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By D. E. Pollock

Recent NIOSH published information has shown an increase of rapidly progressive coal workers? pneumoconiosis (CWP) in the southern Appalachian coal region (SAR) of the U.S., despite the fact that compliance data indicates that most coal miners have been exposed to coal mine dust concentrations below the statutory limit of 2.0 mg/m³. While the exact cause of these elevated CWP levels in the SAR has not been established, several factors may be contributing to the increase in occupational lung disease among coal miners. The mining of high rank coal is known to lead to higher CWP rates, and this type of coal is mined in a portion of this region. Also, a high percentage of the mines in the region are on reduced dust standards because of the high silica content of the airborne dust resulting in miners possibly being exposed to excessive amounts of respirable silica dust. Exposure to excessive amounts of respirable silica dust can lead to silicosis, a disabling and potentially fatal lung disease. NIOSH's Respiratory Hazards Control Branch has been investigating the possible causes that would account for the observed higher trends in disease progression through literature review, data analysis, and in-mine surveying. The investigation to date has revealed that underground mines are faced with cutting large amounts of rock in order to maintain haulage clearances. Cutting rock not only increases the potential for silica exposure, it increases the requirement for machine maintenance which was a concern observed during dust surveys conducted by NIOSH. Over half of the mines operating in the SAR are on reduced standards due to high silica content. Adequate face ventilation of the continuous miner and roof bolter and limited down-wind operations from the miner are also issues of concern and items which require the constant attention of miners operating in these conditions. Disclaimer: Mention of any company or product does not constitute endorsement by the National Institute for Occupational Safety and Health.

Jan 1, 2009

By A. A. Berk

Other Federal agencies have been coming to the Bureau of Mines for help with the purchase and utilization of fuel, largely coal, almost since the day the Bureau was created in 1910. The requests covered a wide range of fuel-economy problems and included boiler-water treatment after it became apparent that water-formed deposits on heating surfaces acted as insulators, decreasing heat transfer and impairing fuel efficiency. Dr. Ralph E. Hall, a Bureau of Mines physical chemist determined the reactions that cause adhering scale to form in boilers (7)2 and went on to introduce scientific principles into water treatment for scale prevention (8). Widespread publicity of these achievements increased the requests for help from Federal steam-generating plants. Since no other Federal agency (even those which were more directly concerned with testing water) wanted to provide boiler-feedwater service, the Bureau decided to continue to give requested help to Federal agencies, Later, the Congress endorsed such agency cooperation as an economy measure,

Jan 1, 1963

Development of Grindability Tests Based on Direct Measurement of Energy Nowadays, for the characterisation of the grindability different grindability indices - Bond-work index (Wi), Hardgrove Grindability Index (HGI) or Zeisel specific grindability (Wt) - are used. Generally, the grindability tests are carried out under relatively simplified circumstances, in a special dry batch mill with defined feed size material until prescribed conditions are reached at room temperature. However, in the fine- and ultra fine grinding, which is a frequent task (fly ash, tailings, alumina, etc), a fine material (<50 - 200 ¦m) is usually ground down to the few micrometers. The conventional grindability testing methods and apparatuses (Bond-, Hardgrove-, Zeisel-processes) for their determination, although, are not suitable directly to measure the grindability of such fine materials, since the maximal particle size of the feed material (0.5 - 3 mm) to be tested is much higher. One of the important goals of the research carried out in our Institute was to develop the novel grindability testing methods, which are suitable for the fine and ultra fine grinding, and additionally provide the possibility for the fast determination of the grindability. In order to realise the above aim the conventional Bond- and Hardgrove- mills were modified in order to directly measure the grinding work. In particular, the Hardgrove-mill was equipped with a simple torque-meter (load cell). The Bond-mill was rigged with a digital electric power measurer. The systematic experiments were carried out parallel in both mills using the conventional and the developed methods. Finally the results of both were compared. The measuring results have proved that the Bond-work index can be determined based on the developed methods. The new grindability testing methods were applied successfully in several industrial research tasks for the determination of the specific grinding energy and the Bond-work index. These methods can be also used in the industrial practice for the control of the grinding process.

