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By I. L. Sills

Introduction So many minerals and mineral products are used in the glass industry that it would require an unduly long paper to deal adequately with all of them. Only those that go to make up the batch for the more common types of glass will be discussed here, and even with these only, the list is a lengthy one. It is true that for the body of the glass comparatively few materials are required-as silica sand, soda-ash, lime, and feldspar. The others are used mainly to colour or decolorize the glass, or to give it some other desired characteristic, such as high lustre, greater physical strength, or opalescence; but, although they may be present in very small quantities, they are just as in-dispensable to the glass industry as are the main constituents of the batch. Sand Sand is essentially quartz, the dioxide of silicon, Si02. Most glass contains from 71J to 75 per cent silica. Sand for use in the glass industry, or 'glass sand', is obtained both from deposits of unconsolidated material, commonly referred to as 'sand', and from solid rock-sandstone, quartz, or quartzite. For the manufacture of glass, the material must possess a high degree of purity, as noted below, so that, although sand is widespread in most parts of the world, and sandstone, quartz, and quartzite are not at all uncommon, it is only in certain places that suitable deposits are found. At the present time, most of the glass sand used in Canada is imported from France, Belgium, and the United States. The French material, from Fontainebleau, near Paris, is known the world over as a very high quality glass sand. That from Belgium is nearly as good and is lower is price.

Jan 1, 1934

By W. B. Coker

A helicopter-mounted lake-sediment and lake-water survey was carried out over Grenville rooks in the Renfrew area (parts of Renfrew and Lanark counties) during four days of October, 1975. In the course of this survey. 1150 square kilometers were covered, with 246 lake-sediment and 276 lake -water samples collected from every body of water on which the helicopter could land. Sample sites, which averaged one per 4.6 square kilometers, included lakes, ponds, beaver ponds, swamps and marshes. Lake-sediment samples were taken using a G.S.C. sampler. Waters were collected directly into polyethylene bottles. At each sample site , surface and bottom-water pH, dissolved oxygen content, conductivity and temperature were measured using a Martel. Water Quality Analyzer. The lake sediments were air dried and then ball milled to pass a minus 80-mesh sieve. Lake sediments were analyzed for U by delayed neutron activation and for Mo, Cu, Zn, Pb, Fe, Mn, Ni and Co by atomic absorption techniques. The organic content of the sediments was determined by loss on ignition at 450 °C. Lake waters were acidified with nitric acid on the day of collection. The U content of the water s was determined by fluorometry; the Cu, Zn, Pb, Fe, Mn , Ni and Co contents of the waters were determined by solvent extraction - atomic absorption techniques. A close relationship was found between bodies of granitic, syenitic and pegmatitic bedrock and elevated U levels in the lake sediments. The Hurd Lake and White Lake granitic intrusive were encompassed by an annulus of higher U activity. Field inspection revealed that the U concentrations occur within a zone which may represent a contact metamorphic aureole. Within these complexes, anomalous concentrations of U appear to be associated with Mo. Information derived from the lake-water data reinforces the geochemical distributions outlined by the lake-sediment survey . This survey was carried out in order to develop optimum sampling and analytical procedures for geochemical reconnaissance of the Grenville Province that may be carried out under the auspices of the Uranium Reconnaissance Program.

Jan 1, 1977

By N. Mejia, Z. Xiao, D. Fragomini, A. R. Laplante

"The adaptation to platinum-group minerals (PGMs) of a protocol developed to predict gold recovery by gravity is presented. The protocol is based on three different data sets: ore characterization of gravity-recoverable minerals, description of their behaviour in cyclones and ball mills, and performance of recovery units. Examples of these are given. It is shown that the gravity-recoverable PGM (GRPGM) content can be very high. A case study at the Clarabelle mill is presented. Sperrylite is the dominant platinum mineral, and its partition curve is very similar to that of gold, despite its lower density. Its grinding kinetics is significantly higher than for gold. As a result, sperrylite accumulates in finer sizes than native gold, but can still be recovered by gravity or flash flotation. Recovery projections based on gravity recoverable data are presented.BACKGROUNDReliable modeling of gold recovery by gravity or flash flotation from a grinding circuit is based on the ability to describe the properties of gold-bearing particles in the ore, their behaviour in grinding and classification units and the performance of the equipment used for recovery, be it gravity or flotation. This is shown in Figure 1."

