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By M. J. Beus

The Bureau of Mines, under a cooperative agreement with Hecla Mining Co., is conducting a rock mechanics study of the 6,200-ft-deep circu-lar, concrete-lined Silver Shaft in northern Idaho. The objective of the project was to instrument and evaluate lining behavior and rock de-formation when a deep shaft is constructed in a high in situ stress field and anisotropic rock mass. Rock mass displacements were moni-tored with multiple-position borehole extensometers. Liner stress and strain were measured with concrete pressure cells and embedment strain gauges. Field data from the 5,955-ft test level show that rock displacement is controlled by rock mass anisotropy. Liner stress and strain levels reflect the high in situ stress field as well as nearby station and raise construction. Maximum stresses measured in the lining, as a result of shaft excavation, are about one-third of its compressive strength. Subsequent loading pocket excavation resulted in signifi-cantly increased stress and strain levels in the liner. Continued monitoring and preliminary analysis of the data indicate that concrete-lined, circular shafts are stable for the high, unequal horizontal stress fields and rock anisotropy encountered in deep-level mining. Adjacent development work can be expected to significantly alter the initial stress and displacement conditions.

Jan 1, 1984

By B. Orberger

The fine fraction (< 2 mm) of the high grade Mn-ore from the world class Moanda deposit, Francevillan basin, in Gabon, contains up to 30 wt. % of manganese and about 0.4 wt. % phosphorous. A pilot study at laboratory scale integrating mineralogy and geochemistry before and after ultrasonic treatment was conducted on the fine fraction (< 2 mm) of oxidized Mn ore in order to reduce the phosphorous content and enrich this fraction in manganese. The fine fraction was dried, crushed at 2 cm and sieved at 2 mm. The two fractions (< 2 mm and 2 mm ? 2 cm) were investigated by X-ray diffraction and scanning electron microprobe ? electron dispersive spectroscopy analyses. Both fractions contain lithiophorite, cryptomelane and pyrolusite as Mn carrier, and goethite, muscovite, illite and quartz as contaminants. The Mn hydroxide nsutite was only found in the fraction 2mm ? 2 cm.The < 2 mm fraction is significantly richer in goethite, muscovite/illite, and quartz. Phosphorous carriers are mainly goethite (up to 2.8 wt. % P2O5), while the Mn minerals contain up to 0.8 wt. % P2O5. The Mn minerals are partly included in an agglomerate of goethite, muscovite/illite, and quartz. The < 2 mm fraction was treated by ultrasound for 30 s in normal water. Mineralogical and chemical analyses after ultrasound treatment showed that the Mn-minerals were largely liberated from the goethite-muscovite-illite agglomerate. Mass balance calculations show that after ultrasonic treatment the < 2 mm fraction was ? 50 % enriched in Mn and ?50 % impoverished in P.

Sep 1, 2012

By Gustavo Henrique Bolognesi Donato

Este trabalho apresenta o desenvolvimento de critérios objetivos para a garantia de validade da mecânica da fratura elasto-plástica monoparamétrica, utilizando o parâmetro integral J como descritor dos campos de tensões, deformações e deslocamentos à frente de um defeito do tipo trinca. O mais importante na vertente monoparamétrica da mecânica da fratura é garantir que os campos de tensões no corpo de prova laboratorial sejam comparáveis com os existentes em uma estrutura real para cujo projeto as propriedades retiradas do corpo de prova serão utilizadas (conceito este denominado similitude). Para estabelecer critérios objetivos para a existência de similitude, esse trabalho comparou os campos de tensões obtidos de estruturas de referência sob alta triaxialidade de tensões (MBL) com aqueles obtidos de corpos de provas de mecânica da fratura em escala de laboratório. A matriz de análise permitiu a determinação dos limites de deformação M para geometrias C(T), SE(B) e SE(T) de diversas configurações e para uma faixa de propriedades de material característica de aços estruturais aplicáveis a vasos de pressão e dutos. Os resultados demonstram a baixa restrição à plasticidade de corpos de prova SE(B) e SE(T) com trincas rasas e os efeitos de profundidade de trinca e espessura nos resultados de M. Ainda, alguns comportamentos inesperados foram evidenciados, como no caso em que (para condições particulares de profundidade de trincas) corpos de prova mais finos apresentaram maior restrição a plasticidade do que amostras mais espessas. Sendo assim, o trabalho oferece uma base objetiva para que a similitude seja garantida nas avaliações de integridade estrutural baseadas na mecânica da fratura elasto-plástica suportada pela integral J, seja com seus valores críticos (Jc) ou curvas J-R.

