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By G. E. Wood

Steep Rock Resources Inc. owns a calcite quarry property at Tatlock, Ontario, and a calcite processing plant at Perth, Ontario. The Tatlock marble deposit forms part of an extensive series of carbonate rocks of the Grenville Geological Province in the Precambrian Shield of southeastern Ontario. The deposit is very unusual, if not unique, in the Grenville area in its combination of characteristics of large size, whiteness, high calcium content, low magnesium and silica contents, and scarcity of accessory minerals. A major expansion of the fine grind products capacity of the plant was undertaken in 1982 and came on stream in 1983. The expansion provides important operating benefits at the plant: greater flexibility as to the product mix and reduced dependence on the single grinding mill previously in place. The expanded facility consists of prima,y and secondary crushers, a rotary drye,~ a screenhouse producing a range of screen separator grade products, an airswept Raymond Mill, and a pebble mill with integrated air classifiers, product storage bins, bulk, semi-bulk, and bagged product shipping capabilities, road and rail access, and a substantial product warehouse. The expansion was designed to be compatible with a move into ultrafine calcite production, and is capable of supplying the anticipated sales growth within its market area during the next 5 years. Products are exceptionally white, with good chemistry, low abrasion, and consistent quality. Markets range, according to product particle size, from pre-cast concrete aggregate to fillers for coatings, plastic pipe, and compounds.

Jan 1, 1984

By Hong Zhong, Shuai Wang, Fangxu Li, Guangyi Liu

"The flotation performances and adsorption mechanisms of a-hydroxyoctyl phosphinic acid (HPA) to malachite, cassiterite and wolframite were investigated by micro-flotation tests and X-ray photoelectron spectroscopy (XPS) analyses. The micro-flotation results indicated that compared with styrene phosphonic acid (SPA), diphosphonic acid (DPA), benzohydroxamic acid (BHA) and salicylhydroxamic acid (SHA), HPA exhibited excellent collecting power to the three oxide ores. In addition, HPA showed superior selectivity against hematite, tourmaline, feldspar and quartz. The results of XPS analysis demonstrated that HPA reacts with active species (M) on metal oxide by formation of P-O-M or P-M bonds.INTRODUCTIONIn mineral processing, flotation has been the main process for separation and recovery of valuable minerals from complex ores (Mei, 2013; Zhou, 2014). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by surfactant (known as collector in flotation) adsorption so that these mineral particles can preferably attach air bubbles in a slurry or pulp (Bai, 2004; Hankins, 2004). To anchor a solid surface selectively, special functional group are designed to adjust the interaction between the surfactant and the active sites of solid surfaces (Wu, 2006; Huang, 2014).Organic phosphorous compounds have strong affinity toward metals or metal oxides because they form more stable metal complexes than metal carboxylates (Pazik, 2001; Zheng, 1998). In mineral engineering, phosphorous compounds have been exploited as metal extractants and flotation collectors (Alguacil, 2002; Sun, 2008). Ni (2012) and Zhang (1998) introduced diphosphonic acid (DPA) as an effective collector for flotation of fersmite and niobite. Liu (1999) found styryl phosphonic acid (SPA) was a superior collector for flotation recovery of finely disseminated rutile ores. Gruner and Bilsing (1992) thought SPA was one of the best collectors for flotation recovery of cassiterite which could obtain a high-grade concentrates of more than 40% with high recovery values. Bulatovic (1999) investigated the flotation performances of phosphoric acid ester (PAE) to perovskite, ilmenite and rutile and found that PAE was an impactful collector for selective flotation of titanium minerals from complex ores in the presence of petroleum sulfate. However, a-hydroxyoctyl phosphinic acid (HPA) as a flotation collector for recovery of titanium ores were hardly reported in the previous literatures."

Jan 1, 2016

By W. Standifird

"Cohesive fracture is a mechanical model widely used for modeling quasi-brittle fracture in rocklike materials. This work discusses use of this model to simulate quasi-brittle fractures generated by injection stimulation during the process of cuttings reinjection in West Africa. Cuttings reinjection is an engineering practice used for disposal of drilling waste. During this process, hydraulic fractures are created at the target formation and milled cuttings are injected with fluid. In practice, this process must remain in compliance with environmental regulations and zero-discharge policies. The purpose of this study is to determine the following factors of injection design for a field in West Africa: (1) pumping pressure capacity required to successfully perform the injection and (2) the injection rate for injection performance and the value of fracture width under injection.A simplified three-dimensional (3D) finite element model (FEM) was built. A poroelastic plastic damage model was used for simulation of the cohesive crack prorogation within the target formation. For simplicity, fracture development in both horizontal and vertical directions was simulated separately. In this way, the computational burden for one calculation was reduced to a reasonably low level, without losing accuracy of the model. Loads of the model include fluid injection and gravity, which balances the initial geostress field. Various values of injection rate were used in these calculations to determine the most reasonable value of injection pressure. The capacity of pressure of a pumping device was determined using this optimized value of injection pressure.Results in values of width and length of fractures created by the injection are presented. Injection pressures at bottom-hole (BHP) corresponding to each value of injection rate are also given. Numerical results for fracture generation and propagation in a horizontal direction were visualized. The pumping pressure capacity required to fulfill the cuttings reinjection work was determined based on the numerical results of optimized injection rates and pressure. The fracture width was determined using the given pumping pressure. The length and height of the fractures was determined using pumping pressure along with the required volume of cuttings waste to be disposed of into the formation.This work presents a case study of 3D finite element modeling of hydraulic fracturing generated by cuttings reinjection. The results of the optimized injection rate and pressure provide a best practice and a useful reference for cuttings reinjection analyses in this region."

