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By G. Mellgren, O. Mellgren

The conductivity of a solution is often used industrially to control the salt concentrations of reacting systems, normally using electrodes made of glass fitted with platinised platinum electrodes. When a standard platinum conductivity electrode was used to control the acid fed to the leaching circuit for an ilmenite flotation concentrate at Titania, Norway, a deposit of calcium sulphate (containing some calcium phosphate) covered both the platinum electrode and the external glass fitting, rendering the electrode inefficient in the course of a few minutes. A new electrode consisting of a casing, two measuring tubes and an electrode stem is described and illustrated. A significant advantage of its design is that the useful range of conductivity measurement can be adjusted by adjusting the concentration of the electrolyte in the electrode. It has been in use at Titania for about four years with an electrolyte consisting of 0-1 n HCI. It is robust and demands little maintenance.

Dec 1, 1971

By F. G. Bell, S. E. T. Bullock

The investigation was undertaken as part of the environmental management programme that must be implemented on mine closure. It involved sampling and analysis of water from boreholes, the tin mine workings, trenches and pits as well as soil and dumps. Both ground- and surface water in the immediate vicinity of the mine was found to have been affected to varying degrees, mainly due to acid drainage from the pyrite dumps. Metal ions and toxic salts are taken into solution with increased acidity and precipitated in the soil when the pH rises again; there are concentrations of metal ions in the soils around the main dumps, but these do not seem to pose a major threat in a regional context. The low groundwater gradients, together with the dyke system in the vicinity of the main dumps and the impermeable nature of the Boschoffsberg rocks, make it unlikely that affected groundwater will migrate further than 1 000 m to the north and north-east. Nonetheless, it has been decided to remove the pyrite dumps

Dec 1, 1995

By Ruddle R. W.

Although copper has been smelted for many years, relatively small attempt has been made in the past to examine the fundamental physical chemistry of the processes involved. Therefore, technological developments apart, slow progress has been made with the development of improved or new principles of smelting. The methods at present in use in the majority of the world’s smelters are essentially those employed at the beginning of the present century; it is significant that many of the textbooks on copper smelting, written some 50 years ago, are still regarded as standard works. The book is divided into seven chapters. In the first the fundamentals of modern smelting processes are briefly outlined for easy understanding of the subsequent sections, while the next two chapters are confined to the more theoretical aspects of the constitution of mattes and slags. Some problems of considerable practical importance are discussed in the remaining four chapters; these are (1) magnetite formation, (2) copper losses during smelting, (3) the recovery of sulphur from the smokes produced during smelting, and (4) the elimination of impurities. A collection of thermodynamic data relevant to copper pyrometallurgy is presented in an appendix, and, for the convenience of readers not well acquainted with thermodynamics, a brief explanation of the thermodynamic terms and methods employed is given in a second appendix

Jan 1, 1953

By V. Distler, E. F. Stumpfl

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The massif contains large chromite bodies of "Alpine-type", ophiolitic affinity. Orebodies reach thicknesses of 150 m and sizes of more than 150 000 000 t chromite ore with average grades of 55-60 wt% Cr2O3. Chromites in the Main ore field are low-Al, high-Cr spinels which exhibit some variation in their Mg-Fe distribution. This differs markedly from high-Al spinels in peridotite host rocks and in narrow chromite pods which occur in the western and northern parts of the massif. Chromites carry silicate inclusions, often hydrous silicates such as amphibole. Chromites in massive chromitites contain micron size inclusions of platinum group minerals (PGM). Composite grains containing two PGM and, occasionally, a hydrous silicate are common. Os-Ir alloys rimmed by PGM sulpharsenides occur in narrow serpentine veinlets that cut chromite and are evidence for the reconcentration of PGE concomitant with introduction of As, probably during serpentinisation. Whole-rock PGE contents are highest in massive chromitites of Diamond Pearl mine (totals of 500 ppb). Chondrite-normalised PGE patterns of chromitites show negative slopes which are typical for ophiolitic, podiform chromitites in mantle sequences. The PGE patterns of host rocks are flat and rather depleted compared with those of chondrites and chromitites. Petrological data from unaltered host peridotites suggest a high temperature overprint leading to sub-solidus re-equilibration of olivine and spinel and to the growth of pargasitic and edenitic amphiboles

