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By M. J. Perpich

Electrochemical and chemical leaching tests were carried out on chalcocite, covellite and chalcopyrite in acidified iron sulfate solutions sparged with a mixture of O2 - SO2. The gas mixture catalyzed the ferrous to ferric oxidation reaction in situ and, therefore, increased the redox potential and oxidizing strength of the solution. Anodic polarization curves in dilute sulfuric acid on copper sulfide electrodes showed that chalcopyrite passivates and dissolves at current densities orders of magnitude less than chalcocite and covellite. The addition of a depassivating agent (Ag+) increased the passive current density of chalcopyrite and caused breakdown near 0.625 V (SCE). The depassivating effect was also observed during the leaching of chalcopyrite particulate samples as small amounts of Ag+ added to acidified iron sulfate solutions in the presence of O2 - SO2 mixtures greatly increased the leaching rate and the total amount of Cu oxidized (> 90%). Passivation was prevented in the absence of Ag+ by decreasing the initial oxidizing power of the solution and by pretreating the sample in a reductive leach. Both of these methods resulted in transformation of the chalcopyrite surface from its characteristic greenish-gold into deep black. Increased concentrations of Fe+++ due to 02 - S02 sparging were then able to oxidize the transformation product.

Jan 1, 1999

By J. E. Dutrizac

A mineralogical study of a weak acid leach residue from the Clarksville zinc plant of Savage Zinc Inc. was carried out. The study focused on Pb and Cd as these elements most significantly impact on the environmentally acceptable disposal of the residue. The residue consists of major amounts of bassanite, zinc ferrite and various Zn-Pb-Fe-Cd silicate species. Also present are lesser quantities of PbSO4, sphalerite, Fe2O3 quartz, Mn-Pb-Fe oxides, SrS04, (Pb,Sr)SO4 iron gel-silica gel, jarosite and Ti oxide. The principal Cd carriers are the zinc ferrite, which contains up to 9.00% Cd and likely accounts for -45% of the total Cd content of the residue, and the various silicate species which contain up to 6.97% Cd and account for about 45 % of the total Cd. The sphalerite is a minor Cd carrier containing an average of 0.35 % Cd and accounting for -5 % of the total Cd; the other carriers contribute only trace amounts to the total Cd content. The major Pb carriers are PbS04, Pb-bearing silicates and Mn-Pb-Fe oxides. Minor proportions of the total 1.09% Pb content of the residue are carried by SrS04 and (pb,Sr)S04' Trace Ph carriers include the iron gel-silica gel, Fe-Zn-AI oxide and bassanite. The residue after the toxicity characteristic leaching procedure (TCLP) is mineralogically very similar to the initial weak acid leach residue; the amounts of calcium sulphate are approximately the same in the two products. The principal Cd and Pb carriers are also the same as those noted in the initial residue, except that some dissolution and reprecipitation of Pb-Sr sulphate takes place. That the residue fails the TCLP test is likely a consequence of the superficial dissolution of Pb and Cd from species such as PbS04 or Zn-Pb-Fe-Cd silicate.

Jan 1, 1995

By Riyad N. Ahmad-Bitar, Shadia J. Lkhmayies

"CdSi-xTex thin films were prepared by first producing CdS:In thin films by the spray pyrolysis (SP) technique and then annealing the films in the presence of Te vapor in nitrogen atmosphere. X-Ray diffraction (XRD) measurements showed that the films are polycrystalline with the wurtzite structure. Transmittance measurements were recorded at room temperature in the wavelength range 400-900 nm and used to deduce the absorbance. The first derivative of the absorbance was calculated and used to find the values of the bandgap energy, where more than one bandgap was obtained for each film. These results show that the films are inhomogeneous or the composition differs with location. The photoluminescence (PL) was recorded at T = 60 K and a deconvolution peak fit was performed for each spectrum. The results of the PL spectra are consistent with those obtained from the first derivative and confirm the inhomogeneity of the films.IntroductionPolycrystalline thin film CdS/CdTe solar cells are promising candidates for low cost and high efficiency photovoltaic applications. The CdS/CdTe interface plays an active role and a detailed knowledge of its properties is crucial for thorough understanding of the device. High efficiency devices have been obtained in spite of the large lattice mismatch (9. 7%) between hexagonal CdS and cubic CdTe. Interdiffusion at the CdS/CdTe interface is considered to affect the performance of the devices [1]. The formation of a mixed crystal or a graded layer at the interface causes a reduction in the lattice mismatch at the CdS/CdTe junction [2] and then a reduction in the number of interfacial states and recombination centers, thus enhancing the solar cell performance [3, 4].The objective of this work is to investigate the transmittance, photoluminescence (PL) and structure of CdSi-xTex thin films prepared by annealing the spray-deposited CdS:In thin films in the presence of tellurium vapor. X-ray diffraction (XRD) was used for exploring the structure. Transmittance is used to deduce the absorbance where its first derivative was used to find the bandgap energy which varies with composition. The evolution of the PL spectra as functions of tellurium concentration was evident and it confirmed the inhomogeneities of the films."

