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By A. M. Alfantazi, R. R. Moskalyk

Over the years, improvements have been made in the recovery of nonferrous metals, including improvements in the areas of mineral processing, pyrometallurgy and hydrometallurgy to extract cobalt as a byproduct from host minerals containing mainly nickel, copper and associated precious metals. At present, the technological emphasis is on solvent extraction coupled with electrowinning (SX-EW) for lateritic sources of supply within the Southern Hemisphere, such as in Australia and New Caledonia. Although sulfide-bearing ores, such as those found in Canada and Russia, will serve as a viable long-term source for cobalt, a ubiquitous metal, the future trend is anticipated to be in the implementation of compact and efficient SX-EW facilities that apply state-of-the -art innovation with environmental compliance This paper serves to collate the known practices for the recovery of market-grade cobalt by means of electrowinning from either an aqueous sulfate medium or chloride medium after upstream leaching, solvent-extraction and solution-purification procedures. For completeness, other commercial production techniques for the recovery of cobalt as a sulfide or oxide product are included in the summary of current cobalt processing practices.

Jan 1, 2000

By A. S. Malicsi, Vathsala Rajagopal, I. Iwasaki

Corrosion and abrasion properties of a series of chromium-containing, cast-iron balls, with Cr contents ranging from 0% to 29%, were evaluated and compared with austenitic stainless-steel and mild-steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite, with either 5% pyrrhotite or 5% chalcopyrite, under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynantic polarization curves under abrasion. Flotation recoveries were determined on a 95% quartzite + 5% pyrrhotite sample ground with various cast-iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with flotation results and with corrosive wear data obtained from marked ball wear tests.

Jan 1, 1993

By R. Merwin, S. Hoff, A. Ellsworth, M. Zhao, X. Jiang

The choice of mill linings in comminution circuits is critical as it affects grinding efficiency, overall cost, and product quality. As a consequence, a variety of liners have been developed over the years in an effort to increase wear resistance, improve grinding efficiency, and reduce energy consumption. One particular type of metal magnetic lining (MML) was developed in China seventeen years ago and has since been installed in over 400 applications throughout the Chinese mining industry. Most recently, one set of magnetic mill liners was brought to the US for installation into a secondary ball mill used for the grinding of iron ore. Protection of the mill is provided through the magnetic attraction and retainment of worn media, ball chips, and other various magnetic particles to the mill wall. This greatly improves the wear resistance and overall life of the liner. The installation and performance data for the magnetic mill liners in a US iron ore concentrator are presented in this paper.

Jan 1, 2007

By R. Mathur

Cu isotope fractionation in low temperature aqueous environments has been well documented. Here we apply Cu isotopes to two distinct, yet related mining problems. First, an exploration geological application where we measured copper isotope fractionation in oxidized leach caps, chalcocite enrichment blankets and hypogene mineralization in 4 porphyry copper deposits located in South western USA. Cu isotope patterns exist in the lateral and vertical distribution within the mines coupled with distinct relationships with Cu grade. Second, a hydrometallurgical application where we measured the leach fluids, feed and residues from a quick leach text of Cañariaco ores. The results indicate the relative proportions of the minerals providing Cu during leaching. Interpretations of the QLT test measurements indicate covellite is the dominant ore mineral providing Cu during leaching. Both applications clearly demonstrate the power and ability of using the Cu isotope technique to understand low temperature aqueous processed involving copper.

Jan 1, 2010

By Charles H. Jacoby

In 1960 the management of International Salt Company made the decision that all waste material from the Watkins Glen plant would be stored in underground salt cavities. The cavities which they contemplated using had been depleted of salt to a point where continued operation would have impaired their structural stability. Originally, the waste to be disposed of included vacuum pan bleeds, cinders, contaminated salt and sewage. It was proposed that this material, in a slurry form, was to be injected into the salt cavity through one of the abandoned wells. Brine, displaced from the cavity, was to be recovered from an adjacent well and subsequently injected into the Cherry Valley limestone, This Cherry Valley limestone which underlies a large portion of north central New York contains a connate water with high concentrations of ammonia, hydrogen sulphide and the chlorides of calcium, magnesium and sodium. A number of questions were immediately raised on various aspects of the technical feasibility of the project. Of major concern was the buildup of insolubles adjacent to the bore of the injection well. Another pertinent question was the carryover in the displaced liquor of finely-divided, mechanically-suspended particles. Criticism was leveled at the inclusion of sewage. Engineering studies were started by the company's Mineral & Mines Development Department and on April 3, 1961 a preliminary feasibility report was issued.

