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The Project ? $1.4 billion project ? 59,000 tonnes of nickel and cobalt ? Large resource base ? First production end of 2004 The Place ? Half the size of Vancouver Island ? Population 210,000 ? 43% Melanesian, 37% European, 12% other South Pacific groups, 8% other nationalities ? Tourism principal industry ? 1/3 of world?s nickel resources The Politics ? French Overseas Territory ?1998 Noumea Accord: increased local control over domestic policy ? Referendum on independence in 2014 ? Seeking more economic autonomy, less dependence on French support

May 1, 2002

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By O. Zach, K. Gamweger

"The Process of gas purging in molten Aluminium has been an industrial practise for many years. The melting of alloying elements and their rapid distribution in the bath is very important. To improve the mixing and homogenisation process, at RHI NON FERROUS METALS ENGENEERING GMBH a lot of CFD calculations were done. The so developed new ""purging program"" was tested at Alumino Catalan S.A., Spain. The results of the testtrials were very satisfactory and corresponds very well with the calculated data."

Jan 1, 2004

By J. G. Peacey

"Canada has a special place in non-ferrous pyrometallurgy because it is the only country in the western world that is a significant producer of all the major non-ferrous metals; aluminum, copper, lead, magnesium, nickel and zinc. This large non-ferrous pyrometallurgy industry has developed because of Canada&apos;s abundant mineral wealth and energy resources. Table I summarizes the number of primary non-ferrous production facilities in Canada and their share of western world production.Production of non-ferrous metals is a mature, capital intensive business and its basic processes have been in use for many years. Nevertheless, these processes have continued to evolve in response to changing needs and external pressures; such as the energy crisis of the early seventies; historically low metal prices in the early eighties and the continuing pressure to reduce plant emissions and improve in-plant working conditions. Canada&apos;s major metallurgical companies: Alcan, Cominco, Falconbridge, Inco and Noranda have played a leading role in pioneering new process technology and continue to meet the difficult challenge of keeping their operations competitive in the global metals market. This paper will try to give an overview of the major developments in non-ferrous pyrometallurgy, largely from the Noranda and Canadian perspectives, highlighting the current status of process technology and possible future directions.AluminumCanada has the world&apos;s second largest aluminum smelting industry and its capacity has expanded rapidly in recent years with the completion of several large projects in Quebec. The location and capacity of the Canadian aluminum smelters are given in Table 2. All these plants use the Hall-Heroult process, that was invented over a century ago but over the last twenty years considerable improvements have been made to increase productivity, reduce power requirements and emissions.The developments in aluminum cell technology can be illustrated by the experience at Noranda Aluminum. In 1971, Noranda Aluminum started its first pot line using Kaiser&apos;s P69 prebake cell, which was considered, at that time, the best available technology. The P69 cell was designed primarily for high productivity, operating at 150 000 amps and high current density to produce just over tonne Al per cell-day. The P69 cell is a simple design, typically operating at about 88070 current efficiency and 15 800 kWh/tonne Al. When Noranda Aluminum decided to expand in 1980, the Alcoa 697 cell was selected as it then represented the most proven, stateof- the-art technology. This cell is similar to that installed at Alcan&apos;s new Grande Baie and Laterriere smelters and is designed to operate at 180000 amps and 93070 current efficiency, producing about 25070 more aluminum per pot-day than the P69 cell using about 15070 less power. The 697 cell has a much more sophisticated cell design, with very good balancing of the magnetic field giving a flat metal pad and allowing efficient operation at the higher amperage. Alumina is fed via point feeders that provide an almost continuous feed allowing close control of the alumina level in the bath and the use of low-ratio bath composition, giving much higher current efficiencies."

