of zinc concentrate flash-roasting, furnaces operating at 1,000-1,200° C. have suffered moderately rapid deterioration due to slagging. The attack is accentuated by high temperatures, and is probably caused by lead oxide volatilized from the roasted concentrate.Resistance of refractories to attack increased with increasing alumina content from 30 to 45 per. cent but at 90 per cent alumina spalling was troublesome. Magnesite bricks were'subject to some spalling, but some types may lie satisfactory. Chrome and chrome-magnesite bricks spalled seriously.Material thought to be suitable for use as a monolithic lining slagged badly and an alternative may be tested.INTRODUCTIONThe Electrolytic Zinc Company of Australasia Ltd. uses two multi-hearth furnaces and four flash or suspension roasting furnaces for the roasting .of zinc concentrates at its Risdon Works. The hearth roasting plant has been described previously by Forster (1949).A brief descriptioI1 of the first three flash roasters was given by Gordon and Forster (1955). A fourth flash roasting furnace began operation early in 1957. This furnace is somewhat larger than the earlier furnaces, and the designed capacity is also higher, auxiliary equipment being altered to suit. An important structural difference between the older furnaces and the fourth flash roaster is that the walls of the combustion chamber of the new furnace are lined with high alumina fire-bricks instead of fire-clay blocks. Thischange was made because the fire-clay blocks in the older flash roasters had shown s-evere wastage due to slagging by lead derived from the concentrate.

Jan 1, 1959

By Stephen A. Gasiorowski, Frank J. Hrach, James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity - up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonne of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle-particle contact. The small gap, high electric field, counter-current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Jan 1, 2012

By Antal Partos

ATLAS Processing Company Shrevesport, LA initiated a major plant expansion in 1980. SITE Engineers, Inc. provided engineering consultation regarding the foundation of the vacuum unit. Four test borings were drilled and laboratory testing completed for shear strength and compressibility. Vertical drains were proposed to accelerate time rates of settlements. Steel erection was completed by May 22, 1981 with very small < 0.1 in., settlements. Hydrotesting was initiated on July 9, 1981 and completed on August 27, 1981. An average rebound of 0.3 in. was computed resulting into an average net settlement of 0.5 in. This paper describes in detail soil behavior during load testing.

Jan 1, 1992

By C Vuillier, A Roshdieh

Water is the main medium for removing impurities from iron ore during wet processing to achieve a higher quality product. However, there is a substantial increase in freshwater consumption due to an increase in demand from the following two factors: in the past 55 years the world population has doubled from 3 to 7.5 billion and crude steel production has increased five times from approximately 350 to 1662 Mt/a (IISI, 2008). Furthermore, social development in developing countries exacerbates water consumption making freshwater an increasingly valuable resource with an average distribution of 70 per cent for agriculture, 20 per cent for industry and only ten per cent for domestic consumption (Hourtolle, 2005; OECD, 2009). Rapidly changing regulations over the access and preservation of water across the world indicates the growing importance of this issue, so the mining industry must adapt to this continual change and must be committed to increasing the efficiency of water usage.Tailings dams receive most of the water used by the process plant. In arid regions where evaporation is high and availability of water low or non-existent, technical solutions other than the conventional tailings dam, such as thickened and/or filtered tailings, exist to optimise the recovery of water and reduce the need for external water consumption. However, these solutions present additional challenges, such as energy consumption and transportation from the process plant to the ultimate storage area.This paper considers a range of alternatives covering thickening and filtering, transportation and storage, water return, closure and rehabilitation. Mining projects in the future will be more affected by the rising cost in water and tighter regulations in accessing water and energy. Good tailings management can contribute significantly to reducing the dependence on these two key commodities (water and electricity), improving the resilience of iron ore projects especially in arid regions and areas with high competition for water.CITATION:Vuillier, C and A Roshdieh, A, 2017. Minimising the water loss associated with mine tailings disposal, in Proceedings Iron Ore 2017, pp 245–250 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Theodore R. Maynard

The history of foundation engineering in Chicago is a tale of innovation, made necessary in order to keep pace with structural technology which allowed taller buildings with heavier bearing loads, to accommodate a non-conducive geologic setting. The geology as it relates to foundation construction and underground construction in general is briefly described. A chronology of important events from the birth of Chicago to the present is presented. The impact of various construction techniques which were either initiated or refined to allow the growth of Chicago are discussed. Introduction The growth of Chicago resulting in today&apos;s high-rise high-density population center can be looked upon as a history of modern underground construction. The two major reasons which explain this are 1) It grew up during a period of rapid development in the Industrial Revolution and 2) Its natural geological setting needed a great deal of innovation for continuing growth.

Jan 1, 1991

By L. F. Albert

The paper describes solutions given to foundation problems during the reconstruction of a power plant set on fire, located adjacent to several still Working Units. After a detailed site and laboratory investigation, it was decided that it could be possible to include within the new foundations the preexisting cast in situ driven piles with enlarged base 50 cm in diameter and let them work with new 41 cm driven, cast in situ piles without enlarged base. Demolition of existing caps was carried out with expansive mortar in order to avoid any possible damage to piles, whose actual conditions were checked by several load tests. New piles were designed to support service load by shaft resistance, in order to limit total and differential settlement. When piles had to be driven adjacent to nearby structures, measurements of peak soil particles velocity were carried out while driving piles at decreasing distance from critical locations. By preboring most of the upper clay layer it was possible to reduce within safe limits for structures the induced vibrations.

