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By Jurgens J. Louw, Vincent C. Smith, Gareth C. Smith, Agit Singh, Dave G. Hulbert

"During 2000 Mintek Developed the PlantStar plant wide control platform for the minerals processing industry. The flexibility of the PlantStar control platform has enabled Mintek to investigate and easily develop new control strategies for both milling and flotation. This includes a Solids Feed Controller, a Safety Limit Controller, Mill Power Optimiser and Flotation Optimiser, amongst others.Processes with long dead times, like a feed belt to a mill, are difficult to control. The solids feed controller was developed for minerals processing plants using a specialised time delay compensator. Using conventional time delay compensators that are purely model based, results in robustness problems due to model uncertainties. The Mintek Solid Feeds Controller makes use of a plant model, but compensates for model inaccuracies, giving more controller stability and a more robust delay compensation algorithm.Often there are more variables on a plant that need to be controlled (process variables) than there are variables to control them with (manipulated variables). Process constraints are often reached and violated. Safety control loops are necessary to prevent constraints being reached. The safety limit controller has been developed to switch smoothly between normal and safety control loops without bumping the process. The safety loop output is chosen in accordance with a predefined list of priorities and whether the respective constraint boundaries are exceeded.The Mill Power Optimiser helps to find the power peak on the mill power curve. It continuously perturb the solids feed rate to learn ‘where’ on the curve the mill ‘was’ and then to drive it continuously toward the middle, maximum power drawn. This insures maximum grind with maximum throughput. It also prevents power dips due to mill overloads by cutting the solids feed to a minimum if the power drop below a specified threshold. Once the power rises above the threshold the solids feed is increased again to an intermediate value from where it start the perturbations again to find the maximum. This makes the milling circuit easier to operate."

Jan 1, 2003

By Knut L. Sandvik, Erik Larsen

"Estimated global solar energy demand in 2001 required approximately 5,500 tons of silicon feedstock. This required 65,000 tons of quartz. If the trend continues, the solar energy demand in 2010 would require approximately 30,000 tons of silicon feedstock and 350,000 tons of quartz, although the need for quartz probably will be lower than this due to higher solar cell efficiencies, larger and thinner wafers, more extensive recycling of waste material and new routes for the production of silicon feedstock. The raw material requirements for the production of metallurgical-grade silicon are most likely to change. This may favour increased beneficiation of primary raw materials in the future solar cell production chain.SOLAR CELL PRODUCTION CHAIN SCENARIOSThe major problem concerning solar cells is the production costs. Electricity produced from fossil fuels and hydropower plants are currently much cheaper than the electricity produced from solar cells. Also, limited availability of silicon feedstock for the production of crystalline silicon solar cells is considered a major threat to the further growth of the PV industry. The present route for solar silicon feedstock goes from quartz, through metallurgical-grade silicon (MG-Si) and to electronic-grade silicon (EG-Si). The reject from the EG-Si production are further processed into wafers and solar cells. This situation is not satisfying, however, because it has created a silicon feedstock shortage and a PV energy price that is not competitive in a large scale.Crystalline silicon solar cells are the most important solar cells manufactured today. This will most probably remain the situation the next decade. Also, the future silicon ""feedstock"" is most likely not reject from the production of electronic-grade silicon, as it is today. There will probably be a more direct solargrade silicon route, excluding the very expensive electronic-grade silicon ""detour"". Quartzite has been regarded as the most suitable primary raw material used in the silicon solar cell production chain. This may change as the raw material requirements for the production of metallurgical-grade silicon are most likely to change. In addition, quartz or other silica-containing minerals from other rocks may be of a higher purity or contain lesser amounts of the most harmful elements. This favours increased beneficiation of primary raw materials in the future solar silicon feedstock production chain"

Jan 1, 2003

By Atsushi Shibayama, Toyohisa Fujita, Luo Lin, Toshio Miyazaki

A novel process is developed in this study for separation of tungsten and vanadium from a leach solution of tungsten alloy scraps. Specifically, a magnesium salt combined ammonium solution is employed to precipitate vanadium and impurities in the purification of the leach solution. This separates vanadium from tungsten by rejecting tungsten in aqueous solution. Finally, tungsten is recovered as the form of ammonium para-tungstate (APT). Vanadium is recovered as the form of ammonium meta-vanadate(AMV).