Jan 1, 2015

By N. Hiroyoshi

In the leaching of chalcopyrite with sulfuric acid solutions, the copper extraction rate reaches a maximum at a given redox potential. This article reviews our studies on the determination of the optimum redox potential for chalcopyrite leaching. Shaking flask and column leaching experiments for a chalcopyrite concentrate were performed under various conditions, and the results were analyzed using a normalized redox potential defined from a reaction model assuming the formation of an intermediate CU2S from chalcopyrite. Factors, such as metal ion concentrations, solid/liquid ratio, and presence of iron-oxidizing bacteria, caused significant variations in the copper extraction versus time plots. However the copper extraction rate versus normalized redox potential plots were independent of the above factors and the copper extraction rate reached a maximum at the normalized redox potentials around 0.43. Converting the normalized redox potential to the solution redox potential gives the optimum redox potential for chalcopyrite leaching as a function of cupric and ferrous ion concentrations. This semi-empirical equation can be used to predict the optimum redox potential during leaching operation, and is useful to design the redox-controlled heap leaching for chalcopyrite.

Jan 1, 2007

By Y. Béliveau

Emission of perfluorocarbon gases, CF4 and C2F6, produced during anode effects from aluminum electrolytic cells are a significant part of the total equivalent CO2 emitted by aluminum plants. With the current concerns about global warming, the reduction of these PFC gases is a key issue in reducing greenhouse gases for a smelter and achieving GHG emission agreement goals. This paper will present the approach taken by the Alcoa vertical-stud Soderberg plant in Baie-Comeau to reduce GHG emissions generated during anode effects and close emission gaps with other Alcoa Soderberg plants. The approach has been to adapt the existing technology in place at the Baie-Comeau Soderberg plant. PFC emissions were lowered by reducing both the anode effect duration and frequency through different methods. Examples of change include: implementing skimming practices and wider side crust break area for better alumina dissolution in bath, increasing the ratio between reacted and pure alumina, reducing the time to declare anode effects in the potrooms, implementing best work practices and finally educating the workforce on the importance of reducing PFC emissions.

Jan 1, 2007

By Hans Lundberg

An electric survey from a 'plane flown over the ground is much faster and cheaper than an electric survey carried out on the ground. The results are obtained as continuous recordings that are resolvable into both a depth expression and a conductivity effect, so that the indications are easier to evaluate, as well as to correlate from one flown line to the other. The prospecting technique adopted in our electric airborne surveys may be brie fly described as follows: A loop of many turns of insulated copper cable is fastened around the fuselage of the 'plane and connected to a generator supplying a few ampere alternating current, usually of a frequency less than 1,000 cycles per second. Just as the current in the primary coil of a common transformer will induce current in the secondary coil when shorted, the alternating magnetic field from this primary current now induces alternating current in electric conductors that happen to be located in the vicinity of the path over which the 'plane is flown. This induced secondary current in each conductive section of the ground causes, in turn, an alternating magnetic field, secondary field, which disturbs or dampens the normal alternating magnetic field from the primary loop flown by the 'plane. These secondary fields are then picked up and recorded by the help of detecting solenoids, amplifiers, and recorders carried in the 'plane. By closer study of such a secondary field it is possible to localize the secondary current causing it and, thereby, the conducting body that contains the secondary current. In the 'plane are continuously recorded, besides the amplitude or intensity of the field, also the phase, which is a measure of how much the recorded secondary field is out of step with the primary field.