Sep 13, 2010

By J Player, P Mikula, G Sweby

A numerical modelling back-analysis exercise was carried out at a WA gold mine at which early signs of seismicity (rock noise, scatts from active faces) were becoming apparent as depth of mining increased towards the 500 m mark. Some strain bursting had occurred and it was necessary to discover what the implications of this were for greater depth. The aim of the modelling was to: 1. Establish a correlation between observed ground conditions and model predicted damage, in overstressed areas of the mine. 2. Use this correlation to forecast rock mass damage and ground control requirements for proposed future stoping panels at greater depth. Good correlation has been achieved between observed rock mass damage, and a 3D Finite-Element RS3 model, run in elastic mode. Two candidate stress field orientations were modelled. The model parameter best fitting the observations was the Strength Factor (SF), the ratio of strength/stress. The good match (correlation coefficient of 0.7) between observed and modelled suggests that the elastic approach is justified for the depth range and rock mass properties analysed. The correlation also enabled a link between observed damage and installed ground support performance. Using the linear best-fit between observed and modelled, a forecasting exercise was carried out using the same RS3 model, modified to include future stoping. The resulting damage and ground support categories were obtained from the modelled SF for each proposed stoping level. Also, a series of generic geometries was assessed to investigate the impact of varying stope face lead/lag distance, sill pillar height and stope pillar size, on ground conditions. The key finding of the generic geometries were: • Ground support schemes have been defined for the expected conditions. • All ore drives are expected to have significant damage in the backs and rehabilitation. • Lead/lag distance not to exceed 10 m. • Sill pillar/level intervals of less than 20 m require an increase in ground support scheme. • Pillar sizes for maintaining footwall and hanging wall stability should be at least 10 m × 5 m.

Nov 29, 2022

By Andrew Thallisson de Souza

Os aços inoxidáveis ABNT da série 300 são ligas austeníticas Fe-C(< 0,08%) - Cr(18 a 20%) - Ni(8 a 10%) são muito aplicados, pois apresentam alta estampabilidade, alta soldabilidade, boa resistência à corrosão uniforme em vários meios corrosivos, no entanto, sofrem corrosão localizada (pites, corrosão sob tensão, fresta e corrosão intergranular). Os aços inoxidáveis da família UNS S32304, têm 23%Cr e 4%Ni. Por terem teor de carbono inferior a 300ppm (0,03% em massa) são resistentes à corrosão intergranular, sofrem pites e corrosão sob tensão (CST). Devido ao alto teor de cromo, o aço UNS 32304 apresenta boa resistência à corrosão uniforme, sendo que na corrosão por pites o mesmo apresenta um comportamento melhor que os aços ABNT 304 (sem Mo) e ABNT 316 (com Mo), de acordo com o Número Equivalente de Resistência ao Pite (PREN). O PREN dos aços UNS 322304 é 26, e para os aços ABNT 304 e 316 são 18 e 25, respectivamente. Este trabalho caracterizou os diferentes aços inoxidáveis química, metalográfica e eletroquimicamente em meios contendo íons cloretos. A partir de ensaios de caracterização eletroquímica, por polarização potenciodinâmica, verificou-se que o aço ABNT 304 apresentou potencial de pite inferior aos aços ABNT 316 e o UNS 32304, em soluções aquosas contendo 3,5% (massa) de NaCl. Verificou-se que estes aços sofreram CST empregando-se ensaios de deformação (corpo de prova em U) e carga constante (corpo de prova de tração liso) nos eletrodos em soluções aquosas contendo 42% (massa) de MgCl2 na temperatura de aproximadamente 143°C. Salienta-se que o comportamento em CST do aço ABNT 304 foi inferior aos demais. As amostras ensaiadas foram caracterizadas fratograficamente (macro e microfratograficamente - empregando-se microscopia eletrônica de varredura). Os corpos de prova que sofreram CST apresentaram facetas de clivagem e “marcas de rios”, características da fratura frágil.

