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"ChairmanThis part of the discussion is intended as an exchange of information between those who have installed rubber liners in their mills and a means of others to get information that may help them decide if rubber liners would be applicable to their mills.To start the discussion and to relate it to the previous section of this symposium Mine Equipment Co. Ltd. have supplied some graphs that will give some idea of the noise suppression that may be expected from the u.se of rubber liners instead of steel. The figures used in preparing the graphs came from installations of rubber liners in Sweden.L. Strah - Mine Equipment Co.The graph, Figure 1, shows on the bottom the octave band range. The noise level generated by the steel liners is represented by the dotted line and lies within the shaded area where it is considered that hearing damage may result. The solid line represents the noise level generated by rubber liners in the same mill and you will see it is below the shaded area. Although it is not marked on the graph I think the decibel range is from 7 5 to 115. The next one, Figure 2 which shows the relative noise levels generated by steel balls and pebbles with both steel and rubber liners shows the decibel range."

Jan 1, 1968

By J. S. Phipps, D. R. Skuse

"Aqueous slurries of fine particle size calcium carbonate are used in a diverse range of end-use products. In many cases, the end use performance is governed by the fineness of the particle size distribution. In turn, the maximum fineness of the particle size distribution is primarily determined by the efficiency of the dispersants used during the production process. Here we report the sodium polyacrylate mediated dispersion of calcite and kaolin. Firstly, we report a colloid chemical description of the dispersant behaviour and attribute the stabilisation to both steric and electrostatic mechanisms. Secondly, we describe how the understanding developed in the first part of the study can be utilised to produce more effective dispersant systems which allow the preparation of, added value, higher solids and finer particle size calcium carbonate slurry products.INTRODUCTIONConcentrated aqueous dispersions of fine, particulate kaolin and calcium carbonate are used extensively in the coating of paper. Currently more than 10 million tonnes of such dispersions are used annually in North America and Europe alone, and worldwide consumption is growing at around 3% per year.Generally, paper is coated to enhance its visual appearance. Firstly, coatings improve the optical properties of the blank sheet, i.e. its brightness (or whiteness), opacity and gloss. Secondly, they improve the physical properties of the sheet that will influence the quality of the final printed image, such as surface smoothness, porosity, and ink absorption. In order to achieve these aims economically, paper coatings must be applied at high speeds and with minimal drying costs.Kaolin and calcium carbonate pigments are the major components of most paper coating formulations. Particle size distributions are chosen to maximise the optical benefits that they confer, and to allow the production of formulations that can be easily pumped, handled and coated. Coating pigments are generally produced and transported as slurries, and so it is important to obtain dispersions with the highest possible solids content, both to minimise drying costs and the quantity of water transported. This paper examines the dispersant technology that is currently used in the industry and the mechanisms by which it functions, and illustrates ways in which this technology has developed and could be further improved in the future."

Jan 1, 2003

By T. A. Grammatikopoulos, B. Vasily, A. H. Clark

"The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoeshaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York, no carbonate protolith is preserved, and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560°C, or, alternatively, 550 MPa and ca. 630°C.Several high-grade zones, averaging >40% but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 cm to 5 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates.St. Lawrence compares favourably to other known prospects and operating wollastonite deposits: having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production."