Aug 17, 2017

By S. Surapunt, C. M. Nyamai, K. Itagaki

"The use of liquid copper as a medium for zinc extraction has been used in the Warner Process as a method of processing zinc-lead sulphide ore. The recovery of zinc metal is based on the reaction:ZnS(s) + 2Cu(l) = Zn(g) + Cu2S(l)In this method, thermodynamic and phase equilibria investigations of the Cu2S-FeS-ZnS and Cu2S-PbS-ZnS systems are of importance and form the basis for the liquid sulphide phase which appears as a product and is used as a solvent in the Warner Process. Phase relations in the Cu2S-FeS-ZnS and Cu2S-PbS-ZnS ternary systems were determined experimentally at 1473°K to provide a fundamental basis for the new zinc smelting process. The results show that the solid solubility of ZnS in the two systems is very small (2 wt% to 3 wt% ZnS in FeS, 4 wt% ZnS in Cu2S for the Cu2S-FeS-ZnS system; less than 0.5 wt% ZnS in both PbS and Cu2S for the Cu2S-PbS-ZnS system). The Raoultian Activity Coefficient of ZnS in the liquid mixtures and the vapour pressure of zinc over the matte in both systems is relatively large (?° = 7.7 – 15.8, Pzn(atm) = 0.088 – 1.026 for the Cu2S-FeS-ZnS system; ?° = 8.9 – 12.9, PZn(atm) = 0.075 – 0.214 for the Cu2S-PbS-ZnS system). On the FeS-ZnS join, the only phases detected are FeS and iron-rich sphalerite (Zn, Fe)S. The binary join mixture occurs at about 92 wt% FeS-8 wt% ZnS at 1473°K. Electron microprobe examination of the quenched samples indicate about 47 wt% to 48 wt% FeS in sphalerite and about 2 wt% to 3 wt% ZnS in the iron sulphide phase. On the Cu2S-ZnS join, microprobe analysis reveals that the maximum solubility is 4 wt% Zn in liquid Cu2S and 3.6 wt% Cu in solid ZnS. In the Cu2S-PbS-ZnS ternary system, microprobe analysis of the quenched samples indicate on average, 5 wt% ZnS in the liquid phase region. The only phases detected on the PbS- ZnS join are ZnS and PbS. The eutectic phase contains, on average, 13 wt% ZnS. The phase relationships, very low solid solubilities of zinc sulphide in the liquid mixtures of both Cu2S-FeS-ZnS and Cu2S-PbS-ZnS systems, coupled with the high Raoultian Activity Coefficient of ZnS as well as the high vapour pressure of zinc over matte all favour the partitioning of zinc metal into the vapour phase. This new process is cost effective and bypassesthe expensive and tedious conventionaltechnique of zinc production involving oxidationof the sulphide ore by roasting followed bya reduction process to extract the zinc. Theresults indicate that a new zinc smelting technologyusing the Warner Process would bemore efficient and preferable over the traditionalmethods of zinc extraction."

Jan 1, 2002

By W. A. Rickelton

Trialkylphosphine sulphides, in contrast to their well known oxide analogues (1,2,3,4), have received comparatively little attention as metal extractants and previous studies have been biased toward analytical rather than commercial solvent extraction applications (5,6,7). The sulphides are soft Lewis bases and only from complexes readily with the limited number of metals in the periodic table which can be classified as soft acids (8) e.g. Ag+, Hg2+ and Pd2+. Consequently, these compounds tend to be more selective than the broad-spectrum, hard-base, phosphine oxide extractants such-as TOPO (trioctylphosphine oxide). The purpose of this paper is to describe a potential application of one phosphine sulphide, CYANEX® 471X extractant, in the selective recovery of silver from base metal sulphate solutions. CYANEX 471X is triisobutylphosphine sulphide (TIBPS).

