Search Documents

By Frederick V. Lawrence

Broadly speaking, fluxes are substances which promote wetting and spreading or enhance the fluidity and manipulative properties of materials in joining, fusion, and smelting operations. The term most strictly applies to substances used to facilitate soldering and brazing; but in .he discussion which follows, the definition will be broadened to include materials used to promote fusion in arc welding and which aid in he smelting of metals. In each of the mentioned applications, the role of flux and its composition differs considerably; consequently n the discussion which follows, fluxes for soldering, brazing, arc welding, and smelting applications will be considered separately. Soldering and Brazing Fluxes Soldering and brazing are metallurgical joining processes in which a joint is formed using a filler metal of composition dissimilar to that of he joined pieces (base metal). The filler metal, older or braze, is always of lower melting point than the base metal. Consequently with these) recesses there is no melting of the base metal. The successful creation of the joint depends upon the wetting and spreading of the solder or braze around or throughout the joint. The obstacles to successful soldering and brazing are contaminants and tenacious oxide films on the metal surfaces. In soldering and brazing applications, fluxes act to remove and exclude oxides and other impurities from the joint. There is no fundamental difference between soldering and brazing. The distinction between them is made on the basis of temperature. Joining operations carried out at temperatures above 500°C are termed brazing. The higher temperatures used in brazing enable higher melting point filler metals to be used which generally provide stronger joints. The higher temperatures of brazing processes also require fluxes which are substantially different from those used in soldering and which will remain effective at high temperatures. Consequently the distinction between soldering and brazing can also be made on the basis of the fluxes used.

Jan 1, 1975

By F. L. Wolf, A. A. Grubb

There is a tendency on the part of practical foundrymen to accept with reluctance the results of tests on sands, binders, and such materials made in the chemical laboratory alone. They feel that such tests frequently emphasize and measure properties that are of minor importance and fail to take account of characteristics that are important in determining the value of the material in actual practice. Experience seems to indicate that the most thorough and conclusive test for any new foundry material is an actual run in the foundry alongside of a standard material of known value. Such a test, however, involves certain difficulties and necessitates certain precautions. It is not always easy to obtain a fail trial for a new material. We all have certain prejuclices, which unconsciously affect our judgment to a marked degree. A practical test frequently involves so many workmen, each of whom reacts in a different manner to the test, that the personal equation becomes very complex and the true results of the test are obscured. There are times, too, when a thorough experimental trial of a material would interfere too much with the. rush of work in a department or would hazard the quality of the product to such an extent as to make it inadvisable. Under such conditions a laboratory test is advisable before the material is sent into the foundry. These tests should be made as practical as possible and so closely related to foundry practice as to give a true index to the value of a product for the purpose desired. Core sands and molding sands are as numerous "as the sands of the sea" and valy as much in quality. Old sources of supply are continually failing and new ones must be opened, so that we must continually search for new and better grades of sand. During the past year, the Ohio Brass Co. has developed tests for sands, cores, and binders which bear a close relation to the particular use to which these materials are put in the foundry and which arc fairly indicative of their value. While the tests thus far have been confined to cores and core sands, it is expected that tests for molding sand will bc developed in the future.

Jan 1, 1921

By Joseph P. Lyden

In the Picher field, structure made openings for the circulation of the mineralizing solutions by flexing, shearing, and fracturing the sedimentary beds. This structure is used with the spatial and genetic relationship of the ore minerals, sphalerite and galena, and the gangue minerals, dolomite and jasperoid, in prospecting for ore bodies.

Jan 12, 1950

By Robert Tally

UNDERGROUND fires have been common in the mines of the United Verde Copper Co. for the past 22 years. The first fire started in the 300 Hampton stope in the fall of 1894, following a cave in that orebody. The soft and highly pyritic nature of the ores is responsible for most of these fires. Since ore characteristics, methods of mining and ventilation, have an important influence on mine fires, they will be described in this paper. Orebodies The ores are mostly chalcopyrite except on the upper levels where considerable chalcocite, black oxides and other secondary minerals occur. The orebodies are in the form of lenses and vary in size. Some are small, while others are several hundred feet in length by a hundred or more feet in width. These orebodies extend, in some cases, from the surface to the lowest levels of the mine and usually at a steep angle of inclination. There are three different classes of ores, classified in accordance with the gangue rock. The copper in all cases, except as above specified, is in the form of chalcopyrite. The largest and most important of these reserves are in a pyrite gangue. Next in order of importance are the schist ores and lastly the quartz porphyries. The pyrite, locally termed iron ores, average from 30 to 42 per cent. sulphur. The schist and quartz, porphyries vary from 3 to 25 per cent. sulphur. Mining Methods All the orebodies were worked by the overhand square-set method of mining prior to 1908; since then the cut-and-fill, shrinkage and mill-hole systems have been largely employed. But 15 per cent. of the total tonnage now extracted is from timbered stopes. Most off this is from the upper levels where the ore is soft, heavy and more or less broken to the surface. Large reserves of these ores are being conserved for more efficient methods of mining.