Jan 1, 2003

By S. Eckert, M. Reuter, D. Obiso, S. Kriebitzsch, M. Akashi

The present paper focuses the application of CFD techniques to investigate the Top-Submerged- Lance (TSL) gas injection in liquid metal. Previous works of the authors have shown that up- and down- scaling procedures based on the modified Froude number have some shortcomings, as this approach does not take into account the interfacial and viscous forces. Indeed, surface tension and dynamic viscosity of the smelting slags (σ = 0.4-0.5 N/m, μ = 0.2 Pa·s) are higher than the operating fluids that have been used in literature (water, paraffin oil) to study TSL injection in down-scaled furnaces. In order to get closer to real systems, the authors study the TSL injection of Argon in a liquid metal. An experimental campaign was carried out in the X-ray lab at Helmholtz-Zentrum Dresden-Rossendorf (HZDR), where the eutectic alloy GaInSn was used as liquid phase. The alloy is liquid at room temperature, and X-Ray imaging is used to picture the multiphase flow in a quasi-2D vessel. The aim of the present work is to demonstrate the applicability of CFD techniques to model multiphase flows involving liquid metals, and validate the model using the data produced at HZDR. The commercial software ANSYS Fluent® was used together with the Volume of Fluid model to directly resolve the gas-liquid interphase. Some features of the flow, such as the void fraction distribution and bubble detachment frequency are tracked with CFD and compared to the experimental data. INTRODUCTION In the last thirty years the TSL smelting technology has increasingly been used for industrial non- ferrous smelting processes and is now one of the significant pyrometallurgical processes. Developed in the early 1970’s at CSIRO, the furnace is nowadays commercialized in different market sectors, including copper and lead smelting, zinc fuming, waste treatment and slag recovery (Floyd, 2005). Despite the wide application of these reactors in the pyrometallurgical market, some aspects of the process are still not fully clarified, since in-situ measurements and optical accesses are prohibitive because of the high temperatures and aggressive conditions. Phenomena such as the bubbling regime, the slag solidification and the submerged combustion still need a deeper scientific investigation to obtain a better understanding of the process.

Jan 1, 2019

By B. R. Hart, S. S. Dimov, J. Fournier

Carbonaceous matter (c-matter) in sulphide ores can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob, gold from a cyanide leach solution. This paper describes a standardized procedure for characterization of c-matter in an ore sample providing detailed information on its composition, maturity and preg-robbing capacity. The procedure utilizes the following complementary analytical techniques in conjunction with several chemical tests and assays: SEM/EDX Raman spectroscopy and TOF-SIMS. Results of the test can be used as a predictive tool to estimate the impact the c-matter will have on the gold recovery process. A comparison between predicted preg-robbing behaviour and cyanidation test results are presented.

Jan 1, 2011

By Elizabeth Gardiner

Tailings and water management facilities are integral components of mine and mill operations. They must be managed for the long term to ensure that safe and environmentally responsible stewardship is achieved. The Mining Association of Canada (MAC) has developed and published two manuals to provide guidance to mining companies on sound practices for the safe and environmentally responsible management of tailings facilities: ???A Guide to the Management of Tailings Facilities; and ???Developing an Operation, Maintenance and Surveillance Manual for Tailings and Water Management Facilities. The Guides were designed to help companies develop and implement tailings management systems that include environmental and safety criteria, to improve the consistency of application of sound engineering and management principles to tailings and water management facilities through their full life cycle, and to demonstrate this to regulators and the public.

May 1, 2003

By M. Cai

"It is well known that Peak Particle Velocity (PPV) plays a critical role in triggering rockburst damage in burst-prone underground mines. To estimate the PPV distribution around excavations, advanced numerical modeling can be used. In wave propagation numerical modeling, velocity field is often assumed to be uniform around an excavation. However, it is observed that wave velocities near mine openings are not constant, but rather non-uniform. Wave velocity in a rock mass depends on many factors such as rock quality and confinement. In particular, confinement has a large influence on wave velocity. The confinement around an excavation is low at the wall boundary and increases gradually and reaches a constant value far away from the excavation boundary. Hence, stress redistribution due to excavation will have a profound influence on wave propagation in underground mines. A better understanding of the influence of excavation effect on wave propagation helps to interpret the field observation of rockburst damage and improve mine safety. For this purpose, a non-uniform velocity model need to be constructed and the influence excavation effect should be taken into account in numerical wave propagation modeling.In the present study, a non-linear velocity model is developed firstly by considering the influence of confinement on wave velocity. This model links wave velocity to confinement explicitly. A coupled numerical method is then developed and used to study the seismic wave pattern around excavations in underground mines. Two codes, FLAC and SPECFEM2D, are coupled in the analysis. The motivation of developing the FLAC/SPECFEM2D coupled approach is to take merit of each code, such as the stress analysis capability in FLAC and the powerful wave propagation analysis capability in SPECFEM2D. The coupling process is realized through three steps: (1) static stress redistribution around an excavation is analyzed in FLAC; (2) data for coupling analysis, such as non-uniform velocity field (based on the new developed velocity model), mesh, absorbing boundaries, etc., are generated by FISH functions in FLAC and passed to SPECFEM2D; and (3) wave propagation modeling is performed in the SPECFEM2D considering a fault-slip seismic source. Because stress redistribution around the excavation is considered, non-uniform velocity field for the SPECFEM2D model can be obtained and this is a notable feature of this study. Very large difference in the S-wave response in these two modeling approaches with uniform and non-uniform velocity fields can be seen from the modeling results.Using the FLAC/SPECFEM2D coupled modeling approach, accurate velocity models can be constructed and this in turn will help to produce accurate PPV distribution around the excavations. Accurate PPV contours can be used to identify high rockburst risk zones for improved dynamic ground support strategy."

