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By Ronald S. Conti

This is the fourth and final article in a series that discusses underground fire-fighting preparedness. As with the previous three articles, it is based on interviews with 214 miners at 7 underground coal mines (referred to as Mines ?A? through ?G?) conducted by researchers of the National Institute for Occupational Safety and Health?s(NIOSH) Pittsburgh Research Center[Vaught et al. 1996]. The first article presented an overview of the study conducted by NIOSH on mine fire response preparedness and provided a general perspective on underground mine fires. The second article discussed miners? preparedness to evacuate a fire and their experience with incipient fires. The third article described miners? experiences in fighting underground mine fires and presented their perceptions of training and readiness for fire-fighting. This final article in the series offers suggestions to improve mine fire-fighting preparedness.

Jan 1, 1997

By M. J. Ferrante

Enthalpy and entropy increments above 298.15° K were determined for cop-per sulfate between 298° and 1,000° K and for copper oxysulfate between 2980 and 1,146° K by the method of copper-block drop calorimetry. Enthalpies, entropies, and heat capacities are tabulated for both compounds. In addition, free-energy functions are tabulated for the sulfate. Equations representing the enthalpies are given for each compound.

Jan 1, 1972

By D. A. Reynolds

[A few studies on the relationship of the fusion temperature of the ash of coke to that of the corresponding coal have been made on commercial high-temperature cokes. R. J. Rose3/ in 1921 compared the' fusion temperatures of the ashes of 10 coals and. the cokes produced from them and concluded tat they were in such close agreement that either figure could be used. More recently, Quarfort4/ found that the ash of coke fused at a somewhat lower temperature than that of the original coals As the ash of a coal and that of the coke produced therefrom have the same origin their chemical composition should be identical, provided that carbonization has not altered the inorganic, or ash-forming, constituents of the coal, and such alteration seems highly improbable. However, it has been shown5/ that coke is liable to contamination by iron during crushing and preparatory to sampling. Pieters6/ found that coke ash was cantaminated in this manner up to 0.4 percent. extraneous iron would lower the ash-fusion temperature because such iron may form ferrous silicate, which is readily fusible,7/ These results provide a basis for the prediction that the ash of coke will fuse at a lower temperature than that of the corresponding coil., especially if the fine grinding of the coke was done by rubbing surfaces of iron, as in a disk pulverizer or bucking plate.]

Jan 1, 1940

By Foster Fraas

The objective of this research was separation of one highly conductive mineral from a second conductive mineral , a procedure which is impractical in commercial electrostatic separators using metal rolls . Such separators permit separation of nonconductive from conductive minerals . A new technique involved use of carrier electrode rolls specially prepared by anodizing and / or oxidizing at high temperatures to form suitable oxide surfaces . Specific oxides included aluminum , copper , and nickel . The significant result provided by the new surfaces was the extension of the separation range to higher conductivities , an extension in relative mineral conductivity from 10-14 mhos . The results are in accordance with the blocking- layer theory .

Jan 1, 1964

By James S. Browning

Recovery of fine mica from a sample of impounded tailing from the Dixie Mines, Inc., crushing and screening operations, Heflin, Ala., was investigated to determine if plant losses of mica could be reduced while econmically producing a commercially acceptable mica concentrate. Conventional wet-tabling and agglomerate-tabling methods yielded concentrates assaying about 95 percent mica from the tailing that contained 17 percent mica. Products containing about 98 percent mica and accounting for mica recoveries of 86 percent were obtained by flotation, using as reagents sulfuric acid, kerosene, and coco amine acetate (a mixture consisting chiefly of dodecyl and tetradecyl amine acetates). The results of the batch flotation tests were verified by tests in a small continuous flotation pilot plant.

