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By Serdar Aktaş, Özgün Küçükoğlu, Burcu Nilgün Çetiner, Mehmet Hakan Morcalı

This study compares the cementation performance of metallic iron, metallic aluminum, and metallic tin in terms of the reaction conditions and parameters in synthetic antimony chloride solutions. The effects on the antimony recovery (%) caused by the cementators’ types, stirring speed, reaction time, and temperatures were explored thoroughly. The cementation kinetics of antimony were also explored for each cementator. The activation energies were determined to be 10.99, 9.09, and 13.58 kJ mol– 1 for Al, Fe, and Sn, respectively. The results reveal that the reaction is diffusion controlled, and comparable results were obtained for each cementator. At 25 °C, 40 mg of iron powder was found to reduce all antimony ions (i.e., approx. 99% recovery), but even when 100 mg of Al and Sn cementators were used, the antimony recovery did not reach 100%. This result shows that iron is the best candidate to cement antimony out of the solution.

Jan 28, 2022

By B. A. Zaharov, J. M. Shneerson, L. V. Chugaev, M. T. Zhunusov, A. M. Markelov, S. V. Drozdov

The main direction of research was the application of autoclave technology for the flotation concentrates or biooxidation feedstocks. The industry modernization also expects the possibility of increasing the yield of the flotation concentrate, to allow an increase in gold extraction in flotation circuit. This paper provides brief description of results obtained for concentrates with the yield of 4 and 8%, as well as corresponding biooxidation feedstocks. Technological efficiency of autoclave oxidation is shown for both concentrates and biooxidation feedstocks. The process has been evaluated on a laboratory and a continuous pilot plant scale. Gold extractions from POX discharge are ranging from 94-97% for each product, with only 5-7 kg/t cyanide consumed.

Jan 1, 2014

By S. J. Cook

The subject of capital and the Canadian mining industry is so broad as to be impossible of comprehensive treatment in brief form. The purpose of the present paper therefore will be only to outline in a meagre and somewhat sketchy way the nature and extent of the mineral industry in Canada and to point out those features which are likely to be of general public interest. Canada's mineral industry has a long and creditable production record. The? value of the output per capita rose from $2.23 in 1886 to a maximum of $26.40 in 1920 and the value of the products from ten million dollars in the former year to almost two hundred and twenty-eight million dollars in 1920. Compared with other primary industries and on the basis of the value of production, mining held third place in Canada in 1920, the premier position going to agriculture and the value of forestry production placing that industry second in the list. In the mineral industry, between six and seven thousand properties are operated annually giving employment to up- wards of sixty thousand employees to whom about seventy-five million dollars is paid in salaries and wages. During 1923, seventeen mineral products reached a production value of one million dollars or over in Canada and in order of the values assigned these were: coal, gold, nickel, cement, cop-per, silver, clay products, lead, asbestos, natural gas, stone, zinc, lime, cobalt, sand and gravel, gypsum and salt.

Jan 1, 1924

By George M. Potter

Under contractural arrangements with the Bureau of Mines, Mountain States Research and Development, Inc. (MSRD) completed a technological investigation to determine the feasibility of in situ mining of metal commodities other than copper and uranium, The study was based upon available literature and experience. The selection of potential candidates for in situ mining was influenced by economic importance, probable amenability to in situ methods, and environmental considerations. Four metals (or metal pairs) were chosen for feasibility studies: aluminum (with a copper byproduct), gold-silver, and manganese were recommended for further study and action; cobalt-nickel was also recommended contingent upon preliminary laboratory leaching and recovery investigations and field geohydrological work. Mining and recovery plans and an economic evaluation are included. Other metals with potential for in situ leaching are lead/ zinc, molybdenum, and vanadium.

Jan 1, 1981

By Shakuntala Tudu, Indrajit Paul, Surajit Sinha, Pulibandla Basaveswara Rao, Shaik Mahaboob Basha, Srinivas Dwarapudi