Jun 16, 1905

By D. H. Watkinson

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Part of the contact of the 4b orebody with the enclosing Murray granite is characterised by the presence of recrystallised and biotitic Sudbury Breccia; in places the contact is faulted and sheared. In other areas of the contact partly silicified granite contains disseminated chalcopyrite and quartz-chalcopyrite veins with other minor minerals. Both ore and veins contain platinum group minerals (PGM); predominant PGM are michenerite, kotulskite, merenskyite and sperrylite with Au, galena and Bi-tellurides. At some silicified-granite contacts Mn-rich garnets, some containing inclusions of PGM and quartz, are associated with biotite + epidote + stilpnomelane + quartz. PGM and Au also occur within Cl-rich biotite and ferropyrosmalite in massive sulphide and in siliceous ore. Quartz, chalcopyrite and feldspar in the contact rocks and in veins contain abundant, highly saline fluid inclusions. Studies showed that the fluids were trapped at intermediate temperatures. The 4b orebody is surrounded by a sheath of brecciated granite but is close to the Contact Sublayer. During and after emplacement of sulphide magma, saline formational fluid that was resident in the breccia interacted with hot massive sulphides in and near the Sublayer and remobilised Cu, Au and PGE. This fluid reacted with cooler rocks and ore in footwall fractures, enriching the 4b protore and producing the adjacent Cu- and PGE-enriched quartz veins. Exploration for Cu and PGE enrichment in footwall rocks of the Sudbury South Range is warranted not only in zones of magmatic ore in the Contact Sublayer but also in fractures and permeable units within Sudbury Breccia

Jun 16, 1905

By P. Danson, D. A. White, S. Bashir

Composite ion exchange materials made of SnO2, TiO2 and MnO2 can be used to remove radioactive contaminants from nuclear waste streams. In several cases their selectivity and capacity are enhanced by mixing hydrous silica into the matrix. MnO2-SiO2 materials are especially useful for a number of reasons, such as their selection of heavy elements over caesium. Distribution constants and determinations of exchange capacities show that in many instances the properties of the composites are better than those of the oxides alone, while the presence of a chelating agent has been found to reduce the uptake of nuclides considerably. Methods are being developed for the bulk manufacture of the materials. Further work on sorption mechanisms is required to explain anomalous results, particularly the variation in exchange capacity for different elements and the ability of the oxides to sorb colloidal material in alkaline solution.

Jan 8, 1992

By A. B. Holland-Batt

Deposition velocities play an important role in many fields of engineering and an impressive range of measured data has accumulated in the literature. Numerous workers have addressed the problems that are associated with the prediction of deposition velocity because of its particular relevance to the design of pipelines and pumping stations. However, despite this extensive effort, the calculation of friction heads still requires reference to experimentally based graphs to determine Durand factors and there is still scope for improvement in the prediction of the deposition velocity at different solids concentrations. Equations to characterise the relationship between the Durand factor and the volume concentrations of solids in the slurry are presented. A correlation for the prediction of the deposition velocity is also developed and tested against some of the classical experimental data. The application of predicted values of deposition velocity in assessing the potential for the sanding-up of spiral separators is then described and a case study is presented.

Jan 12, 1992

By G. I. D. Roach

The leaching, with hydrochloric, sulphuric and perchloric acids, of suspensions and massive specimens of different haematite and goethite samples has been studied. Both accelerating and constant types of leaching curves have been observed. It is concluded that the grain to particle size ratio of the oxide being leached determines which type of leaching curve is obtained, particles containing a large number of individual grains producing the accelerating type of curve

Dec 1, 1971

By H. B. Bell, L. C. Smith

Measurements have been made of the activity of 'FeO' in 'Fe0'-Mn0-Ti02 melts at 1475 degrees C. The results obtained are discussed in terms of ideal mixing of titanates and in terms of a regular solution model. On the basis of the regular solution model activities of Ti02 and MnO in the Fe0-Mn0-Ti02 and Mn0-Ti02 systems have been derived. The data have been shown to be consistent with the liquidus lines in the phase systems. Examples are given of the application of the data to slag-metal equilibria, being used to derive slag-metal data between liquid iron and Fe0-Mn0-Ti02 slags

Dec 1, 1971

By Gibson J.