Jan 1, 2015

By Q. Zhang

The necessary capability of the gravity transportation pipeline system for cemented coal gangue backfilling at the Suncun Coal Mine, China, is about 74.4 m3?h-1 according to mining production and working times in the mine. It is estimated that the working velocity and maximum pipe length-backfill depth ratio of the backfill system are 3.82m?s-1 and 5.4, respectively and that the probable backfill capability of the system is 110.18m3?h-1. Results of hydraulic calculations for the backfill transportation system show that the designed backfill system is reliable in flowability and sufficient for backfill capability needs.

May 1, 2007

By M. Pekguleryuz, S. A. Argyropoulos

"The recovery of additions in light metals is an important parameter influencing consistency of the finished product, which ultimately means cost. Recovery is a function of many parameters such as assimilation speed, addition density, addition practice, liquid metal processing conditions, etc. In liquid metal processing operations, it is desirable to have the maximum possible recovery at the shortest possible time.In this paper a new index will be presented, namely, the rate of recovery (RR). This index quantifies the addition recovery and introduces the time dimension in the recovery increase. As such, the RR equips the liquid metal practitioner with an accurate picture of addition assimilation in liquid metals. Results will be presented on how this index is applied to a variety of additions in liquid aluminum. IntroductionThe data on addition assimilation kinetics offer a valuable parameter describing how fast a given addition enters the metal bath. These data may be expressed as gr m-2 s-1 of additive for a set of experimental conditions which might include bath temperature and degree of bath agitation among others. However, the liquid metal processing practitioner is more interested in the recovery of additions. In other words, the point of interest is the percentage of the used addition entering the metal bath. Ideally, the addition recovery can reach the 100% level. However, in practice, the addition recovery never or rarely reaches that level. Many factors can contribute to this. Some of these factors can be slow assimilation kinetics, addition density, addition practice, turbulence of the melt, etc. In some cases, sloppy addition practices can contribute to low recoveries, or even worse, to erratic recoveries.In this paper a new parameter is introduced. This parameter relates the maximum addition recovery observed over the time needed to achieve this maximum recovery."

Jan 1, 2002

By R. Sharon, P. M. Hawley, X. Ochoa

"Development of Barrick Gold’s Pierina gold mine in north-central Peru requires construction of a waste dump for disposal of nonore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low-quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high-quality, hard, durable, blocky waste rock.A hybrid dump design concept was developed that requires in-pit segregation of highand low-quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included.This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems."

Jan 1, 2003

By Jan E. Nesset, Phillip J. Mackey

"Studies have shown that there is a correlation between commissioning and start-up time, i.e. time to reach full plant design capacity, and the degree of innovation and technical/engineering uncertainty in the project design. The paper describes the types of start-up curves for plants according to the level of technology or uncertainty in the process design. The need to properly describe and understand the commissioning and start-up time is examined using these curves and the importance on project success is highlighted. A number of case histories of recent mining and metallurgical projects are also reviewed. Finally, the paper reviews how to better assess the level of start-up uncertainty associated with a project and makes suggestions for decreasing the commissioning time due to technological risk.INTRODUCTIOThe start-up of a new mining and metallurgical facility, a much anticipated event, is a critical step in the life of such a project. Achieving a successful start-up and reaching the design capacity on-time requires careful planning, a thorough understanding of the key technological and engineering components involved and a well-trained and adequatelystaffed start-up crew. In this paper, some of the aspects related to start-up of a mining/metallurgical project will be explored, and in particular, the impact of the technology component will be examined. In order to illustrate this, a number of case histories based on recent mining and metallurgical projects will be discussed. Ways of assessing and understanding the uncertainty associated with technological issues related to start-up of a mining and metallurgical plant will also be examined.The history on mining and metallurgy is full of success stories of great mines and mills that are now considered “company makers” (well known examples of such successes include the Horne mine for Noranda which had a 1 year start-up in 1926-27, the Dome mine for Placer Dome, the Grasberg deposit for FMI in Indonesia). Less well documented are specific studies relating to plant start-ups and what constitutes a success or a failure, however there are a few notable references in the literature and these will be reviewed."