Jan 1, 2011

By Leah Penner, Thomas J. Ruth, Paul Schaffer, François Benard, Edouard Asselin, Stefan K. Zeisler, Thomas J. Morley

"This paper details the electrodeposition of metallic molybdenum from an aqueous, acetateelectrolyte containing molybdate ions. The deposition is carried out in a highly concentrated (up to I 0 M) acetate bath in the presence of a very low concentration of bone glue (60 µg/L). The molybdenum metal deposits are up to 20 µm thick and adherent. The deposits were characterized by XRD and XPS analysis. The deposition process is very inefficient, as up to 99% of the current is used to generate hydrogen during electrolysis. The effect of acetate concentration, pH, additives and current on the deposition efficiency and physical properties of the molybdenum deposit were investigated and optimized to obtain smooth, adherent coatings.IntroductionMolybdenum has increased thermal and wear resistance properties that are often utilized in material coatings [I]. These coatings are most often manufactured by sintering, pressing or spraying molybdenum powder at elevated temperatures, as a substitute method for standard metallurgical practices, such as electroplating [2, 3]. The lack of reports describing molybdenum deposition is most likely due to the highly oxophilic nature of molybdenum and the stability of its oxides, especially in water. Previous attempts to electrochemically reduce molybdenum from molybdate (Mool·) ions to molybdenum metal have reported the production of either a poorly adherent mixed oxide [4-6], or a thin(< 0.1 µm) metallic film [7-9]. Thick metallic molybdenum is capable of being co-deposited with one of the iron-group metals (Ni [10], Co [11] and Fe [12]) to produce an alloy [13, 14]. These alloys, however, may not be suitable for applications requiring pure molybdenum as they usually contain less than 50% molybdenum (often less than 30%)."

Jan 1, 2012

By Jyri Talja, Shaolong Chen, Hannu Mansikkaviita

"Drying (water removal) prior to smelting is always economically feasible. Unnecessary heating of vapour can thus be eliminated resulting in savings of5-15 MUSD every year.Thermodynamically removal of one ton of water out of copper concentrate at 100 °C (with 10 % moisture) requires approximately 3150 MJ/tH2o, consisting of heating of the water (377 MJ), heating of the concentrate (509 MJ) and water evaporation (2260 MJ). This is quite independent of the selected drying technology. In reality some more heat is needed as higher temperature is practiced to enhance the drying performance and to reduce the equipment size.Major nominator in drying energy efficiency is amount of gases, which depends greatly on the drying technology. Dryers based on direct heating with fossil fuels have high gas flow rates, and thus they require additional energy of about 1400-1600 MJ/tH2o, compared to indirect modemsteam drying at 250-400 MJ/tH2o.Significant benefits in energy consumption (900-1300 MJ/tH2o) with additional potential for a bonus profit of 2-4 MUSD/y year, together with full elimination of some 40 000 tpy CO2 per mid-size dryer is available by selecting sustainable, energy efficient steam drying.IntroductionRemoval of water from the concentrate is very energy intensive thus having a significant environmental impact. However, drying prior to smelting is always economically feasible and very often viable also from the perspective of process operations. This environmental impact of drying can, however, be decreased or even fully eliminated with proper selection of the drying technology.Energy incorporated in drying consists always of a number of phases like liquid (water), solids (concentrate) and gases (water vapour, purging I dilution air, combustion gases). Each phase is heated to a specific temperature during the drying process.Heating of water, heating of the concentrate and water evaporation consumes more or less the same amount of energy despite of the drying technology (3150 MJ per ton of water). In conventional drying this amount of energy is achieved by combustion of fossil fuels wirg subsequent CO2 emission. Alternatively, chemical energy derived from sulphide smelting can be utilized in a form of steam thus generating zero emission ofCO2, in modem steam drying."

