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By M. H. Stanczyk, I. L. Feld

Dewatering of typical Florida phosphate rock slime by electro - osmotic techniques was investigated to determine if a compacted , plastic solid product could be obtained with simultaneous recovery of the water for re - use . Tests with porous cathodes and rod - type anodes imbedded in dilute slime charges of up to 4 tons in weight showed that the slime could be dewatered to about 35 percent solids . The dewatered products had the consistency of modeling clay . In the large - scale tests using 2.5 - foot electrode spacings , about 21 kilowatthours of power were consumed per ton of water removed in thickening the slime from 17 to 25 percent solids , but the rate of water removal was so slow that the process was not considered commercially feasible . Other tests made with electrode spacings of from 2.5 to 8 feet showed that more rapid dewatering could be obtained but that the power required was excessive . However , for special uses such as stabilizing slime pond dikes where the cost of dewatering might not be a prime requisite , high voltages could be used to rapidly remove the water . Tests of 400 - pound slime charges using a combination of electroosmosis and vacuum filtration showed that the rate of dewatering could be expedited . The average power required to thicken a ton of slime from 15 to 35 percent solids was 5 and 50 kilowatt - hours when operating the electroosmotic filtration cell at potentials of 20 and 100 volts , respectively . calculated filtration area of about 10 square feet per ton of slime treated per day was required to thicken the slime from 15 to 35 percent solids .

Jan 1, 1964

By L. B. Pankratz

The heat contents of the sesquioxides of erbium, holmium, thulium, and ytterbium (Er203, Ho203, Tm203, and Yb203) in the cubic crystalline form were measured over the temperature range from 298° to 1,800° K. The erbium and holmium sesquioxides gave regular heat content-temperature curves. Thulium sesquioxide had a minor thermal anomaly near 1,680° K, with a heat absorption of 310 cal/mole; similarly, ytterbium sesquioxide had a minor anomaly near 1,365° K, with a heat absorption of 150 cal/mole. The heat content results are presented in both tabular form (at 100° intervals) and in algebraic form. Entropy increments, corresponding to the tabulated heat content results, also are listed.

Jan 1, 1963

By Lucia Kuizon

The Antimony RARE II area is underlain principally by Mesozoic igneous rocks associated with the Sierra Nevada batholith. The San Andreas fault zone is near the southern boundary. Metallic mineral deposits are associated with the fault zone. These deposits were formed from magmatic solutions, and tend to be along shears and fractures within the country rock. Marble and dolomitic marble deposits occur in Paleozoic roof pendants or inclusions in the Mesozoic intrusive rocks in the area (Troxel and Morton, 1962, p. 52).

Jan 1, 1982

By J. A. Herdlick

"INTRODUCTION The BeVan quartz crystal prospect in the Indian Creek mining district of Lemhi County, west-central Idaho, was examined by an engineer of the Bureau of Mines 3/ on July 9, 1943. As quartz crystals possessing peizoelectric properties were on the critical list of strategic war minerals, further exploration of the deposit was recommended. The Bureau of Mines exploration began in December 1943 and continued through January 1944. Additional trenching was completed during May and June 1944. This report presents the data obtained by this exploration.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual exploratoiy work, and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyses samples and makes beneficiation tests.The quartz crystals found during the exploration were examined and classified at the Bureau of Mines College Park, Md., laboratory and checked at the National Bureau of Standards, Washington, D. C.Fred BeVan, of North Fork, Idaho, and Edward F. Cenis, of the Montana Coal & Iron Company, Spoane, Wash., provided much information on the history and past production of the property."

Mar 1, 1948

By R. Barany

The heats of formation of anhydrous ferric sulfate and anhydrous indium sulfate were determined by solution calorimetry. At 298.15° K the heats of formation from the metal, rhombic sulfur, and oxygen were -615.6 ±O.7 kcal/mole for ferric sulfate and -649.6 ±O.6 kcal/mole for indium sulfate. Heats of decomposition at 298.15° K are given for the reaction that forms metal oxide, sulfur dioxide, and oxygen) and for the reaction that forms the metal oxide and sulfur trioxide.

