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By William B. Harper

Domestic sales of carbon black sustained the upward movement for the 4th consecutive year, reflecting the increased sales of motor vehicles during the same period. Sales of carbon black in the domestic market topped 2 billion pounds for the first time during 1965 and have more than doubled the output of 20 years earlier. By far the largest user of carbon black is the rubber industry. That use accounted for more than 94 percent of the carbon black consumption with the bulk of it being used in tire casings and tubes. Thus demand for carbon black is naturally sensitive to trends in the sales of passenger cars and other motor vehicles, Manufacturers of inks, paints, plastics, paper chemicals, and food are also important users of carbon black.

Jan 1, 1967

By Joan T. May

Anhydrous methods were tested for the extraction of beryllium from low-grade source materials. The purpose of the investigations was to find new extraction processes that are applicable to domestic ores. Beryl, helvite, and phenacite materials containing from 0.1 to 2.8 percent BeO were used as starting materials for direct halogenation tests and pretreatment followed by halogenation. The results of the investigations showed that direct fluorination and carbide-chlorination are two practicable methods that can be applied to low-grade concentrates. Treatment of concentrate-carbon mixtures with anhydrous hydrogen fluoride extracted 99 percent of the beryllium in the concentrate; the soluble fluoride product, converted to an oxide, contained 70 percent BeO. Chlorination of beryllium-silicon carbide, prepared from low-grade concentrates, extracted beryllium into the volatile chloride product.

Jan 1, 1962

By Edward J. Kansa

In a Bureau of Mines study, unsteady, spherically symmetric, one-dimensional, compressible-flow (finite sound speed) equations were solved numerically for a spherical deflagration propagating concentrically in a spherical vessel with Mach numbers ranging from 0.2 to 0.7; trajectory histories agree with the infinite-sound-speed theory developed by Perlee, Fuller, and Saul (PFS). A preliminary result of this study shows that flames propagating with speeds greater than 20 pct the speed of sound in the unburned gas mixture generate a complex history of aerodynamic waves distributed throughout the spherical vessel. Although the average pressure and flame radius agree with those predicted by the PFS models, the aerodynamic waves have a pronounced effect on the flame velocity, differing appreciably from that predicted by the PFS model.

Jan 1, 1976

By Philip B. Lorenz

A Bureau of Mines feasibility study on the use of tracer pulses to assess the degree of fracturing in an underground formation consisted of three phases: 1. A laboratory study on sand packs and open tubes, which developed a correlation between dispersion of the pulse and size of the flow channels. 2. A test on a retort, 11 feet in diameter and 45 feet high, packed with shale rubble. Void volume was measured, but evaluation of channel size was not possible because of interference from the space unoccupied by the matrix. 3. A field test on an explosively fractured shale formation. Pressure, flow, and transit time led to qualitative estimates of fracture pattern, but quantitative detection of dispersion in the formation was overwhelmed by dispersion effects in the well.

Jan 1, 1973

By D. B. Dow

This report on methods employed for dehydrating oil-field emulsions, is the second of a series prepared as a result of a study of oil-field emulsions recently completed by the writer. The first paper2 dealt with the factors responsible for the formation of emulsions. A third paper will discuss the physical chemistry involved in the formation and resolution of such emulsions. In the early development of the oil fields of Pennsylvania, no emulsion troubles of any consequence were encountered, nor to any serious extent in the oil fields of other Eastern States: However, with the development of fields west of the Mississippi in Oklahoma, Kansas, Texas and California, where heavier oils of different characteristics were found, the problem of dealing with cut oil soon became of great importance.

Jan 1, 1925

By Launa G. Mallett, Robert H. Peters, Barbara Fotta

Due to variations in the thickness of U.S. coal seams, there is great variability in the height of the roof where underground miners work. Restrictions imposed by low seam heights have important safety consequences. As the height of their workplace decreases, miners must stoop, duck walk, or crawl, and their vision, posture, and mobility become increasingly restricted. Low seam height also places important restrictions on the design of mobile equipment and other mining machinery. Using the employment and injury data reported to the Mine Safety and Health Administration (MSHA) from 1990 to 19% small underground bituminous coal mines with less than 50 employees were stratified by average coal seam height according to the following categories: low (? 42"), medium (43"60N), and high (? 61"). Injury rates for both nonfatal days lost and fatality cases were examined by seam height and leading type of injury incidents. The leading types of Incidents associated with fatalities were roof falls and powered haulage equipment. In comparison to high-seam mines, miners working in low or medium seams are at higher risk of being killed by powered haulage equipment, roof bolting machines, and falls of unsupported roof. The leading types of incidents associated with nonfatal injuries were handling materials and powered haulage. As mining height decreases, miners are at increasingly higher risk of having a nonfatal injury from incidents involving roof bolting machines, load-haul-dump equipment, personnel carriers, and powered haulage conveyors. As mining height increases, miners are at increasingly higher risk of having a nonfatal injury from slips and falls and incidents involving shuttle cars and roof and rib falls. Knee injuries are a particularly severe problem in low- seam mines. The rate of injuries to miners while crawling or kneeling is 10 times higher in low seams than in high seams

By W. A. Calhoun

The purpose of this investigation was to develop a procedure for removing excess iron from representative samples of bauxite ore from the Quapaw deposit of American Cyanamid Co., Saline County, Ark., in order to produce a beneficiated ore suitable for use in the alum industry, At the request of the sponsoring company, the samples were reduction-roasted at 800° C. and then magnetically separated. Although some rejection of iron was effected under these conditions, the general results were not satisfactory, A much more successful procedure, from the standpoints of both rejection of iron and recovery of alumina, consisted of a short (l5-minute), low-temperature (400° C.) oxidizing roast, followed by a 2-minute interval in a hydrogen atmosphere, then cooling to room temperature, and, finally, high-intensity magnetic separation to remove the iron.