Jan 1, 2012

By G Hope, C Young, R. N. Gow

"The presence of enargite (Cu3AsS4) is problematic in gold processing as it is refractory, increasing cyanide and oxygen consumption, and enviromnentally hazardous. Selective leaching and treatment of the arsenic would prove advantageous to conventional gold leaching methods. The reactivity of enargite samples from Montana, US and Quiruvilca, Peru were studied under alkaline conditions, pH range of 8-13, using a cyclic voltammetry corrosion cell setup. Raman spectra of the surface were taken during and after cycling to compare surface species against theoretical predominance diagrams. Under slightly oxidizing conditions, covellite (CuS) peaks were found on the surface in a short matter of time, above - 200m V vs SHE for pH 9-13, suggesting arsenic leaching, but for longer conditioning times, elemental sulfur peaks were also found, which created a passivating surface layer. By operating above pH 12, under reducing conditions, ~-500mV vs SHE, arsenic can be leached as a thioarsenate (AsS4-xOx3-), without sulfur formation.IntroductionEnviromnental limitations on pyrometallurgical processing of arsenic has pushed the desire to process enargite-, Cu3AsS4, bearing concentrates towards a hydrometallurgical solution. Attempts to process can be broken down into two categories - the co-dissolution of arsenic and copper under acidic conditions or the selective leaching of arsenic under basic conditions. The selective leaching of arsenic would preferably leave behind a chalcocite, Cu2S, or covellite, CuS, phase that would be more amenable to conventional processing methods of the copper and gold industries. These methods employ bi- or poly-sulfides to leach arsenic as Assl· [1-4], hypochlorite leaching [5-7], ammoniacal leaching [8] or fine grinding to mechanically activate the enargite surface and increase normally slow reaction kinetics[9]. This study looked into the surface formations of an enargite electrode under alkaline conditions, in a pH range from 8-13, as it cycled from -1000 mV to 1000 mV vs SHE. The understanding of the formations and under what conditions they form will be helpful in further development of any of the aforementioned processes."

Jan 1, 2012

By Gaballah I.

Elimination of arsenic, mercury and zinc from synthetic solutions containing H;\A.sD4. HgCI2 and ZnCI2 using modified barks was investigated. The pH range was varied from ?1 to 10. The initial concentrations of individual element were 10,100 and 1000 ppm. More than 99 % of mercury and 65 % of zinc cations were removed by the modified bark .. In this case, the modified bark reacts as a cation exchanger leading to the release of &apos; two protons for every HgII or ZnII fixed by this material. About 30 % of arsenic was eliminated from the solution. This &apos;low efficiency could be attributed to? the presence of arsenic ,as. anion. Decontamination of a treated industrial effluent containing 4 ppm of ion? metals was performed on a pilot plant scale by the modified bll(k. More than 70&apos;% of these ion metals were eliminated.

Jan 1, 1995

By Suleyman Tekeli, Serdar Salman, Bulent Aktas

"The effect of La2O3 content up to 15 wt% on phase stability, sintering and microstructure of cubic zirconia (8YSZ) was investigated. XRD results showed that the specimens containing up to 15 wt% La2O3 were composed of only cubic structure. Also, the specimens doped up to 5 wt% La2O3 revealed no La2O3 peaks, indicating that La2O3 was completely solubilized in the cubic structure. However, when> 5 wt% La2O3 was added, the peak of La2Zr2O7 compound emerged, showing that the overdoped La2O3 was not solubilized in the 8YSZ matrix. The lattice parameter of the 8YSZ slightly decreased with the increasing La2O3 content up to 1 wt% but further increase in the La203 amount resulted in an increased lattice parameter. The comparison of grain size of the 8YSZ specimens with various La2O3 content showed that grain size slightly increased with the increasing La2O3 content up to 1 wt% but further increase in the La2O3 amount resulted in a decreased grain size.IntroductionAt atmospheric pressures, three polymorphic forms of Zr02 are stable at different temperatures i.e. monoclinic, tetragonal and cubic. A high-pressure orthorhombic form of Zr02 has also been reported[l]. The successful production of pure Zr02 bodies is not possible all the time due to the large volume expansion associated with the martensitic tetragonal-monoclinic transformation. This fact restricts the applications of zirconia, in spite of its excellent mechanical and thermal properties. However, the stabilization of the high temperature polymorphs at room temperature as stable phases is made possible by addition of suitable dopants. Fully stabilized cubic Zr02 and partially stabilized tetragonal Zr02 show interesting properties and are widely used as ionic conductors, coatings and gas sensors in solid oxide fuel cells and structural applications[2]. Most frequently used dopants include Y203, CaO, MgO and Ce02, although other oxides, such as those of rare earth elements, can also act as stabilizers of the high temperature structures. The incorporation of aliovalent cations to the lattice, forming substitutional solid solutions, allows to control the concentration of anionic vacancies in the structure. This aspect is particularly important in designing ionic conductors[3], and is also determinant in the stabilization process[ 4]. The process of stabilization with larger ionic radii dopants is rationalized by the crystal chemistry model[ 5], that describes the dopant cations as typical stabilizer when they have larger ionic size, lower charged state and higher ionicity than Zr4+ The ionic radius of Zr4+ is 0.84 Å and that for La3+ is 1.016 Å [6]."