Jan 1, 1965

By John Campbell, Miller. W. E., G. W. Jones

"INTRODUCTION Because of its interest in accident prevention, the Federal Bureau of Mines has cooperated with city officials and utilities in investigating the causes of explosions in sewers, manholes, and other underground spaces and has aided in the development of means to prevent such explosions. For several years this Bureau has cooperated with the Boston Edison Co. and the Boston Consolidated Gas Co. of Boston, Mass.,for the purpose of detecting and eliminating combustible and physiologically harmful gases in manholes in Boston and vicinity.These investigations 5/ have shown that combustible gases from the usual sources — leakage from gas—distributing systems and underground tanks and gasoline wastes — can be located and the dangerous conditions remedied by a well—planned, adequately supervised, systematic, and continuous manhole survey. However, other types of gas contamination, termed ""soil"" gases, are present in manholes at times and are more difficult to eliminate because they have no fixed origin and because seasonal and barometric chances affect their production and passage into the manhole. Soil gases usually are abnormally high in carbon dioxide and low in oxygen and contain varying amounts of methane. They are especially dangerous to men entering manholes because they lack sufficient oxygen to support life."

Feb 1, 1940

By S. C. Schaefer

Thermodynamic properties of indium oxide (In203) have been studied with a high-temperature galvanic cell employing stabilized zirconia electrolytes. In the temperature range 790° to 1,230° K the free-energy change for the cell reaction 21n(1) + 3Cu20(c) = In203(c) + 6Cu(c) together with the standard free energy of formation of cuprous oxide gives the standard free energy of formation of indium oxide from the elements as ?Gf° = -218.78 + 75.34 X 10-3T ±0.7 kcal/mole. A third-law analysis yields the standard enthalpy of formation: ?Hf°298.15 = -221.5 kcal/mole.

Jan 1, 1971

By F. W. Lane

Some months ago the Bureau of Mines began research of a fundamental character on sulphur in petroleum. In the course of this work, the usual qualitative test for sulphur in organic compounds1 was applied to certain oils that were believed to contain approximately 0.5 percent sulphur. No sulphur was found, and, as a check on the qualitative test, the oils were subjected to quantitative determination of this element by the oxygen-bomb method.2 The sulphur content of the oils ranged from 0.10 per cent to 0.50 per cent. This experience led to further trial of the qualitative test for organic sulphur, both on the oils mentioned above, and on common sulphur-containing organic substances. No difficulty was experienced in detecting the element in the latter, but with the petroleum oils the test, as usually performed, could not be relied upon to detect less than 0.60 per cent of sulphur consistently. The use of mechanically polished pure sheet copper for the detection of free sulphur, hydrogen sulphide, and perhaps other sulphur compounds has been recommended.3

Jan 1, 1927

By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials such as sphagnum peat moss for extracting metal contaminants from waste waters. The beads, designated as BIO-FIX beads, have removed toxic metals from over 100 waters in laboratory tests. These waters include acid mine drainage (AMD) water from mining sites, metallurgical and chemical industry waste water, and contaminated ground water. Following the laboratory studies, cooperative field tests were conducted to evaluate the metal adsorption properties of the beads in column and low-maintenance circuits, determine bead stability in varied climatic situations, and demonstrate the beads' potential as a viable waste water treatment technique. Field results indicated that BIO-FIX beads readily adsorbed cadmium, lead, and other toxic metals from dilute waters; effluents frequently met drinking water standards and other discharge criteria. The beads exhibited excellent handling characteristics in both column and low-maintenance circuits, and continued to extract metal ions after repeated loading-elution cycles. Based on laboratory and field data, cost evaluations for using BIO-FIX technology to treat two AMD waters were prepared. Operating costs for BIO-FIX treatment, which ranged from $1.40 to $2.30 per 1,000 gal of water treated, were comparable with chemical precipitation costs.

