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By Charles Prasky

This report describes fluidized bed techniques employed by the Bureau of Mines at Minneapolis to differentially sulfatize the manganese in two samples of low-grade manganiferous ferruginous carbonate slates from the Cuyuna Range district, Minn. Suitable mechanics of operation were established. A space rate of 1.25 to 1.5 fps, a retention time of 3 to 3.5 hours, a temperature of 700° C, and a 10 percent sulfur dioxide gas in air were adequate for sulfatizing the slates by fluidization. Under these conditions the overflow product removal rate from the 4-inch-diameter reactor was 4 to 5 pounds per hour. The sulfur dioxide was used more efficiently in the two-stage treatment than in the single-stage treatment. However, approximately 80 percent of the manganese was converted to sulfate by either treatment.

Jan 1, 1963

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0,5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that (1) the cost of slow cooling and crushing off-sets any advantages of higher copper recoveries from slow-cooled slag, and (2) water-quenched slag, which requires no crushing preparatory to grinding, could be treated more economically. Costs based on processing 1,000 tons of slag per day would be $1.85 per ton for quenched slag versus $2.37 per ton for slow-cooled slag.

Jan 1, 1971

By John W. Cole

As part of a general preliminary investigation of lead-zinc deposits in Stevens County, Wash., the Electric Point and Gladstone mines on Gladstone Mountain, in the Northport Mining District, were examined by R. M. Gammell, an engineer of the Bureau of Mines, in June 1946. A trenching and sampling program was executed later the same year under' the supervision of Miro Mihelich and the author. This report presents the factual data obtained from the trenching and sampling operations.

Jan 1, 1949

By B. B. Letson

The heats of formation of lithium chloride and lithium oxalate were determined with the aid of a Bureau-developed, glass Dewar-type solution calorimeter which uses thermistors as its temperature sensing element. Values obtained at 298.15° K were -98.38 ± 0.54 kcal/mole for lithium chloride and -329.02 ± 0.79 kcal/mole for lithium oxalate, using graphite as the standard state for carbon.

Jan 1, 1965

By John B. Gayle

During studies of the various methods for determining and specifying the factors that indicate whether a particular coke is better or worse than other cokes for metallurgical uses, questions arose as to the precision of screen-analysis tests on coke. Although the usual index of precision, the standard deviation of the test result, gives a measure of the precision of these data, the experimental determination of the standard deviation for a particular set of conditions requires tests on a large number of duplicate samples. Because this procedure necessaily involves a great deal of labor, an equation for predicting standard deviations from theoretical considerations has been developed. Results predicted with this equation agree satisfactorily with the experimental values and are applicable to tests on coal, coke, gravel, and other bulk materials.

Jan 1, 1952

By M. J. Sapko

The U.S. Bureau of Mines has developed a portable meter for measuring the component concentrations in binary dust mixtures whose constituents have different optical reflectivities. The meter has been successfully tested with coal dust-rock dust mixtures taken from coal mines in Europe and the United States and fluorinated-carbon mixtures that change from carbon black to pure white during fluorination. Additional study has also substantiated the theoretical expressions used in the design of the meter.

Jan 1, 2010

By Y. Miron

Previous studies at the Bureau of Mines outlined the hazards of ammonium nitrate-fuel oil (AN-FO) mixtures in the presence of pyrite-bearing ores. The recent trend in the mining industry to strengthen AN-FO by the addition of aluminum metal raised the question regarding the effect of aluminum in AN-FO in the presence of pyrite-bearing ore. Laboratory work, similar to that done previously, demonstrated that the temperature of a self-sustaining reaction in the presence of AN-FO ore-aluminum is not lower than that for a comparable AN-FO-ore mixture. However, as might be expected from known thermochemical data, once initiated, the resulting reactions between AN-FO, aluminum, and pyrite are much more vigorous than those observed for AN-FO and pyrites alone. The temperature required to produce a self-sustained reaction for the combinations tested in this study is 250°±20° F while in the previous Bureau study, reactions were noted, in some instances, at 150° F. The different pyritic ores may be the cause of this variation.

