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By G. C. He

Effects of irregularity, rough surface and aggregation of fine particles on ultrasonic attenuation are significant. The effects should be considered while predicting particle size by ultrasonic attenuation technology. The scanning electron microscope micrographs analysis also shows that particles surface is rough and irregularity. Any slurries has its fractal structure and its special fractal scale and dimension, so, effects of irregularity, rough surface and aggregation of fine particles can be de-scribed by fractal model. The discrepancies between predictions of ultrasonic attenuation based on the assumption of smooth spherical particles and data obtained from slurries of irregular particles indicated that there were different fractal structures. The ultrasonic attenuation model was modified by fractal dimensions. The result of experimental data and analogue calculation indicated that pre-dictions of the fractal modification of ultrasonic attenuation model show good agreement with experimental data. On the other hand, from the values of fractal obtained by inversely calculation, the degree of effects of irregularity, rough surface and aggregation of particles can be estimated. The positive value of fractal dimension indicates that the aggregation has the dominant effect on ultra-sonic attenuation, otherwise, the irregularity and rough surface has the dominant effect.

Jan 1, 2014

By R. B. Shu

A moderate thermophilic microorganisms, has been isolated (45?) from a typical sulphide mine in the region of Mo Jiang located in the southwest of China. The culture has been used to extract copper from chalcopyrite concentrates obtained from De Xing copper mine. The majority of experiments were carried out in 300mL Erlenmeyer flasks containing 150mL volumes of mineral suspension. Effects of some variable parameters such as solids concentration, pH and the concentrations of inorganic nutrients on the bioleaching of chalcopyrite obtained from De Xing copper mine were investigated. For a given concentrate the most important factor affecting the fractional copper extraction was the size of the mineral particles. The overall rate of leaching was found to be limited by the area of mineral surface. The attack started in cracks and genetic defects and finally reached the whole chalcopyrite surface. As a consequence of this, the ore showed strongly cracks. The additive of ferrous sulfate increases the bacteria activity, but did not improve chalcopyrite bioleaching. The results indicate that the nature and relative proportions of the various minerals present have been shown to be important factors.

Jan 1, 2014

By T. J. Chen

Vanadium-beard bone coal is one of important vanadium resources in China.To extract vanadium tailings from Stone coal is produced after extracted vanadium from stone coal through the roasting, leaching and other processes. About 120-150 tons of tailings will be produced in extracting 1 ton of vanadium pentoxide. A lot of tailings that are willfully piled up have caused serious environmental pollution and wasting of resources; it is therefore necessary to realize its resource utilization. This study increases the activity of vanadium tailings by means of alkali fusion, and then uses different alkali activators to react with vanadium tailings so that geopolymer with high value added is produced. Sample of geopolymer is acquired from a mixture containing vanadium tailings, alkali activators, water and a little sodium aluminate through compression-molding process under 20MPa pressure. After cured in room temperature for three days, the maximum compressive strength of the sample can reach 36.2MPa. XRD analysis indicates quartz, the major crystal phase in vanadium tailings is decomposed,and the activity of vanadium tailings is heightened. FTIR and SEM analyses show: structural change having an important impact on the mechanical strength of geopolymer occurred during the process of vanadium tailings generating geopolymer.

Sep 1, 2012

By Avinash Tripathi

It is now well known that the size distribution of the particulate solid has a significant effect on the breakage behavior of particles in the wet as well as dry modes of ball milling operation. In the context of the size discretized batch grinding kinetic model, grinding behavior of particles is characterized by the breakage rate parameters, k, and breakage distribution parameters, B. Understanding the nature of variation of these two sets of parameters with particle size distribution is important for simulation and control of operation of production mills. However, so far it has not been possible to track the variation of both the set of parameters with grinding time simultaneously. In this paper an attempt has been made in this direction by using a modified functional form approach with time dependent constants. Keywords: dry and wet ball milling, breakage rate and distribution parameters, effect of particle size distribution

Sep 1, 2012

This study examines the surface alteration and flotation behaviour of synthetic moncheite, PtPd(BiTe)2, in the presence of pentlandite. The telluride minerals contribute around 20% ~ 30% and up to 45% of the PGM present in the Platreef ore and are considered to be slow floating as there is evidence of these minerals reporting to the tailings. It was proposed that oxidation products from other minerals and grinding media would affect the mineral surface composition and floatability thereby causing inadvertent depression of moncheite due to precipitating ions. ToF-SIMS analyses (time of flight secondary ion mass spectrometry) was used to characterise the mineral surface as well as the extent of surface alteration. Microflotation was used to deter-mine the hydrophobicity of the synthetic minerals. Conditioning of moncheite in the presence of pentlandite reduced the flotation response of the + 38 -106µm size fraction from > 99% to 56%. This was due to pentlandite dissolution products (iron and nickel hydroxy species) which formed overlayers on the mineral surfaces thereby inhibiting the adsorption of collector. In addition, further grinding of these samples, with and without pentlandite conditioning showed a negative effect on recovery due to the fineness of the particle size distribution and there was no advantage gained from any possible exposure of fresh sites in the sample.

