Search Documents

By R. J. MacLeod

"INTRODUCTIONThe removal of water or liquid from slurries and solutions is a procedure generally present in many process industries. This has prompted the development of many mechanical and thermal devices with which, I have no doubt you are al1 familiar.In the mining industry, beneficiation of ores necessitates ' the removal of water or other 1iquid from the concentrate material. The most common method of accomplishing this is by means of thickeners, vacuum filters and rotary dryers, generally all three and in that order;The use of spray drying techniques to obtain the same end has many advantages and these will be outlined here.THE PRINCIPLE OF SPRAY DRYINGA Spray Dryer consists of a cyclone shaped chamber where hot air and atomized concentrate are introduced in the upper section. (Sec figure No. 1). Efficient mixing of these two streams produce dry concentrate and moist spent air, both of which are removed from the base of the chamber.Thermal dewatering involves the product ion of heat and spray drying has no special requirements in this area. Generally a direct fired air heater is used and the products of combustion whether they stem from the use of gas, oil or coal fuel go into the spray dryer along with quench or dilution air which is used to reduce the combustion gases to the desired temperature. This generally lies in the range of 1,000 to 1,600° F. In spite of these relatively high inlet temperatures, the spray drying process eliminates the need for refractory lining or indeed any special heat resistant metals except on the air inlet ducting. Waste heat may also be used even if a significant amount of contamination is present."

Jan 1, 1972

By L. D. Eccleston

Any man-made structure will eventually decay, but we are basically concerned with the prevention of corrosion within a fairly limited time span. How corrosion can be minimized by design, the removal of oxides and a careful choice of paint systems is discussed, and mention is made of the electrical nature of most anticorrosive systems. Also discussed are the characteristics of certain paint binders and how mechanical properties will differ for various environments. Corrosion of a substrate by acidic breakdown products of some paints is mentioned in conjunction with a discussion on convenience versus ultimate performance. A brief mention is made of the three main components of a paint system, and the principal types of paint are placed in broad categories, with the main strength and weaknesses of each type listed.

Jan 1, 1979

By Claude A. Jr. Seger

Introduction This paper presents in detailed form the results of settling tests that were published in a few preliminary notes in the April 1949 issue of the Bulletin (p. 166). Carborel is the trade name for sodium carboxymethyl-cellulose and aluminium carboxymethyl-cellulose produced by the reaction of monochloroacetic acid on the alkali cellulose to form an ether. The water-soluble sodium carboxymethyl-cellulose has been known in Europe for several years as sodium cellulose glycolate and has been marketed under several trade names. These cellulose ethers, however, are relatively new in North America, where the name carboxymethyl-cellulose is often abbreviated to C.M.C., or they are referred to as cellulose gum. The particular grade of Carboxel used in the settling tests in the mill of Chesterville Mines, Limited, is the high-viscosity sodium carboxymethyl- cellulose known as Carboxel H.V. It is a white, fluffy powder and is hygroscopic, although not deliquescent. Carboxel solutions in water are colourless, odourless, and resistant to beat and light. They are stable to alkalies, but are precipitated by acids when the pH is reduced below 4.0, and also by solutions of soluble lead, iron, copper, aluminium, and chromium salts. Solutions of Carboxel exhibit the properties of hydrophilic colloids.

Jan 1, 1949

By C. R. Whittemore

PROGRESSIVE industrial organizations have recognized the importance of maintaining an adequate reference library of volumes covering all phases of their particular branch of industry, but it has been the experience of the writer that few engineers know how to use to the best advantage this store of extremely -valuable information which has been accumulated for their service. Nor does the average engineer appreciate the fact that it is only through the current technical literature that he can keep abreast of the rapidly developing fields of engineering. The present-day ramifications of the engineering field are of such wide scope that the human mind is not capable of storing away more than a small fraction of the information available on any particular topie; yet, from time ? to time, such information would prove invaluable. An engineer can know intimately only a small part of his own branch of engineering; but he cannot afford to neglect to take the fullest possible advantage of all that is already known in his own particular field. Technical information may be obtained by one or more of the following methods: (1) by enquiring of the individual who knows; (2) by performing the experimental investigations necessary to ascertain the facts; (3) by consulting the technical literature, where a record may be found of the work of others. This last method is the one we wish to examine. Our main consideration is the question of how to use the library, but first it is necessary to give some attention to the kind of enquiries one takes to the library, and to the nature of the sources of information available.

