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By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company's plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By Gordon W. Hines

This paper, dealing with network planning in an industrial complex, discusses the type and size of project that can be handled on a manual basis. After a review of the fundamentals of network planning, and specifically of the Critical Path Method, the author analyses several different types of projects, each with its own characteristics. Some can be handled in conjunction with a computer, but others can be dealt with equally well without one. Among the projects discussed are a blast furnace reline, the installation of a billet mill flying shear, and routine maintenance-type operations.

Jan 1, 1967

By Marcio Luis S. Godoy

The Salobo Project will be the first Vale operation to use an HPGR mill to process copper-gold ore. The mine is located in Para state, southeast of the Amazon region in Brazil. The circuit was designed to treat 12 million metric tons per year of finely disseminated sulphide ore with high hardness. The comminution circuit comprises a gyratory primary crusher, secondary crushing utilizing two cone crushers, two 2 x 1.5 m HPGR operating in closed configuration with 6 mm screens, followed by two 26 x 40 ft ball mills. The concentration circuit consists of two rougher flotation stages using mechanical cells, regrinding with vertical mills, three cleaner stages with columns and one cleaner scavenger stage in mechanical cells. The concentrate is dewatered, filtered and transported by trucks and train to the port, to be exported. The circuit was designed on the basis of data obtained from a comprehensive laboratory and pilot plant campaign. The ore variability was assessed through simulation using data from a drilling core characterization program. The start-up of the industrial plant is planned for 2011. This paper describes the main aspects of circuit design, as well as information related to the beginning of the project construction.

May 1, 2010

By W. Leblanc, J. C. Marsh, D. Kettle, J. Tompkins, G. Hartley

"The Lingan Mine is the newest of the four operating collieries of the Cape Breton Development Corporation and is located on the east coast of Cape Breton Island. Development of slopes began in 1969 using four Dosco Roadheaders. Production commenced in October 1972, when a partial extraction section utilizing a continuous miner, loader and shuttle car was installed. A second Joy unit is scheduled to begin production early in 1973. This paper describes the production and development operations, the ventilation system and the equipment in use at the mine."

Jan 1, 1973

By C. Riveros, H. Henein

Bulk Metallic Glasses have a high potential as advanced engineering materials due to their various properties including strength and corrosion resistance, to name a few. This paper investigates amorphous phase formation and rapid solidification characteristics of impulse atomized Co-based alloys in order to understand and control the application properties of the final products. Amorphous fraction and kinetic crystallization properties of the atomized Co-based alloy powders were quantified by means of Differential Scanning Calorimetry. In addition, different but complementary characterization tools were used to analyze microstructures of the powders. These include optical microscopy, X-ray diffraction and micro-hardness tests. While the amorphous fraction within the powders is promoted by high cooling rate and smaller powder size as expected, hardness is found to decrease with the fraction of amorphous phase.

Jan 1, 2015

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

By A. G. Lylie

Introduction At the Britannia Mining and Smelting Company's mill, the equivalent of 2,500 to 2,800 pounds of copper sulphate crystals per day is made from copper which is precipitated from the mine-water. This copper sulphate is used in the mill for the recovery of sphalerite by2 flotation. From 1932 until 1936 it was produced by exposing the precipitate to air for thirty days and then dissolving the oxidized copper with dilute sulphuric acid. In 1936, the flotation of sphalerite was discontinued and, when it was resumed in 1947, steps were taken to try to improve the former method. The present paper outlines the way in which this was done, and describes the plant and procedure by which copper sulphate is now being made, and by means of which an appreciable saving is being effected. Aboratory Tests The previous work had established that the precipitate, which consists mainly of metallic copper, must be oxidized before the copper would dissolve in dilute sulphuric acid. Various methods for oxidizing it were tried but in the early laboratory work the only suitable one found was to heat the precipitate to 600°C. and hold it at this temperature for two hours. When this was done, approximately 90 per cent of the copper became soluble in .acid. This percentage was considered satisfactory for practical purposes, but the cost of roasting was prohibitive because only a small amount of roasted precipitate was required each day.