Jan 1, 2014

By Vladko Panayotov, Marinela Panayotova

"Recently, in order to extract metals, the industry is trying to process old metallurgical slag. The material requires very fine grinding that results in enhanced slime-formation. This in turn leads to problems in the course of the flotation process and to a loss of metal. In addition, it causes difficulties in the wastewater treatment aimed at water reuse. The aggregation and separation of the fine particles and their further subjecting to mineral processing would result in more efficient use of raw materials. Closing the water cycle also would be facilitated. The paper presents results from studying sixteen flocculation reagents, commercially available for treating municipal wastewater, including products based on nanotechnology, for their ability to rend the production wastewater in suitable for reuse in the flotation. It turned out that, from all studied reagents, the cationic C-587 is suitable for the purpose. Some of reagents were studied for their ability to flocculate selectively, in presence of coke fines, rich in copper fines which are produced at grinding of a slag from lead-zinc metallurgy. Most promising reagents are chosen, based on the chemical analysis of the flocculated materials. Open-cycle rough copper flotation experiments with the flocculated fines and recycled wastewater gave encouraging results."

Jan 1, 2014

By J. J. Liu

In the Bayer process, control of alumina trihydrate particle size, oxalate stability and morphology and foaming is crucial for improving the yield and quality of alumina trihydrate. One way to economically achieve such control is to employ specifically developed chemical additives, termed, crystal growth modifiers (CGM?s). In this paper, the mechanism of action and practical application of CGM?s in the Bayer process are summarized. The application of CGM additives allows for both enhanced agglomeration and secondary nucleation control, and hence coarsening of the particles. Current research efforts have utilized the information gained from mechanistic studies to enhance the performance of CGM products. It was demonstrated in both laboratory tests and industrial operations that the newly developed CGM formulations have a range of properties with enhanced performance, compared to the current commercial products.

Jan 1, 2014

By M. Etelapaa

A new approach to controlling the process of selective flotation of sulphide minerals from pyrite in a lime environment is covered in the presentation. Advantages of process control based on the electrochemical potential of slurry controlled by ?? ? electrode are proved and compared to conventional methods of ?? ? metering and conductometry. Keywords: flotation, electrochemical potential, automation dosing system, neural network

Sep 1, 2012

By M. Zolghadri

MIBC and sodium metasilicate are used as a frother and a dispersant in coal flotation respectively. In order to study interaction between them, flotation experiments were performed on fine coal (<150 microns). It was found that if the frother (MIBC) dosage is in excess of a certain limit, it has an activation effect on the gangue minerals associated with coal. In addition, it was found that however sodium metasilicate can disperse clay slimes eliminating slime coating, but in the case of excess dosage, could intensify activation effect of MIBC, which is undesirable in coal flotation. Keywords: coal flotation, sodium silicate, frother, dispersion, activation

Sep 1, 2012

By B. Gorain, O. A. Bascur

"The advent of digital revolution has now enabled us with numerous tools that could be leveraged to transform our operational data into actionable insights. Key opportunities with digitization include better visualization, transparency, integrated planning and execution for value-chain optimization, that results in smarter production, intelligent response to changes in ore, process and equipment conditions, reduce energy and waste along with prevention of asset breakdown, safety and environmental issues. It is important to realize that these digital tools have limited value, from a metallurgical operational context, if we cannot bring-in the appropriate domain expertise along with getting the basics right. The focus within Barrick is to ensure that there is adequate depth of different disciplines built into our platforms along with breadth to integrate other disciplines such as geology and mining for an effective Mine-to-Mill integration. A gold recovery improvement strategy based on optimal Gaudin size distribution, leaching performance monitoring and guidance via feed grade maps is discussed. Simultaneous identification of process and equipment constraints enable finding the best overall conditions for Gold recovery. This paper discusses the methodology, findings, and challenges in the ongoing journey of implementing a Metallurgy Analytics platform that evolves from being retrospectively descriptive to anticipatively prescriptive.INTRODUCTION The last few decades have seen some remarkable advancement in information technology, but recently various digital technologies have resulted in several synergies to deliver innovation in diverse applications. The mining industry has been relatively slow in adopting these technologies compared to the other industries, but this scenario is changing fast. Mining companies globally are going through a series of challenges such as declining ore grades with complex metallurgy, increasing depth of ore bodies, high capital and operating costs, lower productivity, shortage of technical resources, significant pressure from stakeholders to deliver, along with growing environmental and corporate social responsibility issues. Improvement in profitability would need significant improvements in operational performance."