Jan 1, 1976

By James P. Bennett

To improve construction materials for emerging chemical and metallurgical technologies, the Bureau of Mines is investigating the acid resistance of ceramic materials. In the study described here, eight commercial ceramic materials comprising two red shale, two fire clay, a silica, a silicon carbide, a carbon, and a high-alumina brick were evaluated. Samples were exposed to 20 wt-pct HC1 at 50° C for 110 days. The test apparatus designed to evaluate the materials is described. Changes in chemical and mineralogical composition, cold crushing strength, volume, and weight, and leach rates of AI, Ca, Fe, K, Mg, Na, Si, and Ti ions were monitored. In general, the statistically significant physical property changes that occurred were small. In many cases, no changes were detected.

Jan 1, 1982

By W. E. Robinson

A laboratory study wan made to determine whether drying and preheating Colorado oil shale with waste retort gases has any appreciable effect on its oil yield. Samples of crushed oil shale were heated at subretorting temperatures in a specially constructed electric furnace by gases similar in composition to waste gases from oil-shale retorts. The results of this study showed that preheating oil shale with nitrogen or a reducing mixture had no effect upon the oil or water yield. However, oxygen in the preheating gas caused a decrease of oil and an increase of water. In general, the oil yield decreased with (1) increase in oxygen content of the heating gases, (2) increase in temperature of the heating gas, (3) increase in heating time, and (4) decrease in the particle size of tho shale. The decrease in oil and the increase in water resulting from preheating were due to oxidation of the benzene-insoluble organic material (kerogen) rather than to oxidation of the benzene-soluble organic material (natural bitumen) in the shale, A small amount of oil was volatilized during preheating, which would constitute an additional loss if prober precautions were not taken to recover it. The results obtained in this laboratory study indicate that oil shale can be preheated without appreciable decrease in oil yield by proper selection of preheating conditions.

Jan 1, 1951

By Y. P. Chugh

This is the final report of a study done by IIT Research Institute for the Bureau of Mines to identify the problem areas and technological inadequacies in noncoal (metal, nonmetal, stone, and sand and gravel) mining and processing systems that are the primary causes of death, injury and occupational disease, and to make recommendations to improve safety and health in these operations. The findings and recommendations presented in the report are based on: (1) analyses of MESA injury and employment data for the period 1961-70, MESA fatality reports for underground noncoal mines (1968-72) and lost time accident data for 1970-72 obtained from mining and processing operation: (2) visits to a variety of noncoa1 mines and mills throughout the country to observe the operations and to study the safety organization and practices used in the industry and (3) interviews with industry and government representatives knowledgeable in the field of noncoa1 mining and processing safety and health. The report provides a comprehensive overview of safety and health problems.

Jan 1, 1974

By J. L. Thompson

The U.S. Bureau of Mines conducted a water-jet-studies program using a single-bit, in-seam test unit to determine effects of a moderately high-pressure (up to 10,000 psi) water-jet-assisted cutting system on rock weakening. The in-seam test unit was used to obtain cutting force data in tangential, normal, and side force directions. Conical continuous miner and radial longwall miner bits were used to penetrate test samples of coalcrete, Berea sandstone, and Indiana limestone with unconfined compressive strengths of 4,600, 8,000 and 10,000 psi, respectively. Depth of cut in the coalcrete tests was 1 in, with 2-in cut spacing (2:1 ratio). Because of cutting equipment and instrumentation limitations, the Berea sandstone and Indiana lime-stone were cut using a 0.5-in depth of cut and 2-in spacing (4;1 ratio). Bit velocity was maintained at 25 ft/min for both bits. Each specimen and bit type was tested using 0.3-, 0.6-, 0.8-, and 1.0-mm-diam nozzles and water-jet pressures of 2,500, 5,000, 7,500, and 10,000 psig. Water-jet-assisted cutting decreased average resultant conical and radiallongwall bit cutting forces 6.4 and 8.4 pct in coalcrete, 5.5 and 1.4 pct in Berea sandstone, and 2.0 and 5.5 pct in Indiana limestone. Slight reductions of power requirements resulting from water-jet assist were ascertained during these experiments.