Jan 1, 1984

By G. Frithum

In the present paper a new and highly economic route for Fe-separation from HCl leaching processes in hydrometallurgical applications is described. In most ore leaching processes, Fe is involved and needs to be separated; HCl has become an interesting leaching agent, because it can be recycled. Usually a mix of Fe2+ and Fe3+ is obtained which can be hydrolyzed directly (in case only Fe3+) or roasted via pyrohydrolysis (in case of Fe2+) to ferric oxide. Economic oxidation of Fe2+ to Fe3+ is described, and potential technologies for regeneration of HCl with separation of Fe are shown and compared.

Jan 1, 2014

By A Remes, A Dennis, M Talikka, T Kotiranta, S Horn

A mine project combines vast amounts of information from various disciplines including but not limited to geology, mining, metallurgy, technology, environment and economics. In many cases, all relevant information is not fully shared between all disciplines. Thus, project performance (technical, economical and sustainability) may be evaluated on basis of insufficient information resulting in non-optimal decisions, project execution and risk management. Advances in computing power and simulation software enable various data sets to be incorporated in a single digital platform enabling more efficient and transparent data sharing. In addition, linked data sets and simulation can support assessment and optimization of the project as a whole rather than focusing on optimization of individual events. CITATION:Horn, S, Remes, A, Kotiranta, T, Talikka, M and Dennis, A, 2018. Evaluation of sustainability of copper production value chain from ore to metal using advanced simulation, in Proceedings Life-of-Mine 2018, pp 87–89 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By Z. D. Hora, W. N. Hamilton

Introduction Some unique opportunities exist for industrial minerals in British Columbia and Alberta. The region&apos;s diversified geology, particularly in British Columbia, offers favorable environments for a rich variety of mineral resources. Many minerals have been produced for years. For some, however, the level of production is far less than the potential. Others have had production in the past, but are not currently produced. Still others are known to exist and may have been actively prospected. But they are not yet developed. In addition, a number of speculative possibilities have recently come to light. The potential significance is not fully confirmed, but is suggested in showings in favorable geologic settings. Location and geography British Columbia and Alberta are the westernmost provinces in Canada (Fig. 1). The region overlaps two major physiographic divisions of the country, the Cordillera and the Interior Plains. It also takes in a small segment of the Canadian Shield on the east. The entire territory is greater than 1.6 Mkm2 (618,000 sq miles). Most of British Columbia lies within the Cordillera, a mountainous belt some 800 km (500 miles) wide. The belt is made up of three main physiographic components, the Eastern, Interior, and Western subdivisions. The Eastern subdivision embraces the rugged, linear ranges of the Rocky Mountains, elevations between 2600 and 3300 m (8530 and 10,800 ft). They form a 100-km (62-mile) wide band straddling the BC-Alberta border and extending northwest across northern British Columbia. The Interior subdivision includes several ancient mountain ranges but is dominated by an intermountane plateau area of low relief (average elevation 1200 m or 3900 ft). The Western subdivision is dominated by the Coast Mountains (elevations between 1800 and 4000 m or 5900 and 13,123 ft). These form a band about 175 km (110 miles) wide into which are sculptured the spectacular fiords of the BC coastline. Alberta lies largely within the Interior Plains, a prairie region of low to moderate relief (elevations between 200 and 1200 m or 650 and 3940 ft) formed of nearly horizontal bedrock strata. The Plains surface rises gradually to the southwest toward the deformed belt of the Rocky Mountains, where the bedrock strata are upturned, folded, and faulted. To the east, the Plains merge with the Canadian Shield, which exposes the Precambrian crystalline basement of western Canada. The total population of the BC-Alberta region is about five million people. Minerals, forestry, and agriculture are the primary industries here. It has well developed infrastructures to service these industries. British Columbia is third among the Canadian provinces in metal mining - $1.1 billion in 1985 - and first in forest products. It is also second in hydro-electric power development. Alberta leads all provinces in total mineral production, largely due to its extensively developed petroleum and natural gas resources - $26.2 billion in 1985.