Jan 1, 1973

By J. F. Cuderman

In situ experiments at the Department of Energy's Nevada Test Site (NTS) have extended the technology of propellant-based fracturing to include liquid- filled, uncased boreholes. Previous work had developed the technology for liquid-free, uncased wellbores. Test results show that fracturing behavior is considerably more complex in liquid- filled boreholes than in the liquid-free case. Compared to liquid-free boreholes, liquid-filled boreholes have faster pressure risetimes and lower peak pressures, large hydraulic-type fractures propagating several meters beyond the end of the test zone, numerous oscillations in the pressure history, and variable types of fracturing within a single test region. Multiple fracturing is initiated in the wellbore of a fluid-filled borehole when the proper propellant mixture is used but, unlike fluid-free wellbores where up to eight fractures propagate, only one to three hydraulic- and/or shear-type fractures propagate. Hydrodynamic effects involving liquid compression during borehole pressurization appear to be responsible for the differing phenomena observed in fluid- filled boreholes.

Jan 1, 1986

By R. P. Stahura

In many ways, conveyors are the lifeline of mining and processing operations. Like arteries in the human body, they continuously supply materials to and carry finished products and waste away from vital on-going operations. And like arteries, when the conveyors are running with less than maximum efficiency and productivity, it spells serious trouble for the operation's overall health. Inefficient conveyors suffer carryback, leading to the build-up of materials on idlers and other expensive components. They spill and leak material at loading zones and conveyor transfer points, causing accumulations that can damage the belt, wear moving components, and increase both clean-up labor and maintenance expense. They wander or mistrack, spilling material and endangering personnel and conveyor components including the belt itself. And through these inefficiencies, they multiply the operation's hidden costs. These added expenses are created in lost production, increased downtime for service and maintenance, and the cost of the replacement of prematurely worn equipment. In addition, the attitude that inefficiency is "good enough" is recognized elsewhere in the organization; as a result, other departments relax or operate at less than peak performance. Quality goes down and with it employee morale.

Jan 1, 1992

By S. S. Vasan, K. A. Natarajan, J. M. Modak

The biological removal of calcium from a bauxite ore in the presence of the soil bacterium Paenibacillus polymyxa is demonstrated. A column bioreactor that can be either operated in a fluidized-bed (FB) mode for coarser particles or in a total-recycle-slurry (TRS) mode for finer particles was designed, fabricated and tested for this purpose. For the efficient removal of calcium from the ore to the required levels, leach solution should not be allowed to accumulate in the reactor. Therefore, the solution needs to be drained out periodically. Cascade leaching was found to be more effi¬cient. A direct correlation between pH changes in the leach solution and calcium solubility could be made. More than 85% of the calcium could be removed through cascade leaching.

Jan 1, 2000

By R. N. Rothan, V. Khunova, C. M. Liauw, G. C. Lees

The interphase modification activity of 1,3-phenylene dimaleimide (also known as m-phenylene bismaleimide (BMI)) has been studied in composites based on magnesium hydroxide (60% w/w) and a polypropylene block copolymer (PPBC) that featured an ethylene-rich elastomeric impact modifier phase. BMI was found to be a unique product that led to significant simultaneous improvements in composite strength and toughness, even at the high filler levels. BMI modification was found to promote encapsulation of filler particles with the elastomeric phase of the PPBC together with formation of a PP boundary layer of increased crystalline content.

Jan 1, 2003

By Michael D. Sopko

This paper describes the project implementation from financing, through the engineering and construction phases, mine and process plant commissioning as well as operating experience realized to-date. The single line flowsheet used to process the lateritic nickel ore to a 75 percent nickel matte is presented with emphasis on the main pyrometallurgical operations. These include a rotary dryer, a unique reduction kiln, a 45 000 kVA electric furnace and two Pierce-Smith type converters. Associated infrastructure facilities and services necessary to sustain the 11 300 tonnes (12 500 short tons) per year nickel production rate are also described.