Jan 9, 1916

By J. E. Burke

THE origin of so-called annealing or recrystalli-zation twins in face-centered-cubic metals continues to be a matter for speculation, and in the present report an attempt is made to explain their origin and to account for at least a majority of the observations concerning their behavior. The fact that annealing twins are prominent only The speelmen was deformed 8 pet in compression and then indented over the lower left-hand corner in a Rockwell in-denter, and then annealed to cause partial recrystallization. Note intense twinning in heavily deformed part and slight twinning in less deformed part. The upper right-hand corner is unrecrystalized. Area reduced approximately 25 pot for reproduction. after recrystallization suggests that deformation may be necessary for their formation. In 1926, Mathewson1 reported the observation by Phillips that annealing twins are frequently parallel to strain markings which delineate octahedral planes in the deformed (and partially recrystallized) matrix, and suggested that strain markings are mechanical twins which grow into annealing twins during recrystallization. Later work by Burke and Barrett' has shown that strain markings are traces of planes upon which slip has occurred, and that there is no evidence for the formation of mechanical twins of microscopically resolvable width in face-centered-cubic metals. Mathewson3 has pointed out, however, that slip may produce twin faults, and later modifications of this hypothesis have assumed that twin faults rather than true mechanical twins serve as the nuclei for annealing twins. Carpenter and Tamura5 suggested, also in 1926, that annealing twins might form by accidents of growth. A close-packed layer of atoms can be added to the octahedral plane of a face-centered-cubic metal in two possible positions, the right position

Jan 1, 1951

By K. P. Gupta, P. A. Beck, N. S. Rajan

By determining the a phase boundaries in the following ternary systems: V-Fe-Si (at 1175oC), V-Co-Si (at 1175°C), V-Ni-Si (at 1175oC), Cr-Mn-Si (at 1000°C), Cr-Co-Si (at 1175°C), Cr-Ni-Si (at 1175°C), V-Fe-A1 (at 1175°C) and Cr-Co-A1 (at 1175°C), it was found that Si exerts a stabilizing effect on these a phases, while A1 tends to destabilize them. Si atoms in solid solution occupy sites D in the a structure, The co/ao ratio increases with increasing Si-, Mn- or Fe-content. The volume of the unit cell decreases with increasing Si-content. THE stabilization of certain metal silicides (the Nowotny phases) by the addition of relatively small

Jan 1, 1961

By W. H. Young, P. D. Torrey

The Eastern fields comprise a distinct geological and geographical unit, located in the northern part of the Appalachian geosynclinal prov-ince. In this area are the fields of New York, producing from rocks of Devonian, Silurian and Ordovician age; the fields of western Pennsylvania, where oil and gas occur chiefly in rocks of Mississippian and Devonian age; the fields of eastern Ohio, where oil and gas are obtained from rocks of Pennsylvanian, Mississippian and Silurian age; and the fields of West Virginia, where oil and gas are produced from rocks of Pennsylvanian, Mississippian and Devonian age. Many of these fields are of great antiquity in comparison to the age of the producing areas in a greater part of this country, and consequently in most instances it is impossible to obtain accurate historical statistics. In addition, the records of many of the more recently discovered fields are either unobtainable or are not sufficiently reliable to justify their incorporation in a review of this character. Rather than overemphasize certain fields and areas, where complete records are available, when there are many other fields of equal importance for which statistical data are not available, the authors have made a tabulation of development that does not take into consideration past operations and production. The records utilized in preparing this paper were derived largely from the scout reports of several of the larger companies, which generously made them available to the authors. These were independently tabulated by counties and townships, in order to eliminate as far as possible duplications and, excepting the Clinton fields of Ohio, where many of the smaller wells have not been individually reported, they represent the most accurate information available. Market conditions in both the oil and gas industry were far from favorable during 1932 and in consequence there was a total decline in drilling in the Eastern States, which is 22 per cent less than the number of completions in the preceding year. This decline was not constant over the entire area, as is shown in Table 1. The oil fields of both New York and western Pennsylvania were the scene of renewed drilling activity, which was largely restricted to the water-flooding operations in the Bradford and Allegany fields. Practically no new operations were started, but a certain number of new wells

