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By W. L. Stuewe

The Dominion Steel and Coal Corporation requires enormous quantities of bricks each year for its Sydney steel plant operations. Clay brick of all types are purchased, while silica brick is made in the Company's plant at Sydney. A description of this plant was given in a paper presented by H. B. Gillis and F. C. Morrison at the 1938 Annual General Meeting of the Institute. The rock used to make silica brick was for years obtained from a quarry at Leitches Creek, about eighteen miles from Sydney. Due to the gradual deterioration of this deposit, the Corporation was forced to look for other sources of supply. In 1945, the problem was presented to the Nova Scotia Department of Mines and, through the efforts of Dr. A. E. Cameron and Mr. J. P. Messervey, an examination was made of a silica-rock deposit some six miles northwest of Yarmouth, N.S. Preliminary samples proved satisfactory, and arrangements were made with the Department of Mines to ship to the steel plant at Sydney a fifty-ton car load for the purpose of further testing. Brick made from this sample shipment stood up very well in the furnaces. At the same time, two hundred and fifty tons of silica rock from a deposit at Lac Bouchette, Que., were purchased from the Industrial Silica Corporation, and brick made from this rock also was found suitable for our requirements. Comparative transportation costs, however, led to a decision to open the Yarmouth deposit. The silica rock, or quartzite, of this deposit outcrops at Chegoggin point along what is known as the 'Pembroke shore', a northerly trending section of the coast-line at the extreme southwest of the Province, in Yarmouth county. The country here is fairly flat, with elevation averaging about twenty feet above high tide, and is for the most part mantled by a growth of brush and some scrub trees, chiefly small fir. Bed-rock is generally concealed beneath three to four feet of clayey soil, but scattered outcrops of the quartzite indicated that a band of this rock, some 260 feet wide, extended inland in a northeasterly direction from Chegoggin point at least to Utleys lake, a distance of about three miles.

Jan 1, 1947

By Peter Heine

Diavik Diamond Mines Inc. (DDMI) has treated systems development as an integral part of the construction project when it built Canada?s second diamond mine. Fully aware that the proper collection and processing of operational data is needed to drive business decisions during production and planning, key Performance Indicators (KPIs) were defined to effectively manage operations when the mine went into production. The Production Information Management System (PIMS) allows KPIs to be measured, reported, and transferred to other systems in a reliable and convenient manner. PIMS provides a mechanism to collect real time production data from the various control systems around the site and acts as a tool to ?drill-down? and establish the important cause-effect relationships that impact the value of a KPI. Thus PIMS provides a data collection, storage, management, and an environment in which cause-effect relationships can be analysed and statistically verified. This understanding of the real cause-effect relationships, close to the source of the data and in the context of the operation, can be used to improve both operations and maintenance performance. The PIMS includes the PI Database implementation, its associated external interfaces with the various Control Systems, Cleaning Packaging Weighing System, Environmental System, Enterprise Asset Management (EAM) System, and Diamond Tracking System (DTS), as well as laboratory data collection, custom applications (downtime tracking, data reconciliation) and user clients. The interface with the EAM system provides material flow quantities and equipment availability on which the plant performance reports are based. The transfer of equipment usage to the EAM system is fed into the maintenance notifications and work orders functionality in the EAM. The environmental system interface provides the mechanism for capturing water consumption data required to generate the various regulatory reports. The interface to the cleaning-packaging-weighing system provides the mechanism for capturing batch data for transfer to the DTS for diamond product tracking at the production splitting facility in Yellowknife. The PIMS lab application provides a means of getting sample data into the system for critical metallurgical metrics, and the data reconciliation application provides a means of manually verifying the data before it is published or passed onto other systems.