Jan 1, 2004

By G. B. Harris, C. W. White

Cyanide has been used for the recovery of gold since the mid 1800s, but several jurisdictions have already banned its use, and environmental pressures are increasing to finding an alternative. Gold also forms chloride complexes similar to those of cyanide, but the use of chloride has never achieved widespread acceptance. This paper describes a chloride-based flowsheet, wherein the key unit process is the recovery and recycle of chloride ion. It is shown that the chloride-based flowsheet is competitive economically with the conventional cyanide-based flowsheets, and that it has a number of other advantages, particularly environmentally.

Jan 1, 2011

By N. T. Oo, L. D. Hutton

"The Banora Point Upgrade Project is a 2.5km long six-lane divided freeway in northern New South Wales, Australia. The geology at the project area comprises a volcanic succession of variably weathered basalt flows and agglomerate deposits that reach 48m in thickness and overlie Mesozoic sedimentary rocks. A site specific rock classification system was developed that characterised all the rock units based on the engineering properties governing the rock mass behaviour i.e. intact rock strength and defect characteristics (spacing, aperture, infilling, wall roughness and weathering) irrespective of the geological origin. This approach simplified the design and the on-site verification processes. Based on this classification system, rigorous quantitative statistical assessments of the available geological information including various laboratory and field testing were performed to derive the geotechnical design parameters for various rock classes. These parameters were used to complete geotechnical designs of retaining wall systems. INTRODUCTIONThe Banora Point Upgrade Project is a 2.5km long six-lane divided freeway in northern New South Wales, Australia. The key features include two interchanges, a 300m long viaduct, a large cutting through Sexton Hill with an associated 100m wide Land Bridge and retaining walls reaching 490m long and up to 22m high. This paper focuses on the derivation of representative geotechnical parameters for geotechnical design of the retaining structures supporting Sexton Hill Cutting including bored pile retaining walls and soil nail walls. The geology at the project area comprises a volcanic succession of variably weathered basalt flows and agglomerate deposits that reach 48m in thickness and overlie Mesozoic sedimentary rocks. Due to the complex geological nature of the site, an understanding of the regional and local geology, the typical behaviour of individual geological units and the implication of onsite variations from design intention are the ultimate challenges to the geotechnical engineer in order to select representative geotechnical parameters for design."

Jan 1, 2015

By R. Grau

"After commissioning and start-up of the first 500m3 TankCell® flotation cell in 2014, the over 300m3 mechanical flotation cells have earned their place in large-scale flotation operations. These 500 to 630m3 cells, designed for projects with large throughputs, are proven to provide savings in project capital and operational expenditure through savings in foot print, energy consumption, and less equipment to install and maintain. Addition to savings in different phases of a project, these cells provides operational flexibility and has shown improvements in metallurgical performance. In this paper a case study from Kevitsa TankCell® e500 installation and Buenavista del Cobre TankCell® e630 installations will be given.INTRODUCTION After development (Grönstrand and Bourke, 2008), characterization (Morales et al. 2009; Yanez et al. 2009; Grönstrand at al. 2009), validation (Elgueta et al. 2009; Coleman and Dixon, 2010), and more than 350 industrial installations of the Outotec TankCell® e300 flotation cell, the well proven energy efficient TankCell® product family introduced the TankCell® e500 forced-air flotation cell late June 2012 (Outotec.com, 2012). The introduction of the 500 m3 flotation cell followed by introduction of a 630 m3 flotation cell, TankCell® e630, in October 2014 (Outotec.com, 2014). These large flotation cells are designed for projects with high throughputs where the number of cells needed for operation with smaller equipment would become large. The benefits of this size of flotation cells comes from the lower capital expenditures due to lower equipment costs, savings in plant footprint, less installation work with less auxiliary equipment, lower energy consumption, and less units per installation resulting in less components, spare parts and maintenance.The first TankCell® e500 was commissioned and taken into operation in October 2014 at FQML Kevitsa Cu-Ni-PGE concentrator, nowadays owned by New Boliden. The first TankCell e630 was taken into operation in January 2018 at GrupoMexico’s Buenavista del Cobre Cu-Mo concentrator. The start-ups of the first TankCell® e500 and TankCell® e630 followed with test work where the hydrodynamic performances of the cells were characterized and metallurgical performance studied. The results of the TankCell® e500 test work were presented in detail by Mattsson et al (2015a; 2015b) and TankCell® e630 by Grau et al. 2018. In this paper the metallurgical improvements achieved with the large cell installations will be presented."