Jan 1, 1933

FRIENDS of the late Charles F. Rand presented in 1930 a sum of money from which the income is available to support various phases of the work of the Institute in which Mr. Rand was so deeply interested. At present the fund amounts to $10,900. The specific terms of the deed of gift are as follows: "The fund collected to establish a memorial to the late Charles F. Rand shall be placed in the custody of the Board of Directors of the American Institute of Mining and Metallurgical Engineers, to be set up as a trust to be known as the `Charles F. Rand Foundation,' the income of which shall each year be applied to a distinct purpose to be decided upon in that year by vote of the Board of Directors. This purpose shall be such as to promote the general welfare of the Institute and to constitute a permanent memorial of the usefulness of Mr. Rand, who for many years gave unstintingly of his time and talents in its service. "It shall be within the discretion of the Board of Directors to establish a medal to be known as the Charles F. Rand Memorial Medal to be awarded at such a time and under such rules as may be determined by the Board of Directors, for Distinguished Achievement in Mining Administration." The establishment of this medal was announced at the annual meeting in February, 1932, the term "mining" being defined in its broad sense to include metallurgy and petroleum. Robert Linton is chairman of the Charles F. Rand Foundation Award Committee.

Jan 1, 1942

By John Birkinbine

THE favor with which the members of the Institute received Mr. Fernow's paper upon the use of charbon roux in the manufacture of iron has encouraged me to present this paper, in the hope of having the discussion upon the manufacture and use of the oldest and undoubtedly the best fuel for producing pig iron continued. Owing to the advances made in employing anthracite coal, bituminous coal, or coke, or mixtures of them, we are apt to forget how much of our present development is due to the pioneers in iron manufacture and the fuel which they employed in the production of pig iron. In Mr. Swank's last compilation of the iron and steel works of the United States, the furnace capacity of the country is given as 5,868,000 tons, of which 1,000,000 tons can be made in the 264 charcoal furnaces. In other words, over one-third of the furnaces now in existence use charcoal for fuel, and produce more than one-sixth of the iron made. If to this is added the 130,000 tons of blooms and billets turned out by the 122 forges and bloomaries, the importance of the charcoal industries will be appreciated.

Jan 1, 1879

By D. K. Sarin

The sub-level caving mining method has been applied in base metal mines in Canada under a wide range of ore body and wall rock conditions. This method has been used for primary, as well as secondary mining of both small and large ore bodies of varying ore values. Early experiences of almost all operations were somewhat disappointing. This paper details the initial problems encountered, the design changes made and solutions evolved. Additional experience and the development of operating skills, have helped the method gain acceptance as a viable method for the mining conditions to which it has been adopted.

Jan 1, 1981

Gentlemen.-It is pleasant to be able to report that the year just closed has been a prosperous and successful one for the Institute. As is shown by the reports of the Treasurer and the Finance Committee, the business affairs of this organization are in excellent condition. With property valued at more than three-quarters of a million dollars, and with considerable sums in various funds and endowments, it is possible to spend on each member of whatever class $22.65 each year, more than the maxi- mum amount of dues received from any one, and substantially twice the average amount, $10.94, received from all. To do this has required close management and a strict regard for our limitations. In 1926, when the Budget was made up, the estimated expenditures for the work which it was felt the Institute must do exceeded the estimated receipts by some $14,000. At the close of the year, despite a number of unexpected decreases in receipts, it had proved possible to accomplish substantially all the work laid out and close the books with the usual transfer of initiation fees to the General Reserve, and still only reduce the cash balance $2,074.54. This was made possible by the hearty and loyal cooperation of the whole staff of employees and the extremely large amount of gratuitous service rendered by the officers, the members of the Divisions and technical Committees, and the membership generally. Even so it was impossible, because of limitations of funds, to undertake many things it is highly desirable for the Institute to do, and it was necessary to refuse the publication of important papers and committee studies, because of the lack of funds. PUBLICATIONS In an analysis of the income and expenses of the Institute published in the February issue of our Journal, MINING AND METALLURGY, it was pointed out that the largest item of expenditure is, as it should -be, for publications. Printing, binding, and distributing the various technical papers sent to the members cost in 1926 more than all the money received from dues, including the portion allocated as subscription to the magazine. Within the. year, the following volumes were printed and, with the exception of the second volume of TRANSACTIONS, which was mailed in January, were distributed : TRANSACTIONS, Volume 73, 1241 pages, covering papers on non-ferrous metallurgy, milling and concentration, non-metallic minerals, iron and steel, and the Institute of Metals Division papers read at the