Jan 1, 1938

By J. W. Sanger

The establishment of a central steam-heating system in Winnipeg and its inauguration in October, 1924, has attracted a considerable amount of attention. Not only does it excite the curiosity of the engineer, but it has stirred financial and civic bodies throughout Canada to such a degree that there is now a much keener general interest in this particular type of public utility than has been shown heretofore. This does not mean that we may expect a mushroom growth of central-heating systems in all our larger Canadian cities in the near future, but it does mean that the pioneer work which Winnipeg is now doing will undoubtedly be used to guide others in their judgment as to the feasibility of similar projects elsewhere. The success of the municipal hydro-electric system in Winnipeg, and the low rates for electricity resulting therefrom, was without a doubt the most important factor influencing the citizens of Winnipeg to venture into this new field. The events which led up to the central steam-heating proposal in Winnipeg are interesting.

Jan 1, 1926

By J. Hansen

"ABSTRACTThe paper addresses the application of automated monitoring, control, and navigation to improve dragline performance. SummaryImproving dragline performance in the Canadian coal mines is critical to the continued success of the industry. Draglines represent a large capital investment and coal prices are low by historic standards. This paper argues that the introduction of monitoring, control, and navigation on draglines offers an opportunity to significantly reduce a dragline’s operating cost per cubic metre moved. To place the importance of this in perspective, a North Dakota mine calculates that every 1% increase in dragline productivity means a savings to the mine of US$340,000 per year. MonitorsAutomated dragline monitoring is a well established technology with commercial products available since the early 1980s. The three main reasons for placing monitors on draglines are (Walker, 1993):1. productivity increases: reduce variations between different operators’ performance across different shifts;2. quality increases: increase the percentage of ore and waste loads that go to the correct destination; and3. special projects (engineering projects): justify installing static field exciters and regulator upgrades; implement power management; aid operator training; study high performance buckets, rigging changes, and various excavation sequences.Mines as diverse as Kennecott’s Cordero- Rojo Complex in the United States and Natal Coal Corp.’s Optimum Mine in South Africa report dragline productivity increases of 10% to 20% in the region attributed to the implementation of dragline monitoring."

Jan 1, 2000

By J. W. Craig

THERE are, broadly speaking, three classes of refractories: acid, basic, and neutral. Fireclay, diaspore, silica, and the sillimanite group of minerals are included in the acid class, which for the most part are not very resistant to basic slags. The neutra! class includes chrome, graphite, and silicon carbide, while most important in the basic class are magnesite and dolomite. Although chrome is a neutral refractory, it has no sharp distinction from magnesitic refractoriness. The two are mineralogically (1) and chemically related, and there is available on the market a complete range of brick from straight chrome to straight magnesite. In many indus trial applications, one. type may be replaced by another. The present paper is confined entirely to such refractories. The following types of basic and neutra! brick, each sold under sorne special trade name, are available for use in Canada: (1) Burned chrome from crude ores (2) Burned chrome from treated ores (3) Chemically bonded (unburned) chrome-magnesite ( 4) Burned chrome-magnesite (5) Chemically bonded ( unburned) magnesite-chrome (6) Chemically bonded (unburned) high-iron magnesite (7) Burned high-iron magnesite (Regular) (8) Burned low-iron magnesite (9) Burned olivine-magnesite (10) Burned magnesitic dolomite-chrome (Magnecon) (11) Chemically bonded magnesitic dolomite-chrome (Magmecom) (12) Dolomitic brick