Jan 1, 2010

By L. R. Burdick

Anthracite barley is considerably cheaper than rice. Its use, therefore, is attractive from a cost standpoint, - but its smaller size (through 3/16 inch over 3/32 inch round-mesh screen) makes it more difficult to use on some equipment when fairly high combustion rates are necessary to carry plant loads. Tests wore made in one plant to determine the performance of rice and various types of barley on a chain-grate stoker in a two-arch refractory furnace. In general, the efficiency and capacity increased with increased fuel size and volatile content. This performance is presented in tabular and curve form, together with a short review of the ignition and burning process on chain-grate stokers and a discussion of the operating procedures and limitations during the tests. In this particular installation, higher combustion rates and efficiencies could have been obtained with barley if the grate links had been designed for more uniform air flow through the grate surface. Careful maintenance and operation are particularly necessary for satisfactory results with barley on equipment not especially designed for its use.

Jan 1, 1950

By W. K. Kleysteuber

This report covers the design and testing of a novel bulk materials conveying device by the Bureau of Mines. The transport concept of the device is to create a traveling wave with a steep front so that the bulk material slides and cascades down the front of the wave with some horizontal motion. Ideally, the front should act like a continuous chute. The concept of moving bulk materials along a belt without any forward movement of the belt itself was demonstrated. The conclusions reached were that the mechanism as designed could not overcome the inherent major disadvantages that would make the undulatory conveyor suitable for practical applications.

Jan 1, 1974

By R. L. Brown

This report, the seventeenth in an annual series, summarizes Bureau of Mines research and technologic work on coal and related investigations for July 1, 1951, to July 1, 1952. It 1s based largely on publications issued during the fiscal year, although 10 some instances data are presented that have not been published previously. Footnote references are given to the publications so that further details on the work may be obtained. Bureau of Mines research on the mining, preparation, and utilization of coal is directed toward developing and encouraging safer and more efficient mining practices and preparing and utilizing coals to the best advantage.

Jan 1, 1953

By R. V. Ramani, A. S. C. Owili-eger

List of Numbers

Jan 1, 1974

By Oliver Bowles

Granites are classed as igneous rocks ; they have been formed by the solidification of rock magmas or solutions from deep within the earth . It is an almost invariable law of nature that magmas which cool quickly form fine- grained or glassy rocks , while those that cool slowly are completely crystallized and are coarser- grained . Granites , being of the latter class , are regarded as having attained their solid form at considerable depth below the surface under conditions of high temperature and pressure . The constituent minerals crystallized out slowly , the crystals interlocking with one another . The great depth of overlying rocks that must have been present when crystallization took place has been removed by erosion over large areas on the surface of the earth , in consequence of which granites appear at or near the surface in many localities . The chief minerals of which granites are formed are feldspars , quartz , and either mica or hornblende . All the essential constituents except mica are as hard as , or harder than steel , therefore granites are difficult rocks to cut and dress . Granites are usually red , pink , or gray , depending on the color of the feldspars . If hornblende or black mica is abundant the rock may be dark green or almost black . Granites are characterized by massive homogeneous texture . They are classified as fine- grained , medium- grained , or coarse - grained . Medium- grained granites are those in which the feldspar crystals average about one- fourth inch in diameter . If relatively coarsegrained crystals appear in a fine -grained ground mass the rock is designated a porphyritic granite . Uniformity in texture and grain size are desirable in building and ornamental stone , although occasionally rocks of variable texture , such as the porphyritic granites , are used . A rock may have the mineral constituents of a granite but show a banded or platy structure due to recrystallization , folding , or other changes while the rock was in a plastic or semimolten condition . Such metamorphic rocks are called granite gneisses . They are used occasionally for building purposes but not as commonly as the uniformly textured granites . - Granites are named from the most abundant mineral other than quartz and feldspar that they contain , being called , for example , biotite granite or hornblende granite . - Commercially other igneous rocks granitoid in texture but more properly classified as syenites , diorites , or gabbros may be classed as granites . Thus the " black granite " of Little Falls , Minn . , is a diorite , and the " black granite " of Eastern Pennsylvania consists of diabase or gabbro . The question is sometimes raised as to the depth to which a granite occurrence may extend . In this respect granites differ notably from limestones , sandstones , or other sedimentary rocks . The sediments were originally laid down in relatively thin beds , and individual formations providing rock of economic value may be quite limited in thickness . Usually the usable beds range between 40 and 200 feet in thickness . On the other hand , granite comes up from below . Its depth is unknown , but in general is very great . It may even be measurable in miles . The reserves of material at depth are to be measured , therefore , by the economic depth of working rather than by the vertical extent of the rock mass . Exceptionally , granites of commercial quality may occur in sills or sheets of limited thickness flanked on either side by rocks of different character , as , for example , at Westerly , R. I.