Jan 1, 1928

By D. Silverman, A. R. Brown

EquipmENT and methods for locating the points of entry of salt water into oil wells are described. These techniques make it possible to delineate accurately the top and bottom boundaries of water zones whether bottom water or intermediate zones of production, Data are given on tests by this survey method on a number of producing wells, Complete results were obtained on wells shelving water percentages ranging from high values to as Little as 10 pct salt water. A number of the wells tested were plugged back and the results are reported in detail. While not all the work-overs were successful, evidence, including the results of reruns by this survey method, points to failure of the plugback operations. The data provided in the tests discussed show, contrary to general opinion, that a large percentage approaching 50 pct of the wells showed intermediate water instead of bottom water. Furthermore, approximately a third of the wells tested showed multiple zones of water production. The equipment comprises a long pipelike assembly carrying 10 pairs of electrodes spaced apart a distance of 4 ft. A surface-controlled solenoid-operated switch is provided to connect each of the individual pairs of electrodes in turn to a single-conductor steel-armored cable by means of which the conductivity of the fluid in the vicinity of each of the electrode pairs can be continuously recorded at the surface. Any number of electrode pairs and any spacing can be used. This assembly is lowered on tubing and placed in position opposite the section of the well to be studied. A conventional rod pump is used to produce the well for the survey. The pump inlet is placed below the lowest electrode pair. The well is conditioned by pumping Out the salt water normally standing in the well and introducing fresh water into the annulus at the surface. When the resistivity of the water standing in the well has been increased to a sufficiently high value, the inflowing fresh water is stopped and the drawdown operation of the survey is started. As the fluid head is lowered by pumping, fluids flow into the well and the entry Of salt water is indicated by the change in resistivity of the fresh water opposite the 'Ones Of water entry, The process can be repeated as Often as necessary with little effort and without moving any well equipment to be sure that the fluids produced from each zone are representative Of the true reservoir content. Introduction The oil industry has been concerned from its inception with the control of fluids entering its wells. In order to effect the greatest economy of operation and to get the greatest total production of petroleum liquids out of the ground, the flow of gas and water must be controlled and often extensive workovers are planned and carried Out for this purpose. This has become even more important in recent Years because of the need for the conservation of natural resources. Whereas producing operations concerned with the original completion of a well are assisted to a great extent by a wide variety of instruments developed and perfected for that purpose, workover operations on oil wells have been greatly hindered by a lack of suitable instrumentation. The industry has searched for many years for a satisfactory instrument and process that