Jan 1, 1936

By J. Oliver, B. Wilson, 10

"Red Dog is one of the world’s largest zinc producing mines and a significant producer of lead and silver. While some of the operational challenges relate to the mine’s location in a remote part of Alaska, there are also challenges in the mineral separation process. Recent processing upgrades have included the installation of two M5000 IsaMills to improve the zinc regrind circuit and of one Jameson Cell to improve the pre-flotation circuit. Relatively fine grinding is required to achieve efficient mineral separation at Red Dog, but while fine grinding aids in the production of high grade concentrates, it also creates challenges in the efficient recovery of fine minerals. Over half of the lead lost to the lead circuit tailings, as well as almost half of the zinc lost to the final tailings, is in the finer size fractions (<10 µm). The high pulp density experienced in the pre-flotation and lead rougher circuits also causes significant entrainment loss of lead and zinc to the pre-flotation concentrate and of zinc to the lead concentrate. To help improve fine mineral recovery, Red Dog has recently plant tested and installed magnetic conditioning technology in the flotation circuits. The equipment aggregates fine paramagnetic sulphides and selectively increases their flotation recovery. This paper outlines the testing and positive results at Red Dog.INTRODUCTIONRed Dog is the largest zinc mine in North America and represents approximately 29% of North American zinc concentrate production. The mine is located in northwest Alaska, approximately 100 miles north of the Arctic Circle and 50 miles inland from the Chukchi Sea. The remote location makes the mine accessible only by air or seasonally by ocean-going barges. Red Dog is a partnership between NANA Regional Corporation Inc, the land owner and Teck Alaska Incorporated, the operator of the mine. Red Dog Ore and Mineralogy The Red Dog deposit is a rich sedimentary exhalative (sedex) zinc-lead-silver deposit. The main minerals present in order of abundance are: quartz, sphalerite, pyrite, barite and galena. Production began in 1989 with mining of the Main deposit. Between 1989 and 2012, approximately 55.6 million tonnes of ore with an average grade of 20.5% Zn, 5.6% Pb, and 97 g/t Ag was mined from the Main deposit. Subsequent to the development of the Main pit reserve, two additional open pit deposits were discovered: Aqqaluk and Qanaiyaq. The first blast in Aqqaluk occurred on June 4, 2010. As of December 31, 2014, the Aqqaluk deposit reserve is an estimated 45.7 million tonnes of ore with an average grade of 15.1% Zn, 3.9% Pb and 71 g/t Ag."

Jan 1, 2016

By Craig Naudé

"An enhanced gravity concentrator was installed in conjunction with an Intensive Leach Reactor at the Sadiola plant in Mali last year and commissioned in Dec 2007.There has been much debate over the years as to the effect of gravity concentration on overall plant performance. The late Dr Laplante suggested that for every 10% of gold recovered by gravity, there was a corresponding 0.1% to 1% additional overall plant recovery. The results at Sadiola are consistent with this hypothesis with an overall 4% gain in plant recovery.With total gold recovery of 12% in the gravity section, grades are increased from 3.54g/t in the gravity feed to an average of 2 600g/t in the concentrator feed to the in-line reactor. The recovery of gold in the in-line reactor is in excess of 98.5%.This paper discusses the background to the project, the laboratory testwork prior to the equipment selection, the operational results of the system, as well as the benefits of the future application of high mass yield centrifugal concentrators in base metals, sulphides and industrial minerals. Bench scale, pilot scale and plant practice examples are also presented.INTRODUCTIONBesides picking nuggets off the ground or out of riverbeds, gravity concentration is arguably one of the oldest methods of recovering gold. In circa 6000BC people discovered that gold can be found behind the rocks and in depressions of creek beds. By placing rocks in a stretch of channel with the proper slope the first sluice is built, probably around 4,000 BC, and this method is still practiced today."