May 1, 1930

By D. P. Desmond

The U.S. Bureau of Mines investigated leaching automobile catalysts with sodium cyanide (NaCN) solutions at high temperatures to recover platinum-group metals (PGM). The feed was virgin monolith rejects, used monolith, and used pellet catalysts. Leaching with a 5-pct NaCN solution for 1 h at 160° C dissolved over 97 pct of the PGM in the virgin monolith, over 85 pct of the PGM in the used monolith, and over 90 pct of the PGM in the used pellet catalyst. Over 99.8 pct of the dissolved PGM was recovered as a precipitate by heating the solution to 250° C for 1 h in an autoclave. The cyanide complexes were decomposed, and free cyanide was destroyed.

Jan 1, 2010

Viable domestic mineral industries are essential to the economic health of the United States and the well-being of its citizens. The charts in this publication reflect developments significant to the Nation's mineral industries during 1975. Last year was a year of reduced activity for the Nation's mineral industries. Although the value of the country's total mineral output rose, for example, the overall production and use of many minerals fell. At the same time, the industry experienced lower profits and higher debt/equity ratios. These and other adverse effects on many segments of the Nation's mineral industries resulted from the overall decline in domestic and international economic activity.

Jan 1, 1976

By D. M. Lewis, J. K. H. Ma, Y. Rojanasakul, J. Y. C. Ma, J. H. Kang, V. Castronova

"Tetrandrine is a bisbenzylisoquinoline alkaloid which has been shown to exhibit antifibrotic activity against silicosis. Tetrandrine is characterized by its strong binding to alveolar macrophages and inhibition of particle-induced respiratory burst activity in these phagocytes. In contrast, tubocurine and tubocurarine are structurally similar to tetrandrine but exhibit little effect on fibrosis or activation of alveolar macrophages. The objective of the present study was to test the effect of tetrandrine on macrophage production of monokines in response to occupational dusts, and to determine tetrandrine's effect on monokine-medicated cell growth using a mouse thymocyte proliferation assay and lipopolysaccharide (LPS) as a positive control. Stimulation of alveolar macrophages by respirable silica dust resulted in a release of monokines which caused a fourfold increase in thymocyte proliferation. Coal dust, on the other hand, had no effect on macrophage production of this cytokine. Tetrandrine was found to exhibit a dose-dependent inhibition of monokine release from both silica and LPS-stimulated alveolar macrophages. In experiments where thymocytes were directly treated with tetrandrine, a dose-dependent inhibition of thymocyte proliferation was noted with both interleukin-1- (IL-1) specific and nonspecific mitogenic (concanavalin A) actions. In contrast to the inhibitory potency of tetrandrine, tubocurarine was found to have no effect on either the production of monokines by LPS-stimulated alveolar macrophages or IL-I-mediated thymocyte proliferation. These results provide a correlation between the ant:fibrotic effect of tetrandrine and inhibition of macrophage activation. INTRODUCTIONThe pathogenesis of chronic pulmonary fibrosis caused by inhalation of occupational dusts has been associated with abnormal activation of alveolar macrophages such as the release of various cytokines capable of inducing fibroblast proliferation and collagen synthesis. These macrophage-derived cytokines include interleukin-1 (IL-1), tumor necrosis factor (TNF), platelet-derived growth factor (PDGF), transforming growth factor-B (TGF-(B), macrophage derived growth factor (MDGF), and interferon [1, 2].Interleukin-1 is a major macrophage-derived cytokine that has been shown to exhibit multiple biological effects on a variety of target cells. It is known to cause leukocyte [3, 4] and endothelial cell activation [5, 6], and to affect the synthesis and maintenance of the extracellular matrix by stimulation of fibroblast proliferation [7-9], synthesis of collagens [10] and gluco-saminoglycans [11], and prostaglandin E2 production [12]. In addition, IL-1 plays an important role in the initiation of an immune response through its direct activation of lymphocytes and stimulation of the production of other cytokines, such as interferons and hemopoietic colony-stimulating factors, needed for the expression of an immune response [13]. As a major cytokine in the immune-inflammatory sequela, IL-1 is also produced by epidermal, epithelial, lymphoid, and vascular tissues after infection, injury, or antigenic challenge [14]. Agents such as lipopolysaccharide (LPS), phorbol myristate acetate (PMA), immune complexes, and particulates are known to activate the synthesis and release of IL-1 by monocytes and macrophages [15]. These substances also trigger intracellular signals leading to altered arachidonic acid metabolism. Although the mechanism is still not clear, prostaglandins have been shown to suppress IL-1 translation via the induction of cyclic adenosine-monophosphate (CAMP), whereas leukotrienes produce a positive signal for IL-1 production [13]."

