Search Documents

By R. J. Wysor

CHARLES H. RICH, Conshohocken, Pa. (communication to the Secretary*).-Mr. Wysor has certainly covered his subject in the most thorough and able manner and his paper will no doubt result in enlarged effort toward the conservation of this important byproduct. Not all furnace burdens are as rich in alkalies as those noted by Mr. Wysor. In our own experience we have never gone into any extended examination of the materials entering the furnace burdens, but have made a number of determinations of the water-soluble alkalies of our flue and boiler dust and found maximum of about 4 1/2 per cent. K20-too small for profitable reclamation. We have, however, frequently encountered the smoky gas described by Mr. Wysor. Such gas carries heavy fume, and buds with a fitful flame difficult to maintain. So pronounced was the inhibitory effect of the fume that, in extreme cases, the flame of a lighted match was extinguished by the current of gas and it was found impossible to conduct calorimeter tests without preliminary washing of the gas. When the gas was led through a washer filled with distilled water and pieces of coke, the fume was absorbed and the gas burned without difficulty. Careful analyses conducted on the water solution from the washer showed cyanides in increasing amounts in proportion to the difficulty experienced in burning the gas. We, note Mr. Wysor's statement that he has never found evidence of cyanides in their gas, ascribing the difficulty of burning such gas to the presence of chlorides. Our determinations were conducted in such manner as to preclude possibility of interference by chlorine.

Jan 3, 1917

JULY was a month of great turmoil, both economic and political, in many parts of the world. Instead of conditions improving, they seem to have been getting worse. In Ireland, civil war is still in progress. Germany was in the throes of a political upheaval. The meaning of the assassination of Rathenau became clear. It evinced the development of a class struggle between the bourgeois and socialistic parties which may rock the country to its foundation and will increase the difficulties of arranging things with the French and solving the reparations problem. In Poland, a similar contest is developing. Austria is already so completely contaminated by the socialist element that it is unable to get outside assistance and is thus falling into a state of despair but little short of what prevails in Russia. The conference at the Hague came to an abortive end for the reason that it was impossible to discuss affairs with the Russians in any reasonable way. The Germans declared their inability to meet the reparation payment that fell clue on July 15 and the Commissioners for the Allies granted them an abate-ment of a portion thereof and are listening attentively to the supplication of the Germans for a moratorium of one or two years. In the United States, July was a month of widespread labor troubles, accompanied by a great deal of disorder and violence, which led to detachments of the National Guard being called out in several states. The railway shopmen, about 400,000 in number, struck on July 1. The road maintenance men decided not to strike, but many thousands of them quit work without the sanc-tion of their union. There were more strikes in the textile industry in New England and in similar industries all over the country. Early in July, it was estimated that about 1,250,000 men were out on strike. The coal strike continued. Early in the month the President summoned operators and miners to Washing-ton and submitted a plan for the compromising of disputes. After a week's consideration the miners re-fused flatly to agree to anything. The majority of the operators consented to accept the proposed arbitration, but a minority refused. Following this abortive at-tempt the President dismissed the conference with the injunction "to return to your mine properties and resume operation." Production has not increased.

Jan 8, 1922

By E. A. Anderson

In another paper' the writer has shown that the low permissible maximum fiber stress in a loaded zinc sheet demands a much closer support spacing than is used for steel. The limiting fiber stress in 13-gage (0.032 in.) sheets having a 1-in. depth of corrugation was found to be about 5000 lb. per sq. in. on a 37-in. span under a load of 40 Ib. per sq. ft. Corrugated steel sheets are commonly laid with spans varying from 48 to 60 in. In order to increase the span in 13-gage zinc to 54 in. (a common spacing) the metal must be capable of withstanding, under long-continued loading, a maximum fiber stress of about 10,000 lb. per sq. in. This is known to be impossible with unalloyed zinc. In this paper the writer describes a series of experiments leading up to the development of an alloy capable of safely sustaining this fiber stress. The effect of alloying on the slow creep of zinc was studied by means of static tensile tests, accurate determinations of apparent elastic limits and finally by means of loading tests on full-size roof sections. Two industrial buildings roofed with alloyed zinc sheets on spans involving fiber stresses in excess of 10,000 lb. per sq. in. have been under observation for over two years without signs of sagging. Experimental Work Two methods of increasing the maximum permissible fiber stress in zinc were considered. Cold rolling, which' increases the stiffness and tensile strength, was found to decrease the resistance to slow flow. Alloying, therefore, provided the only feasible means of obtaining the desired result, It was recognized that the improvement secured by the solid solution of natural impurities was insufficient. A series of alloys was outlined, therefore, in which a number of metals were added separately and together. The sheets rolled from these alloys were tested under