Aug 17, 2017

By D. P. Nicholson

The current phase of office development at Canary Wharf in the London Docklands includes twelve multi-storey buildings varying from eighteen to forty stories in height. The area of Canary Wharf South comprises five multi-storey buildings with low level in fill podium and garden areas. Three of these multi-storey buildings have "pile-cap" designs where the entire building load is applied to the piles. The remaining two buildings have "piled-raft" designs where allowance is made in the design for part of the building load to be transferred to the raft formation. Using a piled-raft design approach has enabled savings to be made on the number of piles used below the raft. This paper describes the calibration analysis undertaken to validate the design method. The ground conditions at the Canary Wharf site are typically fill and recent gravel deposits over the overconsolidated clay and sand of the Lambeth Group. Below these strata is the Thanet Sand. The Lambeth Group provided the founding layer for the raft and contributed to the pile shaft resistance. The Thanet Sand stratum provided the bearing layer for the 1.5m diameter base grouted bored piles. The piled-raft design required an assessment of the building load transfer through the raft to the formation layer. This load transfer led to significant increases in effective stress in the soil below the raft and thence a corresponding increased the capacity of the piles. This interaction of the raft with the prepared formation contributed to between 27% and 45% increase in total vertical load carrying capacity of the piled-raft substructure compared with the pile-cap design method. The development of the piled-raft design was carried out in three main phases: ? Development of the approach and validation analyses. ? Design work on various schemes resulting in detailed design packages. ? Validation analyses using full 3D finite element analysis (presented herein). The validation of the piled-raft design approach was initially carried out against published case histories for piled-raft interaction. To improve on the validation work a full 3D finite element analysis of a simplified pile raft and superstructure (which contributes stiffness to the raft) was undertaken; the analysis included only a quarter of the structure due to assumed symmetry of the structure and vertical loading. This 3D validation analysis is presented herein. The analysis was carried out using the Oasys LS-DYNA finite element program. Prior to carrying out the analysis of the piled-raft an initial finite element analysis was carried out to back analyse a fully instrumented field pile test providing accurate modelling of a single pile performance. This back analysis allowed confidence in the soil parameters used in the 3D model; comparisons of shaft and base resistances between the pile test and the FE model calculations for the single pile are presented. The parameters provided in this work were then carried into the full 3D model of the piled-raft. The 3D model of the piled-raft structure included 18 piles (12 full piles and 6 half piles on an axis of symmetry of the model).

Jan 1, 2002

Sedimentary pyrites from Tasmania have Se contents that are high for it province showing no overall Se enrichment. Sulphides from Devonian granitic rocks, and related cassiterite-sulphide deposits, Sn-Wand PbZn-Ag fissure veins have similar and relatively low Se contents, and pyrites from Devonian gold-quartz veins have very low Se contents. The high concentrations of Se at Mount Lyell are consistent with enrichment in pyritic Cu deposits in volcanic rocks elsewhere, and the dispersion of Se is consistent with a surface volcanic origin for several of the orebodies. In contrast, sulphides from Cambrian volcanic rocks and associated granitic rocks, and from the Rosebery and Hercules pyritic PbZn deposits, also believed to be of volcanic origin, are impoverished in Se.In the Mount Bischoff cassiterite-sulphide deposits there is no relationship between Se content of sulphides and temperature of formation as indicated by fluid inclusion studies, and sulphides from Devonian ores with different temperatures of formation have similar Se contents.The Se content of Tasmanian sulphides appears to be an unsatisfactory discriminant of their genesis and temperature of formation but in volcanic terrains may be a useful pathfinder for Cu concentrations.

Jan 1, 1969

By James M. Spear

The U.S. Bureau of Mines and the U.S. Geological Survey conducted a mineral survey of the Elk Creek RARE II area during the summer of 1981. The study area encompasses 18,900 acres [29.5 sq mi (7,680 ha)] along Elk Creek, 18 mi (30 km) southeast of Covello, California. No mineral resources were identified by the U.S. Bureau of Mines during this survey. Assay results of samples taken in this area indicate only trace amounts of manganese and chromium. No radioactive or fluorescent minerals were detected. No oil and gas, coal, or geothermal leases have been recorded for the study area.

Jan 1, 1982

By M F. Jennings, N J. Corlis, B J. Thomas, L N. Tylkowski, A E. Petts, G D. McDonald