May 1, 2003

By H. H. Wober, P. J. Morgan

"The proposed classification of ore reserves based on geostatistical and economic parameters is designed to be used as a communication tool to identify for investors, bankers, and financial analysts the degree of risk associated with a specific class of ore reserves. The class designation identifies the degree of accuracy of the estimates for tonnage and grade of annual production volumes of ore. It thus enables decision makers to quantify the risks and uncertainties inherent to the ore reserve in achieving over-all economic goals and annual financial objectives.IntroductionDuring the evaluation, in 1980, of the Creede silver deposit in Colorado, U.S.A., as a potential bulk mining project, the authors were faced with the problem of conveying to senior management the risks and uncertainties that are implied by using common or conventional classification systems to categorize ""ore reserves"". The estimated numbers for tonnages and grade of the projected ore reserves represented the only entry for future revenue from the project. It was, therefore, necessary to convey to management the level of risk associated with those numbers when implementing further stages of development, and to convey what impact significant differences would have on the profitability of the project. The desire to quantify these risks led to a revised definition of ""ore"" and to a re-examination of the classification system of ""ore reserves"". Traditional methods for estimating tonnage and grade of reserves do not include a quantification of the errors of these estimates. The advent of geostatistical methods made this quantification possible. The proper application of geostatistical methods, with adequate geological input and a reliable set of sample data, is essential to its validity.Others have proposed a classification of ore reserves based on geostatistical parameters. Diehl and David (1982) recognized ""that concepts of proven, probable and possible have to be linked to the production rate or time horizon"". Royle (1977) had also addressed this problem. Forsyth (1987) pointed out that bankers are concerned with ""the probability that the variability will fall within a certain degree of accuracy"" especially for grade estimates, and would like to see grades expressed together with the error of the estimate at the 950Jo confidence level."

Jan 1, 1993

By J. Huh

Recently, there is growing trend to build the high-rise and install curtain walls. Following this trend, we developed robot for building wall cleaning work, which moves along Built-in guide rail of building. Because it moves attached at building wall for cleaning work, it can be seriously affected by potential threats, like earthquake, strong wind, malfunction, and construction error of built-in guide rail. In order to cope with those threats actively, this paper presents the Fail-Safety system. The building wall cleaning robot consists of two moving system: The Horizontal Moving System which mainly do maintenance work, and The Vertical Climbing System which transport the horizontal moving system floor by floor. We apply the Fail-Safety system to these systems. The Fail-Safety system consists of sensors to detect external situation, and, with information of sensors, give instruction for what to do. This robot system is installed with four kinds of sensors: shock sensor, infrared ray sensor, laser sensor, magnetic sensor. First, shock sensor detects external shock during cleaning work. When shock sensor detects big shock, the robot returns to starting point to inspect how damaged it is. Second, infrared ray sensor detects damage of built-in guide rail. It is to prevent destruction of robot caused by moving along damaged rail. Third, laser sensor gives notice about where obstacle is. It is for robot to avoid crash with obstacle and decrease damage. Fourth, magnetic sensor detects magnetic points, which are installed in rail at regular intervals, and helps robot to find its position, based on location of magnetic points detected. If robot is damaged by external shock and its encoder, which gives information of location to it, is not working, magnetic sensor will give information of robot?s location to robot. And then, robot regulates its velocity depending on position of it, and safely returns to starting point. The Fail-Safety system in this paper is for building wall cleaning robot to sense external threats, and prevent getting worse. Applied to this active protection system, making safe environment of maintenance work is possible for robot system.

Aug 1, 2013

By J. Ouellet

The authors participated in a study for a new mine shaft in Saskatchewan?s Athabasca Basin where ground freezing is desired to reduce water inflows. Constraints were imposed on the design in terms of permissible water leakage (less than 10 m3 / hour) inside the shaft. Since the shaft goes through highly permeable formations, water control measures had to be incorporated into the design. Ground freezing was selected as the most reliable and proven method for the sinking and a hydrostatic liner design was implemented. While exploring various technological options available for providing a fully hydrostatic liner, the authors came up with a new design concept that offers a more cost effective solution while meeting all the design constraints. The new liner concept is a composite design using concrete and a sprayed-on membrane system. A proof of concept program comprising laboratory testing and field testing was successfully implemented. This paper presents the innovative liner design, as well as the adapted sinking methodology, developed for this type of project. The new concept offers a new cost effective high performance hydrostatic mine shaft liner comparing favorably with traditional methods. RESUME: Les auteurs ont réalisé une étude pour un nouveau puits de mine dans le Bassin de l?Athabasca en Saskatchewan. Des limites sévères sont imposées sur le design en terme de volume d?infiltration d?eau acceptable (moins de 10 m3 / heure). Comme ce puits de mine traverse des formations très perméables la congélation des terrains a été sélectionnée, une méthode éprouvée et fiable. Un design hydrostatique a été choisi pour le revêtement du puits. Dans le processus de design, les différentes technologies disponibles ont été étudiées. Les auteurs ont développé un nouveau concept de revêtement composite offrant un rapport performance/prix plus avantageux que les technologies conventionnelles. Le nouveau design proposé est composé de béton et d?une membrane projetée. Un programme expérimental a été réalisé pour démontrer la faisabilité du concept. Cet article présente le nouveau concept ainsi que la méthodologie de fonçage de puits adaptée. Ce concept innovateur offre un revêtement hydrostatique performant à un cout avantageux par rapport aux techniques de construction utilisées jusqu'à maintenant.