Jan 1, 1930

By D. E. Marks, Arnold, C. W, R. J. Robinson, A. E. Hoffmann

The efficiency of operation of a fixed-bed adsorption unit is infEuenced both by the absolute adsorption capacity of the bed and by the rate of adsorption. This paper describer studies of adsorption rate which were conducted in an experimental unit designed such that conditions existing in the treatment of high-pressure natural-gas mixtures could be duplicated. Variables investigated included pressure, temperature, gas composition, adsorbent particle size, depth of packed bed and gas velocity. The adequacy of a simplified mathematical model for predicting the observed phenomena was tested. A correlation is preserited which relates adsorption rate to the process variables stlldied. This correlation is useful in combination with the matheinatical model. INTRODUCTION Of the techniques available for contacting adsorbent particles with fluid streams to be treated, fixed-bed adsorption columns offer definite advantages in simplicity and ease of operation. As a result, they are often used in preference to others for such petroleum industry applications as dehydration and purification of natural gas and hydrocarbon recovery. Fixed-bed adsorption units usually consist of two or more towers filled with a desired adsorbent and operated in a cyclic manner. While one is being used to process the main flow stream, the others are undergoing regeneration to remove the adsorbed phase. When the tower on stream becomes saturated with the preferentially adsorbed material, the roles of the towers are switched, and the freshly regenerated tower is placed on stream. Cacle duration is determined by the bed capacity under the process conditions and by the flow rate through the bed. The sharpness of separation which can be effected is a function of both the absolute capacity of the bed and the rate of adsorption in the bed. The effect of rate for a particular set of conditions is evidenced by the sharpness or diffuse-ness of the adsorption front as it advances through the bed. Since data needed for design of adsorption units to treat high-pressure natural-gas systems were not available, an experimental program was designed to investigate the effects of different variables upon adsorption rate in fixed beds. In the present paper, effects of gas composition, column length, temperature, pressure, adsorbent particle size and flow rate (actual linear flow rate of the gas) are shown, and utility of a simplified mathematical model for describing the process is discussed. As gas enters the top of a cool, clean bed of adsorbent, preferentially adsorbed materials are stripped from the main flow stream by the uppermost particle layers. As these layers become saturated with a particular component, new supplies of this component are carried further down the column until fresh adsorbent is encountered. An adsorption wave thus moves through the column as material is supplied to saturate succeeding elements of the bed. Adsorption from a Multicomponent gas stream occurs as a succession of such moving waves corresponding to the different components in the gas. The leading edge of an adsorption wave for a component of a natural-gas stream moving through a bed of a common commercial adsorbent such as silica gel would be sharp but for the influence of certain broadening fac tors. These factors include a nonuniform velocity profile in the bed, longitudinal dispersion or mixing in the main gas stream, and the time required for a molecule to migrate from the main gas stream and be adsorbed at a site within the body of an adsorbent particle. If packing is uniform and the ratio of column to particle diameter is greater than approximately 15:1, the first factor is relatively unimportant' Longitudinal mixing is of importance only for the case of moderately high mass transfer with extremely slow flow rates.' The sharpness of an adsorption front, therefore, is, primarily a function of the rate of adsorption or the time required to saturate a particle of zdsorbent. Two methods for defining adsorption rate are used in this work. The first is a normalized or relative rate which describes the rate of saturation of a differential element of the packed bed. This can be measured by observing the time required for the concentration of the preferentially adsorbed material in the effluent gas from the bed to rise from zero to a value equal to that in the inlet gas stream. The second definition describes the absolute rate of mass transfer from the gaseous to the adsorbed phase. This definition is used in a mathematical description of the adsorption process. If the concentration of a component in the gas strcam leaving an adsorption column is measured and plotted as a function of time, a curve such as that shown in Fig. I results. It is seen that for a period of time the effluent gas is devoid of the component under consideration. As the bed approaches saturation, a small percentage of this material will appear in the effluent gas. The concentration will then rise with time, or increasing cumulative gas flow, until it is equal to that in the inlet gas stream. If adsorp-

