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By Eduardo A. Pérez, Alejandro R. Alonso, Rosa María Luna-Sánchez, Gretchen T. Lapidus

Rare earth elements have been widely used in various sectors, from the aerospace and steel industries, to electronic applications, particularly in displays and batteries for portable devices. The high demand for newer and better equipment, such as cell phones, tablets and lap tops, has increased the consumption of the rare earth elements and at the same time the need for its recovery from electronic wastes. For that reason, the recycling of batteries is important, principally the Ni-HM batteries, due to their elevated content of rare earths elements, in addition to the high concentrations of cobalt and nickel. The current processes are based on dissolution in strong acid solutions (sulfuric acid concentrations from 2 to 4 mol/L), and temperatures from 30 to 90°C. In the present work, electrodes from spent Ni-HM batteries were leached using 1 mol/L H2SO4, in the presence of ozone as the oxidant, where recoveries of 96% for La, Ce and Nd were obtained at room temperature. The separation of Ni and Co from the leach solutions was performed using an electrochemical reactor, after which rare earth elements were precipitated, obtaining a mixture of its hydroxides with impurities below 1%, according to EDS analysis.

Jan 1, 2014

By Yong Kang, Bingyuan Yan, Dandan Zheng, Xiaochuan Wang, Dengfeng Su, Dongyang Li

"According to the characteristics of rock mass and the directional cutting technology of water jet, a new idea of light shock controlled blasting with water jet slotting was put forward. Based on the fracture mechanics theory and the stress wave theory, the mechanism of damping with water jet slotting was analyzed. On the basis of the above, the evolution law of the pressure wave and displacement field during the blasting were simulated by FEM software ANSYS/LS-DYNA. The result shows that: the oriented slot plays a good role in orientation during the blasting, and makes the energy generated by gas released by the explosives gather at the tip of the oriented slot, which makes it easier for the main crack to expand along the oriented slot and indirectly reduce the stress effect on the protected object. Meanwhile, the energy of the seismic wave is reduced while transmitting through damping slot. Finally, compared with the normal blasting with damping ditch, the maximum acceleration is reduced by 15.62%, the maximum velocity is reduced by 52.99%, and the maximum displacement is reduced by 68.32%. INTRODUCTIONIn recent years, with increasing demand for energy and space, an increasing number of underground projects have been under construction. Drilling-blasting method, as a traditional main method for rock excavation, is still an indispensable means in the engineering construction. As is known, blasting vibration will cause the deformation and unstable of the existing building structures, so how to reduce the influence on the existing building structures caused by the blasting vibration has become the focus. Traditional shock absorption measures mainly include three kinds: the first one is pre-splitting blasting, the second measure is to change the parameter of explosive filling, and the last one is to excavate damping ditch between the protected object and blastholes. However, engineering practices show that: the protected rock may be damaged in the process of pre-splitting crack construction by blasting, the second measure is difficult in operating, and the third measure is troubled by large work quantity (Song Guangming, 1999; Lou Jianwu, 2004; Lou Jianwu, 2005; Li Xibing et al., 2008)."

Jan 1, 2015

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By S. Uddin

Microsegregation manifests its effect on microstructural evolution of cast or welded alloys which in turn influences their important mechanical and electro-chemical properties. In the above context, mathematical models of microsegregation have proven to play an important role in estimating the nature and predicting the effects of this phenomenon in wide varieties of solidification processes. Microsegregation models are useful in designing new commercial alloys, in estimating the homogenization time for the post-process heat treatments and in many other practical applications. In this study, two semi-analytical models of microsegregation were developed to predict the concentration field of solute in the liquid and solid regions for dendritic solidification of binary metallic alloys. Both models assume that the growing dendrites are cylindrical in shape. This assumption is more realistic compared to the common assumptions of plate like dendrites that most of the earlier researchers employed in their microsegregation modeling study. The solute redistribution profile, in the developing solid layer, necessary to determine the back diffusion parameter was derived from Fick's second law for the model without coarsening. The application of this parameter in a wide range of conditions and the use of its basic form in the model with coarsening has been verified. The concept of coordinate transformation and enhancement of back-diffusion Fourier number were used in deriving the model which took into account the coarsening of dendrites. The models are then extended to deal with rapid solidification and peritectic transformations and the results were compared with relevant experimental data for Aluminum and other alloys. A good agreement between model predictions and experimental results was found.