Jan 1, 2012

By Songsong Wang

Recently, replacing Pierce-Smith converting process with the oxygen bottom-blowing continuous converting technology has become a new research focus. Based on the principle of Gibbs free energy minimization, the thermodynamic model of oxygen bottom-blowing continuous converting multiphase equilibrium system has been established. The elements distribution behavior is calculated at the same burden composition and operation parameters as the industrial production. The results show that the absolute errors of the mass fraction (wt%) of Cu, Fe, S, Pb, Zn, As, Sb, Bi in crude copper are 0.06, 0.0030, 0.070, 0.38, 0.39, 0.020, 0.017, 0.034, 0.010, respectively, and the absolute errors of the mass fraction (wt%) of Cu, Fe, S, Pb, Zn, As, Sb, Bi in slag are 0.53, 0.81, 0.020, 0.23, 2.5, 0.0048, 0.0010, 0.0030, 1.49, respectively. The calculated results agree well with the actual industrial production data, indicating that the model can be well applied in the oxygen bottom-blowing continuous converting practice.

By Norihisa Iida, Yutaka Koshiba, Tsutoipu Masui

"Mitsubishi Materials has many years of experience in the production of oxygen free copper (OFC) and its alloys with a fully continuous-casting process. Four grades of OFC, commercial, electronic, superconductor, and ASTM class I are available according to user needs such as stabilizer for superconductivity, magnetron, and ultra-vacuum systems. Along with Cu-Ag and CuSn, we offer OFC based copper alloys such ·as Cu-Cr-Zr, Cu-Fe-P, Cu-Ni-Si and others, that are suitable for lead frame and connectors. Within the maximum sizes of 260mm X 1050mm for cakes and 385mm diameter for billets, we are very flexible and can adjust the ingot size to customer’s requirements. Other products that we can supply are semi-finished products such as hot rolled sheet, ·forged blank, extruded rod and finished products like mold for continuous casting of steel, ring mold for non-ferrous casting and backing plate for sputtering target.IntroductionMitsubishi Materials Corporation developed mass produced high quality oxygen free copper and. high copper alloy ingots in the 1960's. We produce 60,000 - 70,000 tons annually giving us 22 - 23% share of the world's market.Our oxygen free copper and. copper alloys are produced with a fully continuous casting process using only high-grade copper cathodes from our Naoshima and Onahama refineries. The raw material is melted and cast in' a carefully controlled atmosphere resulting in a product with low impurities and excellent properties.Using a controlled atmosphere it is possible to produce high quality copper alloys including active elements like chromium (Cr), zirconium (Zr), titanium (Ti), and magnesium (Mg) which are difficult to produce using standard batch casting methods.Using our own cakes and ·billets we produce and supply worldwide wrought materials like molds for ferrous and non-femous casting. These products receive special patented thermo-mechanical· treatments resulting in high strength and excellent conductivity with low cost."