By Howard Scott

THE GREAT advances made in mechanical engineering during recent years through the use of alloy steels, as illustrated by the development of the airplane and automobile, may be ascribed primarily to the application of nickel as an alloying element. The ternary system iron-carbon-nickel has a wide industrial application and forms, further; the fundamental basis of the even greater class of the widely used quarternary steels such as nickel-chromium, nickel-silicon, and nickel-vanadium. As is not uncommon with such cases of virile growth in an industry, the application of the alloy steel in a largely empirical manner has outstripped its scientific development so that a fertile field for metallographic research still remains. In this field, the basic nickel steels require first consideration and are the subject of the present investigation, which is offered as a preliminary to the study of the more complex alloys of industrial importance. Of the principal tools of metallography-microscopic examination, determination of -mechanical properties, and thermal analysis-the last has developed much more slowly in its application to industrial needs so that the situation often exists that heat treatment operations are based on empirically determined temperatures; that is, temperatures determined without regard to the actual transformation characteristics of the alloy. This situation is undesirable as there is no uniform standard for comparison of results. It is due, outside the usual difficulties involved in temperature measurements, to the pioneer character- of much of the published work; to the lack of definiteness of the Ac2 transformation,1 particularly in low-carbon steels; to the failure to define operating conditions completely; and to the paucity of information correlating thermal characteristics with results of heat treatment.

Jan 2, 1920

THE discussion at the annual meeting of the paper on "Devices for Detecting Dangerous Gases in Mine Air" (published in. MINING AND METAL-LURGY, February 1, 1927, p. 69) was prefaced by the following description of a new portable methane indi-cator, presented by D. C. Ashmead: Two comparatively recent disasters in Utah are directly responsible for the perfection of the new methane detector. The first of these occurred on May 1, 1900, when 200 work-men lost their lives. The second disaster did not occur for more than two decades, when, on March 8, 1924, at the Castle Gate Mine No. 2, 172 workmen were killed. A dis-sembled safety lamp was later found at the seat of the ex-plosion. This indicated, as a possible cause, that the safety lamp had gone out and the fire boss had tried to relight it. These two disasters brought, the mine operators of the State of Utah to the concentrated attempt to end the loss of life through mine explosions. The Governor of the State appointed a committee, known as the Utah Mine Op-erators Committee, to study the phases of the problem, and this Committee in turn enlisted scientists all over the country in cooperative research. One group, under the direction of E. K. Judd, of the Union Carbide and Carbon Research Laboratories, of Long Island City, New York, concentrated its efforts on develop-ing a methane detector which would be completely ade-quate. This is now successful, since in laboratory as well as actual coal-mine tests the apparatus has instantaneously and accurately detected the presence of extremely small amounts of methane.

Jan 3, 1927

By Frank B. Gilbreth

The problem of the crippled soldier in industry is not a problem of war work only; it is a problem of industrial development. As individuals, each one of you is seeking to provide our maimed heroes with such teaching as will render them, in the shortest possible amount of time, productive and satisfied members of the community. As individuals you are interested in the organizations that are preparing to receive these men, to train them and to place them at that work for which they are best fitted. As an organization, it is now your duty to take up the industrial end of the problem, to investigate existing conditions in the industries, to discover where the opportunities for employment lie, and so readjust industrial practice that the cripples may be utilized to their own and the community's good with the least shock to themselves or to the industries, and with the greatest amount of permanent benefit to all concerned. We have divided industrial opportunities suitable for cripples, roughly, into three classes. First, such as already exist in the industries, which can be set aside for cripples only, present occupants being transferred to other work for which they can be fitted but which is not suitable for cripple work; second, opportunities in the industrial world that, through changes in the working equipment or tools, or through appliances attached to the cripple himself, can make the cripple a competitor of the sound worker; third, opportunities not existing at present in the industries, but which could be introduced for the good of the community without placing the cripples into competition with any existing class of workers. As typical of the first type of occupations for cripples, we have mentioned that of store-keeper, of the second type that of typist,2 and of the third type that of dental nurse.3 The last occupation can be so arranged as to take from the overworked dentist the work of cleaning teeth; and