Jan 1, 1950

By J. A. L. Henderson

THE potential oil-and gas-bearing area with "which this paper deals is the large undefined Carboniferous basin, roughly triangular in shape, occupying about 10,000 square miles of southern and eastern New Brunswick. Its base, about 135 miles long, lies on the gulf of St. Lawrence and embraces the whole eastern coast-line of the Province, while its apex lies in the south-west corner of the Province, near the International boundary (see map, Figure 1). The Carboniferous basin may be divided roughly into two areas-the Northern basin and the Southern basin-by a structural feature represented by a ridge of low hills running north-easterly from the Saint John river, near Saint John, on the southwest, to Indian mountain, about eight miles north of Moncton, in the northeast. Within the Northern basin, all evidence regarding the presence or attitude of the older Mississippian Albert Shale series, the only oil-bearing rocks known in New Brunswick, is for the greater part obscured by a thick and practically horizontal blanket of Pennsylvanian strata and, although evidences of oil and gas have been reported, none has been positively identified. Five parallellines of gentle folding, running to the northeast, occur in the Pennsylvanian rocks, within a distance of 100 miles from north to south. This folding is reflected in the courses of the rivers, which lie within the synclines. The relationship of the folding in the younger rocks to structures in the uncomfortably underlying older rocks is unknown, but should now be possible of clarification by means of a geophysical survey accompanied by drilling. Independent geological examinations have yielded no evidence of value in this respect, nor have five exploratory boreholes drilled by per-cussion tools to a maximum depth of 3,645 feet been of assistance, as only one inconclusive hole completely traversed the beds which normally overlie the Albert shales.

Jan 1, 1940

By Qian Liu

Mining in highly stressed ground conditions has been an increasing challenge at the Brunswick Mine. Two large regional pillars were established on the 1000 m Level to support the ground for safe extraction of the surrounding ore. The South Regional Pillar contains about 5 million tonnes of ore and the North Regional Pillar has about 3 million tonnes of ore. In the fall of 2000, mining activities were suspended following a series of ground movements around the South Regional Pillar along weak geological structures. After extensive geotechnical investigations, a decision was made to carry out a mass destress blast in the West Ore Zone (WOZ) to cut the principal stress across an area of 135 m along strike and 86 m high. At the end of July 2001, the WOZ mass blast was successfully initiated. Following this success the mine decided to take a similar approach to destressing the North Regional Pillar (NRP). The final mass blast was taken in early February 2003. Advanced blasting technologies, including state of the art electronic detonators and blast simulation, played an important role in achieving the successful blasts. The high precision of delay timing and long delay duration of the electronic detonators ensured accurate and reliable initiations of over 800 blastholes in the WOZ mass blast. Orica?s DMC_Blast (Distinct Motion Code) simulation code was used to study different blasting blocks for the desired timing in the initiation sequence. This paper describes the process of applying electronic detonators in complex blasts, and discusses how blast simulation results were interpreted to guide engineering design of the mass blasts.

May 1, 2003

By R. A. Hemstock

"Simple classification systems are now being used which will describe adequately the surface vegetation, the topography and the peat for any muskeg condition. Good progress is being made in determining some of the mechanical properties of muskeg and it is apparent that the science of soil mechanics will apply largely to these studies. Correlation is also indicated between shear strength as determined by the shear vane tester and vehicle performance. Several tracked vehicles are now available which perform well in muskeg and advances in this field have come rapidly in the past few years. Testing is under way on the largest of all muskeg vehicles -the thirty-five ton Musk Ox. This vehicle will fill the last gap for the oil industry and will make possible the movement of large drilling rigs at any season of the year."

Jan 1, 1960

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

Arguably the SMC Test® has become the most popular laboratory hardness test in the world with over 17,000 tests having been completed to date, covering over 650 different ore bodies. It is now routinely used in design, optimisation and orebody profiling projects. The test is unique in that from relatively small amounts of drill core it simultaneously provides parameters that are used in simulation modelling of AG/SAG and crushing circuits as well as work indices that are used in power-based equations for predicting the specific energies of AG/SAG/Crushing and HPGR circuits. The very large data base that has been accumulated has provided the opportunity to study the differences in variability from deposit to deposit. This paper describes and discusses the trends that have become apparent from the study of this data base. Recommendations for appropriate selection of sample numbers are also made which are based on these trends.

Jan 1, 2012

By E. L. Bruce

EUROPEAN Russia is mainly a great plain, the average elevation of which is only 600 feet above sea level and the maximum elevation less than 1,200 feet (Figure 1). The main divide between the Arctic ocean and the Black sea and Caspian sea is an indistinguishable topographic feature from which the Dneiper and Don rivers flow southward to the Black sea and the Volga river to the Caspian. The valleys of these rivers are but little below the general level (Figure 2). To the south, this great, rolling plain is broken by a low ridge of Precambrian gneisses and intrusive rocks. The Crimea is an upland from which the descent to the Black Sea coast is precipitous (Figure 3). The Ukrainian Soviet Socialist Republic occupies the southern part of the plain. It is the southwestern unit of the Union, bordered by Rumania and Poland on the west and by the Crimean Soviet Socialist Republic on the south.