Jan 12, 1987

By N. Hadebe, A. Mampuru, F. Jantjies

Mintek conducted test work to study the effect of media wear when using Mintek’s Milling-in-raffinate technology. The grinding media consisted of high-chrome and ceramic balls. The tests were conducted using a laboratory 5L 316 stainless-steel rubber-lined mill. Magotteaux supplied the high-chrome and ceramic balls. The raffinate was synthetically prepared using a typical Cu/Co (2.2 g/L Cu, 3 g/L Co) composition. The milling rate, media wear, mill, leach extraction efficiencies, gangue acid consumption, and residence time were studied. The tests indicated that the high-chrome balls had a higher corrosion rate than the ceramic balls. The ceramic corrosion rate was lower than 0.1 mm/y. The highchrome balls performed better during the leach stages with faster milling time, higher leaching efficiencies for both Cu and Co, lower gangue-acid consumption, and lower residence time

Jan 1, 2023

By M. Bender, H. D. Goodfellow

"Belt conveyors, because of their low capital and operating costs and inherent flexibility in handling a wide variety of products, have numerous applications in the mining industry. With the increased emphasis on improving the workplace environment, dust emissions from belt conveyors at transfer and other points have become a significant problem for many applications.The paper reviews belt conveyor dust control technology and compares dust emissions from belt conveyor systems with other possible materials handling systems. Technical information on existing belt conveyor installations which have been designed to minimize or eliminate dust emissions is summarized. The important features of good design as well as the necessary input from operating and maintenance personnel are highlighted. The status of research and development work on dust control on belt conveyor systems on a world-wide basis is discussed. A proposed methodology for field measurements of emission factors from belt conveyor systems is presented. Data collected from such a test program can be used to establish a design basis for new dust-free belt conveyors.IntroductionBelt conveyors have proven themselves over the year s in the mining industry as a reliable and low-co st method of moving bulk material at high tonnage rates. Because of the above, as well as their inherent flexibility in handling a wide variety of products, belt conveyors are often called the ""workhorses"" of bulk material handling systems. For many processing plants, belt conveyors serve as the ""vital link"" in providing feed to the plant and the removal of the finished product. As would be expected, there has been considerable engineering effort in designing rugged and reliable belt conveyor systems.It is also well known that belt conveyor systems are a primary source of respirable dust emissions. The major sources are from the tail pulley where material is received and the head pulley where material is discharged, from the return idlers, due to the fine material attached to the return belt, and from the take-up pulley. It is usually considered that for dust particles less than 10 microns, these particles will remain airborne and thus can have a profound effect on the workplace environment."

Jan 1, 1982

By Ira N. Holli

A meeting of Engineering Council was held on Thursday, Jan. 22, 1918, at the Engineering Societies Building, New York. Present: Chairman Ira N. Hollis (A. S. M. E.); Dr. Charles Warren Hunt, Alex. C. Humphreys and F. H. Newell (A. S. C. E.); B. B. Lawrence and .J. Parke Charming (A. I. M. E.); Charles Whiting Baker, D. S. Jacobus, and George, J. Foran (A. S. M. E.) ; H. W. Buck, E. W. Rice, Jr., N. A. Carle, C. E. Skinner and Comfort A. Adams (A. I. E. E.) ; Clemens Herschel and Calvert Townley (United Engineering Society); also, by invitation, D. W. Brunton, Chairman, War Committee of Technical Societies of Engineering Council. Of the several actions taken at this meeting, the following are selected as being of most general interest. Chairman-Baker-presented a resolution on the conduct of the war, to which objections were made. It was referred to a special-committee; Charles Whiting Baker, Charles Warren Hunt, and Calvert Townley, for re-drafting and presentation later in the meeting. The revised resolution submitted by this committee led to further discussion and as no agreement could he reached, the matter was laid on the table.

Jan 3, 1918

By L. J. Su, J. Y. Zhang, P. W. Gu, J. F. Xu

Surface tension of mold flux is a key factor affecting optimum casting conditions. A thermodynamic model was developed to determine the surface tension of mold flux containing fluoride based on the ion and molecule coexistence theory of slag structure and Butler’s equation. The relationship between composition and surface tension was investigated by this model. Results indicated that the calculated values showed good agreement with literature data, and the average error was 8.19%. The surface tension value of the CaO–Al2O3-based mold flux was larger than that of the CaO– SiO2-based mold flux. The surface tension in a multi-component system decreased with increasing contents of SiO2, CaF2, and Na2O, which are considered surface-active components. This trend was more significant in the CaO–Al2O3-based mold flux.