Jan 1, 1989

By D. Steele, B. Ndlovu

"Adequate characterisation of clays is becoming increasingly important as operating mines move into areas of more complex ores. The processing therefore needs better mineralogical characterisation to identify problematic ores for better planning before issues arise. While a number of instrumental mineral characterisation methods are available, X-ray Diffraction (XRD) is widely recognised as perhaps the best technique for the identification and quantification of minerals, particularly clays. When an appropriate sequential and systematic sample preparation and treatment protocol is employed with instrumental XRD analysis individual clays can be uniquely identified, and the proportions of interstratified clays can also be quantified. The effect of sample preparation on the XRD analysis and identification of clays was investigated in this study. The results showed that sample preparation protocol is indeed critical to accurately analysis and characterisation of clays. For example, both dry grinding and micronizing affected the degree of crystallinity of kaolinite leading to the formation of reactive surfaces or changes in the physicochemical behavior. It was also found that the apparent degree of preferred orientation in platy minerals correlates directly with the amount of force/pressure applied during the preparation of backfilled powder samples. This work showed that manual preparation can produce highly variable peak intensities especially with minerals that show any preferred orientation. KEYWORDS Clay; XRD; kaolinite INTRODUCTION Clays are important in our life and they have numerous applications in modern world from cosmetics to environmental remediation. Therefore, clays have been extensively investigated for many years. Adequate characterisation of clays is becoming increasingly important as the mineral processing industry faces more complex mineralogy with the need for better mineralogical characterisation to identify problematic ores and plan accordingly. In most studies, X-ray diffraction (XRD) method has shown the unique capability to characterise mineralogy, especially for the fine grained size materials. The XRD technique is particularly diagnostic for clays. It is known that under ideal conditions, the peak intensities of an XRD diffractogram are proportional to the concentrations of individual minerals present in the sample. Hence, the qualitative mineralogical data obtained from XRD can be quantified, using either the internal or external standard methods. However, it is also known that clays are particularly sensitive to the influences of sample preparation method due to their physical characteristics (e.g. fine grain size, morphology, relative physical softness, crystallinity, thermal sensitivity) that could be destroyed by inappropriate preparation prior to the analysis. Thermal and mechanical treatment and grinding of clays can change their crystalline structure, and consequently, their characterisation results by XRD analysis. The behaviour of clays in grinding has been widely studied, especially for kaolinite (Miller and Oulton, 1970, Milocevic et al., 1992, Tomasevic-Canovic et al., 1992). With prolonged grinding time, the crystallinity of the clays can decrease (Filipovic-Petrovic et al., 2002). It has been shown that grinding may gradually cause the loss of hydroxyl ions of kaolinite (Gonzalez Garcia et al., 1991)."

Jan 1, 2018

By D. DePaoli, P. Zhang

"Phosphate ore is one of the most significant secondary resources for rare earth elements (REEs), and Florida phosphate is of particular interest due to its much higher ratio of heavy REEs, especially yttrium. Analyses of numerous samples from different phosphate processing streams in Florida showed that heavy REEs account for about 50% of the total REEs in Florida phosphate with yttrium accounting for approximately 30%. It was estimated that the amount of yttrium from US phosphate processing could meet the world demand for this critical element. This research aimed at recovering both REEs and phosphorus from a phosphate flotation tails. This tails is composed of mainly silica and phosphate with a small fraction of heavy minerals including monazite and xenotime. Since the specific gravity of silica is 2.6 versus 3.2 for phosphate and 4.5-5 for rare earth minerals, pre-concentration of the minerals of interest by gravity separation was investigated first. A pilot scale shaking table was used in this study. One pass gravity concentration achieved a shaking table concentrate analyzing over 600 ppm REEs at about 40% recovery. Flotation of the shaking table concentrate resulted in a product containing 1809 ppm REEs and 26.37% P2O5 with corresponding recoveries of 73% and 82%. Sulfuric acid leaching at 75oC could recover over 60% REE and nearly all the P2O5. Higher REEs (>90%) recovery was achieved by conducting leaching at higher temperature with concentrated sulfuric acid. The phosphoric acid from leaching of the flotation concentrate is of superior quality compared with that generated from regular phosphate rock.INTRODUCTION Rare earths are a group of 17 elements including those of the lanthanum series, as well as the non-lanthanides, yttrium and scandium. These elements have very specific critical uses in a multitude of markets. For example, lanthanum is used as a catalyst in breaking down crude oil to produce gasoline, diesel and jet fuel and neodymium is the core magnetic component in high-strength magnets for electric car batteries, wind turbines and hard disk drives. Rare earths are also essential for many military applications. Many of these applications have no substitute materials and the move to green technologies has dramatically increased their demand."

Jan 1, 2018