Jan 1, 2003

By Xing Jin, Dan Graffi, Glenn MacPherson, Dan Rioux

"The complexity of a modern flotation circuit makes it susceptible to disturbances such as changes in feed, ore mineralogy, equipment degradation, poor measurements and faulty instruments. Good measurements and a robust control system are critical to create and maintain a stable and optimum flotation process.This paper focuses on the development and implementation of process control applications in the flotation circuits at Xstrata Nickel’s Strathcona Mill ( referred to as the mill hereafter ) in Sudbury, Ontario. Following the path of ‘stabilize-improve-optimize’, basic controls to stabilize process variables such as flotation cell pulp level, air and reagent addition rates, cleaning-column feed and wash-water rates have been established. Factors such as best practice in pulp level and valve position measurement, feedforward control and the application of an appropriate control philosophy, have contributed to the significant reduction in process variability. For instance, standard deviation reduction of 79% for the Ni impurity in the column Cu concentrate grade was experienced and is shown. The variability reduction of the flotation circuits’ key process-variables paves the way to further improve and optimize flotation performance. A grams-per-metal unit reagent addition control scheme has been improved upon, particularly for different operating scenarios and better robustness. In addition, following significant stabilization of the primary controls and columns feedrates, Cu/Ni separation cleaning-column bias-control (cascaded to the wash-water rate) and hold-up control (cascaded to air flowrate) have been developed and tested. This strategy – from stabilization to optimization - is expected to achieve a more consistent control of final concentrate grades and improve recoveries.INTRODUCTIONFlotation is considered the most important and value-added process in the milling metallurgical plant and is still undergoing continuous evolution to treat greater tonnage and different ores (Wills, 2006). Starting over three decades ago, with the advent of on-line slurry content analysis devices, flotation automatic control has received persistent interest and a large number of applications have been reported (Thwaites, 1983, 1986 ; Mckee, 1991). Bergh and Yianatos (2011) reviewed different aspects of process control in flotation circuits and have evaluated the applicability of model predictive control to the process. Mckee (1991) analyzed the difficulty in developing lasting/robust process control applications for flotation circuits and stated that the path of stabilization-refinement-optimization would more likely lead to successful flotation circuit process control. Best practice on column process control was discussed by Bouchard, etc. where a multi-layered approach was proposed, provided that the measurement of column process variables ( i.e. bias, froth depth, hold-up, etc. ) are measured reliably (Bouchard & Thwaites, 2008). Wills (2006) stated that the best practice for flotation automatic control starts with fulfilling basic control objectives, such as stabilized flotation cell level, air flow, pH, reagent flow etc., before considering more advanced, or even optimal, control of metallurgical targets, which are more closely linked to economic performance."

Jan 1, 2013

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By Pierre Boileau

Outline ? Who are We? ? Canada?s GHG Emissions 1990 - 2000 ? Emissions from the Petroleum Sector ? Emissions from Petroleum Exports ? Emissions from Manufacturing Industries ? Emissions from Mining and Metallurgy ? Conclusions Greenhouse Gas Division Key Functions: ? National GHG Inventory Report, Emission & Removal Trends Analysis, and Indicator Fact Sheets ? Scientific and Engineering Guidance, Technical Advice, Data Quality Assurance & Quality Control and Methodological/Data Development ? International Negotiations (FCCC) & scientific/technical guidelines (IPCC & ISO) ? Expert Review Teams (ERTs) ? Outreach ? GHG Verification Centre ? Clearinghouse ? Protocol Development