Jan 1, 1948

By A. R. Brown, D. Silverman

EquipmENT and methods for locating the points of entry of salt water into oil wells are described. These techniques make it possible to delineate accurately the top and bottom boundaries of water zones whether bottom water or intermediate zones of production, Data are given on tests by this survey method on a number of producing wells, Complete results were obtained on wells shelving water percentages ranging from high values to as Little as 10 pct salt water. A number of the wells tested were plugged back and the results are reported in detail. While not all the work-overs were successful, evidence, including the results of reruns by this survey method, points to failure of the plugback operations. The data provided in the tests discussed show, contrary to general opinion, that a large percentage approaching 50 pct of the wells showed intermediate water instead of bottom water. Furthermore, approximately a third of the wells tested showed multiple zones of water production. The equipment comprises a long pipelike assembly carrying 10 pairs of electrodes spaced apart a distance of 4 ft. A surface-controlled solenoid-operated switch is provided to connect each of the individual pairs of electrodes in turn to a single-conductor steel-armored cable by means of which the conductivity of the fluid in the vicinity of each of the electrode pairs can be continuously recorded at the surface. Any number of electrode pairs and any spacing can be used. This assembly is lowered on tubing and placed in position opposite the section of the well to be studied. A conventional rod pump is used to produce the well for the survey. The pump inlet is placed below the lowest electrode pair. The well is conditioned by pumping Out the salt water normally standing in the well and introducing fresh water into the annulus at the surface. When the resistivity of the water standing in the well has been increased to a sufficiently high value, the inflowing fresh water is stopped and the drawdown operation of the survey is started. As the fluid head is lowered by pumping, fluids flow into the well and the entry Of salt water is indicated by the change in resistivity of the fresh water opposite the 'Ones Of water entry, The process can be repeated as Often as necessary with little effort and without moving any well equipment to be sure that the fluids produced from each zone are representative Of the true reservoir content. Introduction The oil industry has been concerned from its inception with the control of fluids entering its wells. In order to effect the greatest economy of operation and to get the greatest total production of petroleum liquids out of the ground, the flow of gas and water must be controlled and often extensive workovers are planned and carried Out for this purpose. This has become even more important in recent Years because of the need for the conservation of natural resources. Whereas producing operations concerned with the original completion of a well are assisted to a great extent by a wide variety of instruments developed and perfected for that purpose, workover operations on oil wells have been greatly hindered by a lack of suitable instrumentation. The industry has searched for many years for a satisfactory instrument and process that

Jan 1, 1948

By R. M. Leibrock, J. E. Huzarevich, R. G. Hiltz

The various factors considered in recommending the initiation of a gas injection project in the southern portion of the Cedar Lake Field are discussed. Performance history under gas injection operations is reviewed and these data are analyzed, utilizing both the material balance method and the fractional flow and frontal advance expressions. Results of the analysis of the performance data indicate that the injected gas has contacted and affected at least 60 per cent of the reservoir and a substantial increase in ultimate recovery can reasonably be expected. By holding the reservoir pressure appreciably above the bubble point, the well productive capacities have been maintained substantially above the level predicted for primary operations. The analysis of the Cedar Lake project suggests that in certain limestone reservoirs, at least, the probable success of gas injection cannot be predicted simply from ohservation of permeability distribution throughout the pay section, as indicated by core analysis data, on either one or a number of wells. Further, the performance of this particular project fails to indicate any basis for classifying carbonate reservoirs in general as being inherently unsuited to a dispersed type gas injection program, thus indicating that each reservoir should be considered on its own merits, regardless of the composition of the reservoir rock. INTRODUCTION Early in the life of the Cedar Lake Field, an extensive data gathering program was initiated to provide an accurate record of reservoir performance characteristics. From the study of these data it was apparent that there was a critical need for supplementing the natural reservoir energy in order to maintain well productivities and obtain the maximum ultimate oil recovery. Accordingly, detailed engineering studies were made of the various methods of secondary recovery which might be applicable. As a result of these investigations, the decision was made to initiate a gas injection program of sufficient intensity to maintain reservoir pressure at approximately 600 psia, or some 274 lb above the bubble point pressure of 326 psia. A full scale dispersed type gas injection program has been in operation on leases of the Stanolind Oil and Gas Co. in the southern portion of the field for nearly five years, and sufficient performance data are now available to evaluate the benefits which have been derived from this project. It is the primary purpose of this paper to analyze the performance data for the Cedar Lake gas injection project and to point out the significance of the ohserved behavior with respect to certain hypotheses which have been advanced in recent years concerning the probable success of gas injection projects in limestone reservoirs. This paper properly should be regarded more on the order of a progress report, inasmuch as some revision in interpretation will undoubtedly be required from time to time as additional performance data are obtained, although the satisfactory performance of the project to date leaves little doubt as to the ultimate success of gas injection in the Cedar Lake Field. As a result of the success of the project to date, a unit was formed in the southern part of the field, effective March 1, 1951, for the purpose of continuation of the gas injection program. Participants in this unit are the Mid-Continent Petroleum Co. and Stanolind Oil and Gas Co. GEOLOGY AND STRATIGRAPHY The Cedar Lake Field is located in the northern portion of the Midland Basin area as shown in Fig. 1. The southwest portion of the field lies within a playa, or dry salt lake, which covers an area of approximately eight square miles. As might be expected, it was this lake which furnished the inspiration for the name of the field. Except for its value as a salt water disposal pit, this lake has succeeded only in magnifying the difficulties in developing this portion of the field. Typical of this section of West Texas, the area in general is relatively flat and has a semi-arid climate. The localized structure which favored the accumulation of oil is an anticline with approximately 100 ft of closure. The major axis of the structure extends in a general southeast-northwest direction. Originally this structure was defined by seismograph data, which have been subsequently confirmed by development. In general, the geologic column is typical of that found throughout the basin. From the surface to depth of approximately 1,800 ft, surface sands and undifferentiated red beds. probably Triassic. are encountered. Below this point to the producing horizon, all formations are of the Permian age.