Jan 1, 2009

By E. Watkins, J. C. LeRoy, A. Vivyurka

"TAILINGS REVEGETATIONWelcome to the Revegetation Session. My instructions are to introduce the Speakers and to provide a general introduction.I do the latter with humility not only because of a lack of personal experience or because tailings revegation is not well established technology, but because any general statement on a country or industry as diverse as the Canadian Mining Industry is bound to be wrong somewhere.Laying aside normal standards of accuracy I proceed as follows:In considering the question of tailings revegetation, one asks two basic questions:1. What ought to be done?2. What can be done?The first question can be broken down into three kinds of criteria or objectives:a) Legislativeb) Technicalc) AestheticThe first I leave to the politicians and the last I will avoid. Aesthetics is the philosphy of taste. It is concerned with the appreciation of things rather than what they really are. It is much easier to get into an argument on aesthetics than to get out of it feeling you have said something of consequence.Technical criteria can be divided into the following sub-objectives: 1. To isolate the tailings basin so surrounding land is not degraded. The first step here is stabilization of the surface to prevent wind and water erosion."

Jan 1, 1975

By G. Belzil, F. Robichaud, M. Fullam

"The Goldex mining and milling complex is operated by Agnico-Eagle Mines Ltd. and is located in the Abitibi greenstone belt of Northwest Quebec, Canada. The mill operates presently at a throughput of 8,250 tpd with gold grade varying between 1.8 and 2.2 g/t. The ore is very high in gravity recoverable gold (GRG) at about 92% and as such a significant emphasis was placed on the gravity circuit. Commercial production started in 2008. Average gold recovery is 93.5% with about 68% of gold recovery coming from the gravity circuit. Over the course of the first several years of production, several gravity audits were carried out. In 2009, a complete gravity audit was completed, including ore, classification, Knelson Concentrators, and the gold room. In 2011, an audit was undertaken of the flotation circuit to determine the efficiency by which GRG is floated. Large samples of flotation feed and tails were collected and process for GRG content. This allowed a link between gravity and overall recovery to be made. This paper presents results of the audits and the development of a model linking gravity and overall gold"

Jan 1, 2012

By M. Peshko, J. C. Gingerich, L. W. Matthews

"Noranda has successfully developed and implemented two leading-edge mineral exploration technologies — hyperspectral remote sensing and 3-D seismic surveying. Airborne hyperspectral imaging provides detailed geological and mineralogical mapping capability at both a regional and project scale that facilitates improved selection of prospective terrain and an accelerated exploration cycle. Noranda, in partnership with Falconbridge, has licensed the exclusive use of the Earth Search Sciences Inc. (ESSI) Probe-1 hyperspectral scanners (128- channel, 0.43 µm to 2.5 µm spectral range) that are capable of mapping in excess of 3500 km2 per day at 10 m pixel resolution. The technology has been successfully deployed on four continents over a broad range of terrain from desert to boreal forest and the high Arctic.To augment the company’s deep search initiatives, Noranda has successfully modified and implemented existing 3-D seismic technology to help targeting massive sulphides located at depths ranging from 500 m to 2000 m. In the fall of 1998 and early 1999, Noranda completed an 18 km2, 3-D seismic program in eastern Canada by successfully drill testing acoustic impedance anomalies locating massive sulphides at depths in excess of 1100 m."

Jan 1, 2002

By P. E. Weidmark

"CANMET InformationPART 1-Published PapersAsmis, H. W., ""The dynamic response of caverns in discontinuous rock""; Proc 22nd U.S. Symposium on Rock Mechanics, Cambridge, Mass, June 1981, 272-277; 1981.Austin , M.W., Bray, J.W. and Crawford, A.M., ""A comparison of two indirect boundary element formulations incorporating planes of weakness"" ; Technical Note; Int J Rock Mech Min Sci Geomech Abstr; 19:339-344; 1982.Barrett, J. R., ""Applying geotechnical theory to underground metalliferous mining""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 210-222; 1983.Barron, K., Wright, P.L. and Smales, T., ""Guideline s for the design of coal pillars in the No .4 seam at Mclntyre Mines Ltd ., Grande Cache, Alberta""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of A IMMPE; 559-578; 1983.Bauer, A., ""Wall control blasting in open pit mines""; Mining Engng; 34:155-158; 1982.Bieniawski, Z.T., "" Improved design o f room-and-pillar coal mines for U.S. conditions""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 19-51; 1982.Blackwell, G.H. and Calder, P.N., ""Practical aspects of wall stability at Brenda Mines Ltd., Peachland, BC""; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-A1ME; 3:573-608; 1982.Blake, W., ""Microseismic monitoring for underground stability "" ; Proc 1st Intnl Cont on Stability in Underground Mining; Vancouver , BC, August 1982; SME of AIMMPE; 272-294; 1983.Brawner, C.O., ""Stabilization of rock slopes"" ; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-AIME; 3:289-310; 1982.Bridges, M.C., ""Review of open stope mining in Australia""; Proc 1st lntnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 813-828: 1983."