Jan 1, 1963

By Clarence Hall, J. J. Rutledge

Many of the fatal accidents in coal mines have resulted from the Explosives used in Use of explosives for breaking down the coal. These accidents have resulted both from the use of explo- sives that were not suitable and from the careless or improper use of suitable explosives. Investigation has shown that one of the commonest causes of dis- astrous explosions in the coal mines in this country has been a blown- out shot of black blasting powder or dynamite. The dangers that attend the use of these explosives were perceived several years ago, and in consequence the attention of powder manufacturers was directed to the production of explosives that would be less liable to ignite inflammable gas or dust. The manufacturers have been so successful in their efforts that it is now possible to obtain explosives which yield much shorter and quicker flames than black blasting powder or dynamite, and hence are much less dangerous to use in fiery or dusty coal mines. of explosives. To find out which of the many grades of short-flame explosives Government tests have the qualities that render an explosive most effective and least dangerous for mining coal, the United States Government established a testing station at Pitts- burgh, Pa., in 1908. This station is now under the charge of the Federal Bureau of Mines. Before the station was opened a state- ment of the requirements that the explosives in question would have to satisfy was drawn up and sent to manufacturers. A number of these sent explosives to be tested, and on May 15, 1909, a list of the explosives that had passed the tests was published. Since that date other brands of explosives have been tested and three more lists have been issued. The latest list, published in Miners' Cir- cular 2, Bureau of Mines, contained the names of no less than 71 explosives that had passed the tests prior to January 1, 1911.

Jan 1, 1912

By Melvin E. Poad

This Bureau of Mines report presents two phases of a research program to evaluate a single-entry system for longwall development. Organizations participating in the program; which began in July 1971, include the Bureau of Mines, the Mining Enforcement and Safety Administration, and the University of Utah, working under a cooperative agreement with Kaiser Steel Corp. at its Sunnyside mine in Utah. Part 1 of this report describes the present longwall mining practice, including a brief history, and discusses the advantages and disadvantages of a single-entry development system and its introduction in the United States. Part 2 of the report presents the research program; test design, instrumentation for ground and support evaluation, and the test results from the No. 2 mine. Subsequent reports will describe the research conducted in the No. 1 mine.

Jan 1, 1977

By Michael J. Pazuchanics

This report documents the current status of the U.S. Bureau of Mines ongoing investigation of the use of adaptive signal discrimination (ASD) systems to distinguish between cutting coal and cutting rock. Cutting-tool forces and vibrations were measured in the laboratory using both conical bits and roller cutters in a linear-cutting apparatus for several material samples and two cutting directions. A number of ASD systems consisting of one or more signal classifiers were trained and tested to study how data window size, type of signal feature, and combining (polling) of classifier results influence system performance. The results show that ASD system recognition rates can be improved by increasing data window size, removing air-cutting portions from the signal data, overlapping data windows, and combining (fusing) information at various levels of ASD system operation.

Jan 1, 2010

By A. W. Fahrenwald

Many factors enter into the efficient operation of the reciprocating type of gravity concentrator. Earlier investigators who studied these factor invariably used natural (crushed ore) products for their experiments, but in the present study synthetic products were used. The variables considered were (1) specific gravity of the sand grains, (2) size of sand drains, and (3) shape of sand grains comprising the table feeds. It is recognized, also, that the percentage relationship of the different kinds of grains is a factor affecting results. This factor is variable in one group of experiments but is thereafter kept constant.

Jan 1, 1929

By W. I. Nissen

This Bureau of Mines report presents the design for a commercial-sized flue gas desulfurization (FGD) demonstration plant that uses the citrate process. The goal of the Bureau's citrate process is to minimize the undesirable environmental impacts of industrial plants emitting SO2-bearing gas. The FGD plant is located at the George F. Weaton powerplant, Monaca, Pa. Construction was completed in April 1979 and will be followed by preliminary testing and a 1-year testing and evaluation program. Design capacity of the FGD plant is 156,000 scfm of 0.2-volume-percent-SO2 flue gas yielding about 16 tons of sulfur per day. The plant is intended to (1) clean fly ash, SO2, and Cl- from the gas while cooling the gas in a venturi scrubber, (2) absorb SO2 from the gas using 1,200 gpm of a countercurrent-flowing citric acid-sodium citrate-sodium thiosulfate solution, (3) react the absorbed SO2 in two 13,000-gal stirred closed vessels with added H2S, thus precipitating elemental sulfur and regenerating the citrate solution for recycle, and (4) recover the sulfur from the slurry by air flotation, followed by melting in a heat exchanger and separation from the occluded citrate solution in a sulfur decanter at 35 psi and 135° C.