Nov 1, 2002

By M. Gaumont, F. Robichaud

"Agnico Eagle Mines Limited (AEM) is a Canadian-based gold producer with operations in Canada, Finland and Mexico. In 2010, AEM produced its first gold bar in Nunavut, Canada as it started its Meadowbank operation. It is also in 2010 that AEM acquired the Meliadine property, which is located 25 Km North of Rankin Inlet, Nunavut, Canada. The Meliadine gold project is an advanced exploration and development project, comprising of workers camp, underground and open mines, a processing plant and all the services facilities and infrastructures required to sustain operation in a remote arctic environment.Pending formal board approval, production start-up is planned for Q3 2019 and the process flowsheet is based on an ore processing rate of 1.1 million dry tonnes per year (3,000 dry tonnes per day from underground mining) for the first three years, and 1.98 million dry tonnes per year (5,000 dry tonnes per day from both underground and open pit mining) for the remaining years at 92% process plant availability.To the end of 2015, more than 45 metallurgical test programs have been conducted on the Meliadine deposits. Based on the results of these programs, an optimal gold circuit was designed, comprising of crushing, grinding, gravity separation and cyanide leaching with a carbon-in-leach circuit (CIL), followed by cyanide destruction and filtration of the tails for dry stacking. The assumed gold recovery for the reserves averages 96.0% at a 7.44-g/t gold average mill feed grade."

Jan 1, 2016

By George P. Demopoulos

In a departure from the traditional domain of hydrometallurgical extraction processes we consider new R&D opportunities for innovative application of solution processing into the advanced green energy and clean technology fields. It would not be an exaggeration if we state that protection of the environment via advancement of clean technologies on the one hand, and harvesting and utilizing renewable energy in a sustainable and cost-effective way on the other hand are clearly among the top pressing global priorities. When hydrometallurgy is approached on the basis of its aqueous chemistry and reactive processing fundamentals, it can indeed provide a highly fertile ground for innovation outside the "box". In this context therefore we will present highlights from our recent research that is directed towards the development of new generation HCl recycling, environmental, and solar energy conversion/storage technologies. In all systems the research is approached via the innovative integration of aqueous process engineering and material chemistry principles. The presentation will include discussion of (i) the development of crystallization-based HCl regeneration technologies; (ii) the supersaturation-controlled production and encapsulation of scorodite that was recently commercialized; (iii) the aqueous synthesis of nano-TiO2 and its electrophoretic deposition into solar cell electrodes; and (iv) the hydrothermal synthesis of nanostructured lithium titanate and lithium iron phosphate materials to make lithium-ion batteries destined for electric cars.

Jan 1, 2014

By S. Jayasekera, A. M. T. S. Bandara, J. Kyle, E. Koenigsberger, L. Koenigsberger

The extraction of rare earth oxides from fluoroapatite rich phosphate concentrates often involves a weak acid leach of fluoroapatite and a sulphuric acid bake of the leach residue followed by water leach and precipitation to obtain an intermediate product. The main aim of this study was to determine and rationalize the solubility of rare earth metal ions in synthetic solutions representing various process liquors at the temperatures 40, 60 and 80oC. The liquors contained different acid and metal ion concentrations with respect to sulphuric acid, phosphoric acid and sulphate salts of sodium, magnesium, aluminium, potassium, calcium and iron(III). A solid of mixed rare earth carbonates was used as the source of rare earth metal ions. The solubility tests and characterization of solids using XRD were conducted at Murdoch University laboratories as part of the process development for the Arafura Resources Nolans rare earth project. The composition of initial carbonate solids and the solids and solutions formed after saturation were analysed for rare earth and other elements at TSW Analytical Laboratories in Perth using ICP-MS and ICP-OES. The precipitated solid in sodium-rich acidic sulphate solutions is the double salt NaRE(SO4)2 based on the solid assays. However, in acidic solutions free of sodium or of low concentrations of sodium the precipitated solid appears to be RE2(SO4)3.