Jan 1, 1991

By C. A. Pickles, K. Mackowiak

Black Thor chromite ore from the Ring of Fire deposit in Northern Ontario was carbothermically reduced in a microwave system to produce a ferrochromium alloy. The as-received ore contained 43.0% Cr2O3, 19.9% Fe2O3, 14.5% MgO, 13.4% Al2O3, and 7.0% SiO2. Activated charcoal was utilized as the reducing agent. Firstly, TGA/DTA and permittivity studies were carried out in order to determine the relationship between the reduction process and the microwave susceptibility. Secondly, microwave reduction experiments were performed on the chromite ore. The variables investigated were; the amount of carbon, processing time, input power and type of atmosphere. A maximum chromium grade of 76.1% and a chromium metallization of 82.7% were obtained for a processing time of 20 minutes, a power input of 800 W, and a carbon addition of 15% in an argon atmosphere.

Jan 1, 2017

By Ann Lamontagne

Le parc à résidus de l?ancienne mine Dunraine contient des résidus générateurs de drainage minier acide. Le concept proposé pour la restauration du site est d?utiliser le fort potentiel alcalin des boues rouges, résidus d?aluminerie, afin de neutraliser les résidus miniers. En appliquant une certaine quantité de boues rouges à la surface du parc, on provoquera une neutralisation de l?acidité. De plus, les alcalis contenus dans les boues rouges vont provoquer la précipitation de minéraux stables (sulfates tel la jarosite). La précipitation de ces minéraux provoquera la formation d?une couche indurée qui rendra difficile la circulation de l?oxygène et de l?eau. Bien que ce concept ait été vérifié en laboratoire, ce sont là des hypothèses qui restent à vérifier dans des conditions réelles d?exposition. Les principales questions soulevées par l?utilisation des boues rouges, mis à part le contexte géochimique, est le contexte technico-économique. En effet, le transport de quantité importante d?un matériel argileux humide présente un défi économique important. Outre le défi économique, la manipulation et l?épandage de ce produit sur des parcs à résidus constituent également un défi important. Cet article présente les conclusions d?une étude technique sur le transport, la manutention et l?épandage de boues rouges sur un parc à résidus situés en Abitibi : le site de Dunraine.

Nov 1, 2002

By C. Allen, M. Gangal, J. Stachulak

"Most underground diesel equipment is equipped with diesel oxidization catalysts (DOCs) to reduce carbon monoxide and hydrocarbon emissions. DOCs do not alter nitrogen oxides concentrations but can promote the oxidization of nitric oxide (NO) to the more toxic nitrogen dioxide (NO2). Vale and CanmetMINING have been researching how to reduce worker exposure to diesel emissions by testing mining equipment DOCs. Results indicate a > 77% decrease in carbon monoxide concentration but a 46–315% increase in NO2 concentration for 8-mode test cycles. It is recommended that DOCs that increase NO2 emissions be evaluated regarding their continued use in underground operations.RÉSUMÉ La plupart des équipements miniers souterrains sont équipés de catalyseurs d’oxydation diesel (DOC) afin de réduire les émissions de monoxyde de carbone et d’hydrocarbures. Les DOC ne modifient pas les concentrations des oxydes d’azote mais ils peuvent faciliter l’oxydation du monoxide d’azote (NO) en dioxyde d’azote (NO2), plus toxique. Vale et CanmetMINING effectuent des recherches pour réduire l’exposition des travailleurs aux émissions de diesel en analysant les DOC des équipements miniers. Selon les résultats, une diminution > 77 % dans la concentration de monoxyde de carbone est atteinte mais elle est accompagnée d’une augmentation de 46 à 315 % de la concentration en NO2 pour des cycles d’essais à 8 modes. Il est recommandé d’évaluer les DOC qui augmentent les émissions de NO2 pour décider de la poursuite de leur utilisation dans les opérations souterraines."