Jan 1, 1918

Jan 1, 1919

While mining silver at Butte in 1882, Marcus Daly is reputed to have told his partners in The Anaconda Silver Mining Co., "It looks rather gloomy. The vein is running into copper." Recently, The Anaconda Co. authorized an $11 million expenditure to be made over the next five years to ensure their "running into copper" at deep levels for many more years. The new development program is designed to permit both deeper and more widespread selective mining in "the richest hill on earth" by means of additional shaft-sinking, reactivating closed mines, and establishing new haulageways and centralized hoisting facilities. Historically a deep level selective mining camp, Butte will now continue its uncommon use of three main types of mining methods at one camp-selective mining, block caving, and open pit mining. It was thought by some people that the construction of the Kelley shaft and the subsequent beginning of block caving operations in 1952-outgrowth of the Greater Butte Project-signaled the end of stope mining of high-grade ores at depth. This feeling became more pronounced when, in 1957, the Berkeley open pit commenced operations. During recent years, the tonnage of ore mined selectively underground has decreased, but the new program will maintain the position of selective underground mining in the overall picture of the Butte operations for many years to come.

Jan 7, 1960

By F. N. Rhines

Sintering may be defined as the process by which powders bond themselves into coherent bodies, usually, although not necessarily, under the influence of pressure and elevated temperature. For the sake of clarity and simplicity, the present survey will exclude from consideration the sintering of mixed or alloyed powders, with attendant complications, but at the risk of overlooking information of general applicability. Sintering in the presence of a liquid phase is thus automatically eliminated. The sintering of alloys involves much additional subject matter and deserves separate consideration. Since the literature of the subject is extensive and widely scattered, it will not be feasible to consider the contributions individually. Instead, the subject matter will be classified according to experimental observations and theory, and will be presented in summary form. It should be noted that the appended list of references does not constitute a complete bibliography; it includes only those works quoted below. More extensive bibliographies are included in several of the references; see particularly references 7, 9, 28, 34, 38, 50, 52, 54, a "Bibliography on Powder Metallurgy" published by the Library of Congress and a pamphlet published by the Metals Disintegrating Co. entitled "The Field of Powder Metallurgy and Bibliography." 11. Summary of Experimental Observations The following classified list is composed of general statements of established fact derived from the experimental results reported in the published literature. A few contested observations are included, because of their potential importance; these are labeled as such. Any satisfactory and complete theory must be capable of explaining all of the uncontested facts. Obviously, some important facts may be missing from this list and these may hold the key to the correct explanation of the sintering process, but the possible lack of such material should not deter attempts to understand the subject on the basis of what is available here. A, The Initial Bond at Room Temperature a. To a limited extent uncompressed powders and massive metals adhere at room temperature. Clean tin powder forms a weak "cake" on standing at room temperature, the strength increasing with time. Clean gold surfaces adhere on light con-tact, as do those of many other substances, including nickel.27 b. Upon compression the strength of the bond- is increased progres-ivelv. There is a limit of pressure