Jan 1, 1979

By M. A. Cook

Crude titanium metal, produced by the reduction of titanium tetrachloride with magnesium, is contaminated with some excess magnesium end adhering magnesium chloride when it is removed from the reaction pot. The method of vacuum 'purification is described in which the crude mixture is heated in a vacuum at a temperature of about 1,700° F. and the magnesium metal and chloride are volatilized away from the titanium, leaving it practically magnesium-free in a sponge-metal form. The pilot-plant equipment is described in detail, together with the technique of operation and methods of sponge recovery. Operating data is given, which compares ten 24- to 30-hour heats with ton 48-hour heats, and finally, power and labor requirements are discussed. Vacuum purification of raw titanium produced by the Kroll process has boon employed for treating of several tons of raw titanium with results for superior to those achieved by the method of leaching and grinding. The operations described, while on but little more than pilot-plant scale, indicate commercial feasibility of the process, even though it is a batch-typo operation. All equipment is either of standard manufacture or can be readily fabricated from standard materials, and operation of the units can be satisfactorily maintained by semiskilled labor.

Jan 1, 1952

By Will B. Jamison

An ignition detection and suppression system was developed under the scope of this contract. The objective of this machine mounted system was to detect flames caused by frictional sparking from the cutting bits of a continuous mining machine and to suppress it with sufficient speed to prevent the development of an explosion, and to keep the flame from harming the machine operator.

Jan 1, 1976

By W. F. Wyman, S. F. Ravitz

"INTRODUCTION By far the greater part of the high-grade manganese ore used in the United States is imported from overseas. During the early part of the recent World War importations of manganese ore were seriously threated, and it appeared that it would be necessary to utilize low-grade domestic ores to the fullest possible extent. Among the processes that appeared to offer the best possibilities for beneficating low-grade domestic oxide manganese ores, which ordinarily are net readily amenable concentration by ore-dressing methods, were those involving leaching with sulfur dioxide. The Bureau of Mines therefore investigated the amenability of a large number of such ores to sulfur dioxide leaching.Several sulfur dioxide processes for beneficiating low-grade oxide manganese ores have been proposed. 3/ One of these, based on a patent by Van Arsdale and Maier, 4/ was used recently in a plant constructed to treat 1,000 tons per day of 20-percent manganese ore from the Three Kids deposit near Las Vegas, Nev. 5/ In this process the ore slurry is leached with sulfur dioxide gas, the resulting solution is evaporated to crystallize the manganese sulfate, the crystals are decomposed thermally to produce high-grade manganese oxide and regenerate sulfur dioxide, and the manganese oxide product is nodulized. The Bureau of Mines has recently developed a process 6/ in which a suspension of the ore in calcium dithionate solution is leached with dilute S02 gas, the manganese is recovered from the resulting solution by a simple lime precipitation, and the precipitate is nodulized or sintered to form a high-grade manga¬nese oxide product."

Jun 1, 1947

By W. W. Adams

[Sales of explosives - permissible explosives5/ other high explosives, and black blasting powder - in the United States during the calendar year 1937 reached a combined total that slightly exceeded the quantity sold in 1936. A larger output was reported for permissible and other high explosives but a smaller for black powder. Production of the three classes of explosives totaled 404,744,294 pounds, more than 3 percent over 1336. The total quantity produced included 49,579,441 pounds of permissible, 288,924,253 pounds of other high ex- plosives, 36,403,950 pounds of black powder in pellet form, and 23,836,550 pounds of black powder in granular form. Sales of granular black powder declined 26 percent compared with 1936 and of pellet black powder 12 percent; gales of permissible explosives increased nearly 4 percent and of other high explosives 10 percent]

Jan 1, 1938

By H. E. Perlee

Autoignition temperatures and limits of flammability of nine halogenated hydrocarbons in atmospheres of air, oxygen, and nitrogen tetroxide were measured in a modified standard autoignition apparatus and limit-of-flammability apparatus previously developed at the Bureau of Nines. Of the nine halogenated hydrocarbons investigates--bromochloromethane, bromotrifluoromethane, bromochlorodifluoromethane, 1,1,2-trichlorotrifluoroethane, 1-bromo-l-chloro-2,2,2-trifluoroethane, dibromodifluoromethane, l,2-dibromo-1,1,2,2-tetrafluoro-ethane, 1,1,1,3,3-pentachlorotrifluoropropane, and l-bromo-2,4-dichloro-1,1,2, 3,3,4-hexafluorobutane--two formed flammable mixtures with nitrogen tetroxide and six with oxygen; none formed flammable mixtures with air. Three of the halogenated hydrocarbons formed no flammable zones with any of the three oxidizing atmospheres. For those halogenated hydrocarbons that supported combustion in oxygen atmospheres, explosion pressures developed during constant-volume burning of mixtures near the middle of the flammable zone were observed to range from about 6 psig for dibromodifluoromethane to 158 psig for 1-bromo-1-chloro-2,2,2-trifluoroethane. In all cases, the calculated burning velocities of these mixtures were less than 8 in/sec.