Jan 1, 2007

By G. D. Hibbard

New regions of material property space can be accessed by combining microstructural design at the nm-scale with architectural design at the µm- or mm-scale. In the first case, large strength increases associated with grain size reduction to below 50 nm have driven extensive research efforts into the development of nanocrystalline materials [e.g. 1-3]. For many potential structural applications, however, the density of a nanocrystalline material is just as important as its strength. In fact, reducing the density is more important than increasing the strength for certain weight specific materials performance indices, and it is especially critical for applying structural nanomaterials in the aerospace and automotive sectors. We have developed a new type of structural nanomaterial wherein the effective density of the parent metal is reduced by more than an order of magnitude by incorporating an internal periodic cellular architecture of open space. In one example a low density cellular nanocrystalline material was created by electroforming nanocrystalline Ni around a rapid-prototyped acrylic photopolymer microtruss, Figure 1 [4]. Microtruss materials have periodic cellular architectures that are specifically designed to undergo stretching-dominated deformation as opposed to the bending-dominated deformation in conventional open cell metal foams [5,6]. This new cellular nanocrystalline hybrid material combined the structural efficiency of microtruss architectures with the ultra-high strength that can be achieved by grain size reduction to the nm-scale. Although it played a critical role as a cathode support during the initial stages of nanocrystalline electrodeposition, the polymer core did not contribute significantly to the inelastic buckling resistance of the composite metal/polymer struts and it may therefore be desirable to remove it post deposition by means of chemical dissolution or thermal decomposition [4]. Nanocrystalline electrodeposition can also be used to reinforce conventional cellular metals (Figure 2), creating new types of cellular composites such as metal/metal microtruss hybrids [7-10] and metal/metal foam hybrids [11,12]. For example, nanocrystalline Ni-Fe alloy sleeve thicknesses of up to 400 µm were used to reinforce an aluminum alloy microtruss that had been fabricated using a stretch-bend approach; the nanocrystalline sleeves had the effect of increasing the microtruss strength by up to a factor of twelve and the specific strength by a factor of three [8]. Alternatively, much thinner sleeves can be electroplated to produce structural coatings. In one example, a nanocrystalline Ni coating was designed to provide both corrosion protection and inelastic buckling resistance [10]. Because the ultra-high strength material was optimally located at the furthest distance from the neutral bending axis, only a thin coating of 50 µm was needed to double the inelastic buckling resistance of the 1.13 mm x 0.63 mm cross-section plain carbon steel struts [10]. Overall, the mechanical performance increase that can be obtained through electrodeposition depends on a complex interaction between the starting cellular architecture and the nanocrystalline sleeves.

Jan 1, 2010

By D. M. Xue, T. B. Li

"With the increase of human engineering activities, global climate change and active plate tectonics movement, the giant landslide frequently occurred in southwest China, which caused huge property and human losses. Besides, the potential landslides pose severely threaten to the construction and operation of airports, railways, highways and power stations etc. In order to provide accurate guidance for the landslide investigation, stability analysis and mitigation, the giant landslide is redefined according to landslide volume, depth of slip surface, complexity of landslide mechanisms, and degree of landslide mitigation difficulty, and classified with the typological classification approach based on the twofold attributes of landslide behavior including formation mechanisms and reactivation features. Finally, the threefold particularity of the giant landslide is also summarized, which enables a more effective landslide mitigation design.INTRODUCTIONWith the increase of anthropogenic activities, global climate change and active plate tectonics movement such as continual uplifting of Qinghai-Tibet plateau and strong earthquakes, the occurrence of giant landslides was in ascending trend in southwest China (Huang, 2009), which caused serious destruction, and greatly endangers such engineering construction from safety, time and economic aspects as airports, railways, highways, power stations, etc. Giant landslides have huge scale, complex formation/reactivation mechanisms and mechanical behavior. They may not be identified during the hazard investigation, but may be firstly initiated or reactivated due to the following engineering activities, heavy rainfall or strong earthquakes. Consequently, the landslide mitigation is inevitable and costly. However, it is difficult to control the deformation of giant landslide with lack of a correct understanding of genetic mechanisms (Marui, 2012; Zhang, 2000) and the excessive large sliding forces of the slide blocks calculated by the conventional limit equilibrium method. For instance, the failure of anchored pile wall for the No.102 giant ancient landslide (Zhu et al., 2012) and stabilization measures for the Sidi Rached viaduct landslide(Guemache et al., 2011); four rows of piles had not prevented the occurrence of the No.12 landslide in a high fill slope in the Panzhihua airport (Li et al., 2012)."