Jan 1, 2019

By H. D. B. Wilson

"IntroductionRECENT ADVANCES in geo-chemistry and in •our knowledge •of crystal structure provide a key which enables us to create a systematic picture of the genesis of many ore deposits. This genetic scheme may be used with confidence in assessing certain types of orebodies and may be of some aid in actual exploration, since it affords a rational explanation of the dependence of the composition •of the ore minerals on that of the rock type in which they occur with which they -are •associated. For purposes of the present paper, .the elements chosen are •chromium, vanadium, iron, and titanium. The oxides of all these metals occur in deposits of similar or related type, and it is proposed to show that, for each, the composition of the •ore mineral is related to •the composition of the enclosing :rock, and that one of the principal factors controlling the composition of the ore is the ionic size of its constituent elements.Geochemical PrinciplesThe crystals of the rock-forming silicates and of the magmatic oxide minerals are essentially ionic types. This means that they are composed •of oppositely charged ions such as Mg²+ and 0²-, which are held together by electrostatic attraction. The ions of each element are spherical, with characteristic size known as the ionic radius. Crystals are built up by the packing of these spheres in the most stable arrangement compatible with the size and the size and valence of the ions• involved.Many of the principles governing the formation of ionic crystals are •simple ,and logical."

Jan 1, 1953

By S. P. Chong, N. C. Shih, G. A. Turner

Fine powders, with the bulk of the particle diameters Jess than 10 microns, were aerated so that each particle was, on the average, separated from its neighbours by 1.3 to 2 mean diameters. In this state, measurements were made of the viscosity and settling rate of the powder, and the interfacial tension between it and a moist pellet. From the viscosity measurements, qualitative analogies are drawn between the behaviour of the aerated powder and that of a dense gas near its critical point.

Jan 1, 1970

By Z. D. Hora

The major fluorite producer in British Columbia was the Rock Candy Mine, inactive since 1942. Other deposits of economic interest include the Rexspar deposit, in which fluorite is associated with uranium and rare earth mineralization, and the Eaglet and Liard River occurrences. THE former Rock Candy fluorite mine, located 26 km north of Grand Forks, is the only major past producer of fluorite in British Columbia. The deposit was in production from 1918 to 1929 and again in 1942; total output was about 36,000 tonnes with average grade between 22 and 32 per cent CaF2. The fluorite body occupies a steeply-dipping vein structure, approximately 175 m long and up to 12 m wide, in porphyritic syenite. The chief vein-filling minerals are quartz and fluorite with local small len ses of barite. Fluorite content decreases with depth and the deposit becomes silicified. The Rexspar (or Birch Island) fluorite deposit is located 130 km north of Kamloops. The deposit is complex with rare earth elements and high uranium values, but !1uorite mineralization forms an independent zone adjacent to the uranium orebodies. Fluorite is present as fine-grained impregnations and as breccia cement in strongly schistose or brecciated alkali feld spar porphyry. Reported reserves are 1,088,000 tonnes of 22 per cent CaF2 or 450,000 tonnes of 29 per cent CaF2. 268 Another potential deposit of fluorite is Eaglet, situated on the north side of Quesnel Lake. Fluorite occurs as a stock work with scattered veins and irregular lenses up to 20 centimetres wide and as impregnations in altered Proterozoic Kaza Group feld spathic gneiss over an area of 1,500 metres by 500 metres. To date (1983) approximately $2 million have been spent on the exploration of this property and reserves of 18.8 mimon tonnes grading 11.59 per cent CaF2 have been outlined . A group of significant occurrences is known from north of Liard River Hot Springs Park , where fluorite occurs in small zones up to 17 m thick along the interface between Middle Devonian Dunedin Formation limestone and Middle Devonian to Mississippian Besa River Formation argillite. Fluorite, associated with witherite, barytocalcite and barite, is present as replacement bodies, breccia fillings and minor veins.