Flinders Mines is an iron ore explorer and developer with a tenement package located in the Hamersley Ranges region of Western Australia, approximately 70 km north of Tom Price. Exploration over the past five years has identified a Global Resource in excess of 900 Mt at a grade of 55.2 per cent Fe (+50 per cent Fe cut-off). This resource is spread across multiple deposits and has been divided into a number of mineralisation type domains. These domains are comprised of transported hematite rich detrital iron deposits (DID) and goethite dominant channel iron deposits (CID) as well as in situ bedded iron deposits (BID). The BID at PIOP is low in alumina and silica with a high calcined iron content making it an attractive exploration target. BID exploration techniques include a combination of mapping, structural analysis, downhole gamma logging and 3D geological modelling. Relationships identified between existing BID mineralisation, geology and structure has aided in targeting additional mineralisation across the tenement and highlighted other previously untested areas that warrant further investigation.CITATION:Tylkowski, L N, Corlis, N J, McDonald, G D, Petts, A E, Jennings, M F and Thomas, B J, 2013. The hunt for hydrous bedded iron deposits - an investigation into Flinders MinesÆ Blacksmith Tenement, in Proceedings Iron Ore 2013 , pp 121-126 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By J. P. Brady

A major spontaneous combustion incident occurred in the sealed goaf of the SL3 Panel; Southland Colliery in 2003 resulting in the loss of a longwall and sealing of the mine. The most important issue for the new owners, Yancoal Australia Pty. Ltd, was to effectively manage the atmosphere in the fire affected sealed area. This atmosphere comprised of flammable gases, the products of combustion and excessive levels of oxygen due to pressure differentials across the panel isolation seals with a potential ignition source associated with the residual spontaneous combustion event. The challenges were met in the first instance by the erection of pressure balance chambers with limited success. The problem was not solved until the pressure chambers were pressurized using a Floxal Nitrogen Plant supplied by Air Liquide Australia. Given the success of this approach on a small scale, a higher capacity Air Liquide Floxal Unit was acquired to manage spontaneous combustion at the recommencement of longwall mining operations. This provided the ability to pressurize pressure chambers that were installed in the Maingate Seals behind the face of the adjacent Longwall Block effectively preventing the ingress of oxygen and permitting the goaf to self inert in a reasonable time period. This paper summarizes a new proactive method of mitigating the risks associated with active and sealed goaves. Proactive management of these areas using low flow nitrogen into pressure chambers to maintain a positive pressure has eliminated typical reliance in explosion proof or explosion resistance seals as the primary control.

Jan 1, 2009

By Jeffrey C. Hillman

The need to recruit locally produced engineers by the South African Mining Industry led to the Engineering Faculty at the University of the Witwatersrand developing a number of academic bridging initiatives for educationally disadvantaged students. The graduation rate achieved during the initial five years of operation by the most successful of these programmes has been on a par with that of al other students but the performance of subsequent intakes has declined to such an extent that the continuance of this scheme could now be at risk. One reason for this reduction in throughput is that many of the applicants for the increasing number of mining bursaries have been more interested in the bursary than the profession and have either failed or dropped out due to a lack of application and motivation. This will have serious consequences for both Wits and the Industry if it continues and some method of identifying unsuitable or suspect applicants needs to be introduced as a mater of urgency. It is recommended that an introductory course be set up at a working mine that would be run under the auspices of Wits, as a joint venture with industry, and include a level of academic input that would provide both bridging needs and certain first year credits. The final form of this course will require extensive consultation with al parties but needs to be completed before the end of 1996. It is further recommended that the advertising and promotion of mining careers be expanded and much improved.

Jan 1, 1996

By A. J. Hendron, J. E. Monsees

INTRODUCTION This paper is the outgrowth of work done by the authors to prepare the seismic design criteria for underground structures on the Southern California Rapid Transit District (SCRTD) Metro Rail Project. It is a follow-on to a similar paper presented at the October, 1984, ASCE National Convention (17). For design, the earthquake-induced distortions recommended herein are to be added to the normal static loading conditions for the underground structure. This design approach has been used by 18 section designers on the SCRTD Project. Preliminary results from two- and three-dimensional finite element solutions have partially verified the approach. Areas where additional research is needed for special cases are identified. EFFECTS OF EARTHQUAKE The effects of earthquakes on underground structures may be broadly grouped into two general classes -shaking and faulting. In response to earthquake motion of bedrock (shaking) , the soil transmits energy by waves. Seismologists identify various types of earthquake waves, but underground engineers are generally interested in the effects of transverse shear waves which produce a displacement of the ground transverse to the axis of wave propagation. The orientation of propagation is generally random with respect to any specific structure. Waves

Jan 1, 1985

By Ronald T. Mayerle

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied a 20,500-acre part of the 104,085-acre Rincon Wilderness Study Area (OR-002-082) in order to evaluate its identified mineral resources. The wilderness study area is located in Harney County, OR, about 12 miles west from Fields. No mineral resources were identified within the study area. A literature search found no records of mining or minerals exploration, nor did a ground search find any evidence of mining-related activity. Of seven alluvial samples taken from the major drainages of the study area, all were barren except one. This sample, taken from a dry streambed along the southern boundary, contained $0.07 gold per cubic yard; however, this small amount of gold is of no economic significance, and the source is probably outside the study area. The Pueblo-Steens mining district extends to within 4 miles east of the study area. No evidence of geological environments similar to those that were responsible for the formation of resources or occurrences of metals and nonmetals within the district is known within the study area.