Jan 1, 2018

By V. V. Morozov, Ganbaatar Zorigt, Delgerbat Lodoy, Y. P. Morozov

"At the processing plant Erdenet, a new facility for advanced ore diagnostics in-stream (at the conveyor), based on optical analyser of mineral composition, was tested. Such systems provide highly accurate in-stream measurements of ore properties. The system provided information on the ore mineralogical composition, the particle size distribution and the impregnation of minerals. A special flatbed facility for optical spectrum-based estimation of fine-crushed ore has been developed, being incorporated into the existing system of ore sampling and analysis. Application of the flatbed facility renders possible a high accuracy of determining ore mineralogical composition. High precision of the optical spectrum-based estimation is achieved using special devices, installed in the sampling and the sample analysis flow sheet, applied by the technical control department. Modern systems for optical spectrum-based estimation of ore grade provide a basis for effective automated control of ore benefication processes, based on the principle of advanced ore grade control. Process management task of grinding and flotation was to choose options that take into account the composition and grade of the ore coming. The calculation data array comprises consumption of reagents, ore processing, grind size etc. The systems implemented at the processing plant contributed to increasing copper and molybdenum recovery. INTRODUCTION In-stream ore grade analysis is a new trend in effective control of ore benefication processes. This is realised based on radiometric measurements in the X-ray and visible spectrum regions, in which mineral components of the initial ore (Sbárbaro and Villar, 2010) or the benefication products become apparent (Hyotyniemi and Ylinen, 1998; Haavisto and Hyötyniemi, 2010). An important advantage of such methods is in-stream measuring ore parameters, including mass fractions of individual minerals, which makes it possible to use the information obtained in the processes of automated control."

Jan 1, 2018

By G. Aguilera

The mineral suspensions do not present a newtonian behavior as their continuous phase; they can be pseudoplastic, dilatant, or both. The viscosity becomes as the most important rheological variable because the different industrial processes involve a wide variety of rheological scenes, with a specific rheological behavior for each one. Some authors have tried to model the viscosity of suspensions considering the volumetric fraction of solids and others have also kept in mind the size of the particles (Einstein, 1906; Batchelor, 1977; Jinescu, 1974; Krieger and Dougherty, 1959; Tangsathitkulchai and Austin, 1988). Others consider the shear rate (Cross, 1965; Hershel-Bulckley, 1926; Bingham, 1916, etc). However, none of the models is able to simulate the viscosity involving the physical, chemical and mechanic factors at the same time for crowded suspensions. A new model based on Neural Networks is presented, taking into account all the variables of ceramic clay suspensions and chemical additives. Keywords: viscosity, clay minerals, neural networks, simulation, mathematical function

Sep 1, 2012

The concept of the Unified Comminution Model (UCM) was presented at the 23rdIMPC. The model utilises computational techniques to calculate the mechanical environment in any comminution device, and then incorporates the outcomes from rock breakage tests to predict the product from a device. The model is fully mechanistic, and incorporates the capability to simulate novel equipment. This paper presents the progress on the first application of this concept to applied comminution equipment. This novel comminution model aims to integrate all comminution models within a single struc-ture. This will provide a step change in the predictive power of comminution models, and include a wide range of particle properties that will enable it to be linked to the upstream and downstream process of mining and recovery. Major advances over current models will be the capability to predict liberation, preferential grinding, performance of new and novel devices, and to have power as an integral driver of the comminution simulation process. The methodology and model structure have been developed. An equation within a population balance framework has been derived as the basis for the UCM. A set of SAG mill pilot has been used as the first test case. The breakage characteristics of the ore have been extensively tested utilising a new range of breakage tests required by the rigorous UCM structure. The mill was simulated with the EDEM - DEM software. A partial test simulation of the pilot SAG mill has been conducted. This serves to demonstrate the feasibility of this modelling technique, but still lacks important ore characterisation components that are under development. The study has raised a number of significant challenges to the accepted understanding of the comminution process. Through addressing these challenges considerable insight has been gained into the energy environment in mills and the requirements of breakage testing. The ore characterisation methods and energy transmission derived from DEM simulations remain as major research items.