Jan 1, 1938

By M. Kowalczyk

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of the (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting pre-concentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gemstones.

Jan 1, 2009

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By M. Timmins

Campbell Mine operates a 100 tpd gold autoclave that treats sulphide concentrates at 305 psi and 200 °C. Autoclave feed consists of fresh pretreated concentrate, an acidic oxide slurry recycle as well as other high arsenic sources. The brickwork that is used to construct the five compartments of the vessel must be inspected and repaired periodically. Shutdowns are scheduled to inspect this brickwork and at times replace entire sections of the brick walls or lining. It also provides an opportunity to repair or replace other internal features such as agitator blades or oxygen spargers. Mechanics and contractors are scheduled around the clock to perform the maintenance requirements. There are many safety considerations and precautions that must be taken in order to protect the well-being of the workers and minimize damage to sensitive pieces of equipment. Heat, arsenic and lead contamination and confined space issues are just a few of the hazards involved. The following paper will describe how these safety concerns are addressed and will serve as a guide for future autoclave shutdowns.

Jan 1, 2004

By T. A. Wedge

This paper suggests a crude correction for the impact of raw material quality on factor productivity in the Canadian mining industry. Such a correction would give a figure more dependent on the changing efficiency of the use of labour and capital, and less dependent on the effects of unquantified changes in inputs.

Jan 1, 1973

By A. R. Byers

"Porcupine Peninsular mine is at the extreme southwestern end of North peninsula in Night Hawk lake, Cody township, Ontario. It lies approximately 10 miles east of the gold-producing district of Porcupine.Gold in quartz veins was discovered on Gold -island in Night Hawk lake in 1906, the same year in which the now famous Porcupine gold camp was discovered farther west. Most of the claims now held by the Company were originally staked by Charles Auer in 1907, In 1910 when the level of the lake was exceptionally low, gold was discovered in a quartz vein near the shore and close to the present mine shaft.The mine is developed by a main shaft to a depth of 440 feet, with levels at 80, 180, 300, and 425 feet vertical depth and by a winze to 630 feet. A mill of 200 tons daily capacity was built during 1923, Production commenced on January 4, 1924, and continued without interruption to May 31; 1926, when operations were suspended due to a decrease in the grade of ore. Total production amounted to 27,416 ounces of gold from 99,708 tons of ore, an average grade of 0.275 oz. a ton. Diamond drilling and re-sampling of the mine during 1934 and 1935 indicated approximately 1,480,000 tons, having an average grade of 0.123 oz. gold a ton, above the 625-foot level."

Jan 1, 1954

By Jochen Petersen

This paper gives an overview of the various strands of postgraduate and undergraduate training offered in the Department of Chemical Engineering at UCT. Since 2003 the Department is offering a formal postgraduate MSc programme in hydrometallurgical engineering aimed especially at graduate work-based engineers, with 5 weeks of intensive course work plus a research dissertation on a work-related project. This programme has now run 5 times over the years and produced some 20 degrees. The paper reflects on the experiences with running the course, especially the difficulties experienced with supervising industry-based external students. Furthermore, through the Department a graduate training program is offered for all junior metallurgists at a major South African minerals company. This 2-year program, which is currently on its 12th cohort, offers 1 or 2 week intensive blocks of course work alternating with longer stints where the candidates are based at various operations. Although primarily focussed on minerals processing, it has a significant element of hydrometallurgy in it and in recent years an advanced hydrometallurgy stream has been introduced. The paper reflects on the development of the program over the years, the benefits it has provided to the company as well as some of the challenges that remain. Finally the paper gives an overview of hydrometallurgy related undergraduate and research-only postgraduate MSc and PhD projects at the university. Some emphasis is placed on the recently launched South African Minerals and Metals Research Initiative (SAMMRI), a joint government-industry programme to support university-based research in the area of applied metallurgy.

Jan 1, 2014

By P. S. Arthur, G. R. F. Alvear

Development of a new smelting process is risky. Many novel processes in the metals industry failed to fulfil the initial expectations of their inventors. Large sums of capital have been invested in technologies that either didn't provide a satisfactory return on investment, or didn't perform at all, and had to be replaced. One of the keys to success in process development is incremental scale up of the technology, with potential problems being identified and rectified as early as possible. In this way the cost of any rectification that is required can be minimized. The ISASMELTTM process was developed to maturity by Mount Isa Mines through the 1980's and 1990's using incremental scale up. Commercialization only occurred once the process had been proven on laboratory, pilot and demonstration scale over many years. As a result ISASMELTTM technology now operates successfully at numerous plants around the world. The methodical approach to development of the technology has allowed owners to modernise their existing operations or create new businesses with significantly reduced technical risk.

Jan 1, 2011

By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012