Jan 1, 2003

By Johann Botha, Niel de Clerk, Tony B. Lange

"PROCESS COMPLEXITYDespite many years of research and development, mineral and metallurgical processes are in general highly complex and still difficult to understand and control. One of the biggest factors contributing to this complexity is the highly non-linear, multivariate, chaotic nature of such processes.This complexity is magnified in production environments where business optimisation rather than beneficiation is the primary objective. Return on investment, sustainability, and social issues such as Aids and the environment all form part of the goal hierarchy of industrial concerns. In addition, international competition and price volatility all have a huge impact on these processes in terms of operational constraints.Therefore the optimisation and control of beneficiation processes must take into account many factors other than pure process variables such as flow rates and levels. For example, commodity prices and client requirements all need to be added to the control problem, which together with incomplete process knowledge and non-linearities etc., make automation and optimisation extremely difficult.The ideal solution is to have a controller which in addition to performing full non-linear constrained optimal control can at the same time take into account other non-process factors such as price and client satisfaction."

Jan 1, 2003

By Zhou Junwu, Sun Chuanyao, Wang Fuli

"In this present paper, the authors introduce the artificial neural networks into the modeling of the industrial flotation process, integrating information technology, control theory and intelligent optimizing method to flotation technology. The new idea gives a new way to solve the difficulty in this field, and therefore brings the study on the automatic control of flotation process in China into a new start.The Radial Basis Function (RBF) network, featuring a quick learning speed, is one of the feedforward neural networks. It has attracted much attention from automatic control recently for its implementing the nonlinearity mapping through adjusting the parameters of the nonlinearity transfer function. One of the online adaptive learning algorithm—the nearest neighbor-clustering algorithm, which can automatically determine the number of hidden units, has been implemented in the MATLAB programming language in this paper, laying the foundation for the flotation models.The relation model between ore pulp characteristics and reagents consumption has been proposed using the RBF networks based on the industrial lead rougher flotation of lead & zinc ore, and the simulation has been conducted in the laboratory with the results matching the samples data very well. The Xilin Lead & Zinc Mine Flotation Process Intelligent Consultation System of Reagents Consumption, which suitable for industrial process, has been developed. The reagents consumption advised by this system would stabilize the flotation process, and increase the recoveries. It could be used for providing the technological consultation to flotation operators in site, and for training new operators."

Jan 1, 2003

By Jochen Petersen, Harro von Blottnitz

"The landfill disposal of slags is common practice in the metallurgical industry. Chromium may be a minor constituent in many cases. It is present mostly in the form of chromites, which are considered environmentally benign and hence safe for disposal. Wastewaters from metal finishing operations are most commonly treated by reduction and precipitation of dissolved metals, including chromium, by lime addition, and subsequent landfill disposal of the resulting sludge. The metals contained in such sludges are mostly in the form of hydroxides, and as such considered environmentally stable.Thermodynamically, trivalent chromium, which is the predominant form in these waste materials, can be oxidised to the hexavalent form by atmospheric oxygen. Detailed research work on both slags and sludges has shown that a gradual emergence of hexavalent chromium can indeed be observed. The mechanism is governed by close physical contact between chromium oxide (or hydroxide) phases on the one side and calcium oxide (or hydroxide), which is present as flux in slags and residual lime in sludges, on the other. If oxygen can migrate to the points of contact, gradual formation of calcium chromate ensues.Hexavalent chromium is associated with high environmental toxicity, and hence undesirable in landfilled materials. Moisture migrating through landfill deposits can mobilise the highly soluble chromates and thus potentially transport them into natural waterways. Such gradual release from stainless steel and ferrochromium slag deposits has been demonstrated in a column experiment."

Jan 1, 2003

By M. T. Spyridopolous, S. J. Neethling

"There has been a significant research interest in the stability of single thin films, including prediction of their failure based on disjoining pressure and film thickness experiments and DLVO theory. It is, however, notoriously difficult to correlate information on the failure of a single thin film with measurements of foam stability. This is particularly true for the prediction of dynamic foam stability indicators, such as equilibrium froth height and surface bubble size.An alternative experimental approach to studying single thin film failure for predicting foam stability is to measure directly the coalescence probability between two approaching bubbles in a surfactant solution. These experiments can be performed under different chemical and physical conditions by using a micromanipulator that allows variation of bubble size, surfactant concentration, approach velocity and stationary position. The interface radius of curvature, the time to coalescence and the film area between the bubbles can be measured directly using image analysis.In a foam, the force exerted on the thin film separating two bubbles depends on the local radius of curvature of the Plateau borders and vertices, which depends in turn on the local liquid content. Results from different bubble sizes in the micromanipulator therefore translate into regions of different liquid content in the foam. Small bubbles, having a high radius of curvature correspond to the low-liquid content (Polyhederschaum) region higher in the foam, and large bubbles to the wetter (Kugelschaum) region closer to the liquid-foam interface. Experiments with different holding distances between the bubbles correspond to differences in bubble size in the foam, as the size of the film between the bubbles varies."