Jan 1, 1946

By F. N. Rhines

Sintering may be defined as the process by which powders bond themselves into coherent bodies, usually, although not necessarily, under the influence of pressure and elevated temperature. For the sake of clarity and simplicity, the present survey will exclude from consideration the sintering of mixed or alloyed powders, with attendant complications, but at the risk of overlooking information of general applicability. Sintering in the presence of a liquid phase is thus automatically eliminated. The sintering of alloys involves much additional subject matter and deserves separate consideration. Since the literature of the subject is extensive and widely scattered, it will not be feasible to consider the contributions individually. Instead, the subject matter will be classified according to experimental observations and theory, and will be presented in summary form. It should be noted that the appended list of references does not constitute a complete bibliography; it includes only those works quoted below. More extensive bibliographies are included in several of the references; see particularly references 7, 9, 28, 34, 38, 50, 52, 54, a "Bibliography on Powder Metallurgy" published by the Library of Congress and a pamphlet published by the Metals Disintegrating Co. entitled "The Field of Powder Metallurgy and Bibliography." 11. Summary of Experimental Observations The following classified list is composed of general statements of established fact derived from the experimental results reported in the published literature. A few contested observations are included, because of their potential importance; these are labeled as such. Any satisfactory and complete theory must be capable of explaining all of the uncontested facts. Obviously, some important facts may be missing from this list and these may hold the key to the correct explanation of the sintering process, but the possible lack of such material should not deter attempts to understand the subject on the basis of what is available here. A, The Initial Bond at Room Temperature a. To a limited extent uncompressed powders and massive metals adhere at room temperature. Clean tin powder forms a weak "cake" on standing at room temperature, the strength increasing with time. Clean gold surfaces adhere on light con-tact, as do those of many other substances, including nickel.27 b. Upon compression the strength of the bond- is increased progres-ivelv. There is a limit of pressure

Jan 1, 1946

The co-operation of the members of the Institute is earnestly sought by the Committee on Nominations, recently appointed by the Board of . Directors, in its work of formulating a ticket for officers and places falling vacant in the Board of Directors in February, 1916. The Committee must present the official ticket of nominations to the Board of Directors at its October meeting. Members are, therefore, urged to send promptly their nominations for officers and Directors in order that the Committee may have an opportunity to give them full consideration. The officers to be elected at the annual meeting in February, 1916, are: One officer, known as Director and President. Two officers, known as Director and Vice-President. Five officers, known as Director; The attention of members is called to Articles V and VII of the Constitution, and to By-Law XIII, which reads as follows: "The geographical districts to be considered by the Committee on Nominations shall he as follows, until otherwise ordered by the Board. District No. 1. New England, New York, and New Jersey, excepting New York City and district., which is provided for in the Constitution. (N. B.-New York City and district is designated District 0.) District No. 2. Pennsylvania. District No. 3. Ohio, Indiana, Illinois, Iowa, and Missouri. District No. 4. Minnesota, Wisconsin, and Michigan. District No. 5. Montana, North and South Dakota, Wyoming, Nebraska, Kansas, Washington, Oregon, Idaho, and Alaska. District No. 6. California and Nevada. District No. 7. Utah, Colorado, Arizona, and New Mexico. District No. 8. Louisiana and Texas. District No. 9. Other Southern States and District of Columbia. District No. 10. Mexico. District No. 11. Canada."

Jan 7, 1915

By M. E. Shank, J. Wulff

In view of the current interest in magnetic materials having rectangular hysteresis loops, as for example those obtained with the grain oriented 50 nickel 50 iron alloys,t we wish to call attention again to the results obtainable with the perminvar (Co-Ni-Fe) alloys heat treated in a magnetic field. Data taken from direct current measurements made prior to and during World War II give the typical values shown below for two of the perrninvar alloys. Fig 1 and 2 show- the hysteresis loops for these samples. The first sample above consisted of small rings punched from 0.014 in. sheet stock. These rings were heat treated at 1000°C for one hour in a hydrogen atmosphere and then cooled with the furnace to 750°C at which point they were subjected to a magnetic field of 15 oersteds maintained during cooling to room telmperature. The molybdenum perminvar sample consisted of a spirally wound core of 0.001 in. tape. The heat treatment was the same except that box annealing methods were used and no hydrogen atmosphere was employed. Even better properties might be expected using hydrogen. The heat treating temperatures and cooling rates are not critical. Rectangular hysteresis loops produced in other perminvar alloys by heat treatment in a magnetic field were described earlier.',? Properties similar to those described above are realized in perminvars manufactured by conventional methods. Drastic cold working which in practice limits the final thickness and is gen- erally expensive may thus be avoided. This information may be of interest to those concerned with magnetic alloys and the development of contact rectifiers, magnetic amplifiers and so on.