Jan 1, 1979

By K. S. E. Forssberg, K. Hanumantha Roa

Batch flotation tests are carried out with phosphatic material from LKAB, Sweden containing carbonatic and siliceous gangue while using sodium oleate as collector and sodium silicate as modifier. The pulp liquid is analysed for oleate, silicate, carbon dioxide, calcium, magnesium and phosphorous after each flotation test under different reagent conditions and flotation pH. Theoretical calculations of thermodynamic chemical equilibria in apatite-calcite-sodium oleate-sodium silicate system have been carried out with the help of SOLGASWATER computer program. During the calculations, the chemical variables are maintained similar to the operating chemical variables in flotation. A comparision between the experimental and theoretical chemical equilibria has been made and the flotation behaviour of apatite is discussed with reference to the theoretically calculated pulp model.

Jan 1, 1993

By Christian Jeger

After recalling the principles underlying fire-damp flow in coal and the essential part played by permeability (Darcy's law) in the intensity of flow, a few theoretical and experimental results showing the possible causes and range of variation of coal seam permeability are presented. The study of firedamp flow into gate roads and of residual gas concentrations in coals as a function of the gate road distance, shows that, in French mines, coal seams in a virgin zone have a very low permeability, but they become permeable when destressed by mine workings, in particular overlying workings. This is the case not only in the fractured zone round a mine excavation in which the gas is released, but also beyond the limit of the zone degassed by the excavation. In the floor of flat seams, upward boreholes can be used for predegassing seams that have been relaxed but not degassed, as the result of an overlying coal face. In this respect we shall describe the predrainage experiment carried out in the Marienau district of the Lorraine coalfield. Predrainage can contribute considerably to the reduction of methane emission in the ventilation of newly opened longwall faces. But to be efficient and useful predrainage should meet certain conditions.

Jan 1, 1980

By D. M. Muir, C. Cao

Many gold ores have copper mineralisation which presents problems in a carbon-in-pulp operation. Various types of copper-gold ores and ways of tackling the problem are discussed. In some cases copper and gold can be upgraded to a concentrate by flotation; otherwise, copper or gold can be selectively leached. When both copper and gold cyanide are present in solution, it is possible to minimise copper loading onto carbon or to selectively strip the copper from the carbon. Alternative leach solutions like thiourea and bromine are discussed and results obtained with the ammonia/cyanide system are presented in the light of our present understanding of the chemistry involved.

Jan 1, 1989

By P. Somasundaran, Bruno Lartiges

Two different groups of mechanisms have been considered in the past to explain the effects of chemical additives on grinding. While one group of explanations is based upon alterations of surface and mechanical properties of the individual particles, the other group depends mainly on the arrangement of particles and their flow in suspensions. In this paper some of the past work on grinding aids is reviewed and attrition grinding of a commercially important ceramic material, zirconia (stabilized with yttria) with polyaaylic acid as grinding aid, is studied in order to determine the effect of the aid on the ground product itself. It was observed that even though polyaaylic acid did cause a drastic decrease in the viscosity of the pulp, it did not have any major effect on the grinding of zirconia at least up to 2000 ppm and only minor detrimental effect above it. Importantly, complexation by the polymer was found to cause extraction of yttrium into solution with possibly significant changes in the surface chemical composition of the product.

Jan 1, 1992

By Thomas H. Hibner, Daniel Tempelis, John E. Shamma

Environmental protection of nearby resources is an issue that can not be ignored in tunnel construction. The Inland Feeder Arrowhead Tunnels Project is no exception. With keen interest from various stakeholders, Metropolitan developed a Groundwater Monitoring and Mitigation Plan. This plan provides for monitoring and management of selected water resource features within the San Bernardino National Forest along the proposed tunnel alignment. The plan specifically provides for monitoring of streams, springs, seeps, and piezometers for water temperature, pH, specific conductance, and chemical analyses, as well as flow or groundwater elevation. Metropolitan uses the data to evaluate for and manage potential impacts from groundwater ingress during construction of the Arrowhead Tunnels.

Jan 1, 2003

By Yannis Faitakis, Brenda M. Wright, Gail Powley, Mark Hamblin, Randy B. Paine

A major problem in the ore extraction process is the high degree of variation in the mix of materials that make up the mined ore. The mix of materials makes it extremely difficult to characterize and predict the behavior of the ore when it is processed. The Quality Production Database (QPD) tool was successfully used in order to predict and transfer information regarding the quality characteristics of the ore being delivered to the extraction and hydrotransport unit operators. This paper describes the use of QPD in the prediction of various ore characteristics at the Syncrude Canada Ltd. processing facility.