Jun 1, 2012

By Euler De Souza, Kyle Penner

"Booster fans play an important role in assisting main fans by boosting the air pressure of the ventilation air passing through it. The correct placement of underground booster fans in a mine is a critical decision since it not only influences the mine’s operational capacity in terms of costs and efficiency, but also affects safety and environmental conditions. There are many booster fan installations around mines that are inappropriate, in some cases resulting in system failure (fan stall) or in a major negative impact on mine production. Inadequate booster fan placement has resulted, in some cases, in extensive air leakage which has compromised the economics of the operation and, in other cases, in recirculation of contaminants which has seriously compromised safety. This paper provides guidelines for proper design and siting of booster fans underground, to not only achieve an economic ventilation system but to create safe work conditions and efficient atmospheric conditions. Procedures for the planning, installation, operation and maintenance of booster fans are also presented. A case study illustrating the design and siting of a major booster fan installation in a potash mine, supported by computational fluid dynamics analysis, is presented.INTRODUCTIONIn large underground operations with complex ventilation networks offering high resistances, the never ending increased required quantities of air can almost only be supplied through use of high pressure main fan systems. These fans may, in effect, induce significant leakage losses in the system, having a negative impact on safety performance. In such cases, booster fans can be designed to decrease the main fan pressures and reduce the leakage flows, improve system efficiency and reduce costs. In well designed systems, booster fans can thus be used to redistribute the airflow and assist the main surface fans.When the pressure supplied by the main fans is insufficient to meet the ventilation circuit pressure requirements, booster fans are placed in strategic locations where pressure boosting is essential. Booster fans are typically sited in sections of the circuit offering high ventilation resistance and requiring this form of ventilating air motivation. Booster fans are thus required when the mine expands, and so the resistance of the ventilation network, and the primary fans no longer can supply the required pressure and flow."

Jan 1, 2019

By J. B. Evans

"THE OPPORTUNITY to participate in a CIM seminarconcerning the direction of mining engineer trainingis perhaps fortuitous as it comes at a time when theengineering schools which have invited inspection byCanadian Accreditation Board of the Canadian Councilof Professional Engineers are examining theirrespective curricula.Currently there exists considerable soul-searching in various engineering schools across Canada where questions such as the following are being posed.- Have we achieved the correct balance between subjects related to technical methodology and subjects devoted to conceptual planning and design?- Should we include ""applied humanities"" in our program? (Whatever ""applied humanities"" might mean!)- Should courses covering pollution control, ecology, economics, technical writing, professional conduct and ethics be offered as compulsory subjects, as electives, or not at all?- Is it a better scheme to have students complete an Arts or Science degree before entering engineering?- Do we place too much emphasis on pure mathematics and sciences with the result that insufficient time is available for instruction in the engineering applications of these subjects?- Should English expression and/ or literature be included in the engineering programs and, if so, should these subjects be presented by the English department or by English lecturers captive to the engineering school? - Is the present program directed primarily at research activities rather than preparing engineers for their future roles in industry? - Should we teach our own versions of mathematics and physics? - Do we have sufficient engineers on the faculty strength or are we overloaded with Ph.D.'s from the pure sciences? - How flexible should the program be, what should the compulsory vs elective course content be, and what freedom of choice, if any, should be given with respect to elective courses? - To what extent should students contribute to faculty decisions?- How far should we pursue computer science subjects and do we need to make our students proficient in computer programming? - How far should operations research and mathematical models be carried in the undergraduate program when the students have limited experience in the real engineering world? - Realizing that an engineer never completes his education, should the undergraduate program cover ""bare bones"" engineering and should instruction in particular disciplines be left to graduate schools and / or industry?"