Jan 1, 1951

By J. E. Huzarevich, R. M. Leibrock, R. G. Hiltz

The various factors considered in recommending the initiation of a gas injection project in the southern portion of the Cedar Lake Field are discussed. Performance history under gas injection operations is reviewed and these data are analyzed, utilizing both the material balance method and the fractional flow and frontal advance expressions. Results of the analysis of the performance data indicate that the injected gas has contacted and affected at least 60 per cent of the reservoir and a substantial increase in ultimate recovery can reasonably be expected. By holding the reservoir pressure appreciably above the bubble point, the well productive capacities have been maintained substantially above the level predicted for primary operations. The analysis of the Cedar Lake project suggests that in certain limestone reservoirs, at least, the probable success of gas injection cannot be predicted simply from ohservation of permeability distribution throughout the pay section, as indicated by core analysis data, on either one or a number of wells. Further, the performance of this particular project fails to indicate any basis for classifying carbonate reservoirs in general as being inherently unsuited to a dispersed type gas injection program, thus indicating that each reservoir should be considered on its own merits, regardless of the composition of the reservoir rock. INTRODUCTION Early in the life of the Cedar Lake Field, an extensive data gathering program was initiated to provide an accurate record of reservoir performance characteristics. From the study of these data it was apparent that there was a critical need for supplementing the natural reservoir energy in order to maintain well productivities and obtain the maximum ultimate oil recovery. Accordingly, detailed engineering studies were made of the various methods of secondary recovery which might be applicable. As a result of these investigations, the decision was made to initiate a gas injection program of sufficient intensity to maintain reservoir pressure at approximately 600 psia, or some 274 lb above the bubble point pressure of 326 psia. A full scale dispersed type gas injection program has been in operation on leases of the Stanolind Oil and Gas Co. in the southern portion of the field for nearly five years, and sufficient performance data are now available to evaluate the benefits which have been derived from this project. It is the primary purpose of this paper to analyze the performance data for the Cedar Lake gas injection project and to point out the significance of the ohserved behavior with respect to certain hypotheses which have been advanced in recent years concerning the probable success of gas injection projects in limestone reservoirs. This paper properly should be regarded more on the order of a progress report, inasmuch as some revision in interpretation will undoubtedly be required from time to time as additional performance data are obtained, although the satisfactory performance of the project to date leaves little doubt as to the ultimate success of gas injection in the Cedar Lake Field. As a result of the success of the project to date, a unit was formed in the southern part of the field, effective March 1, 1951, for the purpose of continuation of the gas injection program. Participants in this unit are the Mid-Continent Petroleum Co. and Stanolind Oil and Gas Co. GEOLOGY AND STRATIGRAPHY The Cedar Lake Field is located in the northern portion of the Midland Basin area as shown in Fig. 1. The southwest portion of the field lies within a playa, or dry salt lake, which covers an area of approximately eight square miles. As might be expected, it was this lake which furnished the inspiration for the name of the field. Except for its value as a salt water disposal pit, this lake has succeeded only in magnifying the difficulties in developing this portion of the field. Typical of this section of West Texas, the area in general is relatively flat and has a semi-arid climate. The localized structure which favored the accumulation of oil is an anticline with approximately 100 ft of closure. The major axis of the structure extends in a general southeast-northwest direction. Originally this structure was defined by seismograph data, which have been subsequently confirmed by development. In general, the geologic column is typical of that found throughout the basin. From the surface to depth of approximately 1,800 ft, surface sands and undifferentiated red beds. probably Triassic. are encountered. Below this point to the producing horizon, all formations are of the Permian age.