Jan 1, 2016

By Leibniz University, D. Zapf

"The demand for gas storage operations with high withdrawal rates and operation modes different to a seasonal storage regime requires a more detailed rock mechanical consideration of thermal induced stresses in the vicinity of the caverns. This means that the change of gas temperatures during operation and the consequences of these temperature changes on the stressing of the salt rock mass must be taken into account in the rock mechanical dimensioning. Within the rock mechanical calculations a loading history, i.e. a pressure versus time dependency, has to be defined. As rock salt has a time dependent material behavior stress redistributions in the rock salt mass take place even under constant internal pressure conditions. Therefore not only withdrawal and filling periods but also the duration of phases with nearly constant internal pressure is significant for the resulting state variables. Within the paper the differences and consequences for the rock mechanical recommendations are discussed. As a result it can be concluded that recommendations with respect to minimum operation pressure as well as for maximum withdrawal rates can be answered only in connection with the respective time intervals."

Jan 1, 2015

By K. Yoo

Chalcopyrite is the most abundant copper sulfide mineral, which is normally processed using pyrometallurgical methods (i.e., smelting) to produce copper metal. Smelting has several major disadvantages, such as high gas-handling costs, high capital costs, saturation of sulfuric acid market, and inability to treat low-grade concentrates and to recover some by-products, such as zinc, nickel and cobalt. The development of hydrometallurgical processes for chalcopyrite is desirable to overcome the problems of smelting. Because chalcopyrite is refractory, the leaching rate for chalcopyrite is very low. Therefore, increasing the leaching rate has been extensively investigated, both in sulfate and chloride media, as well as in the presence of bacteria. Chloride leaching processes have shown relatively high leaching rates. The mechanism of the chloride leaching process has been investigated, but the behavior of chalcopyrite leaching in chloride solution is not clear. Therefore, the effect of the solution redox potential on the leaching rate of chalcopyrite in chloride solution was investigated. In the present study, leaching experiments were carried out using 0.1 M chloride solutions and the results indicate that high leaching rates of chalcopyrite can be achieved at relatively low solution redox potentials.

Jan 1, 2007

By W. G. Worcester

THE chief object in presenting this paper on bentonite is to attract general attention to one of the least known and most neglected industrial minerals of Canada, a mineral of extensive commercial possibilities, as evidenced by its development and exploitation in other countries, principally in the United States and Germany; countries upon which some of our most important Canadian industries are dependent for their supply of special clays, such as Fuller&apos;s earth and activated bentonite. It was in view of these conditions and the knowledge of the presence of large quantities of bentonite in the Canadian West that the work here reported on was under-taken. While the investigational studies have not been completed, the results indicate that among the many samples tested there are some of real merit and industrial importance. While it has been the author&apos;s privilege to examine deposits and samples of bentonite from all of the Western provinces, his chief activities in the field and in research studies have naturally been confined largely to Saskatchewan materials. Notwithstanding this, however, this paper is presented in the hope that it may stimulate a more general interest in, and study of, Canadian bentonites as a whole, a matter of such importance that provincial boundary lines should be overlooked. GENERAL CHARACTERISTICS OF BENTONITE According to Schurecht and Donda (1), bentonite is commonly composed of the mineral montmorillonite, (Mg,Ca)O.Al203 5SiO2 .nH2O, though some are known to consist of beidellite, Al2O3 3SiO2.nH2O: where n is approximately 4, and in certain cases the Al2O3 may in part be replaced by Fe2O3. For present purposes, however, it may be sufficient to state that, in general, bentonite is a "soapy&apos; clay-like mineral or group of minerals composed largely of hydrous aluminium silicate, but frequently carrying small percentages of the alkalies, alkaline earths, and free silica, as well as silicates, gypsum, and other admixed detritus such that purification is usually necessary.