The iron and steel manufacturing sector directly accounts for 7–9% of global CO2 emissions. Raw material preparation, such as iron ore sintering, pelletizing, and cock making, is the major CO2 emitter. As climate change becomes a bigger concern, steel manufacturers need to lower CO2 emissions without hindering efficiency or increasing costs. In recent years, the percentage of iron ore pellets in blast furnaces has increased due to its uniform size, good reducibility, and high tumbler index. Pelletizing is energy-intensive and emits considerable CO2. Around 20% of CO2 emissions during pellet making come from fluxes. In the present work, the authors established a novel CO2- free flux called wollastonite (CaO.SiO2) for sustainable palletization. Pellets with varying percentages of wollastonite (0–6%) are prepared and tested for chemical, physical, and metallurgical properties. Image analysis through an optical microscope is carried out to quantify the phases of fired pellets. SEM–EDS is performed to evaluate the chemical composition of the melt and slag phases. The results showed that the reducibility index (RI) and swelling index (SI) of pellets decreased with an increase in wollastonite dosage. Pellet strength increases with an increase in wollastonite addition up to 1.2% CaO (2.27% wollastonite), and a decrease in strength is observed thereafter. The increase in strength is attributed to the increase in slag bonds. The decrease in strength beyond 1.2% CaO is mainly because of an increase in low melting eutectics and more magnetite content. Pellets with 2.27% wollastonite to get 1.2% CaO showed good physical and metallurgical properties.

Mar 4, 2024

By H. W. Kilau

The Bureau of Mines tested chromium-bearing waste slags from industrial stainless steel and other chrome alloy operations to determine their chromium leachability characteristics under acid precipitation conditions and to devise measures to prevent any pollution originating from this source. Two critical slag composition factors were found to control the chromium leachability: (1) CaO:Si02 ratio and (2) magnesium content. Above a 2.0 CaO:Si02 ratio, chromium exists in slag as CaO·Cr203, which can be vulnerable to leaching by acid precipitation especially if oxi-dized to CaCr04 when exposed to the environment over an extended period. Maximum chromium leachability from industrial slags occurred when the composition of the slag had about a 2.0 CaO:Si02 ratio. Between a 1.0 and 2.0 CaO:Si02 ratio, in the presence of sufficient magnesium, MgO ·Cr203 was formed, which is very resistant to oxidation and to dissolution by simulated acid precipitation. Addition of magnesium silicates to molten slag to fix the chromium in the MgO·Cr203 form was successful in preventing chromium leaching in simulated acid rain solutions. Experiments showed olivine and waste taconite tailings were suitable for this purpose. Olivine addition to a waste slag having a composition vulnerable to leaching (CaO:Si02 > 2) reduced the chromium leachability more than 80 pct.

Jan 1, 1984

By John F. Papp

Based on a review of historical domestic and international chromium metal production capacity, production, consumption, trade, and trade literature, world annual chromium metal production capacity in 1995 was estimated to have been 38,300 metric tons, a drop from 43,500 tons in 1994. World chromium metal production and consumption were estimated, on average from 1984 through 1992, to have been 21,000 tons per year. U.S. consumption was estimated, on average over the same time period, to have been 6,200 tons per year. The major world chromium metal producers between 1984 and 1995 were China, France, Germany, Japan, Russia, United Kingdom, and United States. From 1984 through 1992, world trade averaged 8,400 tons per year. Germany and the United States accounted for over 75 percent of imports on average during the same time period. U.S. chromium metal import value rose from under $1 per kg before 1964 to over $6 per kg in 1993. Over the same time period, prices rose from about $4 per kg to about $10 per kg. Chemical specifications have become more stringent. Detailed chromium metal trade, prices, value, chromium metal chemical specification, and production capacity by country are reported. A shift in trade patterns was anticipated as Japan exits production and displaces Germany as the second largest importer and as Russia increases its role in world trade.

Jan 1, 1995

By D. V. Keller

The use of a static bath of a heavy liquid of intermediate density between two mineral phases has been employed for beneficiation for over one-hundred years (1-6). In the case of the heavy liquid separation of coal from its included mineral matter, laboratory (3) and commercial (2,4) techniques have employed a halohydrocarbon or mixtures thereof, or solutions of inorganic salts and water with a specific gravity in the range of 2.0 to 1.30. As a laboratory tool, the heavy liquid separation is generally regarded as a standard permitting the "ideal" separation of a product coal and reject mineral matter. Each of the products in this case is polyphase since the separation is only based on apparent specific gravity of the product or reject material. The "Otisca Process" is an anhydrous heavy liquid separation process which employs a parting liquid with certain physical and chemical characteristics which make it particularly advantageous for expanding the laboratory separation process into the realm of commercial coal cleaning. The two key characteristics of the parting liquid are: 1) the heavy liquid does not react significantly with the coal product or reject material, and 2) the liquid permits complete dispersion of the coal product particles throughout the separation bath. The first point, i.e., the lack of liquid coal reaction (7-11), may be cited as one of the major reasons for the failure of other attempts at commercialization of heavy liquid processes. For example, if reaction does occur between the heavy liquid and coal or mineral matter, complete heavy liquid recovery becomes a very expensive complex process. The costs of heavy liquids alone prohibit their loss in the process as will be demonstrated later.