Jan 1, 1951

By S. G. Epstein

Electromigration has been measured in dilute liquid alloys of lead in antimony and antimony in lead. In these alloys antimony migrates with the electron current; lead migrates in the opposite direction. These results, which contradict the mass criterion, were predicted by the electron drag model for electromigration in liquid alloys. The existing experimental data are shown to correlate with the difference in electrical resistivities of the alloy components. FOR many years investigators have attempted to relate observed electromigration phenomena in liquid alloys to the physical properties of the alloy components. The most successful correlation was found by Angus et' al.,1 who in 1959 proposed an empirical criterion for predicting the relative direction of motion of the components of a liquid alloy in an electric field: the component with the smallest atomic mass concentrates at the cathode. While this criterion is obeyed in nearly all the alloy systems which had been investigated, the physical basis for such an effect was not understood. It was also disturbing that the mass criterion predicted the wrong sign for the Haeffner effect; observations with pure liquid metals revealed that in every instance the lighter isotope was transported to the anode.2 Klemm3 explained these isotopic separations by suggesting that the lighter isotopes were more mobile and more easily carried to the anode with the electron stream. Additionally, several deviations from the mass criterion have been found in liquid alloys, notably involving transition metals such as chromium, nickel, palladium, and zirconium, which migrate to the anode in liquid bismuth.4'5 Recently, a model has been proposed6 in which electromigration in liquid alloys is attributed primarily to the interaction between the electron stream and the metal ions. In essence, this model predicts that the component with the greater electron-ion scattering cross section will be preferentially transported to the anode, displacing the other component to the cathode. The electrical resistivity of each pure component at its melting point is taken as the measure of its scattering cross section. This model was developed from the results of systematic studies with various solutes in liquid mercury,7'8 bismuth,9 and sodium.10 In every alloy, the component with the greater resistivity has centrates at the anode. Coincidentally, in every instance the component with the greater resistivity has also the greater mass, apparently satisfying the mass criterion. In order to differentiate between electron-ion coupling and atomic mass as the relevant physical prop- erty influencing electromigration, measurements were made with Pb-Sb alloys. Lead has an atomic mass nearly twice that of antimony, but lead has an electrical resistivity of 91 microhm-cm while antimony has a value of 113.5 microhm-cm at their respective melting points. The mass criterion predicts that in an alloy of the two antimony will concentrate at the cathode; the electron drag model predicts that antimony will concentrate at the anode. EXPERIMENTAL To conclusively determine the relative motion of lead and antimony in each other, solute electromigration was measured in dilute liquid alloys of antimony in lead and lead in antimony. Both starting materials were 99.999+ pct pure. The measurements were made with the same capillary-reservoir technique previously used for measuring electromigration in liquid bismuth alloys.11 Several changes in the experimental apparatus were necessary, however, to accommodate liquid antimony, which has a higher melting point than bismuth. The modified apparatus is depicted in Fig. 1. In each experiment four quartz capillaries were filled with the molten alloy. A direct current was passed through two of the capillaries; the electrode in one of these capillaries was made the cathode, and the electrode in the other was made the anode. The remaining two capillaries sampled the alloy in the reser-

Jan 1, 1969

By Raymond Howe

SOME time ago,, a prominent engineer asked a representative of the firebrick industry to prepare a comprehensive paper on blast-furnace refractories. It was to have been the purpose of this paper to gather practical experiences from widely different sources, in the hope of determining what kind or kinds of firebrick were best adapted for certain uses. This engineer sent questionnaires to the large consumers of blast-furnace linings and stovebrick and received very detailed replies as to their experiences. These replies are conflicting, but, having been turned over to the writer, form the basis of this attempt to meet the request. Because of the impossibility of making final recommendations at this time, a few of the more interesting and commonly known methods of studying refractories are also discussed, as well as the more recent developments in this field. The first reply to, the questionnaire stated that good service was being secured from the linings. This satisfactory condition was attributed to the use of a very good distributor. The writer believed that manufacturers try to and do produce a good product and that the proper handling of equipment is of the utmost importance, if good results are to be secured. The type of bricks used was not mentioned. The second reply stated that good life was secured from the furnace linings, but that the writer had had soft-fired stovebrick crumble and, for that reason, preferred a hard-fired product for use in this position. The type of bricks used was not mentioned. The third reply stated that firebrick had crumbled from the mantle up; the cause was not known. The fourth reply stated that the stove linings were satisfactory. Hand-made furnace linings failed after 4 years' service so a steam-pressed lining was installed which was still good after 4 years of service. Consequently, a second steam-pressed lining was installed but this disintegrated at the top after the furnace had been in- blast 7 months. The firebrick manufacturer attributed this failure to the expansion of iron blocks that had been installed at the stock line to prevent erosion.