Jan 1, 2000

By Jingbo Liu, Zhimin Wang, Wenchao Li

"IntroductionThe advantages of non-stoichiometric perovskite material are highlighted in many papers[l]and many of this family of materials are well-suited to integration into microsensor devices. Among them, barium titanate is the most promising due to it's piezoelectric, pyroelectric, dielectric properties. Through modification, BaTiO3-based materials can be utilized in many kinds fields, such as surface wave probe; pholoconducting devices, field-effect transistor, permanent memory permanent storage, and ultrasonic transducerl2-3l. In this Paper, a series of BaTiO3-based polycrystals were synthesized by sol-gel processing which appears to be a very promising method for the manufacture of ceramic, because it offers significant advantages such as high purity, chemical homogeneity, controlled particle sizes of ceramics, and lower processing temperatures [4]. In a sol-gel process, alkoxides of the constituent elements show different reactivity toward water so that the preparation of multi-component homogenous system is difficult. In the experiment, inorganic salt was substituted for some of the alkoxides. Acetic acid which is employed for the solvent and catalyst, acts as donor ligand to titanium alkoxide and controls, the hydrolysis polycondensation reaction. Taking these aspects into consideration, we select the system Ba(OAc)2, , La(OAc)3, Ti(O11Bu)4 and acetic acid which is used as both solvent and homogeneous catalyst for the first time.ExperimentalA series of La3+-doped BaTiO3-based nano-crystals were prepared with sol-gel technology using various parameters. The precursor solution was prepared in the presence of barium acetate, lathanium acetate, and titanium tetrabutoxide monomer in butyl alcohol. According to the flow chart (fig. I.), Ba(OAc)2, La(OAch dissolved in the glacial acetic acid (0. lmol/40ml) in a three-neck flask were mixed with a solution of titanium tetrabutoxide monomer in butyl-alcohol(l 7ml/20ml) at room temperature and under constantly, vigorous stirring conditions. In most cases, the resultant solution was golden yellow and stable in the air. To this precursor solution, containing Ba, La, Ti in the desired ratio, water was added incrementally for hydrolysis under continuous stirring until sol was formed. After aging for more than 2 hours, sol was transformed to gel at room temperature. If heated during aging, the gel was formed in a shorter time. The wet gel was allowed to dry at 50°C for more than 10 hours. The dried gel was transparent or light yellow. In order to obtain BaTiO3-based nano-crystals, the amorphous dry gel was calcined at 600°C, 700°C, 800°C, 900°C, 1000°C respectively[5]. The ceramic humidity sensor was formed through the cold-pressed, aged, capsulated routes. The dried gels were crushed in an agate mortar and then pressed into discs of ? 1.5 X l.5mm (l.5mm diameter and l.5mm thickness), then held at about 16.5 MPa pressure for 3 min [6]. The disc was sintered at 1350°C and 1400°C for I hour respectively. During the processing, an Ag-Pt electrode was inserted in the sensor [7]. (See the flow chart.)"

Jan 1, 2000

By Matthew C. Binsfield

The simultaneous electro winning of zinc and manganese from waste water treatment plant sludge was studied as a part of the overall research program, which was conducted to develop the methods for removal of environmentally hazardous metals from the Bunker Hill Superfund Site. This paper discusses the electrolytic method for recovery of zinc and manganese from the solution produced by leaching of sludge with S02 + H2S04. After three stage purification of the leaching solution, zinc and manganese were electro won simultaneously in an undivided electrolytic cell. Zinc was deposited on an aluminum cathode, while manganese was simultaneously produced (as Mn02) on a lead silver anode. The electrowinning parameters studied were the effects of: temperature, current density, electrode material, spacing of electrodes, composition of electrolyte, and electrolyte additives. Anodic and cathodic efficiencies were 30 and 91%, respectively. In light of the process design parameters discussed in the paper, which are affecting the electrowinning, these efficiencies were found as acceptable with regard to the quality and marketability of the products.