Jan 1, 1951

By JOHN H. HUDSON

Ceramic clays of the Prairie Provinces range in age from Lower Cretaceous to Pleistocene and Recent. Two significant ceramic clay horizons are the Paleocene Willo wbunch Member of the Ravenscrag Formation in Southern Saskatchewan and the Upper Cretaceous Whitemud Formation, which is found in Saskatchewan and Alberta. The Willowbunch Member is worked at one locale in Saskatchewan; the Whitemud Formation is worked at several locales in Saskatchewan and Alberta. Bentonite operations are found at Morden in Manitoba, Rosalind and Onoway in Alberta, and Wilcox in Saskatchewan.

Jan 1, 1984

By M. Rafieazad, P. Fathi, M. Mohammadi, A. M. Nasiri

This study examines the impact of low-temperature heat-treatment cycles on microstructure and corrosion performance of Direct Metal Laser Sintered (DMLS) AlSi10Mg_200C alloy. It is known that the morphology and the size of eutectic silicon are the two most critical factors affecting mechanical properties of the AlSi10Mg alloy. Although high-temperature heat-treatment cycles are common practice for the strengthening of the cast Al-Si-Mg alloys, in the case of DMLS fabricated AlSi10Mg alloy, high-temperature solutionizing and low temperature annealing cycles result in mechanical properties degradation primarily due to a dramatic decrease in the solubility of Si in the super-saturated a-Al matrix of the as-printed alloy. In this study, low-temperature heat-treatment cycles that only promote precipitation of Mg2Si accompanied by the interruption of the silicon network were investigated. SEM and XRD analysis were utilized to observe the evolution of microstructure after different annealing heat-treatments at 200, 250, 300, and 350°C for 3 h. Increasing the heat-treatment temperature contributed to the Si networks interruption and an increased precipitation of Mg2Si phase. Low-temperature annealing from 200 to 350°C was found to promote the homogeneity of the microstructure characterized by a uniform distribution of eutectic Si in ??-Al matrix. Additionally, in order to investigate the impact of different heat-treatment cycles on corrosion resistivity of DMLS-AlSi10Mg_200C, the potentiodynamic polarization testing and electrochemical impedance spectroscopy were performed in a 3.5 wt.% NaCl solution. The results revealed more uniformly distributed pitting attack on the corroded surface by further increase in the annealing temperature, which was attributed to the uniformity of Si dispersion. In comparison, low temperature annealing at 200°C led to a penetrating selective corrosion attack along the melt pool boundaries, resulting in a higher corrosion rate associated with the lower absolute value of impedance of the protective passive film on the surface.

Jan 1, 2018

By R. S. Douglas

Introduction During the past few years, a number of changes in the mine operations at Copper Mountain have taken place. The modernization and mechanization were necessitated and given impetus by wartime and other conditions, which were: (1) The urgent need for copper for wartime purposes. (2) The scarcity of skilled labour for underground work. (3) The increase in labour and supplies cost. (4) The necessity of finding ways and means of increasing the output per man-shift, because of the scarcity of skilled labour and the rising cost of labour. (5) The desire to increase safety measures, reduce the silicosis hazard, and aid mine ventilation. (6) The desire to improve the general working conditions in the mine for all workmen. (7) The desire to reduce the amount of dilution in the ore stream by a more selective yet highly productive method of mining. To this end, mining with diamond drills, and transferring broken ore with slusher hoists, appeared to be the answer to the problem. After considerable discussion and estimation of costs for comparison with those of the operation as carried on at that time, the proposed methods were tried out and, in practice, gave very gratifying results. Reference at this point is made to the paper written by C. H. Brehaut, W. N. Taylor, H. A. Shannon, and R. S. Douglas, which was published in the September, 1945, issue of Mining Technology, by the American Institute of Mining and Metallurgical Engineers, Inc., and subsequently in commercial mining journals. Since that time some improvements have been made in undercutting an orebody - the first through experiment and practice, the second through making use of the earth's barodynamic or gravitational forces. It is the purpose of this paper to describe and discuss these later developments.

Jan 1, 1947

By H. M. Lewis

The current status of the international zinc market is summarized, and a supply /demand outlook is presented for the next five years. A number of technical problems facing the industry are outlined. Introduction ZINC has sometimes been called the unknown metal. Considering that on a world basis it ranks third among non-ferrous metals in production and consumption, zinc retains a certain modesty. It has no distinctive colour like copper, lacks the low density of aluminum or magnesium and is not always easy to identify as a product. The 'spangle' of galvanized steel is probably zinc's most distinguishing feature. The purpose of this article is to develop an over-all review of zinc. Starting with the current position of the metal, the major factors that will shape its future will be described so that an assessment of the outlook for zinc can be made.