Jan 1, 1987

By J Samosir, L Snyman

Northparkes was the first mine in Australia to use block cave mining method which relies on gravity and natural rock stresses to fragment and recover the ore. It was also the first hard rock mine to use hydraulic fracturing, in conjunction with CSIRO, to promote caving of E26 Lift 1. The technique was later used on E26 Lift 2 wedge and E48 prior to undercutting.Northparkes production is currently sourced from the E48 Lift 1 block cave mine and E26SLC. The E48 block cave contains economic ore to the north and south of the current cave footprint. To recover this ore the footprint has been extended on the north and south with two extraction drives and one extraction drive, respectively. Modelling of cavability above the additional drives indicated that the cave would not readily propagate to a sufficient height of draw to mobilise the ore and tended to arch over into the existing cave. To address the modelling results and to reduce the risk of the project, rock mass preconditioning was adopted.This fracturing campaign was performed from surface drill holes adjacent the subsidence zone angled to intersect the higher grade and higher elevation ore zones.Optical televiewer surveys, run prior to fracturing, picked intervals and fault zones to be avoided. Holes were resurveyed post-fracturing to detect newly created fractures and as a measure of success of the program.During fracturing operations water and gel fractures were run at varying depths and pumping pressure was logged for each fracture. The mine seismic system monitored significant events and dye in the fluids utilised for tracking water inflow locations during underground inspections.Towards the end of the project, guar fibres from gel were detected within the mill circuit and required treatment to resume optimum processing.CITATION:Webster, S, Snyman, L and Samosir, J, 2016. Preconditioning E48 cave extension adjacent to an active cave, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 471–478 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By S Robinson, R Perkins, D Barrett, D Kepert, C Fowers

The discovery and delineation of significant mineralisation in the Eliwana region continues Fortescue Metals Group’s strong exploration success. In the decade after the first hole was drilled into Christmas Creek in mid-2004 a total of over 11 Bt of hematite-goethite mineralisation have been delineated supporting the raising of $13 B, construction of five mines, 620 km of rail and a five-berth port. As of June 2014, Fortescue was shipping at the rate of 155 Mt/a. The area including the Eliwana and Flying Fish deposits is one of a number of future growth opportunities that Fortescue is currently evaluating.The Eliwana and Flying Fish deposits occur on the south dipping limb of the Brockman Syncline/Jeerinah Anticline. The Eliwana group of deposits are hosted by the Brockman Iron Formation with the Flying Fish/Broadway group hosted by the Marra Mamba Iron Formation.Structurally the area is dominated by moderate southerly dips of the regional dome and keel style folding. The regional limb is locally cross-cut at a small angle by asymmetric north facing Ophthalmian folds trending 110°. These fold sets, in part, preferentially host subsequent supergene mineralisation. Faulting is only locally apparent.Early phases of exploration commenced in 2006, with mapping of Flying Fish and reconnaissance drilling in 2007. However, due to the concurrent discovery (Clarke et al, 2009) and subsequent fast tracked development of Solomon channel iron deposit and Firetail bedded iron deposit (Simpson et al, 2011) priority was placed on developing Solomon due to its relative proximity to existing Fortescue infrastructure. Staged follow-up drilling of both Marra Mamba and Brockman targets at Eliwana was progressively undertaken from 2008 onward.As of 20 May 2014 a total of 1494 reverse circulation (RC) holes for 54 248 m and 13 diamond holes had been completed, resulting in the delineation of a Mineral Resource of 740 Mt. Exploration via mapping, drilling and metallurgical evaluation of adjacent prospects continues with additional resources expected in the future.CITATION:Barrett, D, Perkins, R, Kepert, D, Robinson, S and Fowers, C, 2015. Geological setting of Eliwana and Flying Fish deposits along the north limb of the Brockman Syncline, Hamersley Province, Western Australia, in Proceedings Iron Ore 2015, pp 219–228 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Dale Bartholomae, David Harrison, Edward J. Walter