Jan 1, 2000

By Yukika Miyashita, Takahiro Inoue, Kenji Namikawa, Masashi Matsumoto, Junichi Koseki, Yoshihiro Terashima

"In order to construct an underground two-layer expressway branch junction structure with a height of 14.7 m and a width of 22.3 m, two shield tunnels in each layer were combined by using a non-cut-and-cover enlargement method in sedimentary soft rock. Before and during the construction work, preliminary analysis, in-situ investigations and laboratory tests were conducted to ensure the construction safety and to evaluate the deformation characteristics of sedimentary soft rock. The construction project was safely executed without any water leakage or collapse of tunnel working face. The predicted results from preliminary analysis were almost similar to the measured values. From the detailed investigation of measured results, it was confirmed that the deformation characteristic of the sedimentary soft rock was observed to a small extent as the ground deformation derived from construction work. INTRODUCTION In recent years, some newly constructed urban expressways in Japan are being planned as underground structures due to the consideration of roadside environment. The construction of such underground expressways is frequently conducted using a shield tunneling, a typical one of non-cut-and-cover methods, to prevent any adverse effect to traffic in arterial roads, operation of nearby commercial establishments, and daily lives of local residents during construction work. For underground urban expressway, the connections with existing road network on ground surface or on elevated sections are indispensable, which require the construction of an underground branch junction with large cross-section. This raises a technical difficulty regardless of the open-cut or non-open-cut construction method."

Jan 1, 2016

By Yu. P. Astafyev

The, control of drilling and blasting is a complicated dynamic system whose aim is to ensure safety and prepare rock of required grade and the standard level of broken material reserves Unlike other processes drilling and blasting, as an object have the following features: -a large variety of drilling and blasting methods due to specific conditions of blasting, various types of drilling equipment, schemes-of blasting, types of explosives and others; -relative continuity of drilling, the character of mammoth blasts being discrete; -increased requirements to the safety of blasting;; -a great. number of control parameters, some of them having a qualitative characteristic but not a quantitative one; -availability of feedforward and feedback with other mining processes in terms of time and space. These features predetermine the hierarchical structure of an automated system of planning and control of drilling and blasting (fig.1). The system is implemented on the basis of unity of the data base and in interre lation with other problems of controlling mining operations. An automated system of this kind makes it possible to take optimal decisions actually on all the levels and stages of operations, with rock having been blasted before extraction.

Jan 1, 1986

By Richard A. Williams

The design, modelling and simulation of solid-liquid mixers remains one of the least advanced aspects of minerals processing, due to difficulties in quantifying complex slurry hydrodynamics from first principles, and in acquiring reliable experimental data for model verification and development. This contribution describes the application of electrical resistance tomography (ERT) for three dimensional imaging of the concentration of mineral particulates in a slurry mixer as a function of key process variables (particle size, impeller type, agitation speed). It is demonstrated how ERT can provide a wealth of detailed data to allow model development, which ultimately will lead to much improved design capabilities and the generation of mixing models which could reside within Particle Process Simulators. This principle is illustrated using descriptions of mixer behaviour based on an empirical approach, although the measurement methodology described is equally suited to development of computational fluid dynamics models, cellular models or design approaches based on artificial intelligence. The experimental data can be built into a visualisation data bank, which acts as a "process toolkit" by allowing a library of process responses to be catalogued. Hence these data can be accessed for the purposes of model development, equipment selection, optimisation of operating conditions or testing on-line control strategies.

Jan 1, 1995

By Jose M. Milian, Raphael F. Matson

An intensive study was started in 1968 to determine the most economical process for winning nickel and cobalt from an extensive de- posit of complex, low grade nickel-cobalt ore (1.6% Ni, 0.10% CO) designated "the Greenvale ore." In 1974 the commercial plant at Yabulu, in Queensland, Australia, began processing the ore. In the interim, a great deal of laboratory and pilot-plant effort was applied to develop technical, process and commercial design data to demonstrate to potential financial backers and customers that a full-scale plant was feasible. The laboratory test work, pilot plant facilities and pro- gram are briefly reviewed in this paper.

Jan 1, 1979