Jan 1, 1977

By R. Gilges

The implementation of effective techniques for meeting the maintenance requirements of the new Utah Copper Division smelter, one of the largest in the Western Hemisphere, is a goal of the smelter management and supervisory personnel. Kennecott's Metal Mining Division Computing Center has been working with smelter personnel to implement a computer program to provide instantaneous access to equipment specifications, maintenance and cost histories, spare parts, preventive maintenance scheddes, etc. for several hundred pieces of equipment. This information will be available to all smelter personnel via visual display terminals. The system will dramatically reduce the time now spent in search of pertinent information required in effectively performing the maintenance functions. It will also be used to analyze practices, detect trends, prepare budgets, and substantially reduce the paper work normally associated with the running of a large and complex maintenance organization.

Jan 1, 1977

By T. V. Swaminathan

Monazite sand is normally processed by, the caustic soda route to produce mixed rare earths chloride, thorium hydroxide and trisodium phosphate. Bulk of the mixed rare earths chloride is used for the preparation of FC catalysts. Recently some of the catalyst producers have shown preference to cerium depleted (lanthanum enriched) rare earths chloride rather than the natural rare earths chloride obtained from monazite. Therefore, a process for producing cerium depleted rare earths chloride, cerium p thorium and uranium from Rare earths + thorium hydroxide obtained by treating monazite based on stepwise hydrochloric acid extraction, was developed in our laboratory. The process involves drying of the mixed rare earths-thorium hydroxide cake obtained by monazite-caustic soda process followed by stepwise extraction of the dried cake with hydrochloric acid under specified conditions.

Jan 1, 1989

By Mototsugu Matsuno

A new process has been developed to treat fly ash generated from municipal incinerators, which contains not only toxic metals such as lead and cadmium, but also dioxins. The process includes the following steps; fly ash is formed into green pellets with some additives and the pellets are then roasted to eliminate or stabilize the toxic metals and to decompose dioxins. A pilot plant with a capacity of approximately 100 kg/hr was used to test the process. The tests verified that heavy metals were either volatilized or stabilized and dioxins were decomposed by high-temperature roasting. The pelletized ash was found to be non-toxic, so that it can be recycled as artificial lightweight aggregate. It was also found that volatilized metals collected as secondary ash can be recycled as smelting resources.

Jan 1, 2003

By Harry V. Makar

As part of a continuing research program for conserving domestic mineral resources, the Bureau of Mines is investigating new and improved scrap identification techniques to improve sorted mixed scrap purity. This report focuses on various classes of wrought and cast copper alloys produced with recycled scrap. Based on a survey of the literature, principal alloys, such as the brasses and bronzes, are examined with respect to impurity elements and their effects on metallurgical behavior. Effects of elements such as lead, antimony, iron, chromium, and aluminum are discussed. The metallurgical effects described include hot shortness, fire cracking, and undesirable phase transformations.

Jan 1, 1985

By Ivan Malinsky, Gérard Castonguay

"On a développé un procédé qui donne une fonte (2,3% C, 0,07% V) du V2O5 (99%) et un rutile synthétique (94% TiO2) à partir d'un minerai, dont les réserves au Québec sont importantes. Le procédé comprend les opérations suivantes: 1) la concentration magnétique du minerai (30% Fe, 9% TiO2 et 0,65% V2O5) pour produire un concentré (65% Fe, 7% TiO2 et 1,6% V2O5); 2) le smeltage du concentré aggloméré dans un four à arc, sans fondant, pour produire une fonte et une scorie (30% FeO, 40% TiO2 et 8,0% V2O5) qui contient plus de 95% du vanadium et du titane présents dans le concentré; 3) le grillage alcalin (37% Na2CO3) de la scorie suivi d'une lixiviation à l'eau et de la précipitation de l'hexavanadate d'ammonium à partir du filtrat; 4) la lixiviation du résidu par l'acide sulfurique pur ou usagé pour produire un rutile synthétique. Un estimé préliminaire de la valeur économique du projet laisse croire à sa rentabilité à la condition que l'investissement pour le smeltage soit inférieur à environ 400$/tonne de fer.IntroductionLes gisements de magnétites titanifères sont nombreux dans le monde. Ils consistent en une magnétite étroitement liée a l'ilménite, La teneur trop élevée en TiO2 empêche l'exploitation de ces gisements pour la production de fer. Cependant, dans certains cas, la magnétite a une teneur intéressante en vanadium qui peut rendre l'exploitation de ces gisements rentable. Aujourd'hui, les magnétites titanifères constituent la plus importante source de production de vanadium. On estime qu'environ 70% du vanadium produit provient de ces sources."