Jan 1, 1996

By Kun Wang, Xinhui Li, Huaqing Xie, Qingbo Yu, Qin Qin

"Three typical model compounds of bio-oil (ethanol, acetone and phenol) were studied in the steam reforming process for hydrogen production. In the thermodynamic analysis, the three componds showed the similar trends. The hydrogen yields increased with the increase of steam/carbon (S/C) ratios, and the temperatures of the maximum hydrogen yields moved afterward to low temperature zone. However, the hydrogen contents were just about 70%. For improving hydrogen yield, a new system for steam reforming of bio-oil with site CO2 capture was put forward. This system required the catalst with the larger granularity having greater mechanical strength and higher abrasion resistance. So, six Ni-base catalysts loaded on Al2O3 particles prepared were used and among them, Mg-Ni/Co catalyst showed the best catalytic performance. For the simulated bio-oil (the mixture of the compounds), the hydrogen yield can attain 63% with Mg-Ni/Co catalyst with the good stability and regeneration ability.IntroductionCurrently the interest in the use of hydrogen as a clean energy carrier is increasing, and the main way for producing hydrogen is steam reforming of fossil fuels, containing steam reforming of nature gas, naphtha and coal. But this way caused substantial amounts of CO2 emitted, and these sources of hydrogen which are non-renewable energy will eventually be used up [1, 2]. As a kind of renewable energy, biomass is recognized as an attractive alternative to fossil fuels, because of its neutral CO2 emissions [3]. There are mainly two thermochemical processes using biomass to produce hydrogen, gasification and flash pyrolysis followed by steam reforming (SR) of the biooil produced in the flash pryolysis process [4]. The latter was known as one of the most promising and economically viable methods for hydrogen production [5]. In the last decades, the biomass flash pyrolysis technology was adequately developed and fairly mature [6]. But the steam reforming of bio-oil is still at the research stage and yet has been leading to more and more concerns by the researchers. In their research, the catalysts were widely studied and yet mainly were powdery[7-10], and the reactors manily were fixed bed reactors[11-13], readly causing the carbon deposition and the catalyst deactivation, against the continuous running. In this paper, a new systerm was put forward and could realize continuous production of hydrogen, yet needed catalysts with the larger granularity having greater mechanical strength and higher abrasion resistance, as well as powdery CO2 sorbents which mainly calcium oxide based ones.In this paper, the thermodynamic analysis of the steam reforming processes of three typical bio-oil model compounds (ethanol, acetone, phenol) was performed, and the effect of S/C ratio and temperature on the hydrogen yield and the compositions of gaseous products were investigated. Then, a new systerm for steam reforming of bio-oil with site CO2 capture was put forward, and the catalysts with a certain granularity were prepared and studied."

Jan 1, 2014

By J. Markussen

The Falconbridge Matte Leach Plant was based on leaching Ni-Cu matte with strong hydrochloric acid in rubber lined equipment. It operated from 1968 to 1983 as a precursor to Nikkelverk&apos;s present C12 Leach. The process comprised two S.X. systems. NiC12.4H20 crystallization, crystal drying, NiC12.H20 pyrohydrolysis and HC1 gas recovery. The naphtha fired fluid bed pyrohydrolyzer produced granular NiO, subsequently reduced with H2 to granular nickel for sale. The development and operation of the pyrohydrolyzer are described

Jan 1, 1991

By Ikuhiro Sumi

A new steelmaking process, in which manganese ore was intentionally reduced, was developed to achieve a higher manganese Yield using a combined blowing converter. In this study, manganese behavior was discussed through the introduction of a model. Apparent reduction rates of manganese were calculated by the two terms that were determined experimentally, with SOkg and 2S0ton combined blowing converters. The model calculated manganese changes during the operation. We applied the model to the actual operation and found that manganese behavior was predicted fairly well by this model.

Jan 1, 1996

By Duck Jae Lee, Kwan Ho Kim, Ji Whan Ahn

"In Korea, reutilization of constructions waste is gaining an increasing attention as generation of construction waste is projected to increase continuously. In current practices, the concrete waste is simply crushed and used as a low application such as paving, back filling, etc. In this study, a new process was developed comprising of heat pretreatment, autogenous milling, and density separation for complete reutilization of concrete waste. Firstly, the concrete waste was crushed using autogenous milling. The coarse size fractions from autogenous milling have a density of 2.5g/cm3 and a water absorption ration 3.0%, which meet the specification of the first class of KS F 2573. The fine size fractions were further separated using a hindered-settling column into two products 1) underflow, 2) overflow. The underflow sample was a high quality fine recycled aggregate which can be used for concrete making, and the overflow sample was an enriched cement material can be also used for CO2 sequestration by mineral carbonation. Introduction Kwan Ho Kim1, Ji Whan Ahn2, Duck Jae Lee1, Hee Chan Cho1 Recently, the importance of resource recycling is gaining a greater attention due to the increasing price of natural resource. Recycling is beneficial for not only the management of waste, but also the reducing of consumption of natural resources and huge energy consumption to treat of natural resource. The construction and demolition waste comprises the major industrial waste generated in Korea. It increased to 54 million tons in 2004, and is projected to increase to over 300 million tons in 2020, as many buildings reach the end of their 30 years life. Among total waste, the proportion of concrete waste was about 30% in Korea. Due to its large volume, recycling of concrete waste is the most important aspect of the waste management. In the current practices, the concrete waste is simply crushed and used as a recycled aggregate. The recycled aggregate has a low quality and most of them are down cycled for usage as paving material, back-filling material, concrete bricks, etc. It cannot be reused for replacement of natural aggregates because cement mortar is not separated perfectly from aggregates. These kinds of recycled aggregates tent to be weaker, more porous and have a higher value of water absorption. When these aggregates are used in concrete making, there are problems of higher total water demand, low compressive strength and durability [1-5]. And recycled fine aggregate is not almost recycled due to its low quality. In this study, a new processing circuit is developed to produce not only highquality recycled coarse aggregates but also fine aggregates and cement material from concrete waste."