Jan 1, 2014

By N. Vasumathi

Most of the Iron ore washing plants set up in India in the earlier days consist of sizing of the ore by dry / wet screening, washing and classification by screw classifiers. In this classical approach, iron values were lost in the form of fines and ultrafine into the tailing ponds as they had little commercial value in those days and accumulated in huge quantities over the years. As the high grade deposits are getting exhausted and the demand for high grade finer material for pellet making is ever increasing, focus is shifting towards recovering the values from the erstwhile tailing ponds by column flotation. This is also supposed to mitigate to a certain extent the environmental problems caused by the ever expanding and unmanageable tailing dams. A case study is presented wherein a composite sample is prepared from samples drawn systematically from multi - locations in a sprawling tailing dam. Laboratory scale column flotation tests on this composite tailings sample, basically originating from two operating iron ore beneficiation plants of JSW Steel Ltd., one of the leading producers of steel in India are found to be encouraging. Desliming followed by reverse and cationic flotation tests using flotation column resulted in the concentrate of 61.88% Fe, 4.81% SiO2, 2.52% Al2O3 and 3.30% loss on ignition (LOI) from the tailings analyzing 57.86% Fe, 7.10% SiO2, 3.52% Al2O3 and 6.14% LOI with 52% weight recovery. The causes for the quality improvement could be attributed to desliming of un-liberated ultra fines of kaoline and hydrated iron oxides and their further reduction by efficient flotation process. The process and the cationic collector developed for this purpose are adopted in the new flotation plant created to treat these tailings. Keywords: iron ore, washing, ultra fines, tailings pond, column flotation

Sep 1, 2012

New technology for on-line particle size analysis of mineral slurries has opened up new applications for particle size measurement. In some cases the particle size distribution of the final concentrate is an important quality issue. This paper discusses established on-line particle size analysis technologies and presents experiences on the use of a new technique employing laser diffraction in several minerals processing operations. The main innovations in the new instrument are a simple dilution system and multiple scattering correction algorithm, which allows wide solids content variations of diluted sample in the measurement cell. Representative sample for laser measurement is produced by a simple and reliable dilution system. The applications discussed are; Blaine number measurement of Fe concentrate before pelletizing, grinding of variable batches of ore and paste thickener control.

Jan 1, 2014

By M. M. Yahyaei

The Sarcheshmeh new concentration plant uses a 32 ft×16 ft constant speed (10.5 RPM) SAG mill with two 5500 hp motors which could rotate in two directions. The mill liners are chrome-molybdenum steel casting type with a Brinnell hardness between 325 and 375 with the lifter face angle of 14° and lifter height of 152 mm. The shell liner consists of 120 (two 60 rows) pieces with a High-High configuration in a rail design. A specially designed liner wear profile measuring device enabled fast and accurate measurements inside the mill during the mill shut-down periods. The measurements indicated that the liner wear profile along the liner length is non-uniform and the highest wear occurs between 1.25m and 2.75m of the mill length. The average weight of liners at the time of removal was 47% of the original weight indicating a significant metal loss. The modification of liner shape was undertaken with the aim of having a uniform profile at the liner removal time. The proposed liner unlike the pervious type did not have a uniform shape with a lifter height of 187mm at the section where the wear rate was high. It was believed that this new profile could arrive at a uniform profile at the liner change out time. A study was also directed to the possible change of charge motion due to the liner profile modification. The dynamic behaviour of charge was investigated through the analysis of forces acting on a single ball using mill characteristics such as mill diameter, rotational speed, lifter height and release angle. The simulation of charge motion with this method and Milltraj TM software indicated that the impact position of charge will change only one degree due to the maximum increase of 35 mm in the lifter height. This assured that the installation of the modified liner would not have any adverse effect on the mill because of ball impacting the mill shell. It was predicated that the amount of scrap metal will reduce to 30% from the current value of 47% beside 1500 h increase in the liner life time.

Jan 1, 2014

By Carlos G. Rudolp, Julio C. Videla, Mario Zuleta

"The present paper summarises the results of gravity pneumatic concentration of a borax ore with 17.5 % B2O3. The sample was extracted from the Tincalayu ore deposit located in the Salta Province of Argentina.The applied methodology was based on a former study (Zuleta, 1985). It consisted of sample characterization by means of physical and mineralogical determinations, chemical analyses as well as pneumatic table concentration tests. In this, a simplified concentrating flowsheet was utilized.A concentrate with 30.6 % B2O3 and 74.7 % recovery was obtained. The recovery was 8.8 % less than previously reported and that was of 30.6 % B2O3 with 87 % recovery. Nevertheless, the simplified flow sheet presented processes only two granulometric fractions, - 6.4 mm + 0.3 mm and - 0.3 mm, compared to the three granulometric fractions used in the previous study: - 6.4 mm + 1.4 mm; - 1.4 mm + 0.3 mm and . 0.3 mm. This would simplify industrial implementation."