Jan 1, 2003

By Roberto C. G. Oliveira, Scott C. Brown, Brij M. Moudgil

"The wettability or surface energy of particle surfaces dictates a number of multiphase ensemble interactions that have a significant impact in mineral processing. Dispersion, bulk powder handling and flotation are just a few of the processes that are largely influenced by the degree of hydrophillicity or hydrophobicity on particulate surfaces. Because of the importance of surface wettability, a number of simple, precise and accurate techniques for accessing surface wettability or contact angle on macroscopic flat surfaces have been developed. However, these techniques cannot be directly applied to the particulate surfaces that are often in query. Though a number of techniques are available for accessing the wettability of particulate surfaces, these methods are either relative, application specific or prohibitively tedious. In the present study, key features of existing techniques are combined to formulate an improved method to delineate particle wettability that is simple, versatile and capable of providing reproducible measurements in an industrial environment.Through the use of an inert adhesive and an inert macroscopic surface as a support, it is illustrated that precise measurements of particle wettability are obtainable under suboptimal or ‘shop floor’ conditions. The measurement of the maximum external meniscus height formed between a test liquid and a particlecoated rod is employed to estimate phenomenological contact angles on particles ranging form a few nanometers to several hundred microns in size."

Jan 1, 2003

By B. C. Qi

"In water treatment, flocculation or coagulation with aluminium or ferric salts has been widely used for many years to remove natural organic matter (NOM), including humic acids. However, the adsorption of NOM to aluminium hydroxide flocs during conventional coagulation/flocculation processes is very complex, with the flocculation of aluminium hydroxide particles and the adsorption of NOM molecules on flocs occurring simultaneously. Any effect on the surface characteristics and micro-structures of the humic acids and aluminium hydroxides could affect the adsorption efficiency.It has been widely observed that if a reaction system (liquid-liquid or liquid-solid) is exposed to an ultrasound field, under appropriate conditions, a variety of physical (emulsification, aggregation/flocculation) or chemical (the production of radical and exited species; single electrotransfer) actions may be activated. Though the ultrasound effects have been used in biological and chemical decontamination in many conventional environmental protection practices, the idea to explore the ultrasound effects in the removal of humic acids by preformed aluminium hydroxide flocs is relatively new. In this paper, the effect of an in-situ ultrasonication on removal of the humic acids extracted from the acidification fermentation of lignocellulosic residues, by a preformed aluminium hydroxide, was evaluated; the effect of ultrasonication on the surface complexation of the humic acids with the preformed aluminium hydroxides was investigated."

Jan 1, 2003

By Daniela Venter, Stephen Chryssoulis, Ken Stowe

"A sampling campaign was conducted at Kemess in order to identify and assess the chemical and physical factors, which control free gold flotation kinetics in the rougher and cleaner circuits. The rationale behind this approach was that accurate knowledge of the parameters affecting free gold flotation kinetics, can be used to determine how to accelerate free gold flotation. Collected samples were composites of 5-6 cuts over a four-hour period, at steady plant conditions.In the rougher circuit, coarser equidimensional gold particles floated ahead of the finer grained and the flaky gold. Sulphur followed by molybdenum and to a lesser extent silver enhanced gold flotation kinetics, while hydroxyl followed by carbonate ions induced depression."

Jan 1, 2003

By Jian Zhang, Yongfu Yu, Fuguang Zhang, Liping Che

There is one large-scaled iron ore deposit in Inner Mongolia of China, but it is very complex which includes about 170 types of minerals and 71 elements. The hematite, magnetite are mainly iron ores. It is difficult that the iron mineral can be separated efficiently by common dressing methods due to the complexity, and the iron concentrates in the mineral processing factory contains many foreign substance such as K, Na and Si so that the process in iron mill is influenced because of the foreign substance, so it is vital reducing the foreign substance.