Jan 1, 1984

By Edward R. Rose

This paper summarizes and emphasizes the potential importance of Canadian rare-earth occurrences, and recommends that efforts to locate and evaluate rare-earth deposits should be increased. Increasing world markets, depending on intensive applied research into the numerous unique and remarkable chemical and physical properties of the rare-earth elements (REE), are developing; their properties and uses are becoming better known; methods of separation are much improved. The REE group comprises a Cerium (Light) subgroup of 7 metals and an Yttrium (Heavy) subgroup of 9 metals. REE are trace elements in many rocks and minerals, and major constituents of more than 50 rare-earth minerals, many of which are difficult to detect and identify. They occur preferentially in acidic and alkaline igneous and metamorphic rocks, including carbonatites, as well as in placer deposits, certain uranium deposits, phosphate rocks and others. The main ores now are bastnaesite (in Precambrian carbonatite), monazite and xenotime (in Recent beach sands) as well as uraninite and brannerite (in Huronian quartz-pebble conglomerate) and loperite (perovskite) and apatite (in alkaline complexes). World resources are summarized. Twenty mines in 1973 produced an estimated world total of about 31,000 tons of contained rare-earth oxides (REO), 19,341 tons of which came from one mine at Mountain Pass, California. A selected fifteen, of 315 or more Canadian occurrences, are briefly described and compared, and their relative merits indicated. Their abundance and variety suggest the possibility of finding high-grade deposits in many geological terranes in Canada.

Jan 1, 1979

By Peter Silveston, Earl Shannon

Process-oriented experiments on the use of coal as an adsorbent for certain soluble components of sewage are described. The capacity of Canadian coals for these components was less than 0.1 per cent by weight for the highest concentration at which these components could be expected to be found in domestic sewage. This is much less than values reported in the past. A pronounced selectivity between components was observed. Experiments on bacteria removal in beds of coal, regeneration of spent coal to restore adsorption capacity and COD contributions of coal are reported in the paper. The simple application of coal as an adsorbent does not seem promising.

Jan 1, 1970

By P. G. Rueffel

"Natural deposits of sodium sulphate are the result of normal geological processes. They are world-wide in occurrence and are found in depressions in arid and semi-arid regions. Primarily, the sodium sulphate deposits of the prairies are post-glacial and differ from rock salt deposits, which originated from connate water (fossil sea-water). Sodium sulphate on the Canadian prairies occurs as brine or in beds of intermittent and/or permanent crystals. Most beds are contaminated with various amounts of silt, sand and decayed organic matter. Soluble impurities such as chlorides, carbonates and bicarbonates of sodium and sulphates of magnesium and calcium are leached out from the soil of the surrounding run-off area of the deposits.In this paper, the origin of sodium sulphate, and the physical and chemical aspects related to the development of the Ingebrigt Lake deposit are dealt with. The problems of garnering raw material, and of refining and de-hydration are discussed, with emphasis on the Ingebrigt Lake plant. The utilization of the ""Total Power Concept"" in a sodium sulphate plant is described. The principal uses of sodium sulphate are also discussed."