Jan 1, 1950

By P. R. Bradley

This paper gives a brief history of the mining and milling operations in the Juneau gold belt, and a general description of the geology of the district, followed by a suggestive discussion of the general problem of sampling gold ores and a detailed description of the mining methods used in the Alaska Juneau mine. The paper indicates that variations in assaying ore similar to that from the gold belt are unavoidable on account of the erratic distribution of the gold. A caving system that accepts dilution was adopted for the Alaska Juneau mine; the ore is sorted and the final mill feed has nearly twice the assay value of the ore trammed. THE property of the Alaska Juneau Gold Mining Co., covering the Juneau gold belt for over a mile in length, consists of 136 claims and 24 mill sites; these are near Juneau, Alaska, in what is known as the Harris mining district.

Jan 3, 1924

By H. A. Schwartz, Wolfram Ruff

The spheroidal form of the temper carbon nodules in malleable cast iron and of the graphite mottles of "mottled" cast iron suggests that in both all the graphite in a given mottle or nodule grew from a single center of crystallization or nucleus. $ There is, however, a distinct metallo-graphic difference between the mottle and the nodule; the area of mother metal impoverished in combined carbon by the crystallization of graphite in a mottle is practically coextensive with the ramifications of the graphite, while the impoverished zone of metal corresponding to a given nodule is always larger, and usually much larger, than the approximately spherical mass of graphite crystals forming the nodules. Furthermore, the mottle probably is formed during freezing and the nodule almost always at a considerably lower temperature. Assuming that the nodules or mottles can be used as a measure of the existing nuclei (capable of germination) we propose to record certain observations as to the graphitizing reaction in the light of the number and habits of growth of these nuclei. The present authors, in cooperation with others'-', have reported upon various cognate aspects of the problem. The fact that temper carbon is a mass of flakes and not a solid granule has become well recognized since the introduction of an improved polishing technique8, 9, 10 for cast iron. The problem of deriving from the circular planar intercepts of a mass of spheres of varying sizes their number and size distribution in space has also been satisfactorily solved12, 13 Growth of Nuclei in White Cast Iron It has already been shown1, 3 that the progress of graphitization with time is usual1y consistent with the assumption that nodules grow in size

Jan 1, 1936

By Wolfram Ruff, H. A. Schwartz

The spheroidal form of the temper carbon nodules in malleable cast iron and of the graphite mottles of "mottled" cast iron suggests that in both all the graphite in a given mottle or nodule grew from a single center of crystallization or nucleus. $ There is, however, a distinct metallo-graphic difference between the mottle and the nodule; the area of mother metal impoverished in combined carbon by the crystallization of graphite in a mottle is practically coextensive with the ramifications of the graphite, while the impoverished zone of metal corresponding to a given nodule is always larger, and usually much larger, than the approximately spherical mass of graphite crystals forming the nodules. Furthermore, the mottle probably is formed during freezing and the nodule almost always at a considerably lower temperature. Assuming that the nodules or mottles can be used as a measure of the existing nuclei (capable of germination) we propose to record certain observations as to the graphitizing reaction in the light of the number and habits of growth of these nuclei. The present authors, in cooperation with others'-', have reported upon various cognate aspects of the problem. The fact that temper carbon is a mass of flakes and not a solid granule has become well recognized since the introduction of an improved polishing technique8, 9, 10 for cast iron. The problem of deriving from the circular planar intercepts of a mass of spheres of varying sizes their number and size distribution in space has also been satisfactorily solved12, 13 Growth of Nuclei in White Cast Iron It has already been shown1, 3 that the progress of graphitization with time is usual1y consistent with the assumption that nodules grow in size