Jan 1, 1937

By Barbara Kirby

Mining Industry Human Resource Council Who we are: National Sector Council for the Minerals and Metals Sector 18-person Board of Directors Over 100 Industry Volunteers PPP - Funded by HRSDC and industry What we do: Identify national HR challenges and opportunities for the Canadian mining industry Create national solutions through collaboration, partnerships and Synergy

Oct 1, 2010

By K Byrne, W. Hawker

The average grade of copper concentrate is steadily declining, forcing the industry to turn to lower grade and metallurgically challenging orebodies. When faced with a low grade, challenging ore, mining companies are often forced to choose between high recovery at low grade or low recovery at high grade. Hydrometallurgical processing of copper concentrates using metathesis reactions, which replace iron with copper in copper-iron sulphide minerals and increase the copper to sulphur ratio in copper sulphide minerals, provide an opportunity to upgrade copper concentrates and potentially allow high copper recovery for a high grade concentrate. Factors such as concentrate mineralogy, reaction time and temperature, and the concentrations of copper, chloride and acid in solution are reported to affect the reaction extent and mineral phases formed by metathesis. In this paper, a copper concentrate has been studied over a wide range of conditions to investigate the influence of these key parameters on the extent of copper metathesis reactions and product phases formed. Solution and solid phases are assayed with the main mineral phases identified by Quantitative X-Ray Diffraction. INTRODUCTION The minerals present in copper deposits determine the prospective processing options either: pyrometallurgical or hydrometallurgical. For copper oxide ores, copper is typically present as oxides, carbonate, chlorides, silicates and sulphates. These minerals are readily solubilised in acid and are usually treated through hydrometallurgical processes. The typical process route for copper oxides is to leach copper into aqueous solution, purify and upgrade the solution phase through solvent extraction and then recover copper as metal by electrowinning (Davenport, King, Schlesinger, & Biswas, 2002). Copper sulphide deposits may contain a multitude of copper bearing minerals, including chalcopyrite, bornite, enargite, covellite, digenite and chalcocite. The copper ore grade and treatment options are affected by the mineral type and distribution. Sulphide ores are typically treated through comminution and mineral flotation to form concentrates, followed by pyrometallurgical smelting. Hydrometallurgy can also be used to process sulphides depending on the mineralogy and impurity levels (Davenport et al., 2002). The trend of decreasing copper grade with increasing impurity levels are common across the mining industry and pose future challenges to copper processing. This trend has prompted research into hydrometallurgical options for upgrading copper concentrates. One promising hydrometallurgical option is using metathesis reactions. Metathesis reactions, sometimes also called double replacement or displacement reactions, are chemical processes involving the exchange of bonds between two chemical compounds or species. In this case, the metathesis reactions involve copper in solution exchanging with cations in the solid sulphide concentrate. The driving force for copper sulphide metathesis is the relative affinity of the exchanging cation elements for sulphide. Based on sulphide precipitation diagrams, the expected order of affinity for sulphide should be Hg2+ > Ag+ > Cu+ > Cu2+ > Bi3+ > Cd2+ > Pb2+ > Sn2+ > Zn2+ > Co2+ > Ni2+ > Fe2+ > Mn2+ (Monhemius, 1977). Hence, copper metathesis reactions are capable of increasing copper content and removing impurities such as iron, nickel, zinc and lead from copper concentrates.

Jan 1, 2019

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By C. J. Sullivan

Many metalliferous ?provinces are co-extensive with particular groups of sedimentary, volcanic, or :basic plutonic rocks. Deposits may be truly syngenetic (Rand, Rhodesia-Katanga, Mans-field, Blind River, White Pine); re-. concentrated by circulating waters (Colorado Plateau, Red Bed Coppers) ; or re-concentrated thermally during metamorphism and granitization (most uranium and lead-zinc provinces ?and some copper and gold provinces). Basalts may yield important cop-per provinces when folded and re-heated. Granitization of basalts which have not reached the chlorite-carbon-ate phase of metamorphism may produce copper provinces. If they reach ?the chlorite-carbonate stage, granitization may result in a gold province. Copper and copper-nickel provinces may result if gabbros are granitized, and a ?similar alteration of per-idotite may result in asbestos or nickel ores. Many similar associations are known. Granite is not a source of ore, but a result of heat. A classification of ?ore with respect to source rocks is of greater prospecting value than are classifications based on magmatic differentiation and hydrother-mal solution theories. Volcanic centres are important ore foci because the thermally unstable metallic sulphides may be concentrated here by a distillation process. The ores found in the hot spring deposits, viz., mercury, mercury sulphide, sulphur, and the compounds of ?antimony and arsenic, are not those which are soluble in water at low temperature (epithermal sub-division of hydrothermal class), abrut those which are unstable thermally at comparatively low temperatures . Water is one of the most common thermally unstable minerals, and generally accompanies the thermally activated ore-forming sulphides.