Jan 1, 2015

By S. Bergquist

In this paper, it is investigated how different types of automation would affect the safety for workers in asphalt paving. The risk for the workers on road construction sites is consistently high in comparison to the average risk of the working population. Automation has been suggested as an alternative for improving the safety in roadside construction assuming that removing workers will inherently eliminate the risk of them being injured. In this paper, the potential for improving the safety using automation is analyzed in detail. By investigating accident statistics and understanding the type of accidents that appear, several different automated functions for increased safety are proposed and described. Based on available statistics, it is possible to estimate the safety benefit, as the reduction in fatalities, for several of the proposed functions. The highest safety benefit would be achieved by automating the road traffic driving through the work zones. This has the potential of reducing the total number of road worker fatalities with over 30 %. In addition, it would decrease the number of road traffic accidents in work zones. Automation of construction machinery and dump-trucks also has the potential to increase the safety.

Aug 1, 2013

By Hani S. Mitri

Overhand cut-and-fill mining of narrow vein orebodies inevitably leads to the creation of horizontal pillars. As the thickness of the overlying crown pillar diminishes, stresses build up in the pillar. More often than not, this situation causes an increased level of seismicity and possible pillar burst. One well-known strategy to reduce the hazard of crown and sill pillar burst in cut-and-fill vein mining is that of destress blasting. The paper first reviews the methods used for the monitoring and assessment of potential pillar burst in narrow vein cut-and-fill mining. The influence of horizontal stress, mine depth and pillar thickness on stress build-up in the crown pillar is examined through a characteristic narrow vein numerical model. The paper then presents, with reference to three mine case studies, the benefits of destress blasting and the factors affecting its success as a ground control technique.

Oct 1, 2001

By M. Kreuh

An investigation of the pressure pulse spectrum generated by the gas dispersion processes in a Peirce Smith copper converter was undertaken via the simultaneous measurement of four tuyeres using high frequency pressure transducers. The data was captured, stored, and analyzed using digital data processing techniques; including power spectral density plots, band-pass filtering, and a principal component analysis (PCA). The process was characterized throughout by a dominant 3 Hz pulse signature attributed to the formation of lateral gas envelopes. In particular, test tuyeres in the tuyere line tended to operate synchronously at the dominant frequency, regardless of operating conditions tested and despite being distributed along the converter. Synchronous behavior is thought to arise from the acoustic coupling and possible resonance behavior of the gas delivery system on the converter.

Jan 1, 2007

By S. Shairp

The first commercial application of the Dynatec two-stage zinc pressure leach process commenced operation at the metallurgical complex of Hudson Bay Mining and Smelting Co., Limited in Flin Flon, Manitoba in 1993. A key feature of the successful leaching operation is the presence of iron in solution, which facilitates oxygen transfer in the autoclaves and enables rapid oxidation of zinc sulphide minerals. At the same time, the solution from which zinc is recovered must be essentially iron free. Precipitation of iron from the solution starts in the autoclaves and is completed in subsequent atmospheric purification steps. Conveniently, these iron precipitation steps also remove nuisance elements such as arsenic and fluoride from the solution, while producing solids with good liquid-solid separation characteristics. This paper provides an overview of the current operations in Flin Flon, with particular reference to the behaviour and deportment of iron throughout the zinc plant.

Jan 1, 2006

By I. Demers

The abandoned Manitou mine site covers an area of approximately 190 ha near Val d?Or, Quebec. This old site has been generating acid mine drainage for several decades. In 2006, a partnership was established between the Quebec Ministry of Ressources Naturelles (MRN) and Agnico-Eagle Mines to reclaim the Manitou site using tailings from the nearby Goldex mine. These neutral tailings were to be deposited on top of the Manitou site. An extensive study was performed to evaluate specific reclamation scenarios to control acid mine drainage using Goldex tailings as cover material. The article first describes the global approach used for this evaluation, which includes in-situ hydrogeological monitoring, tailings characterization, laboratory column tests, and numerical modelling. Of the thirteen column tests, three were conducted to evaluate the parameters affecting the performance of covers made of Goldex tailings placed over the spillage area of the Manitou site. Geochemical and hydrogeological parameters were assessed during the leaching column tests for almost two years. The tests aimed at evaluating the effect of water table level and monolayer cover thickness on the overall performance. The testing procedure involved monthly leaching and measurement of geochemical parameters. Results indicate that water table position is the most important factor affecting the monolayer cover performance to control AMD. Based on these results, it was established that the water table must be located near the interface between the Goldex and Manitou tailings to effectively reduce AMD generation. Cover thickness also has an impact on cover performance, which is however less significant than the water table position. The testing scenario with a water table located at the interface with a one-meter Goldex tailings cover showed progressive improvement in effluent quality.