Jan 1, 1972

By Réal Marcotte

L'industrie minière représente un apport économique important pour le Québec ; cette production est très diversifiée et répartie dans plusieurs régions. Hormis les forges du St- Maurice au XVIIe siècle, l'industrie minière québécoise commence en 1862 dans la Beauce avec l'exploitation de placers aurifères dans les affluents de la rivière Chaudière; à la même époque, on met en production les mines de cuivre Eustis, Albert et Capelton, près de Sherbrooke1; à partir de 1881, les mines d'amiante et de chromite au voisinage d'Asbestos et de Thetford commencent à voir le jour. Dans les années ?20, l'extraction de métaux précieux et usuels débute en Abitibi- Témiscamingue; durant les années '50, le fer et l'ilménite de la Côte Nord, ainsi que le cuivre de Murdochville et Chibougamau, commencèrent à être mis en valeur. Plus récemment, soit durant les années '80, le sel des Iles-de-la-Madeleine et le graphite des Hautes Laurentides s'ajoutèrent aux produits que nous commercialisons. Finalement, soit en 1998, le Québec devenait un important producteur de nickel avec le démarrage de la mine Raglan, au Nunavik. L'exploitation d'une mine peut nécessiter l'extraction de grandes quantités de roches stériles, particulièrement lorsque la production se fait à partir d'une fosse à ciel ouvert. De plus, étant donné que les minéraux et les métaux mis en marché ne constituent qu'une fraction du minerai extrait, il faut le concentrer : on se retrouve alors avec des proportions plus ou moins importantes de résidus finement broyés. Ces deux types de rejets totalisent bon an mal an environ 100 millions de tonnes. Lorsque cela est possible, ceux-ci sont, soit valorisés comme matériaux de construction ou retournés dans leur lieu d'origine afin de soutenir les murs des excavations. Toutefois, une bonne partie est accumulée en surface dans des aires aménagées spécifiquement à cette fin ; comme le montre la figure 1, la superficie utilisée à cette fin a progressé parallèlement aux booms miniers que nous venons de mentionner pour atteindre actuellement environ 15,600 hectares, dont environ la moitié sont situés sur des aires encore en activité.

Nov 1, 2002

By Brian W. Mackenzie

"This paper briefly outlines the characteristics which should be considered in assessing the economics of mineral exploration, and illustrates such an assessment by using data from the Canadian base metal sector. Implications for the sector are found to include the following:(1) base metal exploration has the potential to create a substantial amount of new wealth;(2) investment incentive for exploration under current conditions is not unattractive over-all;(3) because of existing taxation policies, there is much more incentive for large companies to explore than for smaller enterprises;(4) succesful exploration is sensitive to the size, financial resources and organizational structure of the exploration entity;(5) the general level of recent exploration expenditures should be adequate to maintain the current rate of production and perhaps to support very modest growth; and(6) there is an important opportunity for growth in the sector.The findings of the study suggest that government policies should be made more flexible, in order to take into account the risks associated with exploration and with price fluctuations in the base metal sector. Recommendations are also made concerning improvements in provincial regulations for disclosure of exploration information."

Jan 1, 1981

By P. Farsangi, A. Hara

"Kidd Creek Mines places approximately 10 000 tonnes of consolidated rockfill on a daily basis. Consolidated rockfill is comprised of sized aggregate mixed with different ratio and amounts of binders. Consolidated rockfill, with closely controlled specification, is employed for subsequent pillar recovery and improved passive active/ ground support. With the same amount of cementing agents consolidated rockfill mass yields a higher, compressive strength, modulus of elasticity, cohesion, and angle of friction compared to a typical cemented hydraulic fill mass.The consolidated rockfill at Kidd Creek Mines is designed to sustain not only the gravitational loading of the overlaying fill material, but also to some extent the dynamic loading applied during blasting of the adjacent stopes and/or pillars.The quality control of materials used in Kidd Creek's rockfill system could be effected in three stages of handling: (1) at the surface backfill plant; (2) during transportation; and (3) placement of the fill.The emphasis in this paper is placed on individual stope backfill design and quality control measures at Kidd Creek Mines to place fill in large-scale open stopes which eventually could be exposed on all four walls during pillar recoveries."

Jan 1, 1993

By E. G. Joe

The continuing increase in costs for power and fuel are affecting significantly the cost of milling Canadian ores. In order to ascertain the scope and source of energy consumption in Canadian mills for further energy conservation opportunities, CANMET, in cooperation with the Canadian Mineral Processors, carried out a detailed survey on the metallic mineral processing plants. Sixty-seven mills representing almost 300 million tons of annual capacity participated in the survey. The results indicated that, in general, copper and iron ore mills, representing the bulk of the tonnage, consumed relatively low levels of energy per ton. Nickel-copper, zinc-copper and lead-zinc .ore mills were moderate in energy consumption, and uranium and some copper-lead-zinc mills reported much higher energy consumptions due primarily to the increased heat requirements of the ore pulp. Although plant heating costs varied somewhat with location, it was apparent that the lowest heating costs were achieved by those plants built with proper insulation and energy conservation design. If the cost per million British thermal units is taken as $2.00, the mill energy costs generally ranged from 40ft to $1.20 per ton.