Jan 1, 2003

By P. M. Solozhenkin

"Galvanochemical process (GChP)) cleaning of sewages is realized in the field of shortcirquited galvanic elements from the mixture current the materials place in purification’s solution and form multitude galvanopairs without external electric field in presence oxygen of the air. The galvanochemical process is electrochemical process utilizing galvanic pairs: coke - iron, iron - copper and others and process does not require chemical reagents.The effect of basic parameters of the cleaning effectiveness have been studied depending on oxidizing of galvanopairs. Adjusting nature, type of galvanic pairs and forming three component system possible to enlarge emf circuits to 2.378 V.The role of ?2, as basic agent, for generation of hydrogen peroxide and hydroxyl ions.It was stated, that removing of metal ions from solutions occur mainly on account of sorption and hydrolytic sedimentation of iron oxihydrates.Determined separate stages of the process: coagulation, sorptions of admixtures on freshly formed ferric oxides and oxidizing destruction of organic components of effluents in presence of ?2 ? ?2?2. Shown efficiency of the method for removing of Cu, Cr, Ni, Zn, As ions, as well as fluoride, phosphate and cyanide anions and oil products, surface-active and flotation reagents. Cleaned water can be recycled for some processes non-critical toward residual concentration of admixtures, as total salt contents is lowered on 60-75 % and reaching limits of concentration for toxic components.The concept of high power unit creation was developed, and galvanochemical pulsator is presented. The pulsator is not expensive, and exploitation expences are low, as well as servise is simple with high effectiveness, and capacity. The galvanoflotation process is developing, combining galvanochemistry and flotation of hydrofobic admixtures (oil, surface-active agents).The galvanochemical flotators are presented."

Jan 1, 2003

By Isaak I. Maksimov, Tatyana E. Koltunova, Mikhail F. Yemelyanov, Liudmila A. Otrozhdyonnova

"INTRODUCTIONMetals losses amount up to 50% in coarse fractions in (>100 µm) and composite particles, and to 20- 25% in fine fractions (<10 µm) at non-ferrous floatation concentrating plants of the CIS. Therefore, reduction of metals losses in difficult fractions is of high significance.IMPROVEMENT OF FLOATABILITY OF COARSE AND COMPOSITE PARTICLESReagent regimes with application of strong collectors – xanthates ?5-?8, combination of butyl xanthates and aerofloats ?10-?12, butyl xanthates with hydrocarbons are proposed for this purpose. Application of such reagent regimes for copper and copper-molybdenum ores permitted to increase copper and molybdenum recovery by 0.5-3.9%.Studies, performed by means of specially designed non-frothing flotation machine with independently controlled agitation intensity and narrow size-ranges of air bubbles, established that the best results are achieved with employment of bubbles of 0.5-0.8 mm size regarding particles of any size, with small amounts of up to 2 mm size “transport” bubbles to be expediently used for floatation of coarse particles.Energy dissipation in the main volume of floatation cells must be lower than 0.2-0.25 m2/s3.Performed experiments permitted to formulate requirements to development of machine for floatation of coarse and composite particles. Such floatation machine with volume of 8.5 m3 provided for weak agitation in the main volume of floatation cell and uniform distribution of coarse particles throughout the depth owing to establishing of pulp circulation with upward flows. In addition, in the upper part of floatation cell where agitation is considerably weaker, favorable conditions are created for attachment of particles to bubbles. Testing of this floatation machine demonstrated a 7.5% increase in recovery of +0.2 mm particles in pyrite floatation and a 12-14% increase in recovery of +0.2 mm particles in apatite floatation as compared with a reference floatation machine."

Jan 1, 2003

By X. M. Wang

Magnetic floatation column (MFC) is a new equipment used for increasing content of iron, in which magnetite is separated in open gradient magnetic field. Simulation study was performed to investigate the separation characteristics of the separation method by analyzing the dynamic motion of magnetic particles. In this paper we compare two magnetic fields created by different magnets. The obtained simulation results give perspective in industrial design of MFC as the basis stage.

Jan 1, 2014