Jan 1, 1989

By Phillip N. Yasnowsky

This Bureau of Mines report summarizes State severance taxes imposed on minerals and mineral fuels, provides a hypothetical example of how a State severance tax affects selected components of a firm's income statement, and uses the Bureau's Minerals Availability System (MAS) to estimate the effect of assumed changes in State severance tax rates on copper recovery cost at given levels of potential copper availability. A reduction of the rates to zero or a doubling of them results in changes in costs that are of the same order of magnitude as the cost of transporting copper to the United States from major foreign producing countries.

Jan 1, 1982

By [F. P. ] Stambaugh

Results of research on the hydrothermal precipitation of zirconium oxide from the Bureau of Mines' zirconyl chloride-sulfate strip liquors indicate that nuclear grade material can be prepared by this process. Greater than 99% of the zirconium value can be precipitated at 250-260°C in short (5-10 minutes) reaction time without consumption of acid value of the liquor. Thus, precipitation of zirconium dioxide on a continuous basis, i.e., the zirconium dioxide is precipitated in a continuous mode of operation by pumping the strip liquor through a heated pressurized reactor and recycle of the acidic (spent) liquor to the process stage are favored. The results of accompanying studies of liquod/solid separation, product washing and dewatering, product purity, and chlorination of the product are presented and discussed.

Jan 1, 1980

By Lulie H. Crump

U.S. supply and demand data for petroleum and natural gas liquids, by States and regions, were tabulated for the years 1960 and 1965. Estimates arcs provided of State-by-State quantitative data for the petroleum and natural gas liquids industry that can be integrated into State, regional, and national energy balances by source, form, and consumer sectors, and used for determination of interstate and interregional energy flows. Tables 1-4 show the estimated total supply of petroleum available for consumption and the supply's distribution among the major consumer demand sectors (household and commercial, industrial, transportation, and electricity generation). To obtain summary figures for the major proportion of refined products by States, individual tables were compiled for the six major products (tables 5-16). To enable comparison of petroleum data with those for other energy forms, conventional volumetric data in barrels were converted to their British thermal unit (Btu) equivalents. Interregional shipments of crude petroleum and theoretical flow patterns for petroleum products are shown in figures 1-4.

Jan 1, 1969

By D. I. Bleiwas

The Bureau of Mines determined the costs associated with lithium production (in various products) from demonstrated resources in seven market economy countries (MEC's). This analysis evaluated the relative economic and resource position of 16 mines or deposits, including 6 producers and 1 (Bernic Lake) operating at pilot scale. The demonstrated resource of recoverable lithium within the deposits studied is approximately 2.2 million metric tons (mt). Virtually all known MEC resources and production were covered, including resources in Chile (59 pct of the total), the United States (13 pct), Australia (11 pct), Canada (10 pct), and Bolivia, Zaire, and Zimbabwe (combined 7 pct). In addition, the large potential of lithium-enriched brines is assessed, especially those in the Atacama Basin, Chile, where production began in 1984. The lithium resource consists of lithium in spodumene, brines, and to a small extent lepidolite and petalite. Most MEC lithium trade originates from the United States, though development of brine deposits in Chile, and potential development in Bolivia, could threaten the U.S. position. Economic analysis indicated that all lithium being recovered from producing properties could be produced at less than the published market price, and that MEC resources from these properties are adequate to supply any foreseeable demand.