The writer hopes to prove that the economical tram is of even greater importance than, say, the economical engine, and as no difficult and involved calculations are required, and all the governing facts are simple and well known, the former is more easily attainable than the latter. In the first section of this paper the factors that determine the size and the construction of the tram are examined; whilst in the second section the road on which it runs is dealt with

Dec 1, 1916

By T. J. White, R. A. Farnfield

Early computerised blast monitoring equipment consisted of a digital version of the existing analogue machines with, perhaps, a few enhancements. Many additional facilities have since been developed to enable the efficient collection of high quality data. These developments are examined with reference to digital sampling, triggering systems, the storage of complete recordings and signal processing. Recent advances have been made in the use of blast monitoring systems that comprise multiple blast monitoring locations with centralised control and data collection. Software has been developed to help record blast parameters and assess environmental effects. Computer databases have many advantages over their paper counterparts. Data can be easily retrieved and processed. The scaled distances used in the prediction and control of peak particle velocities can be calculated rapidly when the data are obtained directly from a database. Since the whole vibration signal can now be recorded, signal processing can be used to provide information such as signal length, dominant frequency and response spectra.

Jan 4, 1993

By T R. Marrero, J W. Wilson

This paper presents costs for a coal log pipeline that can transport coal over distances from 50 km to 1500 km. The coal log pipeline (CLP) concept is a new technology in w hich coal is compacted into water impermeable circular cylinders that can be suspended in water flowing through an underground pipe. CLP includes processes to prepare the run-of-mine coal for compaction, the injection of coal logs into a pressurised water-lilled pipeline, the conveyance of the coal through a pipe including special pumping stations, and the treatment of the coal logs and water at the pipeline outlet. An 8 inch (203 mm) pipeline can transport more than 2 Ml of coal per year. CLP components have been extensively tested in bench-scale facilities where these tests have included start up/shutdown steady state flow behaviour, end of pipeline treatment of water and coal log handling, water hammer effects, abrasion of logs and pipeline, coal log manufacture, and other engineering operations. Several sites are being considered in the United States (US) for the first commercial demonstration that will probably take place in 1998. The cost calculations are based on realistic values for all the components of a CLP. including a return on investment. For pipelines of different diameter, values for coal transportation are presented in terms of $(USVtonne as a function of distance.

Jan 10, 1996

By P. Rama Krishna, B. Narasimha Rao, P. Ali i Peera

Induced polarisation (IP) surveys are commonly used in uranium exploration programmes in India. The IP method is effective in detecting the disseminated metallic sulphides that are often associated with uranium minerals. However, conductive and polarisable host rock or overburden often introduces inductive or electromagnetic (EM) coupling into time domain IP measurements. This makes it difficult to distinguish between responses due to such coupling and those that might indicate economic mineralisation. Attempts must be made to remove the EM effects before the IP technique is used in drilling programmes. Transient decay curves which were recorded during field surveys at Pisnari were factorised using the Marquardt algorithm. Dispersion plots of the amplitudes and relaxation times of the composite exponential function enable a clear distinction to be made between the effects of EM coupling and those of mineralisation.

Jan 4, 1993

By R. W. Ruddle

"Besides copper, iron, silicon, and oxygen, a large number of elements may be present in copper ores, the more important of which are zinc, lead, arsenic, antimony, bismuth, selenium, tellurium, nickel, cobalt and the precious metals; impurities of less importance are calcium, magnesium, aluminium, barium, sodium, potassium, manganese, lithium, fluorine, titanium, uranium, vanadium, tin and molybdenum. All of these elements are eliminated to some degree in the subsequent roasting, smelting and converting operations.Information on the elimination of impurities during the smelting of copper is surprisingly meagre, however, rather more information is available on impurity removal during the smelting of the ore in reverberatory or blast furnaces."