Jan 1, 1978

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By J. E. Hawley

Introduction The Siscoe gold mine is the most easterly producer of gold from deposits lying in the belt of Keewatin and Timiskaniing rocks which extends east from Kirkland Lake, Ontario, and on through the Rouyn copper area. Unlike many of the deposits in this belt, those of Siscoe are contained almost entirely in a stock of much-altered granodiorite which intrudes Keewatin lavas. They are situated on an island of about one square mile in area, lying in lake De Montigny, Dubuisson township, 40 miles south of Amos, on the Transcontinental branch of the Canadian National railways, and 52 miles east, and slightly south, of Noranda. Geographically, the deposits are favour-ably situated with respect to transportation facilities, a through water-route being available from Amos, along the Harricana river and its lake expansions. The deposits consist of auriferous quartz-tourmaline veins of the fissure-filled type and are of particular interest because of their geological structure and genesis. Furthermore, deposits of a similar type occur both in the Keewatin and in granodiorite bodies to the east, in Dubuisson, Bourlamaque, Pascalis, and Louvicourt townships, and it is hoped that the following discussion may be of some aid in the exploration work now being carried on throughout this general area.

Jan 1, 1932

By P. Lind, A. Gagnon

"Goldcorp has embarked upon an ambitious, industry-leading, multi-year water use reduction effort. This is a proactive, voluntary effort that reflects our commitment to truly sustainable mining. This effort will focus on increasing water re-use and recycling, and reducing water inputs ultimately towards zero. All of our operating mines are expected to contribute to this effort and are currently in the process of developing plans to meet short and long term objectives. One of the largest needle movers to increase water re-use and recycling is in the area of tailings management. Within five to ten years at Goldcorp, it is envisioned that the need for wet tailings dams will be eliminated and that all new tailings facilities will consist of only filtered or dewatered tailings. Filtered tailings is developing into a mature technology with wide application in mine waste management. This paper describes a conceptual level evaluation on the transition from a slurry to a filtered tailings operation at the Cerro Negro mine in southern Argentina. Key benefits and challenges are highlighted.INTRODUCTION Goldcorp’s Cerro Negro operation is located in the Santa Cruz province in the Patagonian region of Argentina. Cerro Negro has been in operation since 2014 and commercial production was achieved on January 1, 2015. The processing capacity of the plant is 4,000 tonnes of ore per day and in 2016 produced 363,000 ounces of gold and 3.1 million ounces of silver (Goldcorp Inc., 2017). As the mine is located in a semi-arid area, it is important to evaluate technologies that could reduce freshwater consumption and maximize water re-use and recycle rates. The current tailings operation at Cerro Negro incorporates pumping of tailings slurry into a conventionally lined Tailings Storage Facility (TSF). Water is reclaimed from the tailings supernatant pond to the process plant via pumps, however, water losses occur due to evaporation and solution retention within the slurry tailings voids. Converting to a filtered or dewatered tailings operation would allow for increased water recovery prior to tailings disposal, and decreased water losses from evaporation and from retention in the tailings solids void space. This paper describes a conceptual level evaluation on the transition to filtered or dewatered tailings with the primary objective of moving closer Towards Zero Water."

Jan 1, 2017

By C. Butcher

Numerical simulations of straight tube hydroforming of a dual phase steel were performed using both upper and lower bound constitutive models for porous ductile materials. The Gurson model is based upon an upper bound approximation to the material behavior and thus overestimates formability. Conversely, a lower bound solution to Gurson's unit cell geometry was developed by Sun and Wang to provide a conservative estimate of formability. The effect of a compressive axial load (end-feed) on damage development and tube formability is investigated. The resulting upper and lower bound models successfully captured the experimentally determined burst pressure, formability and failure location.