Jan 1, 1986

By J. W. Howland

A demonstration of dozer blades, designed for recontouring area-mined spoil and shown effective at Kansas and East Texas surface mine sites, was conducted at a Northeast Arizona surface coal mine to determine their effectiveness in different climate and soil conditions. The specialized tools were: 48-ft angle blade (on side-by-side tractor), 24-ft grading bar, modified 24-ft "U" blade (on side-by-side tractor), and a 13-ft deep "U" blade. Interest in the increased dirt-handling capacity of a previously built 22-ft blade, resulted in the design of a new Centerflow Blade of good versatility, able to maintain increased flow in otherwise difficult-to-move spoil. The demonstration involved 263 acres and showed a reduction of 50% in reclamation costs and 20% in fuel requirements for this mine site over conventional equipment. This savings resulted from improved technology, trained operators, and rigorous application of supervisory and monitoring techniques. Procedures and results of the demonstration are presented and analyzed here, along with guidelines for application of findings.

Jan 1, 1982

By William C. Cooley

A review was made of two Russian books and a chapter from a third book dealing with pipeline transport of coal. Emphasis was placed on hydrotransport of coarse coal in underground mines or surface pipelines. The books reviewed were: "Means of Increasing the Effectiveness of Hydrotransport," by V. N. Pokrovskaya (1972), "Parameters and Modes of Hydraulic Transport of Coal" by V. V. Traynis (1970), and the chapter "Calculations of Hydrotransport of Useful Minerals and Waste Rock" from the book "Hydromechanization of Opencast Workings" by G. A. Nurok (1970). All three are unique and useful additions to the world literature on hydrotransport. The Traynis book reveals the development and results of circular wheel stand tests to simulate hydrotransport in horizontal pipes, which is a potentially outstanding contribution to slurry pipeline technology. Graphical data and equations are presented which suggest that headlosses for coarse coal can be predicted with good accuracy for pipe sizes up to 14 inches in diameter. Wheel stands permit tests for pipe wear and lump degradation without recycling coal through pumps. Recommendations are made for wheel stand tests and for correlation of existing data.

Jan 1, 1976

By L. J. Kane

While analyzing synthesis gas produced from coal, the Bureau of Mines found that conventional procedures for naphthalene determination were difficult and time consuming. The Bureau developed a rapid and sensitive turbidimetric procedure, which requires only simple instruments and hence can be used in plant-control laboratories. The gas is passed through a saturated aqueous solution of picric acid at 3° to 4° C. whose turbidity is then measured at room temperature. A dispersing agent is added to prevent coagulation of the suspension on warming. Only about 1 mg. (0.015 grain) of naphthalene need be absorbed, and precision and sensitivity are a few ten-thousandths of a grain, or a few hundredths of a grain per 100 cubic feet. The determination can be completed less than 10 minutes after absorption. INTRODUCTION One of the functions of the Branch of Coal Gasification, Bureau of Mines, Morgantown, W. Va., is to develop economical methods for manufacturing, from coal, a mixture of hydrogen and carbon monoxide for producing hydrogen, methane, and other gaseous fuels. This raw gas may contain many impurities, including naphthalene. This impurity is usually determined by first forming naphthalene picrate in a water solution of picric acid, separating the picrate, and titrating the unreacted picric acid or the picrate itself.

Jan 1, 1957

By James R. Boyle

The mining methods and practices used at the Young zinc mine, American Zinc Co. of Tennessee, have resulted in a low-cost, high-yield operation. Zinc ore (sphalerite) occurs in limestone-dolomite beds of the Kingsport Formation and is mined by modified room and pillar method. Utilizing trackless mining equipment which incorporates a high degree of flexibility, this operation has had a steady increase in productivity.

Jan 1, 1965

By J. R. Bartels

The U.S. Bureau of Mines has established a wire rope research laboratory to examine the factors that affect the life of wire rope. Two sin-diameter 6x25 fiber core (FC) ropes were degraded on a bending fatigue machine, These were the second and third ropes in a series of tests on this construction and size rope. Tensile and nondestructive tests were performed on samples of the rope to determine the relationship between rope deterioration and rope breaking strength. The tests indicated that once a wire rope nears the end of its service life, both deterioration and the consequent loss of rope strength begin to increase at an accelerated rate.

Jan 1, 2010