Jan 1, 1953

By A. Hemami

In order to automate the operation of mechanical loaders it is essential to have a knowledge of the forces that act on the bucket and of the trajectory that the bucket should follow. A trajectory for the cutting edge of a bucket is derived from studies of the forces acting during the scooping phase. The proposed trajectory has a minimum energy consumption and is simple to automate. It is determined initially by setting to zero certain components of the resistive forces to the bucket motion which would otherwise result in unnecessary work and consequent energy wastage. The method for finding the appropriate trajectory is discussed on the basis of the properties of the material to be loaded and the loader size.

Jan 4, 1993

By M. Thompson, B. Coles, M. Hale

The use in regional geochemical reconnaissance of replicate analysis of natural coatings of iron and manganese oxides on the surface of pebbles in stream sediment is described. Pebble coatings were selectively analysed for their relative contents of absorbed trace elements by ablating a small quantity of the coating with a laser beam and sweeping the aerosol obtained into an inductively coupled plasma atomic emission spectrometer. Using this procedure, a geochemical survey in northwest Wales revealed anomalous concentrations of Cu, Mo, As, Zn, Cd, Pb and Co in the pebble coatings of streams draining the mineralised Coed-y-Brenin diorite and the Dolgellau gold belt.

Jan 4, 1992

By J. R. Budden, P. A. Spencer, J. Barrett

The initially produced arsenic (III) is very toxic to the unconditioned culture but the mixed culture has the capacity to oxidise it to arsenic (V) in the presence of iron (III). It was possible to build up the resistance of the culture through progressive sub-culturing on arseno-pyrite until it could tolerate steady-state concentrations of 30 mM arsenic (III) and 200 mM arsenic (V). With some samples tested in the continuous systems the final arsenic concentrations reached 330 mM. It proved possible to use the laboratory batch data to establish the optimum operating conditions for continuous test systems with capacities of up to 32 m3. Data on the residence time, oxygen uptake rates and gold extraction from the bio-oxidised residues could then be confirmed by continuous testing without the need first to use empirical means to determine optimum conditions for continuous bio-oxidation. The data on residence time, oxygen uptake rate, solids density and neutralisation could be used to estimate the capital and operating costs of treating any given tonnage of the concentrate of interest. It was established that the arsenopyrite concentrates can be suitably bio-oxidised to cause the liberation of at least 90% of the gold content. The method is simple to operate and is flexible over a wide range of external conditions

Apr 1, 1991

For the convenience of those who are unfamilar with thermodynamics, the following brief description and explanation is given of the thermodynamical terms and methods used in this book. It must, however, be strongly emphasized that the account given below is not an introduction to chemical thermodynamics; its sole purpose is to give the reader a rough understanding of the methods used in the earlier chapters. For further information, reference must be made to the standard textbooks on chemical thermodynamics by Glasstone.

Jan 1, 1953

By D. F. Ball, P. R. Dawson, J. T. Fitton

Report of discussion at December, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, September, 1970, pp. C189-96, plus the authors' replies. Contributors included Cohen E., Hope B., Wasse D.G., Shakespeare A.G., Burwood D.S., Jones H.A., Dartnell J., Carter G.C., Henderson T.A., Relf G. and Clark S.W.

Dec 1, 1971

By B. H. Smith

"Most of the discoveries of nickel sulphide deposits in Western Australia have followed the search for gossans. The chances of further discoveries depend on improving our understanding of the cover of strongly leached and transported materials that obscure approximately 85% of the area of the Yilgarn Block that has nickel sulphide mineralization potential. The lateritic profiles that are observed on the Yilgarn Block today were formed over a period of more than 100 m.y. of warm and humid climates. This lateritized land surface has been preserved by induration during subsequent arid climates as well as by the structural stability of the Yilgarn Block.In geochemical surveys of lateritied terrain samples have to be taken from at least the saprolite zone usually by drilling so that confident predictions can be made of the significance of analytical data. Account must be taken of the mineralogy of samples, as well as the nature of the horizon of a laterite profile that is being sampled, owing to the concentrating effects on trace elements of Fe and Mn oxides.Multivariate techniques have been applied successfully to analytical data in gossan recognition when textural evidence is ambiguous. Pathfinder geochemistry has also been used in gossan recognition and the most significant recent advance has come from studies of platinum group metals in nickel sulphides and their dispersion during weathering."

Jan 1, 1984