Jan 1, 1983

By B. G. Cousins, L. Racine, R. S. MacPhail

"FLEX 31 is a chemically enhanced sodium isopropyl xanthate that has shown improved collection properties over SIPX for copper-bearing and copper-activated minerals. Characteristics such as improvement of recoveries with lower dosages and high pyrite and pyrrhotite rejection capabilities have all been exhibited by FLEX 31.The most improved results have been seen insphalerite flotation. Plant trial work carried out in the zinc circuit at the Louvicourt Concentratorin northern Quebec has produced data showing superior grade and recoveries from rougher concentrates that previously had not been attain-able with other reagents effectively. The improvement over SIPX adds up to an almost$1,000,000 annual improvement on the mine’s bottom line at present zinc prices.IntroductionSodium Isopropyl Xanthate (SIPX) is one of the most popular flotation chemicals on the market today. Somewhat more specific than amyl xanthates, SIPX is used in a variety of ores like copper/zinc, lead/zinc, arsenopyrite/pyrite, and many others (Melis et al., 1991). An investigation carried out by Tennants Research Technology Applications (TRTA), a division of Charles Tennant & Co. (Canada) Ltd., produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries of copper and copper activated minerals. The new product has been named FLEX 31. Currently, FLEX 31 is manufactured at the Prospec Chemicals, another division of Charles Tennant & Co. (Canada) Ltd.A large amount of laboratory testing pro-grams have been carried out with FLEX 31 todate (MacPhail and Cousins, 1995; Cousins and MacPhail, 1996). One of the minerals that has a defnite affinity to improved fotation is sphalerite (ZnS). Once activated with copper sulphate, sphalerite has produced some of the most spectacular test work when FLEX 31 is compared directly to SIPX. Plant trials of FLEX31 at Aur Louvicourt Inc. carried out in 1995show that FLEX 31 is far superior to SIPX for activated sphalerite flotation."

Jan 1, 1997

By Yongsheng Song, Yong Chen, Wenjuan Li

"Detailed characterization and improved recovery of a micro-fine, low-grade refractory gold ore from a beneficiation plant in Yunnan Province, China, was investigated. Different analytical techniques, such as videlicet size analysis, scanning electron microscopy, and mineral analysis by a Mineral Liberation Analyser, were used for mineralogical characterization of the ore. This paper describes an experimental study on the effect of the grinding fineness and the use of various flotation reagent regimes involving collectors, depressors, and activators on the flotation behaviour of micro-fine auriferous pyrite. Two-stage flotation resulted in high gold grade (32.71 g/t) and gold recovery (80.02%) of the bulk gold concentrate. This process opens the possibilities of maximizing Au recoveries in a micro-fine low-grade refractory gold ore where low recoveries are common.INTRODUCTIONWith the rapid development of the gold industry, refractory gold ores are becoming increasingly important resources for gold production (O’Connor & Dunne, 1994; Agorhom, Skinner, & Zanin, 2012). Among these refractory gold ores, sulfur and micro-grained native gold ores represent a significant challenge, since they are not amenable to gold recovery by direct cyanidation. The gold contained in this type of ore is very finely disseminated and encapsulated in sulfides, which makes it inaccessible to the cyanide solution during direct cyanidation (Bulatovic, 1997; Allan & Woodcock, 2001). Autoclave pressure oxidation (AC POX) of the sulfide ore and subsequent cyanidation is a common technology used to recover the gold in such types of ore. Flotation is often used as a pre-treatment method to refractory gold ore (Monte Lins, & Oliveira, 1997).As the gold-carrier minerals are usually finely disseminated (sometimes under 10 µm) and intimately associated with gangue minerals, a fine grind is necessary to get a high degree of liberation. At the same time, the fine grind usually causes the production of significant quantities of slimes, which comprise easy-to-float gangue minerals such as mica, dolomite, and calcite. These mineral phases are naturally hydrophobic and float readily, competing with the value minerals in the froth phase and resulting in lower concentrate grades."