Aug 1, 2013

By Dale Coffin

Definition Of A Crisis Crisis \kri-ses:\ An unstable or crucial time or state of affairs whose outcome will make a decisive difference for better or worse (Webster's New Collegiate dictionary) An event or set of circumstances that could significantly affect a company?s ability to carry out its business, damage a company?s reputation and/or threatens the health, safety and well-being of employees, the community or the public at large You?re Having A Crisis When... . The emergency poses a significant threat to the public or employees . The emergency situation provokes government scrutiny . The company no longer has full control of the situation . The situation has created significant regional, national or international media interest . The corporation?s reputation may be damaged or there is a threat to the bottom line or share value

May 1, 2004

By Royston Colbourne

Objectives Of Presentation - Identify specific risks - A fresh look at risk - Provide a moment reflection on risk - Open discussion on risk A route to solution and advanced thinking.

May 1, 2010

By K. Mayhew, K. Murray

The CESL Copper Process was developed as a hydrometallurgical alternative to smelting and refining for copper sulphide concentrates. As the majority of such concentrates contain appreciable gold and silver values, effective recovery of these metals is essential to the economics of this technology. Unfortunately, conventional cyanide processing cannot be used on the residue from the copper process, clue to its unusual characteristics when compared with naturally occurring gold and silver ores. An abundance of elemental sulphur, as well as the presence of cyanide soluble copper, leads to the formation of both thiocyanate and copper cyanide which is detrimental to process economics clue to excessive cyanide consumption. This, however, can be reduced to acceptable levels by process innovations such as pressure cyanidation and cyanide recovery. This paper outlines the successful application of the CESL Gold Process to various gold-bearing copper concentrates from bench to demonstration scale.

Jan 1, 2011

By A. McLean, Q. R. Yang, Y. D. Yang, G. F. Zhang, P. Wu

A considerable amount of waste slag from the pyrite roasting process is discharged every year. Recovery of iron from the waste slag is of great interest for comprehensive use of mineral resource, reduction of environment impact and improvement of economical benefit to related companies. The objectives of the present work are focused on: (1) Compare various procedures for recovery of iron from the waste slag and select a best procedure for industrial trial which is roasting of the waste slag under reducing condition followed by magnetic separation; (2) Investigate the optimum conditions for maximum recovery of iron from the waste slag. The experimental result shows that under the treatment condition found in this work about 36 to 40% of the iron oxide was recovered from the waste slag, where the iron content in the concentrate is 57%. The total recovery ratio of iron, up to 70%, from the waste slag was achieved. After the treatment, sulphur content in the waste slag was reduced significantly and gangue materials, such as SiO2, Al2O3 and TiO2, were reduced effectively.

Jan 1, 2011

By Wael Abdellah

Mine haulage drifts are the primary access to the mining blocks of an orebody in a multilevel mining system of a tabular ore deposit. The stability and functionality of haulage drifts are thus crucial to the success of a mining operation. Drift instability could lead to serious consequences such as injuries, production delays and higher operational cost. In this paper, the performance of the haulage drift stability is evaluated on the basis of the primary rock support system comprising 1.8 m resin grouted rebars in the drift walls and 2.1 m long bolt in the back. Two failure criteria namely the extent of Mohr-Coulomb yield zones around the drift, and linear elastic brittle shear failure are adopted and compared, with respect to lower level and same-level mining and filling sequence in the vicinity of the haulage drift. The case study is one of the #1 Shear East zone of the Garson Mine in Sudbury, Ontario. Random Monte Carlo (RMC) technique, which has been previously established to assess the haulage drift stability, is employed in this investigation. The RMC technique is used in conjunction with finite difference modelling software FLAC for random assignment of model input parameters in the FLAC grid. Deterministic model results reveal the drift behaviour in terms of deformation (convergence) and mining-induced stress distribution. Comparison between the two different criteria is carried out to determine which method is most suitable in evaluating unsatisfactory drift performance. The results are presented in terms of probability of instability and categorized with respect to failure condition and mining step. It is shown that the brittle shear failure condition based on linear elastic response calls for enhanced support system at a later mining step than what Mohr- Coulomb yielding condition does. The paper presents a detailed discussion of the stochastic analysis results.