Jan 1, 1957

By K. Sugawaral, W. Tongampl, K. Hiruta, Takasaki Y., A. Hosoi, T. Katol, A. Shibayamal

Printed circuit boards of discarded personal computers, televisions, mobile phones and so on contain a significant amount of valuable metals. For the recycle of valuable metals contained in the printed circuit board wastes (P CB W), the effect of temperature on chlorination-volatilization of metals under chlorine gas flow was studied. The experimental sample used was powder of two types: crushed PCBW (Sample 1) made from PC and industrial machines, and crushed-combusted PCBW (Sample 2) made from Sample 1. The principal element in Sample 1 and Sample 2 was copper, about 13 wt% and 20 wt% respectively. Sample 1 was composed of pure metals such as copper, tin and lead. In comparison, Sample 2 consisted of oxide metals such as copper oxide, tin dioxide and silicon dioxide. The two samples were heated at predefined temperatures (ranging from 300 °C to 900 °C) in chlorine gas. The chlorine gas flow into the furnace was set at a rate of 100 mL/min. As a result, copper in Sample 1 began to volatilize at 600 °C and completely vaporized at 700 °C. While in Sample 2, copper started to volatilize at 600 °C and reached 100% vaporization at 800 °C. For Sample 1, zinc finished volatilizing at 500 °C, while for Sample 2, zinc volatilization reached only about 80% (maximum). Also, lead, nickel and titanium showed similar results. Consequently the volatilization rate of Sample 1 is higher than Sample 2 and the temperature dependency was verified for copper, lead, zinc, nickel, antimony, titanium and chromium. In fact, the volatilization rate of these metals increased with the temperature. This result reflects the difference between pure metal and metal oxide, as Sample 2 was combusted before the chlorination-volatilization test. Moreover, the chlorination reaction may be accelerated by a reductive atmosphere because Sample 1 contains carbon. In this study, the volatilization behavior of some valuable metals in PCBW by chlorine gas was observed. Further improvement in the rate of volatilization can be achieved by optimizing the experimental conditions.

Jan 1, 2011

By D. G. Macintyre

Thick westward prograding clastic wedges were deposited along the margin of ancestral North America from Mid-Proterozoic to Mid-Paleozoic time. Periodic rifting and tectonic subsidence resulted in the formation of starved sub-basins along this otherwise passive continental margin. These sub-basins host important sedimentary exhalative barite-zinc-lead-silver deposits. In northeastern British Columbia, a thick succession of Paleozoic basinal facies clastic rocks is preserved within the northwest-trending Kechika Trough. Within the trough, sedimentary exhalative barite and barite-sulfide deposits occur in starved basin sediments of Middle Ordovician, Early Silurian, and Late Devonian age. The last are the most economically sigrrificant and are hosted by carbonaceous cherty argillites and siliceous shales of the Middle to Late Devonian Gunsteel Formation of the Lower Earn Group. The largest deposit, Cirque, has reserves in excess of 35 million tonnes averaging 100J0 (Pb +Zn) and 47 g/t Ag. Other potentially significant deposits include Driftpile Creek, Bear, Mt. Alcock, Fluke, Pie and Elf. Stratiform barite deposits are also common, particularly near the basin-to-shelf transition zone. The Late Devonian barite-sulfide deposits typically are zoned: interlarninated barite-sphalerite-galena-pyrite occurring near suspected vent areas grades outward into bedded barite. Laminated beds of pyrite typically occur in hangingwall siliceous shales, particularly above the inferred vent zone. The apparent absence of epigenetic stringer sulfide zones and footwall alteration implies that the deposits were formed from ponded brines at relatively low temperature. Away from the main deposits, the favourable stratigraphic interval is marked by the presence of thin beds of nodular and laminated barite and thin laminae of pyrite. Thin tuff beds also occur locally in this stratigraphic interval and are evidence for a Late Devonian volcanic event. A paleogeographic reconstruction of the Kechika Trough in Late Devonian to Mississippian time suggests that the barite-sulfide deposits formed in third-order starved basins between uplifted, northwest-trending horst blocks that were capped by shallow-water carbonate banks. The presence of intraformational breccias suggests that fault movement accompanied barite-sulfide precipitation. This tectonic activity may have allowed the escape of heated, overpressured metalliferous brines from permeable reservoirs within the sedimentary pile. Sedimentary exhalative deposits formed where these brines were exhaled as buoyant plumes onto the seafloor, cooled, and ponded in anoxic seafloor depressions.