Jan 1, 1983

By Mark Sheppard

[Considerable research work hi been done on secondary crushing and coarse and fine grinding, and the literature on the general subject of Crushing contains many references to the work of investigators on the laws governing end the factors entering into the economical production of fine materials. However, little information on primary crushing in available The literature deals mainly with problems and practices in ore dressing, end in this field the engineer or investigator is concerned largely with the production of fine material and the unlocking of minerals in the ore. Under such conditions close control of screen sizes of primary-crusher products is a secondary consideration and has received very little attention.]

Jan 1, 1938

By Xin Wang, He Shao, Wenpu Li, Yiyi Zheng, Xi Chen, Yurong Gao

This study utilized experimental and numerical simulation methods to investigate and analyze the atomization characteristics of three internal air–water mixed atomizers under different operating conditions. By comparing the research results, the effective dust control working parameters for the application of the selected atomizer in the engineering field were determined. Firstly, the atomization characteristics of the three atomizers were studied using a customized experimental system. The results indicated that nozzle 2 had a wide atomization range, a small atomization distance, and small droplet size; nozzle 3 had a narrow atomization range, large droplet size, and fast atomization speed; and nozzle 1 not only had a large atomization range but also could produce droplets of dry mist size with fast atomization speed, meeting the dust reduction requirements of the Majiliang Coal Preparation Plant. Secondly, Fluent software was used to simulate the atomization process and particle size distribution of the three internal mixed atomizers, determining the working conditions of the atomizers, the required number of atomizers, and the application angle of the atomizers in the internal mixed dust removal system. Finally, the atomized dust control system was applied on-site, achieving a total dust removal efficiency of 90.72% and a respirable dust removal efficiency of 89.75%.

Mar 9, 2024

By Jean Igor Margem

Materiais sustentáveis estão sendo investigados para substituir os materiais sintéticos, os compósitos com matriz polimérica têm sido aplicados em componentes, tais como capacetes e blindagem para os quais a resistência em um requisito importante. O presente trabalho avalia a classificação energética de impacto Charpy e Izod da matriz de epóxi compósitos DGEBA / TETA, reforçado com até 30% em volume de fibras de malva contínuas e alinhadas (Urena Lobata, L). Os testes de impacto foram realizados em amostras padronizadas em matriz de epoxi obtidas por aplicação de pressão em molde com cura a temperatura ambiente por 24 horas. Os resultados mostraram aumento significativo da energia de impacto com a fracção de fibras incorporadas de malva. A superfície de fratura foi analisada por microscopia eletrônica de varredura, SEM. O desempenho das amostras incorporados com 30% de fibras, sofreu apenas ruptura parcial devido a dificuldades impostas ao quebrar-se as fibras, e, consequentemente, a natureza dos quais fendas tendem a propagar na interface entre a matriz de fibra / resina epóxi, o que ajuda a absorver a energia do impacto.

Aug 17, 2017

By BHAMIDIPATI S. SASTRY, ANMAYA NAIK, ASIF AHMAD, Srivatsan Jayaraman Sridharan, ADITYA PANDEY

Wet kata cooling power (WKCP) as measured by a kata thermometer is a well-known heat stress index used in the mining industry. Although, over the years, several researchers proposed different heat indices and indicated limitations of the kata thermometer, WKCP is used in the South African gold mining industry due to its simplicity and rapidity of assessment. This paper presents a comparative analysis of the newly developed empirical expression for the WKCP and some of the more commonly used empirical models. For this purpose, WKCP measurements are obtained based on experiments conducted in a low-speed wind tunnel. Based on a regression technique, the analysis presented aims to assess the disagreement between the empirical model predictions and actual measurements. The correlation is also presented between WKCP and the well-established thermoregulation models using parameters from the low-speed wind tunnel experiments, including dry-bulb temperature (Td), wet-bulb temperature (Tw), barometric pressure (P), and wind speed (v). It is found that the proposed empirical model for the WKCP represents the bioclimatic interaction quite well under the specific parameters that defines the harsh thermal environment and air condition, such as metabolic activity, clothing of the person, and the velocity of the ventilating air in which the person is working. The statistical analyses performed show that the empirical model proposed for the WKCP produces satisfactory estimates of the thermal stress experienced under lower air velocities, light clothing, and higher metabolic activity rates.