Jun 1, 2012

By Mel Owen, Bob Tipman

"A number of studies have identified the presence of heavy minerals in the Athabasca oil sands. A 1996 Mineral Development Agreement study into the recovery of Co-Products identified low operating costs, a simple flowsheet and access to market as key drivers in advancing interest in a viable project.Commercial bitumen extraction processes recover 50% of the titanium heavy minerals and 85% of the zircon into froth containing 1 % of the feed solids. Froth treatment tailings grade is 11.5% Ti02 and 3.6% Zr02.Processing this high grade feed in a combination of flotation, roasting, screening, gravity concentration and magnetic separation, results in concentrates of rutile, leucoxene, ilmenite, zircon and rare earths of marketable quality.A combination of high grade feed and a simple process lead to operating costs among the lowest in the industry. Low cost heavy minerals and low energy costs indicate an intriguing potential for low cost pigment production in Alberta. The production of heavy minerals from oil sands remains one of the largest untapped resources in the Province of Alberta1.0 IntroductionThis paper describes the results of an investigation into the recovery of heavy minerals from tailings produced by the major oil sands plants. The study was carried out under a Canada-Alberta Mineral Development Agreement (Alberta Chamber of Resources 1996). The MDA Co-Products Study examined the potential for the economic recovery of heavy minerals from oil sands tailings."

Jan 1, 1998

By Thomas Kilpatrick

The liability created by building this railway is the great financial problem before the people of British Columbia at the present time. In dealing with the subject, I propose to divide it into three periods: The Past - The Present - and The Future. The Past The primary objects in building the railway were to provide an independent and direct route for the Grand Trunk Pacific railway into the city of Vancouver, and to open the central and north-eastern portion of the province.. This vast territory, almost one-half the entire area of British Columbia, has great wealth in fruit, agricultural, and grazing lands; timber, coal, water-power and minerals of all kinds, including some of the richest placer deposits in the world. Rivers and lakes teem with fish. Big game, including moose, elk, caribou, deer, grizzly and black bear, mountain goat and sheep, is plentiful and there is an abundance of small game and fur-bearing animals. In addition, its scenic attractions are unsurpassed in Canada. To develop these resources it was considered necessary to build a railway from south to north as a main artery of transportation and, if necessary, branch lines to carry heavy .shipments of coal or other commodities. Lighter freight may be handled by motor trucks from distant points to the railway.

Jan 1, 1925

By K. R. Nichol

The author points out that corrosion works 24 hours a day, every day. It is an economic reality that the cost of corrosion is inevitable and that its cost should be incurred in the least expensive way. An economic evaluation technique to properly assess its relative impact is the Discounted Cash Flow Method. Various remedial and corrosion control measures are available and these, when coupled with a planned corrosion control program, help reduce the cost of corrosion.

Jan 1, 1973

By D. M. MacLean

THE property of Howey Gold Mines, Limited, is situated at Red Lake, Ontario, one hundred and seventy-five miles east of Winnipeg and eighty miles north of the Canadian National railway. The mine has been a continuous producer since April, 1930, and, at present writing, a total of 3,042,690 tons has been hoisted, giving a production of $6,422,858.55, for a grade of $2.32 per ton. From 1,064,477 tons mined during the past two years, however, the yield has been only $1,389,607.03, or $1.41 per ton (gold at $20.67). Present output is at the rate of about 1,470 tons. per day. THE ORE-BODY AND WALL-ROCK: The Howey ore-body is part of a quartz porphyry dyke, which has. intruded an area of greenstone. The dyke strikes north 65° east, and its dip varies from 85° to the south at the surface to practically vertical below the. 1,000-foot horizon. Both along the strike and on the dip, the width of the dyke varies from 25 to 200 feet, the widest portion occurring below the 1,000-foot level. To the east of the ore-body, the dyke increases in width and finally splits into tongues of porphyry enclosed in greenstone, diorite, and congloJ11erate. To the west, it passes into the adjoining property, its width at the boundary being 100 feet. The rock in the ore-body is hard to drill, but, because of numerous horizontal slip-planes, it breaks well when blasted. This characteristic makes it possible to break large breasts or benches with a relatively small number of holes. The ore broken in this manner is consequently quite coarse, a large part of it requiring secondary breaking.

Jan 1, 1938