Jan 1, 2016

By Pavel Vasak

The Laurentian University Virtual Reality Laboratory (VRL) has provided a unique platform for the development and testing of novel seismic and microseismic data processing and visualization technology. In collaboration with Vale?s Creighton Mine, the technology was implemented at the mine site and consists of a VRL system and site calibrated Seismic Excavation Hazard Map (SEHM) software. The SEHM was developed as a practical solution for the mine operator to identify areas of elevated, active rock mass damage processes caused by recent mining activity. This paper is a pictorial representation of the 3D stereoscopic demonstration of the Creighton Mine seismic data distribution and interpreted SEHM for the first quarter of 2009. A live demonstration is scheduled at the Laurentian University VRL as one of the conference field trips. The demonstration highlights the technology transfer of research concepts into a near-real-time excavation hazard system that utilizes the key aspects of virtual reality technology; the ability to integrate large datasets (geology, mine excavation, (seismic) monitoring data, production scheduling, stress model, etc.); the ability to manipulate and visualize large datasets in both space and in time (mining sequence); and the ability to review the datasets by a group of experts in an immersive (3D stereoscopic), collaborative environment to better understand the processes and context of the mining-induced seismicity and evaluate potential risks to the mining operation.

Oct 1, 2010

By M. Saghaeian, R. Hejazi, Sheikhzadeh. V., A. Abazarpoor

"The morphology of iron ore concentrate particles is known to influence several properties of iron ore pellets, including drop number, compression strength, and reduction properties. This study aimed to determine why grinding methods and particle morphology influence green pellet properties. Particle morphology can be directly related to the grinding method: ball mill (BM) or high pressure grinding roll (HPGR). In this research, two iron ore concentrates, namely Gol-e-gohar and Ardakan, were ground by a BM and HPGR to produce a suitable Blaine value for pelletizing (nearly 1,900 cm2/g). Morphological features of particles were subsequently investigated by sieving and cyclone sizing for particle size distribution, the Brunauer-Emmett-Teller (BET) and Blaine methods for specific surface area (SSA) and scanning electron microscopy (SEM) for the evaluation of shape descriptors. It was concluded that HPGR resulted in generating a greater proportion of fine particles compared to ball milling. The BET results showed that the SSA of HPGR pellet feed was higher than that from the BM due to a greater proportion of cracks, indents and bulges and the creation of new fracture surfaces. SEM images processed by ImageJ software indicated that particles ground by the BM tended to be more rounded and less elongated than HPGR particles because of the breakage model of each method. To show the effect of morphology on the green pellet quality, green pelletizing was performed in a pilot pelletizing disc. The HPGR pellet feed had a higher drop number in comparison to the BM pellet feed, due to the angular and rough shape of the particles.INTRODUCTIONThe demand for fine or ultra-fine particles as feed material for ceramics, composite materials, and mineral processing is on the rise (Kotake, Kuboki, Kiya, & Kanda, 2011). The final concentrate of iron ore processing plants (filter cake) has a size range roughly between 0 and 300 µm, depending on the liberation of Fe containing particles (Meyer, 1980). In general, to produce a suitable pellet feed of appropriate quality, Blaine numbers of 1800–2000 cm2/g should be achieved (Van der meer, 2015)."