Dec 11, 2024

By William H. Pelton

The presence of high-grade massive sulphides near York Harbour, Newfoundland has been known since the turn of the century. In the early 1900&apos;s a small, massive-sulphide deposit was worked by conventional hand methods and yielded about 100, 000 tons of high grade copper-zinc ore. Since that time, a number of mining companies have held options on the property and an exploration adit was driven along the fourth level of the original mine. Underground drilling revealed several additional massive sulphide lenses in the range of 10, 000 to 60, 000 tons (Fig. 1). The problem facing Long Lac Mineral Exploration Ltd. when they undertook an option on the property in 1969, was to outline any possible extensions to the known sulphide lenses which were outside the reach of underground drills and to search for new ore deposits which might double the known reserves into a feasible project for development. GEOLOGY AND PHYSICAL PROPERTIES: The geology is typical of many massive sulphide deposits within volcanic rocks in the Canadian Shield. The sulphide pods appear to occur along a complex andesite-basalt contact. Identification of the two volcanic types is difficult since they are almost the same colour. The most direct means of identification is by the slight difference in their magnetic susceptibilities. Pyrite, chalcopyrite and sphalerite are the main minerals in the sul¬phide lenses. The ore is massive, differing in density from the host rock by at least 1.0 gm/cc. There is little pyrrhotite or magnetite associated with the sulphides, so there is no appreciable difference in magnetic susceptibility between the sulphides and the basalt. Also, there is no alteration halo around

Jan 1, 1971

By V. C. Koppe, J. F. C. L. Costa, D. M. Marques, A. Amaral

Errors associated with estimating the grade of an attribute of interest in a deposit can compromise planning, sequencing, and mineral beneficiation decisions. Several factors are associated with estimation errors. Among them, we can highlight the factors associated with sample spacing, the size of production volumes, and the variability of the attribute considered in the estimation. The access to estimation error can be obtained by some geostatistical methods, for example, by stochastic simulation. However, this is a process that in some situations is computer intensive and takes time. Previous works have proposed a simplified method to access the Maximum Estimation Error (MEE) associated with different types of grade variables, depending on the sample spacing, at small production volumes and considering specific coefficients of variation ranges. This paper presents an approach to assess the MEE associated with long-term volumes. Considering the methodology proposed, it is possible to approximate if a specific drilling pattern used in a deposit provides an acceptable pre-determined estimation error for Resource Classification. Results and considerations on the impact of the geometry of larger production volumes on the MEE calculation are also presented.

Jun 25, 2023

By Frederic P. Dewey

(New York Meeting, February, 1912.) By the old method of determining platinum in ores and bullion, the silver-alloy first obtained in the regular course of assay is parted in strong sulphuric acid and the residual metal weighed. This is re-alloyed with silver by a second cupellation and parted in nitric acid, the residual metal being again weighed. Any difference shown between the two weighings is assumed to be, and is called; platinum. Sometimes it is so, and if any considerable amount of platinum be present, there will be a decided difference between the two weighings; but a slight difference is no real evidence whatever of the presence of platinum. On the other hand, the second weight may equal or possibly exceed the first, even when traces of platinum are present. Again, other members of the platinum group may go into solution in nitric acid more or less. If present, these would be called platinum and escape detection. The method does not provide any direct tests whatever as to the presence or absence of platinum. It is often indecisive, and sometimes jives erroneous results. It is, therefore, quite unsatisfactory. Being called upon many times to determine platinum in a wide variety of materials, particularly when present in very small amounts, I have realized the disadvantages and defects of this old method. In an article on the solubility of gold in nitric acid, 1 I have briefly outlined a method of gathering a little gold out of a solution containing much silver, which furnishes the basis of

Apr 1, 1912

By Rafael Alves Frederico de Alencar

O comportamento mecânico dos diferentes tipos de materiais é influenciado por diversas variáveis, dentre as quais, as condições adotadas para o processamento mecânico dos mesmos, as características estruturais e os aspectos metalúrgicos, por exemplo. Considerando essas variáveis, este trabalho apresenta o estudo do comportamento mecânico do aço inoxidável ferrítico AISI 430, estabilizado ao nióbio, para diferentes modos de pré-deformação: estampagem (estiramento) e tração com o subsequente carregamento em cisalhamento. Os resultados indicaram que o comportamento mecânico do material variou em função da direção de aplicação do esforço mecânico e do modo usado para a pré-deformação desse aço, ocasionando endurecimento e amaciamento.