Jan 1, 1936

By Read Winterburn

This study of the relationship of the accumulation and drainage of oil to the structural conditions in the Wilmington oil field is presented with the hope that the data contained herein will aid in efficient exploita-tion of other fields where similar conditions exist. It is also probable that the conditions observed in this field will enable accurate comparisons of various well-spacing programs as to efficiency of production and ultimate recovery. Formations in Wilmington Field Age Formation Thickness Lithology and Remarks Quaternary and Pleistocene. San Pedro 1000 t Fresh-water sands, gravels and clays Pliocene Upper Pico 800 t Alternating sands and silt- Stones Pliocene Middle Pico 0-200 ± Sands and siltstones Unconformity Pliocene Repetto 875-1150 Gray and green shales, silt-stones and sands at top grading to interbedded gray-ish brown shales and fine-grained sands toward bot-tom Miocene Puente 4100± Hard brown shales and sands. Sands are fine and uncon-solidated at top, becoming firmer and coarser grained toward bottom. Top por-tion contains layers of lam-inated diatomaceous shale Unconformity Schist The data included herein are not complete as to all areas and zones, being confined mostly to the area south of Anaheim Street. The sections presented are illustrative of edge-water conditions in the Terminal zone and Tar zone, but have not been extended down the structure far enough

Jan 1, 1940

By James E. Dunn

For several years, ground support at the Pitch uranium mine has been a serious headache to the management. The "moving" ground raised havoc with standard timber sets as well as steel sets. The author discusses this problem which has led to the adoption of heavy cribbing practices in drifts and raises.

Jan 6, 1961

By H. A. Buehler

The Ozark region occupies a large part of the southern half of Missouri, the northern portion of Arkansas and comparatively smalll areas in northeast Oklahoma, southwest Kansas, and southern Illinois. It is a roughly elliptical plateau which has been deeply dissected by stream erosion, and which slopes imperceptibly into the prairie regions to the north, east, and west, but which terminates rather abruptly along the Arkansas River on the south and Tertiary lowland to the southeast. The Boston Mountains extending for a distance of some 200 miles (321 km.) along the Arkansas River rise to an elevation of 2000 ft. (609 m.), forming the most prominent topographic feature of the region. The so-called St. Frangois Mountains in St. Frangois, Madison, and adjoining counties in southeast Missouri, form a prominent but more restricted topographic feature, the highest point rising to an elevation of 1800 ft. (548 m.). The remainder of the region is largely a plateau area varying from 800 to 1500 ft. (243 to 457 m.) in elevation. Stratigraphy The region is underlain chiefly by sedimentary formations, which outcrop in roughly concentric bands around a comparatively restricted area of igneous rocks in the St. Frangois Mountain district. Although located geographically near the eastern edge of the Osarks, the St. Frangois Mountains have apparently suffered the greatest orogenic movement and the lowest formations of the succession are exposed in their immediate vicinity. The various sedimentary formations of the region do not show any considerable metamorphism and have suffered little change since consolidation. With the exception of a few basic intrusions in Ste. Gene-vievg County and a pegmatite dike in Camden County, Missouri, there is no evidence of igneous action, since the first sedimentary beds were deposited.

Jan 1, 1918

By P. E. Doherty, R. S. Davis

Sub boundaries and micropores, as well as certain other imperfections, may be revealed in aluminum by the formation of pits on the surface during cooling from elevated temperatures. The pits are attributed to the condensation of vacancies from supersaturated solution. This "vacancy pit" phenomenon has been used as an etching technique for studying the structure of aluminum specimens grown from the melt. Three fundamental structures were studied: stria-tions, cells, and dendrites. Two types of striations, as well as a crosswise structure are reported. Mic-roporosity is observed to occur in the cell walls on freezing. Subboundaries between primary, secondary, and tertiary branches are observed in dendritic growth. A special case is cited in which cellular growth suppresses the formation of striations. SMALL, well-defined pits have been observed to form on the surfaces of electropolished aluminum specimens during cooling from elevated temperatures.' This phenomenon was attributed to the condensation, from supersaturated solution, of vacancies at particular points on the surface. It was shown that the amount of cooling required for the formation of pits increased exponentially with decreasing holding temperatures in a way that was consistent with the thesis that a critical supersaturation of vacancies was required for the pits to form. Pits do not form in the vicinity of certain imperfections, namely, subgrain or normal graind boundaries, phase boundaries, certain surface irregularities, and pores. The width of the pit-free region increases with decreasing cooling rate. This observation suggests that the imperfections in question are effective sinks for vacancies and that the pit-free region around them is material that is not sufficiently supersaturated with respect to vacancies to nucleate the surface pits during cooling.

Jan 1, 1962