Jan 1, 1979

By E. I. Vargha-Butler

The determination of surface tensions and contact angles of coal particles is of great interest for coal beneficiation processes such as froth flotation and oil agglomeration and for the inclusion of coal particles into oil droplets as a means of enriching the fuel. Methods for contact-angle measurements on small irregularly shaped solid particles have not been available in the past. Therefore, we recently developed a novel technique to determine contact angles and surf ace tensions of coal particles. Two types of bituminous and one type of subbituminous coal particles have been tested. The technique used is called the freezing-front technique and it considers the behaviour of the test particles (in the range of 20-250 pm) at the solidification front of carefully selected, well-defined solidifying melts (matrix materials) such as thymol, biphenyl, naphthalene, salol and 2-phenyl phenol.The results show that the technique works well, providing quantitative and detailed information on the wettability of coal particles. The sensitivity of the method is so high that a difference in contact angle of approximately 4 degrees between the smaller and the larger particles is clearly registered.

Dec 1, 1981

By K. L. Ford, D. R. Lentz, J. H. Rickard, R. P. Taylor

Abstract - Coupled gamma-ray spectrometric and lithogeochemical studies throughout the Heath Steele Mines area, Bathurst Camp, New Brunswick, indicate that primary and secondary geochemical differences exist between the stratigraphic footwall and hangingwall crystal tuff units which host the massive sulfide deposits. Of particular interest is Th, and to a lesser extent, Zr and Y, which are more concentrated in the hangingwall than the footwall crystal tuffs, whereas the opposite is true for TiO2. This expands on earlier lithogeochemical-chemostratigraphic results concentrated in the eastern part of the Heath Steele belt that led to revision of the local stratigraphy, and necessitated a structural re-interpretation of the area with implications for exploration. Although K depletion (decreased K and K/Th) is typical of chloritized footwall zones of chloritization, these features were not fully apparent here due to the recessive nature of these altered zones. In situ radiometric analysis using a portable gamma-ray spectrometer is a rapid, inexpensive analytical technique for chemostratigraphic characterization of rock units within volcanogenic massive sulfide deposit settings, provided there is a contrast in the distribution of natural radioelements, particularly Th and K.

Jan 1, 1998

By K. G. Markkola

Since 2005, Compafifa Contractual Minera Candelaria (CCMC) has defined various strategies which aim to optimize the usage of the available energy in each of the SAG grinding circuit modules (SABC-A configuration). For this purpose, the use of larger size balls along with operating with an optimum balls/load ratio has been implemented. Additionally, in the ball mills, the amount of balls in relation to the equipment's usable diameter has been optimized. In the pebble crushing circuit, the percentage of material passing 12 mm (112 in) product has been increased by 15% by: (1) modifying the crusher mantle profile, (2) implementing a strategy for maximizing the power in each crusher, (3) using continuous improvement tools (Lean - Six Sigma), (4) redesigning SAG mills discharge grates, and (5) changing discharge grates in order to control the crusher feed size distribution profile. All these activities have improved plant throughput by 1,000 t/d with no significant capital investment. As part of the energy consumption optimization study, we have considered determining the optimum operational rate of each SAG mill, in relation to the mill liner life and also the improving the control strategy in conventional grinding.

Jan 1, 2007

By P. Patnaik, F. Cuneo, D. M. Wang

Microwave (MW) energy has been used widely for several decades for communications, food processing, wood drying, vulcanization of rubber and medical therapy. Recently, this technology was found to be capable of successfully sintering ceramic and metallic powder materials, with the advantages of reducing soaking times and sintering temperatures. Unlike conventional heating, MW radiation works through the absorption of the microwave energy by a material placed in an electromagnetic field within the microwave cavity. A far more efficient heating process is produced due to the unique ability of microwaves in selectively heating a pecific part of the material with desirable dielectrical properties. This exploratory research was initiated with the objective of locally sintering the thermal barrier coating of gas turbine components using MW radiation. This novel technique may allow repairing of the component without subjecting the entire piece to unnecessary elevated temperatures and reduction of process time and cost. Y ttria stabilized zirconia was used in this study and sintering was conducted using a multimodal 1.2 kW microwave facility. Three configurations of heating setup were experimented and the preliminary results will be discussed in this paper.