Jan 1, 1957

By D. L. Paulson

The Bureau of Mines is investigating pyrometallurgica1 and" chemical methods to recover valuable constituents from metallurgical dusts and slags. Under this program a technique was developed to recover iron from molten copper smelting furnace slags by carbon injection. Slags from gas-fired reverberatory and electric copper smelting furnaces were treated in an 800-kva electric-arc furnace by injecting coke breeze into the bottom of the molten bath. Over 95 pct of the iron and over 90 pct of the copper contained in the smelting furnace slags were recovered, while up to 85 pct of the carbon injected into the system was utilized. It is anticipated that the metal product containing approximately 95 wt-pct iron and 2 wt-pct copper will be a satisfactory medium for recovering copper by cementation.

Jan 1, 1977

By B. J. Scheiner

Silver ores from the Candelaria District, Nevada, and Round Mountain District, Colorado, were investigated mineralogically and metallurgically. Silver minerals of four distinct groups were identified: (1) silver sulfide; (2) argentojarosite; (3) silver contained in the iron oxide; and (4) manganese carbonate-oxide minerals, Electrooxidation and acid-chloride leaching techniques were investigated as means of altering silver minerals, and their effects on subsequent silver extraction were determined. Application of the knowledge obtained from mineral leaching studies resulted in development of a sulfur dioxide-sodium chloride leaching sequence for extracting silver from these types of ores. Silver extractions of 80 to 85 percent were obtained by leaching the ores with a sulfurous acid-sodium chloride system. This was an increase of 9 to 61 percent silver extraction over that obtained by conventional cyanidation techniques.

Jan 1, 1973

By Ann G. Kim

Methane in coal constitutes a serious hazard during mining. Draining the methane from large blocks of coal in advance of mining is an effective method of improving the safety and efficiency of coal mining. Because of the similarity of the two gases, drained methane can be recovered and added to pipeline supplies of natural gas. To effectively apply advance drainage techniques and recover drained gas, a gross estimate of the methane content of coal is necessary. Using data from previous investigations, the virgin reserves of the Pittsburgh coal in the central and southwestern parts of Washington County, Pa., are estimated at over 1.5 billion tons, with a methane content of 50 to 100 fts/ton. The Pittsburgh bed in this area of approximately 265 mi2 contains over 130 billion ft3 of methane.

Jan 1, 1974

By D. H. Chambers

The Bureau of Mines developed a process for producing high-purity zinc and tin by electrorefining from liquid amalgams. Commercial grade metals were dissolved in mercury to produce saturated amalgams at room temperature. Amalgams were also prepared by electrolytic transfer from soluble anodes of the metals to a mercury cathode. Amalgams formed by both methods were used as anodes in electrorefining cells to produce high-purity cathodes. Metal impurities, excluding mercury, were at levels of less than 5 ppm in zinc and 9 ppm in tin. Mercury content was about 2 to 10 ppm in zinc products, and this was effectively removed by heating the cathodes in a vacuum. Mercury was excluded from tin cathodes by pumping the tin electrolyte through tin turnings and controlling the cell temperature.

Jan 1, 1969

By M. B. Cooke

An analytical method for the determination of the gum-forming material in gasoline has been developed by the Bureau of Mines, during a study nor in progress to determine the best rays for elimination of such constituents from gasoline. This method is similar in principle to that previously described by Smith end Cooke,2 which involved evaporation of e sample of gasoline in a small glass dish. The evaporation was started on an actively boiling steam bath and completed in an air oven at 105°C. In the improved method described below, the stem bath has been replaced by a steam heated oven in which an inert atmosphere is maintained. Air is excluded from the oven, consequently the precision of the determination is increased. Furthermore, evaporating dishes different from those previously described may be used.

Jan 1, 1925

By W. W. Weller

This report provides low-temperature heat-capacity data and entropies at 298.15° K. for magnesium metavanadate (MgV206) and magnesium pyrovanadate (Mg2V207). The work completes low-temperature measurements planned for alkaline-earth vanadates; an earlier report dealt with calcium vanadates.4 No similar data for these compounds have been published previously. Free energy of formation values at 298.15° K. were derived by combination of the present entropy values with heat of formation data. MATERIALS The materials used in the measurements were portions of the samples described in a previous Bureau of Mines publication by King, Koehler and Adami.5 Methods of preparation, chemical analyses, and X-ray examinations are covered in this paper. The indicated purity of the samples was 99.9 pct.