Jan 1, 2008

By Payal Bakshi, Sangeeta Tiwari, Mohini Saxena, Anusha Sharma

"Recycling and reuse is perhaps the most favorable and beneficial way to solve the problem of industrial waste disposal. However, the use of industrial wastes like fly ash, tailings etc is in practice for brick manufacturing, land filling, embankments filling etc. These existing practices do not add enough value to the wastes. Moreover, some wastes may have very good potential to be incorporated in valuable products like paints. This study reveals about the value addition of industrial wastes like fly ash, copper tailing and blue dust as an extender in paints. Comparative properties and characteristics of these three wastes for application in paints are discussed. Fly ash, copper tailing and blue dust were characterized for physical, chemical and mineralogical properties and used in different paint formulation based on their potential to the particular application. Fly ash has been found very useful in enamel, primers and flat paints while copper tailing was found suitable in oil based paint formulations. The performance of fly ash and copper tailing paints were evaluated by comparing with those of conventional whiting extender. Blue dust was compared with conventional iron oxide for use in priming coats. The extender properties of these new material and paints prepared out of blue dust, fly ash, copper tailing, were found better than the existing related materials.IntroductionIndustrial development and environmental reforms should run parallel to benefit each other. This is the best policy, which must be adopted by industries for the sustainability of the current modern life. The high degree of industrialization and urbanization adds scads of waste resulting problem of pollution and challenges of their safe disposal. The nature of waste depends on the process that produces waste as its by-product. Therefore, policies/plans are prepared by keeping the view of possible potential hazards. Among the different wastes some are generated in the industries, which have great importance in the country’s economy, like fly ash waste from thermal power industry and mining waste. In India the total contribution of thermal power in the total electricity generation is more than 70% and it produces about 123 million ton of the fly ash annually [1]. On the other hand mining plus extraction of ferrous and nonferrous metals also produce waste in million tonnes of categories [2]. Since the generation of this waste is very high they cover large land area for their disposal and dumping [3]. The storage of this waste in the dumping sites for long time duration may cause problem of land, surface water, ground water and fertile soil contamination [4]. As far as Indian fly ash is concerned it does not contain toxic element over the limits of hazardous waste [5]. However, in general most of the metals deposits are found in the form of pyrite based ores. Mining wastes contain toxic elements e.g. heavy metals in varying amount, which get mobilized when pyrite get oxidized to sulphate producing sulphuric acid [6,7]. These ores contain very less amount of targeted metals in themselves thus they require extensive preprocesses for concentration of the metals [8]."

Jan 1, 2008

By Lv Guozhi, Niu Liping, Liu Yan, Zhang Zhiqi, He Jicheng, Zhang Ting’an, Dou Zhihe