Methods that involve the use of signature blast holes in order to identify the particular frequency characteristics of a geographical area are widely available. Information acquired can be used to determine optimum blast hole timings to produce the desired constructive and destructive inference. However, these types of analyses can be both complicated and expensive. This study will investigate the use and practicality of signature hole and/or shift and sum analysis software and their application to small diameter construction utility blasting operations in Pennsylvania and faster moving projects in general. A determination will then be made as to whether this technology can be utilized by today’s blaster, from both a functional and a cost effective basis. Single hole blasts will be detonated on various smaller construction projects and will be monitored with an array of seismographs. The collected data will be analyzed in order to determine the optimum timing between holes to produce the preferred frequency content while keeping in mind the explosives user’s current inventory of blasting supplies.

Jan 1, 2005

The problems of using comparatively simple x-ray diffraction equipment for quantitative analysis are examined. Internal standard and direct calibration procedures based upon the measurement of integrated diffraction energy (diffractometer peak area) have been developed for the determination of quartz in Broken Hill dusts. By these methods an accuracy of ± 10 per cent of the true value can be obtained and this can be improved to ±2 1/2 per cent by statistical methods if necessary.Rapid analysis for the components quartz, muscovite, rhodonite, galena, fluorite, sphalerite, calcite, and garnet has been developed by adaptation of direct calibration procedures and use of maximum diffraction energies (diffractometer peak height). Until more is know!) about the pathological effects of multi-component dusts of the Broken Hill type it seems undesirable to fix theIr allowable concentrations in terms of the quartz content.

Jan 1, 1968

By W. B. Berwald

[Accurate ~cusirc::ie t of euusu.rface r,resw rus £Uld tee:: ?er:~t:,res in producin+ oil and as wells is one of tine ast iy,ulortant steps ever t,.s:en to place the rprwctice of retroleum ,-iroduction on an exact scientific basis. i'reerures and teial.or-tures in a -petrolcuia r4:, rvoir. have a rn..r..ed influence over the o:wvement of oil and ~c s both within the. reservoir and t~:rou,=Ii the various-size "flow otrin;;u" of proLucin,; wells to tine surface. Knovrled: ?c of theso fc,.ctgrs form a Laois for cny attei:ant to [.,-~ly eciantific j:cthods to the solution or analysio of mc.nj proble;ae encountered in the production of oil and 1c_c, Without a.ccur:tc mcaaurx,ients of reosures r:.nd tcn::paratuxes within the rocervoit and -well 'flo-,r strinL:s" tae aI,licution of w.ny proved enbinecrin and scientific princiy-,loo is on %,]

Jan 1, 1935

By E. Bakhtavar

All parameters influencing the decision for selection of a suitable extraction method were first selected as the base of this study. Then these parameters were categorized in two main groups. The first group of the parameters includes ?geomechanical and inherent characteristics of the dimension stones? such as hardness, RQD, compressive strength, joints plane orientation and spacing, and water content. The second group was named ?technical and economical parameters associated with the investor?s objectives? like for example extraction capacity (production rate), blocks recovery, mechanization, capital investment and operational costs. Finally, the influences of all mentioned parameters on the selection of the most applicable extraction methods have been assessed and discussed.

Jan 1, 2012

By John Kosek

The electrochemistry of carbon monoxide, nitric oxide and nitrogen dioxide was investigated at a variety of electrode materials in different supporting electrolytes. A portable detector for carbon monoxide was developed using a porous gold anode in perchloric acid supporting electrolyte. This detector has two full scale ranges, 0-100 ppm and 0-500 ppm. A portable detector for mixtures of nitric oxide and nitrogen dioxide was developed using a porous silver cathode in sulfuric acid supporting electrolyte. Nitrogen dioxide was determined in the gas stream by electroreduction. The nitric oxide in the gas stream was oxidized to nitrogen dioxide by passing it over Cr(VI) on firebrick. Electroreduction gave the sum of NO + N02. Analog circuitry was used to display the amounts of NO and N02 separately. Two ranges were available for each gas. They were 0-10 and 0-50 ppm for NO and 0-2 and 0-10 ppm for N02.

Jan 1, 1979