Jan 9, 1919

By C. S. Barrett

It has been observed that deformation in iron takes place by slip on (110) + {112) + (123) planesl, 2, but in silicon ferrite with low deformation temperatures or high silicon contents (exceeding 4 per cent) the authors have found that slip is confined wholly to (110) planes, at least with small amounts of deformation. The purpose of the present investigation was to determine the effect of this alteration of slip mechanism on preferred orientations in cold-rolled and recrystallized strips. Incidental observations on the effect of the recrystallization temperature were also made. The numerous determinations of the texture of cold-rolled iron and steel have been in satisfactory agreement as to the principal features of the texture (with the exception of a few conclusions that apparently have been based on insufficient data). The texture is chiefly one in which 11101 directions of the grains lie along the direction of rolling, with a deviation of a few degrees, and in which the (100) planes lie in the plane of the rolled sheet, with a deviation from this position chiefly about the rolling direction as an axis. This deviation about the rolling direction as an axis has been measured by different observers and lies between about 45" and 50" or 60" for iron5, 6, 9 and is usually in the neighborhood of 50" for mild stee16, 7, 8. The range of this deviation is a function of the percentage of total reduction8, 10. Post8 reported that it decreases with increasing percentage reduction, but apparently he studied only the surface material, which Gensamer and Meh17 found to be somewhat differently oriented from the material in the inside of the sheet. McLachlan and Davey10 found that the deviation also decreases with increasing percentage of total reduction for the material in the interior of the sheet and is independent of the percentage of reduction per pass. The deviation about the cross direction as an axis (the direction in the

Jan 1, 1937

Faulty rock dusting of the New Orient Mine at West Frankfort, Ill. was declared to have been the primary cause of the extent of the blast that killed 119 men on December 21. Walter Eadie, state director of mines and minerals, ascribed the explosion to the ignition of methane in a working place about a mile northwest of the shaft of the mine. The initiation of the combustion was either by a spark from electrical machinery or from men smoking in the mine. It was surmised that a train of empty cars stalled in a ventilation door, had caused sufficient disturbance in the ventilation system to permit accumulation of gases. The Federal Bureau of Mines said that the Illinois explosion was caused by an electrical spark that touched off the clouds of gas present because of the faulty ventilation equipment. The bureau report listed three conditions as primarily responsible: An inadequate ventilating system, operation of faulty electrical equipment and the presence of large accumulations of fine coal dust capable of exploding. "This coal dust, principally along roadways, was not removed from the mine or rendered inert by the application of sufficient rock dust," the report stated. Investigations showed that an even more disastrous blast was averted because the explosion eventually reached areas where it could expand into open workings and where enough rock dust had been applied to retard it.

Jan 1, 1952

By R. O. Williams

The concept of biaxial pole figures which completely represent sheel textures is defined and an iterative least-squares solution given. The method has been applied to rolled copper, aluminum, and brass. The results show that the prior ideal textures are reasonably correct but incomplete. The major components in all three cases consist of a continuous range of orienta-tions roughly described as starting from (211) [111] continuing to (110) [112] to (110) [001], the details dif- THIS paper considers the problem of representing rolling textures in the most useful and comprehensible manner possible. A representation called a biaxial pole figure which completely represents such textures fering in all cases. For brass, in particular, the last part of the range is the most important. A minor cube component is established for the copper and aluminurn. The results were also analyzed by means of sets of three axial (inverse) pole figures to give similar, less-detailed results. The method of analysis is outlined. Such a representation is significantly less powerful than the biaxial method, but it has considerable utility in the calculation of anisotropic properties. is defined and an iterative least-squares solution is given. Such textures may be approximated by treating the principal directions as fiber axes to give three axial (inverse) pole figures. This representation is very useful for calculating anisotropic properties. New data for rolled copper, brass, and aluminum are given by both methods. In an axial pole figure the relative frequency or probability of a given physical direction (normally the

Jan 1, 1969