Mar 1, 1992

By Thomas G. Murdock

ALTHOUGH the contribution of Algeria, including the Sahara, to the local economy and to world mineral supply was small for many years, the spectacular development of an important petroleum and natural-gas industry has changed the position of the country. In 1963 there were decreases in output of most mineral commodities, however oil and gas production forged ahead and established new records. The impact of adverse market conditions and especially the competition from lower cost producing areas was felt by both the metals and nonmetals industries. This and the general economic conditions related to the recovery of the country following the years of strife attending its emergence as an independent state combined to hold back production and development commensurate with resources. The principal events of the year were in the petroleum sector and included the first commercial production from several new fields, some new discoveries, the virtual completion of the first petroleum refinery in the country, and installation of additional pipelines. Progress was made toward the further utilization of the vast resources of natural gas and the provision of additional transportation and refining facilities. In the mining domain the government took over two iron-mining operations, and progress was made towards expanding production of phosphate rock and determining methods of upgrading the Tindouf Iron ores. Completion of the iron and steel plant near Bone was further delayed. The only coal mine reportedly closed down in late 1963.

Jan 1, 1964

By Curtis A. Jones

Continuing interest has been shown in developing processes for extracting nickel and cobalt from low-grade domestic deposits of these metals and in improving existing methods. Of special concern is the nickel-recovery installation at Nicaro, Oriente Province, Cuba, operated for the General Services Administration. The Bureau? of Mines felt that a bibliography would help familiarize personnel at various Bureau of Mines stations and General Services Administration contractors with extraction methods both in the United States and in foreign countries. When this task was under way it became apparent that to compile a complete bibliography would require considerable time, so it was decided to limit the first part to the later literature and issue it independently, thus making it available sooner. The present work supplements the first part and extends the coverage to the earliest years of nickel and cobalt metallurgy.

Jan 1, 1959

By J. B. Ligon

Blast induced stress waves, propagating along the surface of a drift of an underground hardrock mine, were recorded and analyzed. Resistance strain gages, accelerometers and a velocity pickup were used in making the measurements. Although a full face blast was recorded, the stress waves were initiated by single borehole blasts for the majority of the project. A special instrument trailer was designed, constructed and utilized during the project. A reliable strain wave transducer was developed for measuring the stress waves propagating on the drift surface. A correlation study between strain and acceleration signals for P-waves was made which agreed well with theory. The use of stemming was found to reduce strain and acceleration magnitudes as predicted.

Jan 1, 2011