Jan 1, 2010

By Rick J. Chalaturnyk

In Alberta, oil sands bitumen is utilized for synthetic crude oil production by surface mining, bitumen extraction followed by primary (coking) and secondary (catalytic hydrotreating) upgrading processes, or by catalytic hydrocracking and hydrotreating replacing the primary and secondary upgrading processes. Oil sands tailings, composed of water, sands, silt, clay and residual bitumen, is produced as a byproduct of the bitumen extraction process. Several processes have been proposed for the treatment of oil sands tailings, resulting in different recovered water characteristics, consolidation rates and consolidated solid characteristics, which may have effects on the performance of the overall plant operations. A process for the same purpose has been developed by treating the oil sands tailings with CaO lime and CO2 and thickening it using a suitable thickener. In this process a release water of acceptable properties is recovered in a short retention time, which makes it possible to recycle the recovered water, probably after a reconditioning treatment, as warm as possible to improve the thermal efficiency of the extraction process. The paper presents the theory and laboratory results for the CaO and CO2 thickening of low temperature flotation tailings. The water release rates, segregation potential of the thickened underflow and chemistry of the release water are shown and discussed. It is suggested that in using the proposed process, the thickened tailings underflow can be disposed for further consolidation, or combined with the coarse tailings to produce Blended Composite Tailings, corresponding to the Composite Tailings process in the existing hot water extraction plants.

May 1, 2002

By Chris Dougherty

"This presentation will provide a demonstration of the methodology used in designing a modern shaft and hoisting plant utilizing a review of the challenges faced and solutions delivered for the Elk Creek Superalloy Materials Project (Niobium/Scandium). The development of the design required the review of complex hydrogeological conditions, mine production requirements, demanding capital expenditure (CAPEX) limitations and tight schedules. Through an extensive review of various alternatives to satisfy these constraints, the Nordmin Group (including Nordmin Engineering Ltd.) (Nordmin) was able to define a concept and design that addressed risks to the project, met production requirements, cost and schedule constraints and improved constructability. INTRODUCTION The Elk Creek Project, owned by NioCorp Developments Ltd. (NioCorp) presently, will become Nebraska’s first underground metals mine, built to access the Elk Creek Niobium/Scandium deposit. The development of the design for this facility required the review of challenging hydrogeological conditions, mine production requirements, demanding CAPEX limitations and tight schedules. Through an extensive review of various alternatives to satisfy these constraints, the Nordmin Group was able to define a concept and design that addressed risks to the project, met production requirements, cost and schedule constraints and improved constructability. This paper will review the challenges faced, and solutions arrived at in a demonstration of a methodology used in designing a modern shaft and hoisting plant. THE CHALLENGES Nordmin became involved in the project in 2015, invited by the Feasibility Study Consultant to provide input on estimating and layouts for the new operation. Many of the fundamental decisions regarding mining methodology, water handling and production strategy had been made, and the scope of Nordmin’s involvement was very limited in this first engagement. Following submission of that study in late 2017/early 2018, Nordmin had opportunity to discuss the overall effort, and its many assumptions and challenges, with NioCorp’s project team. The dialogue quickly identified several significant opportunities to improve the project construction schedule and costs along with the mine production profile and operational approach while reducing project risk."

Jan 1, 2019

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By S. S. Sephton, Kirit C. Vyas, Melvin J. Greaves

Energy requirements for various pelletizing systems are considered from a fuel and power aspect, with the presentation of typical energy heat balance flow sheets. A partial calculation for the firing zone of a straight grate system is shown and a comparison of an actual measured and a theoretical-calculated heat balance for a grate-kiln is presented. The power used for each pelletizing system and future possible energy savings a1•e also reviewed.

Jan 1, 1976

By J. E. Hawley

Abstract Spectrographic methods for the analysis of minor constituents such as platinum-group metals, gold, silver, and silica in palladium and platinum refinery sponge are described. These involve the conversion of the sponge metals to the black form by reduction with high purity aluminum filings in either acid or alkaline media. Standards of known composition are prepared in the same manner from either refinery or spectrographically standardized sponge metals. Samples of the black metals are mounted in pellet form and a multisource spark discharge used for excitation. The range of concentrations of impurities studied are those common to refinery samples. Excellent reproducibility of intensity ratios using major constituents as internal standards, is demonstrated and two methods have noted by which the accuracy of the procedures are shown to be of the order of 3 per cent, on the basis of synthetic preparations. Introduction During the past two years an investigation has been carried out in the Spectrographic Laboratory, Queen's University, to determine the suitability of modern spectrographic techniques for the precise analysis of the platinum-group metals palladium, platinum, rhodium, iridium, and ruthenium in the form of refinery sponge analyzing about 99 per cent of the major constituent.

Jan 1, 1951