Jan 1, 2014

By P. V. Avotins, I. Djurkovic, D. R. Nagaraj, M. Grunjic, A. Day

"As part of a major reconstruction and expansion of the Majdanpek Copper Mine, an investigation and optimization of the flotation collector regime was undertaken. The flotation response of the major minerals to various reagents and the effect of pulp chemistry was studied from both a fundamental and practical point of view. These studies led to plant trials and the eventual adoption of a modified collector suite which improved both copper and gold recoveries.INTRODUCTIONThe Majdanpek Copper Mine processes 40,000 tons per day of ore containing about 0.43% cu. In addition to copper, the ore also contains recoverable quantities of molybdenite and gold. The mine has been in operation since 1961 and is the largest in Yugoslavia. It is currently undergoing major reconstruction and expansion. The flowsheet of the Majdanpek concentrator is shown on Figure 1.The ore body is variable in composition and changes in mill feed require proper control of operating variables to achieve the optimum metallurgical results. A detailed study including grindability, flotation response, and solid-liquid separation was carried out on several samples of the ore. Flotation response and the choice of reagent chemistry were found to be very important in achieving the highest recoveries of metal values. An automatic reagent control scheme insured that optimum dosages were used in the plant.The flotation collectors used at the present time include sodium isopropyl xanthate (SIPX), AERO 3302 Promoter and AERO 5415 Promoter. The addition of AERO 5415 to the reagent suite is a recent development and was based on the favorable results obtained in the extensive laboratory testing program conducted to establish the optimum reagent combination and dosages. Subsequent plant tests confirmed that AERO 5415 provided significant improvements in copper and gold recoveries. A description of the mineralogy of the Majdanpek ore and details of laboratory and plant metallurgical data are given in this paper. The chemistry of AERO 5415 Promoter and its interaction with minerals relevant to Majdanpek ore are also discussed."

Jan 1, 1992

By Hannu J. Häkkinen

Metal clusters exhibit unique size-dependent physical and chemical properties that differ from those of bulk materials or large particles. Here we discuss recent theoretical investigations of the catalytic properties of free and MgO-supported gold clusters. The catalytic activity of gold clusters depends sensitively on the environment, charge state, and chemical composition of the catalyst. Relativistic bonding effects stabilize large planar structures for gas-phase gold clusters, and non-compact ?quasiplanar? structures are present as important isomers also for surface-supported clusters. The hybridization of the atomic 5d and 6s states is significantly enhanced by the relativistic effects, and large spatial variations in the nature of the local electronic structure make the low-coordinated gold atoms preferable adsorption sites for oxygen molecules. The adsorbed oxygen molecules are activated to superoxo- and peroxo-states via charge-transfer from gold, and Eley-Rideal and Langmuir-Hinshelwood reactions with CO proceed via low-barrier formation of intermediates, which do not require O-O dissociation as precursors. This facilitates the low-temperature (below 300 K) activity of gold nanocatalysts in CO oxidation. Other gold nanostructures, such as mono-atomic gold nanowires, may also become important prototype systems in chemical sensing and nanocatalysis; here we show that they are active promoters of hydrogen dissociation.

Oct 1, 2003

By David Evans, David Barnes, Robert Raponi

"The Williams Mine processes, on average, 6,450 t/d of gold bearing ore using two parallel grinding circuits, leaching and C.1.P., carbon stripping, electrowinning and refining. At present, each grinding circuit consists of a SAG mill in closed circuit with a spiral classifier and a ball mill in closed circuit with two stages of cyclones.Since grinding has always constituted the largest portion of milling costs, the Williams Mine has been proactive in trying to reduce such costs through innovative changes. One project under consideration is the replacement of one spiral classifier by a vibrating screen.This paper discusses the testwork performed to evaluate the replacement of one spiral classifier by a vibrating screen, and the preliminary engineering performed to date.IntroductionThe Williams Mine, located in northwestern Ontario, approximately 40 kilometres east of Marathon, is part of the Hernia gold camp. The mine is operated by the Williams Operating Corporation and is owned by the Teck Corporation and Homestake Canada Incorporated. Operation of the mine started in October 1985 at a rate of 3,000 t/d. After a mill expansion in August 1988, throughput increased to 6,000 t/d. Production has increased steadily since the mill expansion and in 1995, an average of 6,450 t/d of ore was processed at a recovery of 95.1 %."

Jan 1, 1997