Jan 1, 1968

By H. Zhu, Q. Jiang

The leaching kinetics of iron during the atmospheric direct leaching (ADL) of marmatite concentrate was studied under the following conditions: reaction temperature of 343-383 K, slurry pressure of 0.3-0.7 MPa, particle size of (-74 ?m, +63 ?m), (-63 ?m, +44 ?m), (100%-44 ?m). The statistical effects of reaction temperature, total pressure and particle size of concentrate on the extraction and the leaching rate of iron were analyzed. The results show that reaction temperature is a significant factor while slurry pressure and particle size are not statistically meaningful with respect to the extraction or the leaching rate. The extraction of iron fits better to the mixed-controlled shrinking core model and the apparent activation energy was calculated to be 37.66 kJ/mol. The leaching of iron is mixed controlled by the interfacial chemical reaction and diffusion across the product layer.

Jan 1, 2014

By D. A. Livingstone

Abstract Golden Manitou Mines, Limited, nine miles east of the town of Val d'Or in northwestern Quebec, are presently milling, at the rate of 1,000 tons daily, a relatively complex 3.11-phide ore and producing, in decreasing order of value, zinc, silver, gold, lead, and copper. The products are a zinc concentrate, a silver-lead-copper concentrate, and a silver-gold precipitate from cyanidation. Although several independent pre-production metallurgical investigations into the treatment of the ore were carried out, current practice is different from any of the recommended methods and, while still leaving room for improvement, is considerably more effective than earlier performance. Flow-sheet developments from the commencement of operations in 1942 are dealt with briefly, showing the reasons for making numerous changes, the shortcomings of the various schemes tried, and, finally, covering data pertinent to present-day practice. From the recovery standpoint, silver has presented the greatest difficulty. The writer's association with the Company coincided with the start of production. Characteristics of the Ore The predominant metallic minerals present in the ore, in decreasing order of their abundance, are: pyrite, sphalerite, galena and chalcopyrite, with lesser amounts of argentiferous tennantite-tetrahedrite, arsenopyrite, covellite, bornite, and chalcocite. The sphalerite is mostly light in colour, sometimes colourless, and practically free from combined iron. Some of the sphalerite is very closely associated with minor amounts of pyrite, chalcopyrite, and galena. Pyrie is abundantly disseminated as medium to fine grains; more rarely it is massive and contains occasional grains of sphalerite, galena, and chalcopyrite.

Jan 1, 1952

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By R. M. S. Häggblad

The article deals with stabilisation and regeneration of Ce02 and Ce02/Zr02 based Pt water gas shift catalysts, subject to high initial deactivation. The reaction gas species effect on the catalyst deactivation was investigated by H2-TPR. Activity measurements enabled the effect of different promoters, some added to the Ce02 based catalysts and some to the Ce02/Zr02 based Pt catalysts, to be investigated. The catalysts were also characterised by BET and CO-TPR. Deactivated catalysts activity was restored by using various regeneration methods. Of the two selected carriers the Ce02/Zr02 based Pt catalyst showed the highest resilience to deactivation. For the two different carriers, Ce02 and Ce02/Zr02, Wand Re were the best promoters when the catalyst was subject to deactivation. Experiments with Hr TPR indicate a fast initial change in the platinum oxides concentration and composition. The CO-TPR was used to make conclusions about the various regeneration effects of water and oxygen on the catalyst. Finally it is suggested that not one deactivation mechanism is possible and which mechanism that dominates is dependant on the catalyst and the reaction gas composition.