Jan 1, 2016

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By J. Oyunaa, P. Munkhbaatar, A. Sarnai

"The molybdenum mining process used at Mongolia Erdenet Company is a selective flotation of molybdenite from the copper porphyry ores in which the extraction of molybdenum comes as a byproduct of the ongoing copper production.The mineralogical composition of molybdenum concentrate is 99.4% molybdenite (MoS2), 0.09% molybdenum oxide (MoO3), 0.52% powellite (CaMoO4) and wulfenite (PbMoO4) and content 47.76– 47.92% molybdenum, 1.5–2.67% copper, 0.04% renium.From compared solvents sodium and carbonate and ammonia are like extracted molybdenum than hydrochloric acid, which contained 96.23–97.72 p.c. of its total amount. Hence to take into consideration abundance, cheap and suitable for analysis and processing the molybdenum concentrate ammonia is choosing as a basic solvent. By direct evaporation of ammonia extract solution, we obtained ammonium ortomolybdate, which contains 73.47% MoO3. INTRODUCTIONMolybdenum occurs in the earth’s crust in an abundance of about 10–14%, mainly as molybdenite, MoS2. Small quantities are also associated with other metals having similar chemical properties. Thus wulfenite (PbMoO4) is found in oxidized parts of sulfidic lead deposits in many regions of the world; powellite [Ca(Mo,W)O4] is a calcium molybdate usually formed from the modification of molybdenite in deposits containing tungsten as scheelite (CaWO4) and tungsten substitutes for molybdenum up to about 10%. Ferrimolybdite (Fe2Mo3O12·8H2O) is the product of oxidation of molybdenite in the presence of iron (III) compounds. Molybdenite is the primary source of molybdenum. Should demand for molybdenum rise so that additional sources become necessary, wulfenite, powellite, and ferrimolybdite may become commercially significant. Molybdenum ore is mined by underground and open-pit methods. A typical primary molybdenum ore body contains 0.05–0.25% Mo, and secondary ore bodies (copper porphyry ores) average 0.3–1.6% Cu and 0.01–0.05% Mo. Flotation remains the preferred and almost exclusive method of upgrading the molybdenite mineral to an industrial-grade molybdenite concentrate containing 90–95% MoS2, the balance being gangue (Habashi, 1997)."

Jan 1, 2016

By Jr. Blanchette, Claude Bazin, Paul Blatter

"Reporting of the gold production during a month implies to estimate the mass of gold that is processed by a mill, recovered as dorés, lost to the tailings and the change of gold inventory within the plant equipments. Carbon in pulp and/or carbon in leach tanks may contain gold inventory as large as 72 000 g (2 200 troy oz) of gold which needs to be estimated from measurements obtained from sampling the material contained in a tank. Sampling and analysis introduce measurement errors that could be systematic and/or random. This paper examines the effect of measurement errors on the estimation of the gold inventory and on the variation of the inventory in the carbon in leach tanks of the Agnico-Eagle Mines Limited Lapa concentrator. Results of the analysis demonstrate that the inventory is measured with ±10% reproducibility, while the variation of inventory used for mass balance is known with ±300% reproducibility.INTRODUCTIONThe preparation of a production report implies to reconcile measured data with the constraint of material balance over the considered period of production. The sampling and data reconciliation problems were recently reviewed by Morrison (2008) and Jansen (2009a; 2009b). Typically a production report is prepared to cover a period over which the mass conservation hypothesis can be considered valid. In gold processing plants, the change of inventory can seldom be neglected and plays a significant role in material balance calculations. This is particularly true for circuits using carbon adsorption, where the complete cycle of carbon is measured in days.In a 2000 t/d gold ore processing plant, the inventory can be as large as 140 000 g of gold in gravity concentrator bins, carbon in pulp tanks and in the electrolysis circuit. This is equivalent to the mass of gold that fed the circuit during 10 days of operation with 7 g/t feed assays. The change of inventory may therefore strongly impact the production figures and especially the plant recovery at the end of a week or a month. Despite the financial impact associated with gold inventory, few publications are devoted to the subject. Bruington (1991) and Morrison (2008) discussed the problem and stressed the need for the development of reliable methods to estimate the gold inventory in carbon in pulp or carbon in leach circuits."

Jan 1, 2011