Jan 1, 1962

By D. G. Kesterke

Research was conducted to determine the feasibility of extracting elemental oxygen from silicate-bearing melts by high-temperature electrolysis. The method was based on a modification of existing processes for electrowinning metals from their oxides dissolved in molten halide systems. Electrolyses were performed at temperatures ranging from 1,050° to 1,250° C in boron nitride cells that incorporated a silicon carbide cathode and an iridium anode. The electrolytes contained volcanic scoria as the oxygen source, plus mixtures of BaF2 and LiF as fluxing agents. Cell gases containing almost 14 volume-percent oxygen were obtained. The average anode current efficiency for several experiments of extended duration was calculated to be 55 percent. Cell design and operating conditions are described, and some of the problems associated with the process are discussed.

Jan 1, 1971

Develop methods to detect and repair poorly functioning dust collectors on roof bolters. Approach In conjunction with a research project to reduce silica dust in coal mines, a variety of roof bolting machines operating under different conditions were examined to find out how much these machines were contributing to the silica dust problem. Results The investigation concluded that if the bolting machines' dust collector is properly maintained, very little dust can be measured in the air, even with minimal airflow over the bolter. Poor maintenance, however, frequently results in high dust levels. Three major problem areas were found. These were: (1) filter leaks, which allowed dust to escape, (2) accumulations of dust in the collection system, and (3) low airflow at the bit due to hose, fitting, and relief valve leaks.

Jan 1, 1984

By R. O. Pynnonen

Tunnel-driving is recognized as a hazardous occupation; adequate support of roof and sides for preventing accidents from falling material is usually one of the most important safety problems. Where extraordinary conditions of sand and water are found, this problem becomes even more difficult. Tunneling at the Tioga No.2 mine was stopped when a 22-foot bed of water-saturated, fine gray sand was encountered. The tunnel, designed to house an ore-conveyor belt, was being driven from both ends. Driving was extremely difficult at both the upper and lower faces when the sand horizon was reached. A distance of 178 feet remained between the faces. Heavy pressures deformed the steel-supporting rings at the upper face, and there was an inrush of mud and sand at the lower face.

Jan 1, 1958

By Harold W. Lipper

HELIUM shipments in 1963 exceeded the volume shipped during the previous year for the 14th successive time. Shipments from Bureau of Mines plants were 627.3 million cubic feet, an increase of 5 percent over the volume shipped in 1962. Production from Bureau of Mines plants totaled 774.2 million cubic feet. The Bureau purchased 1,420 million cubic feet of helium in the helium conservation program and stored it underground for future use. Each of the five plants, financed and built by private industry for helium conservation, made deliveries during the year. Helium continued to playa key role in space, atomic energy, defense, and other research programs. Additional capacity for liquefying helium became available, and the first civilian helium-cooled nuclear-powered reactor in the United States began pre-operation testing.

Jan 1, 1964

By Kenneth M. Earl

The purpose of this investigation was to obtain subsurface information on the John Burdette barite-fluorite deposit, Garrard County, Ky. The deposit was intersected in each of five inclined diamond-drill hales aggregating 1,163 feet. All holes were drilled from the hanging wall of the deposit; the inclinations varied from minus 41° to minus 75°. Disseminated metallic sulfides were noted in the drill cores from holes 1, 2, 4, and 5. The deepest drilling was hole 5, which intersected the deposit at approximately 490 feet down dip. Visual inspection of the cores did not indicate mineralization of economic importance; therefore, no chemical analyses were conducted. Condensed logs of diamond-drill cores are included in this report. All drill cores were shipped to the Bureau of Mines core library in Minneapolis, Minn., for future reference,

Jan 1, 1959

By A. E. Prokop, J. P. Rider

Previous research on continuous mining operations has shown that significant interactions exist between dust control parameter application and the resulting respirable dust levels, but simply increasing the level of the controls does not guarantee a reduction in respirable dust levels. Full-scale laboratory tests are being conducted to provide information to longwall operators which would assist them in selecting control parameters that would reduce dust levels for mine-specific conditions. The interactions between face air velocity, shearer water quantity, drum water spray pressure, external water spray pressure, and spray system design were evaluated in a simulated 2.13. m (7-ft) coal seam for two cutting directions. Locations around and downwind of the shearer were monitored to evaluate relative changes in respirable dust levels as a function of each control parameter.

By Lambert Dolphin, George Oetzel, Robert Bollen

An electromagnetic sounder developed for an archaeological application in Egypt has been successfully tested in a California dolomite mine. Chambers in the mine 100 to 130 feet from the surface gave intense, well-defined echoes consistent with an average attenuation coefficient of 0.6dB/m and a relative dielectric constant of 11. By moving the transmitter and receiver units on the hillside above the underground chambers, various characteristics of the propagation could be observed such as dispersion, chamber aspect sensitivity and cross section. The transmitted pulse was one to one-and-a-half radio-frequency cycles long at a peak power of 0.2 MW. Frequencies employed were 16 to 50 MHz. The light weight, highly portable, battery-powered equipment is potentially suited to other underground sounding applications.

Jan 1, 1973