Jan 1, 2006

By E. C. Keeley

THE property of Buffalo Ankerite Gold Mines, Limited, is in Delora township, Porcupine area, Ontario. The southwestern part of the property is ground formerly owned by Marbuan Gold Mines, Limited, which was acquired by Buffalo Ankerite in January, 1936. Until 1938, the Ankerite (or North) mine and the Marbuan (or South) mine continued as separate operations, each developed through a surface shaft and winze to the 1050 level and each having its own mill. This meant high hoisting costs, which, in 1936 and 1937, amounted to 36 cents per ton. In 1938, the underground workings of the two mines were connected on the 1050 level, and ore from both mines was hoisted at the main, or No. 2, shaft of the North mine, location of which is shown in Figure l. This shaft was discontinued at a depth of 1150 feet because, owing to the soft nature of the talc (serpentine) rock in which it was sunk, it had to be concreted throughout, and also because of its great distance--1,100 feet and 1,400 feet, respectively-from the North and South orebodies.

Jan 1, 1945

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By R. Bonifaz

The Chagres Smelter, part of the Anglo American plc group situated 80 Km north of Santiago in Chile, completed a series of operational improvement in 2005 resulting in an optimum capacity in its operational units. At present the Chagres Smelter has developed an operational strategy which seeks to reduce bottle-necks in the production process. In this way we have managed to lower operational cost, decrease energy consumption and maximize the capacity of the Acid, Oxygen, and Smelting, Converting, Refining and Casting units. A constant application of international benchmarks together with continuous staff improvement and the latest smelter technology have combined to place Chagres among the finest smelting works in the world. In response to environmental challenges, we have studying various options for investment suitable for a profitable business of benefits to both Anglo American and Chile as a whole. The most relevant technical indicators are the figures : Energy consumption less than 6,3 GJ/ton fine copper, Intensity of smelting rate in Flash Smelting unit of 6900 ton of copper concentrate/m2 settler of furnace area and be one of the top five smelter in direct cash cost .

Jan 1, 2007

By L. Fernandes

A factorial study was performed to investigate the relative effects of temperature, copper concentration and meso-2,3-dimercaptosuccinic acid (DMSA) concentration on the performance of thiosulfate leaching of gold. A total of 24 leaching experiments were performed representing eight unique combinations of high-low levels of the three factors performed in triplicate. All investigations were performed in an electrochemical cell with an electrolyte composed of 0.1 M sodium thiosulfate with a combination of copper (either 0 mM or 1 mM) and DMSA (either 0???or 1µM). All leaching investigations were conducted under open circuit while the electrolyte, which was open to the atmosphere and mechanically stirred, was maintained at either 25°C or 50°C. After 1.5h of leaching the amount of gold in solution was quantified using ICP-MS analysis from an aliquot of the electrolyte. Results indicate that DMSA addition improved gold leaching performance, most notably at 50°C and with addition of copper. Under this unique condition, the quantity of gold in solution was reproducibly and significantly above the average response of all other factors studied.

Jan 1, 2014

By László Guczi1

Nanosize model gold particles with varying size were fabricated by deposition of a 10 nm thick gold film onto SiO2/Si(100) substrate by electron beam evaporation followed by modification using low energy Ar+ ion bombardment. The change in particle size were monitored by the Au 5d valence band states determined by ultraviolet photoelectron spectroscopy (UPS). The gold/iron oxide interface was studied by iron oxide deposition on gold. It was found that the energy profile of Au 5d valence band states are strongly redistributed with decreasing the gold particle size mostly affecting at the lowest and at the highest binding energies. The size effect in the UPS spectra can be interpreted by the energy redistribution rather, than by narrowing the 5d states. The iron oxide deposition increases the catalytic activity in CO oxidation whether it is on gold nanoparticles or on a continuous 80 nm thick gold film. The activity enhancement is significantly larger in case of gold nanoparticles. The interface interaction is operative in enlargement of the catalytic activity even if gold particles are not exposed to the surface, but they are located below the iron oxide layer.

Oct 1, 2003