Jan 1, 2005

By Richard W. Hutchinson, Christopher Osterman

Abstract -The Selebi-Phikwe deposits are hosted by amphibolite to granulite facies gneisses of the Limpopo belt. The sulfide orebodies are generally stratiform and conformable to the foliation of the wallrock gneiss. Sulfide remobilization has occurred during metamorphism and has produced discordant sulfide veins, called piercement structures, which project into the hanging wall and foot­ wall gneisses. These piercement structures are compositionally similar to the stratiform sulfides, consisting mainly of pyrrhotite, pentlandite and chalcopyrite. However, texturally the piercement sulfides are coarse grained and inclusion-free, whereas the stratiform sulfides are fine grained and packed with tectonically produced wallrock inclusions. The piercement structure sulfides and adjacent stratabound sulfides were sampled and analyzed for major base metals and PGE's for comparative purposes. Most of the piercement structures were enriched in Cu, Ag and Au, whereas they were generally depleted in Ni, Co, Fe and PGE's. Changing elemental associations were observed from the stratabound sulfides and along the length of the piercement structures. This and the degree of depletion or enrichment of various major and minor elements in the sulfide piercement structures may reflect the relative mobilities of metals under metamorphic conditions. The similarities between sulfide piercement structures and the footwall Cu-POE veins in some Sudbury deposits are reviewed.

Jan 1, 1994

By Selwyn G. Blaylock

I.-THE HISTORY OF THE SYSTEM TO trace the history of the development of the Co-operative Committee System in The Consolidated Mining and Smelting Company of Canada, Limited, one must look backward about twenty years. In 1915 and 1916, the first years of the W ar to really affect Canadian life, there were sixteen hundred men working in the Trail plant. These men were, on the whole, a splendid body of men and pa trio tic to the core. They were almost one hundred percent organized, ninety-five percent of them be-longing to the Union of the Western Federation of Miners. Most of the tradesmen belonged to their craft unions as well. For example, there were ? local machinist, steel workers', electrician, boiler maker, bricklayer, and carpenter unions. The Company had always maintained an open-shop policy and refused to enforce membership in any union, but recognized the right of every man to belong to unions. The only exceptions have been the I.W.W. and the One Big Union. Both of these organizations have always been fought by the Company. By 1916, membership in the Western Federation being practically 100 per cent, the Company recognized this organization's authority to make agreements, and a wage and hour agreement was drawn up and signed by the Company and the local officials of the Union, and ratified and signed by the Head Office of the Union in Denver, Colorado. This agreement was for the duration of the war.

Jan 1, 1936

By S. V. Burr

"A 28-year study of cross folds leads to the conclusion that the northwest-southeast folds recognized in many areas of North America are part of a regional pattern. Detailed examination of over 650 geological maps and reports of Ontario indicates that this folding can be traced across the province. Evidence is presented that this fold pattern played an important part in determining the pattern and scale of intrusion, that its recognition in the field can aid in defining stratigraphy, folding and faulting, and that it may have played an important role in channeling hydrothermal or magmatic mineralization. IntroductionThe concept of regional cross folding in Ontario is not new. W.H. Gross (1955) discussed regional cross folds in the Archean of Northwestern Ontario, and A.M. Goodwin (1961) referred to regional cross folds in the Archean of Ontario and Quebec. However, the interpretation in this paper is new.The writer saw a cross fold for the first time, underground, at Little Long Lac Gold Mines in Geraldton, Ontario, in 1951. This recalled the ""transverse folds"" on E.R. Faribault's classical maps of Nova Scotia, published by the Geological Survey around the turn of the century; M.E. Hurst's cross fold(s) at Timmins, Ontario (Figure I); and the cross folds mapped by A.W. Jolliffe in the Yellowknife area of the Northwest Territories. All these mapped cross folds had one thing in common with the fold at Little Long Lac: A northwest-southeast axial trend. Were such cross folds of purely local extent, or might they be indicative of a widespread regional fold pattern? If so, has such folding any significance for mineral exploration or potential?By 1959, based on a study of about 1000 Canadian geological maps and reports, including 291 in Ontario, the writer reached the conclusion that cross folding trending northwest-southeast is so widespread as to constitute a pattern of folding, and that such cross folding should produce changes in plunge along pre-existing greenstone fold belts."

Jan 1, 1980

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016