Jan 1, 2003

By Jan J. Cilliers, Nicolas Barbian, Esther Ventura-Medina

"Mineral froth flotation is one of the most widely used processes to separate particles of valuable mineral from its associated gangue. It involves the selective separation of the hydrophobic particles from the slurry into the froth. The hydrophobic particles attach to the air bubbles and rise up to the froth phase on top of the slurry. The valuable mineral is collected when the froth overflows the cell wall. The separation performance of the process can be linked to the amount of solids and valuable material loaded on the bubble shells. In addition, it is well known that in most mineral systems, the presence of solids can enhance the stability of the froths. How the solids get to be distributed and what proportion is actually attached and stabilising the bubbles is not well known.This study aims to establish the relationship between operational variables, solids loading on bubbles and flotation performance. For this purpose, a series of industrial experiments to sample the solids in the bubble films under different operational conditions were carried out in two copper concentrators under steady state conditions. Samples of the lamellae were taken by touching the top surface of the bubbles with a glass slide. The amount of solids and liquid per unit area in the bubble lamellae can subsequently be estimated gravimetrically and by image analysis. The grade of the attached particles was also measured by adequate sampling. This gives an indication of the maximum grade that could be achieved from the process under the operating conditions."

Jan 1, 2003

By Paolo Bevilacqua, Paolo Antonini, Lorenzo De Lorenzi

"Italy is one of the major producers of ceramics in the world. Ceramic production requires large quantities of K-feldspar, which is commonly sourced from granites, alkali-granites, and “granitic” sands. These rocks contain other minerals, such as quartz, plagioclase and mafic minerals, which are undesirable for ceramic production. Due to the coarse mineral grains that constitute these rocks, a reasonable liberation is achieved at a relatively coarse grind size.This paper reports a study conducted on the separation of K-feldspar from quartz, plagioclase and biotite, from a feed of ground granite. The feasibility of the separation using a dynamic dense medium separation system has been investigated, as an alternative to the traditional flotation technique. The use of a two stages cylindrical vessel (Tri-Flo) was preferred to a conical vessel, due to the improved separation efficiency. Tests were conducted on two samples of crushed granite having size distributions of –3 +1 mm and –1 +0.5 mm.Heavy liquid analysis was performed on the two samples. As the rheological properties of the dense medium interact with the separation efficiency, the stability and viscosity of the dense medium were controlled and kept within an appropriate range; which was achieved with the addition of an artificial contaminant (clay) to the dense medium."

Jan 1, 2003

By Victor Avdokhin, lvan Kovlekov

"Studies of the process of concentration of gold-containing sands and technogenic resources show that the main reason of gold losses is misbalance between size of gold particles and degree of roughness of mineral bed. This results in free circulation of small gold particles in pores with following washing off the particles from the bed by turbulent flows.We elaborated design of magnetic sluice, intended for improving efficiency of recovering fine gold by optimizing magnetic field of a magnetic system on the base of forming catching coat from magnetic mineralsThe magnetic sluice includes trough-shaped body from magnetic-conducting material. On the bottom of the trough, magnets are placed, and opposite poles of the magnets are oriented outwards. Thickness of the bottom is determined to be sufficient for locking magnetic lines of force of the magnets on each other. The magnets of rectangular plate shape are placed on the rough bottom, covering the whole surface or with spare areas; the magnets are placed across the trough with alteration of rows with the same pole orientation."

Jan 1, 2003

By Wang Xiaotie, Yu Yongfu, Che Liping, Zhang Fuguang

The flotation process of native Rare Earth minerals such as bastnasite, monazite, mixed minerals of bastnasite and monazite, using the new effective collector Dh was studied in this paper, respectively, and the flotation properties are described. The good qualities of the new collector Dh were revealed through comparing with other collector of Rare Earth minerals. The test results of different ore samples show that at moderate pulp pH (8.5-9.5), Rare earth minerals can be effectively separated from barium, calcium and silicon bearing intergrowth minerals (barite, calcite and silicate minerals) and high quality Rare Earth concentrates can be obtained successfully by the new collector Dh, acid silica gel, turpentine and reagents fitting together rationally. In order to determine optimum technical conditions, the effect of pulp pH, pulp temperature, pulp density and the effect of dosage of reagents (Dh and acid silica gel) on the flotation were investigated in the test.

Jan 1, 2003

By Jan J. Cilliers, Nicolas Barbian, Esther Ventura-Medina

"Froth structure and stability are known to play an important role in determining flotation recovery and selectivity. An industrial sampling campaign was performed to develop a clearer understanding of the effect of flotation variables on froth stability and the role played by the resulting stability on flotation performance.Froth stability was estimated as the fraction of bubbles bursting on the surface of the froth through image analysis and the solids loading on the bubbles at the top surface. The image processing was performed using the Smartfroth software on the top surface of the froth. The system gives measurements of bubble size distribution, average bubble size and froth velocity. The froth velocity was used to estimate the volume of bubbles overflowing the weir yielding to the fraction of air overflowing the cell. This measurement is the complement of the rate of bubble bursting on the top surface. Also samples of the lamellae were taken by touching the top surface of the bubbles with a glass slide. Then, the amount of solids and liquid per unit area in the bubble lamellae was estimated gravimetrically. Both measurements were used to establish stability criteria.It was generally found that high air flowrates resulted in a drop of froth stability showed by a drop in the fraction of air overflowing and a decrease in the solids loading and simultaneously produced low copper recoveries and low concentrate grades. Deep froths only allowed a small fraction of air to overflow and consequently produced low recoveries. An increase to high frother dosage did not result in an improved fraction of air overflowing, hence producing low recoveries. Likewise, low frother addition only allows low recoveries because the resulting unstable froth cannot support itself. Low aeration was found to be preferential as it allowed high particle loading, therefore high bubble stabilisation, and low gangue entrainment, resulting in the highest flotation performance."