Jan 1, 1966

By A. J. Kraemer

For a number of years the Bureau of Mines has been conducting an investi-gation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from some oil fields of Louisiana are given in Bulletin 291. Analyses Of 26 representative crude oils from various producing formations of southern Louisiana are given in this report. These samples are from 14 fields in 10 parishes in the southern part of the State, usually designated as the "Louisiana Gulf Coast area."

Jan 1, 1934

By F. P. Haver

Primary lead is produced in the United States by the pyrometallurgical smelting of lead sulfide (galena, PbS) concentrates, which poses sulfur dioxide and lead air pollution control problems. The Federal Bureau of Mines has investigated an alternative hydrometallurgy procedure that does not generate gaseous sulfur oxides and diminishes the potential for the escape of lead into the atmosphere. The procedure involves leaching galena flotation concentrates with ferric chloride (FeC13) solution to obtain lead chloride (PbC12) and elemental sulfur as expressed by the following chemical reaction: PbS + 2FeC13 ? PbC12 + 2FeCl2 + S°. At 100° C, over 99 pct of the PbS in the concentrate is converted to PbCl2 in less than 15 min. The leach solution, composed of brine (NaCl) containing slightly more than the theoretical required amount of FeC13, dissolves the PbC12 as it is formed, leaving a residue of elemental sulfur plus gangue. High-purity PbC12 (>99.9 pct) crystallizes from the leach filtrate on cooling and is electrolyzed in a low-temperature, fused-salt cell to obtain corroding-grade metal (>99.94 pct Pb). Spent leach solution (FeC12) is regenerated for further use by reaction with the chlorine obtained in the electrolysis of lead chloride. Other values, such as Ag, Cu, Zn, and S°, are recovered by additional treatment of either the leach solution or leach residue.

Jan 1, 1976

By K. L. Paciorek

The aim of the present study is to determine on a gram per gram basis the toxic products of the thermal oxidative degradations of selected compositions. Four families of materials were investigated under the subject contract namely polyvinyl chloride and neoprene compositions, rigid urethane foams I and woods. Three methods were employed to conduct the thermal oxidative degradations: a sealed system (quiescent environment) I a stagnation burner arrangement (dynamic environment) I and a flow-through apparatus (dynamic I but less severe than stagnation burner conditions). The majority of tests were conducted using the first two systems; only limited experiments were carried out employing the third decomposition procedure. All decomposition was done at temperatures of 370 -4000C I the higher temperature being used in the stagnation burner. It has to be stressed that the nature of the products and the relative product concentration are temperature dependent. Thermogravimetric and differential thermal analyses were performed to supplement and extend the above delineated studies and to explore the feasibility of using these analyses as a method for material differentiation.

Jan 1, 1973

By Parry. V. F., John B. Goodman

"INTRODUCTION The Denver region coal field, covering an area of approximately 7,640 square miles, extends from the Wyoming State line to the middle of El Paso County, Colo. The coal in this region is subbituminous in rank. Much of it is used as domestic fuel. During the last decade the production of coal in this field has remained fairly constant at an average of 2,600,000 tons per year. This production has come from 50 to 60 mines, 88 to 90 percent of the production being from the section of the field north of Denver.According to the Standard Specifications for Classification of Coal by Bank of the American Society for Testing Materials 4/ the coals in this region are classified in the Subbituminous B and C group. On the as—mined basis, they contain about 22 percent moisture and average 9,600 B.t.u. per pound. They are noncoking and slack to a variable extent when exposed to the weather. This is characteristic of subbituminous coals."

Aug 1, 1939

By L. M. Irwin

This Bureau of Mines investigation relates the physical properties of copper reverberatory furnace slags to changes in composition, The smelting of upper Michigan copper ore presents some problems that probably differ from those of other copper smelting areas. The study of these problems has, however, provided important data regarding slags in general and therefore will be of value to other operations as well. Conclusions reached from this study were: (1) Slag fluidity and refractive indices varied directly with the iron content and inversely with silica, lime, and alumina, and (2) there was no apparent correlation between slag fluidity and its copper content.

Jan 1, 1962