Sep 2, 2021

By Gene Asai

The Bureau of Mines investigated the caustic extraction of alumina and soda from retorted dawsonite-bearing oil shale, as part of a program to devise technology for treating alternative domestic sources of alumina for the production of aluminum metal. Colorado oil shale yielding 13 pct oil (35 gal/ton) and containing 12 wt-pct dawsonite (representing about 4 pct extractable alumina) was retorted to obtain oil-free (spent) shale Spent shale was leached with dilute NaOH to determine the effect of particle size, retorting temperature, leaching variables, and storage conditions on extraction of alumina and soda and dissolution of impurities. Maximum alumina and soda extractions were obtained by promptly leaching minus 28-mesh spent shale, obtained by retorting raw shale at about 5000 C, with 0.5N NaOH. Under these conditions, dissolution of impurities such as Ca, Fe, Ti, and P was low. Leaching tests were made on spent shale stored for periods of up to 30 days at 0° to 42° C and at 0 to 100 pct relative humidity (RH). These tests indicated that significant reductions in alumina extraction would occur if spent shale were stored in ambient Colorado air under naturally fluctuating temperature and humidity.

Jan 1, 1983

By J. J. Demeter

As part of its work on converting coal to fluid fuels, the Federal Bureau of Mines has been studying the synthesis of liquid fuels from carbon monoxide and hydrogen by Fischer-Tropsch synthesis. A fluidized bed of nitrided, fused-iron catalyst has been operated successfully to produce high yields of oxygenated compounds. Trouble-free operation continued for over 800 hours, and the test was terminated voluntarily. About 85 percent of the fresh feed was converted when the unit was operated at a space velocity of 500 hr.-1, a 12:1 recycle-to-fresh-feed-gas ratio, a 300-p. s. i. g. pressure, and a temperature of 252° C. When operating at a fresh-feed-gas space velocity of 1,000 hr.-l and a 9:1 ratio of recycle to fresh gas, conversion of fresh feed was 68 percent, and the product yield was 235.9 grams per cubic meter of synthesis gas converted. The oxygenate and C5 and heavier hydrocarbon yield was 110.6 grams per cubic meter of gas converted, 83 percent of this was oxygenates. The atom ratio of N:Fe of the catalyst, initially 0.455, decreased to 0.288 by the end of the 800-hour experiment. Nevertheless, the yield of oxygenated compounds per cubic meter of H2 + CO converted at the end of the run was approximately the same as that obtained 500 hours earlier with identical operating conditions. X-ray analysis of the discharged catalyst indicated that only ?-iron carbonitride was present. Sieve analysis of the discharged catalyst indicated that only 2 percent of fines was produced during the reduction, nitriding, and synthesis.

Jan 1, 1959

William Clinton Brown, Brooklyn, N. Y.: The demand for an apparatus for cooling water for condensers, refrigeratingmachinery and air-compressors, as well as water-jacketed furnaces, has led manufacturers to put such an apparatus on the market, so that it is now possible to purchase a cooling-tower, properly designed and constructed, by simply stating the amount of water to be cooled and the temperatures of the hot and the cold water. The principle is similar to that described by Mr. Henrich, but wood is not used in the best apparatus. There are two great objections to wood: First, it cannot last long under the very trying conditions to which it is subjected; and second, it absorbs the organic matter with which water in constant use becomes impregnated, and the resulting odor is very disagreeable. A few days ago I saw a cooling-tower and condenser, built by the Henry R. Worthington Co., in operation at the Edison electric-lighting station in Brooklyn, N. Y., cooling the water for a 700 horse-power condenser. It consisted of a large stack of iron, about 15 feet in diameter by about 30 feet high. This stack was filled with tiling through which the water falls. A whirligig distributes the water evenly over the top, and a large fan, about 6 feet in diameter, driven by a 10 horse-power electric motor, blows air into the bottom, thus giving a positive circulation. The water, in running down the sides of the tiling, is met by the blast of air, and enough is evaporated to cool the rest. The vacuum-gauge on the condenser showed 26 inches; so the condenser was undoubtedly getting sufficient cool water.

Jan 1, 1896