Jan 1, 2003

By S. Fiore, M. C. Zanetti, C. Clerici

The processes and fluxes of a cast iron foundry plant located in the North of Italy were analyzed in order to determine the amount and kind of wastes produced from the different activities. The main fractions are the molding sands, furnace muds and powders coming from the dust abatement plant, the exhaust lime, the furnace refractory, the metallic shotting and the sludges and powders coming from the dust abatement plant of molding lines for a total production equal to 800 t/d. All wastes were sampled and particle-size and chemically characterized to evaluate the best recycling or reuse solutions. Wastes were sieved and divided in three categories according to the particle-size dimensions: below 0.1 mm, between 0.1 and 0.6 mm and above 0.6 mm. The fraction above 0.6 mm dimension underwent magnetic separation to recover and quantify the potentially available iron fraction. The fraction between 0.1 mm and 0.6 mm was chemically characterized in order to understand if it could be fed to the sand regeneration plant. The below 0.1 mm fraction was characterized to evaluate the following recycling and reuse solutions: additive for molding sands and/or raw material for the concrete industry.

Jan 1, 2003

By A. V. Nozhkina

"Transformation of diamond into graphite was investigated in the region of diamond metastability under the action of media chemically active relative to carbon in the temperature range from 770 K up to 2200 K and pressure range from 10-3 Pa up to 3 GPa/IV VIII group metals of periodic system and oxygen were used as media chemically active relative to diamond.Methods of electron diffraction, chemical analyses, emission spectroscopy and X-ray phase analyses were used for determination of the reaction products.It was found that in the region of diamond metastability the stage of catalytic phase transformation of diamond into graphite took place during the interaction between diamond and metal. Metal reduce activation energy for transition of diamond into graphite from 109,4 kcal/mole to 77,4 kcal/mole.Kinetic of phase transformation of diamond into graphite was investigated.Pressure does not considerably influence on the rate of phase transformation of diamond into graphite in the presence of transition metals."

Jan 1, 2003

By Christopher Davey, Marian Mazurkiewicz, Yvonne Spooner, Dana Hankey, Peter Kanjorski

The concept of a high pressure liquid jet mill with highly unsteady flow, has been developed and recently patented by Cornerstone Technologies LLC (CsT), for the purpose of micron and sub-micron particle production. The mill accepts feed sizes up to 15mm for some materials and is capable of submicron production. Successful material range from precious metals such as silver and palladium to dielectric components and substrates such as Barium Titanate slips, zirconia, titania and silica. The process has also succeeded in adequately reducing the size of materials for both composite and coating uses such as anthracite coal, graphite, chrome metal, wollastonite and more than 100 others. A unique design approach has been taken to highly maximize the energy flux in the mill's chambers to create extremely high turbulence and destructive cavitation. This is assisted by shock waves, which cause particles to undergo ultra high frequency pressure pulsations, high frequency collisions and then abrasion, shattering, hydrowedging, and cleaving. Due to these extreme properties the processing occurs in just fractions of a second allowing throughputs up to 1000 kg/h on a machine that would fit inside a 60 cm box. The technical solution and technological advance, as well as the environmental and economic benefits indicate rapid and wide spread acceptance of high-pressure liquid jet milling in modern industry.

Jan 1, 2003

By P. Huang, D. W. Fuerstenau

Various factors that control the natural flotability of talc, including differences due to crystal face and edge effects, were delineated. For study of talc depression phenomena, dextrin was used as a model depressant. For the enhancement of talc flotation, dodecylammonium acetate (DDAA) was used as the collector. The interaction of DDAA with talc was assessed by flotation experiments and electrokinetic (zeta potential) measurements, from which the role of hydrophobic bonding can be demonstrated. The results presented in this paper provide useful information on how the crystal chemistry and surface chemistry control the electrical double layer, adsorption phenomena, wettability, and flotation behavior of talc in aqueous media.

Jan 1, 2003