Jan 1, 1992

By M. A. Roche

The property of the Hudson Bay Mining & Smelting Company, Limited is located at Flin Flon lake, 85 miles northwest of The Pas, Manitoba, on the Manitoba-Saskatchewan boundary. The area is at latitude North 54°, and is approximately 1,000 feet above sea level. The ore-body occurs in amygdaloidal greenstones, which are to be referred to the earliest basic volcanic flows in the district. It was discovered in an outcrop on a point of land jutting into Flin Flon lake, and subsequent diamond drilling proved that it extends under the lake both to the north and south of the point of discovery. After the taking of soundings from the ice during the winter months, it was estimated that l,000,000 tons of overburden, mainly mud and clay, would have to be removed to expose the underlying ore. Flat diamond-drill holes indicated that the ore-body was separated into more or less independent lenses by horses of unmineralized greenstone, and that in places the overall width, including horses of waste, reached 450 feet. These several] conditions were the main factors influencing the management in their decision to adopt an open-cut method for the mining of the upper portion of the ore-body. Before it was possible to commence stripping operations, it was necessary to dam-off the eastern portion of Flin Flon lake, instal pumps, and de-water the dammed-off area. Dams for this purpose were constructed of mine waste rock and clay filler from nearby hillsides. Material for the bottoms of the dams was taken across Flin Flon lake in hopper-bottom barges. Trestles were then built on the dam bottoms and dams were complete by the time trackage was available. De-watering commenced in April, 1930, and was completed by the latter part of May of the same year. Estimated pump output for the period was roughly four billion gallons. Two Morris 10-inch dredging pumps were used, direct-connected to 250 h.p. electric motors. Individual pump capacity was rated at 3,000 g.p.m. against a 150-foot head. Average head for the operation was 50 feet, which increased the total output considerably. The pumps were mounted on floating barges in cribbings of piling driven at the lowest points in the lake bottom.