"CuCr alloy can be extensively used as contact materials in integrated circuit, electrodes, electric contact and high strength conductor. We proposed thermit reduction-electroslag remelting method of preparing the large scale CuCr alloy. But there are pores and oxide inclusions in CuCr alloy prepared by thermit reduction process. This paper studied mainly the effects of ratio of reactant and additive on the inclusion type and their occurrences in CuCr alloy. The slags and CuCr alloy were characterized respectively by XRD and SEM. The results show that when the additive is Na3AlF6, the slag consist of Al2O3 and Cr. When the additive is CaF2, the slag consist of Al2O3, Cr, CaF2 and CaAl4O7. The inclusions in CuCr alloy are mainly Al2O3 and pores which disperse in Cu-rich zone and Cu-Cr phase interface. When 5% CaF2 and 5% KClO3 are added, there are fewer pores and inclusions, and the more better microstructure.1 IntroduceCuCr alloy is the contact terminal material with an eximious properties[1,2], which gradually replaces CuBi alloy becoming the first choice for contact terminal material in the medium and high power vacuum switch after the 1970s. The traditional preparation methods of CuCr alloy mainly contain powder metallurgy, infiltration process and vacuum electric arc melting methods. But the above methods exist some shortcomings, such as poor product quality, high cost of production, processes complex ect[3-9]. CuCr alloy is made by the thermit reduction self-propagating method, which uses CuO, Cr2O3 and Al as raw material to get the high-temperature melt, and then casts to manufacture CuCr alloy ingot, which response equation follows as:"

Jan 1, 2012

By Hsi-keng Hu

"This paper deals with the flotability of stibnite and summarizes the major experiences and technological innovations of some typical practices of antimony sulfide ores in China. Experiences of cyanide-free and -less flotation of complex antimony sulfide ores and the application of the heavy media process to the preconcentration are described.Performance improvements obtained by innovations in operating techniques are also outlined and discussed. Technical innovations involve: (1) ramification roughing and differential-rate cleaning of stibnite-arsanopyrite ore; (2) the application of the new flotation reagent system; (3) process of separation flotation of Sb-Hg bulk concentrate; (4) extraction of gold from Au-Sb bulk concentrate; (5) flotation recovery of coarse stibnite particles.IntroductionChina is rich in natural resources of antimony and is one of the major antimony producers in the world. During the past several decades, a lot of research works have been done and many experiences in milling practices were gained, some of which are summarized briefly as follows.I. Heavy Media separation of Antimony sulfide Ore at Xikuangshan Hill, Hunan province (1)HMS as a technique of preconcentration of antimony ore has been performed more than ten years in China with good results.1. Ore characteristics The antimony ore of Xikuangshan belongs to the epithermal- metasomatic-filled doposit of antimony sulfide. Major minerals are stibnite (92.1%), antimony oxides (7.9%) and a small amount of pyrite and pyrrhotite; the gangue minerals are quartz, silicic limestone, calcite, hydrous kaolin, sericite, barite and others. The specific gravity of the ore is 2.8 and the specific gravity of stibnite and gangue are 4.6 and 2.654, respectively."

Jan 1, 1988

By Huimin Lu, Shi Zhou, Lisha Yang

"The Zeolitic imidazolate frameworks (ZIFs) were successfully synthesized by applying a combination of ionothermal synthesis and microwave energies for rapid synthesis. The synthesis was proceeded under various conditions including different raw materials, reaction temperature as well as microwave irradiation time. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are new type of porous materials formed by inerratic polyhedral in three-dimensional. They are the ideal crystalline substances for gas separation and storage. The assynthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and C02 adsorption test. Results illustrated that the synthesized samples had stable structure, high thermal stability (up to 530 °C) and C02 adsorption capacity (10.2 cm3/g at 0°C under ambient pressure). This novel method also showed great advantage with high energy efficiency, safe synthesis conditions, and rapid crystallization time (60 minutes).IntroductionNowadays, carbon dioxide capture has become imperative due to the global warming caused by the increase of C02 in the atmosphere, especially produced by the concentrated sources such as power plants [1]. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are ideal crystalline substances for gas separation and storage due to their structure diversity, high thermal and chemical stability [2-5]. They are formed by inerratic polyhedra in threedimensional with large cages and small apertures. Traditionally, ZIFs are synthesized by solvothermal method in a sealed autoclave under autogenous pressure [6-9]. However, in order to generate the products, the solvothermal temperature should not be lower than 100°C according to the sovlothermal mechanism. Moreover, at such a temperature, molecules with a low boiling point (such as water) may generate high pressure in reactor which might cause danger [9]. Thus the synthesis requires the equipment to possess resistance to autogenous pressure and corrosion. Further, conventional solvothermal methods need a long time to prepare products, usually a few days, which is a large energy consumption and inefficiency. So it is interesting to synthesis ZIFs through other ways under mild reaction condition with high energy efficiency."

Jan 1, 2012