Jan 1, 1933

By A. Valdivieso

Reducing accident rates keeps getting more and more complex as the usual tools enter a curve of diminishing results. Fortunately, nothing modifies behaviour in a stronger and wider way than having a robust safety culture. On the other hand, managing cultural change is difficult and the risk of back-fire is very high, especially if the workforce does not trust our intentions. A personalized approach of well chosen and targeted actions tends to be the only yet difficult option. We have found, via experience in the metallurgy and chemistry industries, a way of preparing the company and the workforce to accept these sorts of culture changing measures faster and easier. Using company-wide changes based on workplace perception, yields the most optimal acceptance. It is based in the principle that we all use clues in our environment as guides to choose our behaviour. So, controlling the perception that our workplace generates can affect behaviour and simplify our task before it even starts. It is a matter of using the tools that other disciplines such as marketing, social engineering and architecture bring to us and adapting them to a very defined objective: Having our installations “sell” safety so that our people unconsciously believe that they must adapt to safety values in order to “do well” in said environment. INTRODUCTION After decades of improvements in accident rates, we are understandably hitting a diminishing results curve: most actions that spectacularly reduced accidents in the past (e.g., Innovation in Personal Protection equipment, adapting international standards and legislation, and innovative safety programs; Figure 1) now hardly get us the exponential gains we saw years back, regardless of the investment we put on them. Furthermore, the improvements in safety of the last 3 decades have been creating new sets of issues that start to show their face such as: By reducing accidents we can create feelings of invulnerability as we lose view of the consequences. With innovative protection equipment we increase Risk Homeostasis, meaning that people behave in a more dangerous way in order to maintain a constant level of risk in their lives (Getting closer to fire after getting better fire-proof garments for example). Too much Legislation can create a feeling of disengagement from personal responsibility. And despite improvements, we haven’t really solved the production vs safety confrontation, it is now stigmatized and less visible, yet it tends to reappear in moments of weakness.

Jan 1, 2019

By A. Ghahreman

Activated carbon is proven to be able to catalyze arsenic oxidation in aqueous solution under acidic conditions. A commercially available granular coconut shell based activated carbon (AC) has been evaluated for catalysis of arsenic oxidation in this study. The rapid small-scale column test (RSSCT) has been developed to simulate and predict the performance of a carbon-based arsenic treatment system in a pilot scale reactor. Effects of residence time, aeration rate, and initial arsenic concentration in the influent solution on the AC catalysis of arsenic oxidation under dynamic and continuous conditions were studied by manipulating these parameters during RSSCTs. The effectiveness of the AC on arsenic oxidation was examined over the course of constant diffusivity based RSSCT operation. Residence time and initial arsenite concentration are proven to be the most effective impacting parameters on the arsenic oxidation process. For the 218 min residence time, the highest steady-state arsenic oxidation efficiency achieved was 98% with 1 g/L As(III) being treated at pH=1 under 0.05 L/min oxygen aeration. In a long-running RSSCT, the oxidation efficiency did not seem to deteriorate over a course of 666 hours operation, corresponding to 13986 mL total influent throughput volume. INTRODUCTION Arsenic is toxic to both animals and plants and inorganic arsenicals are proven carcinogens in humans. The increased extraction of low grade and complex mineral resources has introduced high ratios of arsenic into metallurgical processes. Discharge of arsenic by acid mine drainage resulting from mining activities has added intensive pressure on the need for proper treatment (Lawrence & Higgs, 1999). Since trivalent arsenite is more toxic and has lower affinity to solid surfaces for adsorption, many treatment systems initiate with an oxidation step to convert arsenite to arsenate and reach the ultimate immobilization of arsenic by the following precipitation of arsenate (Nazari, Radzinski, & Ghahreman, 2016). Scorodite precipitation has been studied extensively as a means of arsenic immobilization due to its high stability and negligible potential of releasing arsenic (Filippou & Demopoulos, 1997). As a stable ferric arsenate mineral, crystalline scorodite can contain up to 30 wt% arsenic (Paktunc, Dutrizac, & Gertsman, 2008). Arsenic must be in its pentavalent oxidation state in order for scorodite to be precipitated via oxidizing ferrous ions (Clancy, Hayes, & Raskin, 2013).

Jan 1, 2019

Sustainable Development SAFETY ?Safety is the most important element of sustainability. ?One bad experience or incident can mar a company?s reputation for a long, long time. ?News travels faster than ever ?Internet, blogs, texting, peer-to-peer communication, etc. and unfortunately sometimes the information is not always accurate. ?Rarely do we hear in the news about the mining companies or projects that are done safely ?we always hear about the exceptions. ?Safety is just like TQI / TQM ?the process of improving can never stop.

May 1, 2010