Aug 17, 2017

By R. D. Brown

Manitoba has now joined Ontario and Quebec in providing for new incentives and lower tax rates for the mining industry. A single rate of tax (to replace the former two-tier royalty), an investment tax credit and a relatively straightforward set of rules for calculating taxable mining profits are the main features of new mining tax legislation announced by Manitoba&apos;s Finance Minister Donald W. Craik in his May 15, 1979 budget address. On introducing amendments to reform The Metallic Minerals Royalty Act, the Finance Minister indicated that the new tax regime is intended to restore the Manitoba mining tax system to a competitive position in Canada, and should result in renewed investment in the province&apos;s mining industry. 1n this regard, the government could be right-there is little question that the new tax regime will produce greater incentives for the mining industry than the two-tier royalty system introduced by the New Democratic government in 1975. The proposed changes, contained in Bill 57, would largely be effective January I. 1979.

Jan 1, 1979

By B. Yu, Y. O. Oyediran, M. Robart

"This paper presents the latest flotation development testwork conducted in 2015 on the ‘B Zone’ samples from the Strange Lake Alkalic Complex (SLAC). Since the discovery by Iron Ore Company of Canada (IOC), metallurgical development has been under taken by a number of mining companies targeting various value metals, including yttrium, zirconium, niobium, and rare earths.Most recent, Quest Rare Minerals Ltd. (Quest) completed a Pre-Feasibility Study (PFS) in 2013 where the flowsheet was relatively complex and led Quest to explore alternative options. In 2014, the PFS flowsheet was simplified and one of the features introduced was pre-concentration by rougher flotation. The combined rougher flotation concentrate and slimes successfully recovered >90% TREE in 60% mass thus reducing capital cost and technical risks of the downstream hydrometallurgical processes. The latest flotation development testwork focused on achieving a pre-concentrate in which >80% TREE are recovered in 20% mass. Two separate reagent schemes, based on an ester phosphate collector (Clariant 1682) and a benzoylhydroxamic acid collector (Florrea 7510), were developed. Parameters evaluated in the development testwork included desliming, secondary yttrium and zircon collectors, depressants, temperature, conditioning temperature, time, and density, pH, sodium silicate type, cleaning, and flowsheet configuration. Both developed reagent schemes achieved the targeted metallurgy.INTRODUCTIONThe Strange Lake Alkalic Complex (SLAC) was discovered after geological survey and mapping studies by Geological Survey of Canada and Newfoundland and Labrador Department of Natural Resources between 1967 and 1980. Subsequent exploratory drilling programs by Iron Ore Company (IOC) in the 1980s found that the REE and high field strength element (HFSE) mineralization were within the central region of the SLAC which was named A Zone by IOC and later renamed Main Zone by Quest Rare Minerals Ltd. (Quest). Additional exploratory drilling outside the Main Zone by IOC and later by Quest, led to the discovery of B Zone, which was recognized as the most significant deposit of rare earth elements, yttrium, and zirconium in the SLAC. The B Zone Indicated Resources are estimated at 278.13 Mt at 0.93% total rare earth oxide (TREO) and Inferred Mineral Resources are estimated at 214.35 Mt at 0.85% TREO (Oyediran et al., 2014)."

Jan 1, 2016

ERRATA-AUTHOR&apos;S REPLY IN SEPTEMBER, 1970, JOURNAL: PAGE 52 I. Left half of the page, 4th paragraph, fifth line from the bottom: for 22 / 5 1/2 %, read 22 / 5 1/2 %. 2. Right half of the page, fifth paragraph from the bottom, third line from the bottom: for N(l - p), read N(1 - p)x. 3. Right half of the page, fourth paragraph from the bottom, second line: for: at time t after time zero, read: at time x after time zero. NOTICE TO ALL STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY The Institute offers each year for competition among Student Members of the Institute a prize, or prizes, should entries so warrant it, of up to the value of R100 to be awarded to the Student Member or Members who submit the best paper or dissertation on a topic appropriate to the interests of the Institute. In the case of Student Members who are in full time study at a university the dissertation or thesis which they may have to write in part fulfilment of their university curriculum may be accepted provided it is presented in a manner and on a topic suitable for publication in the Journal. The closing date for the receipt of papers shall be 31st December each year.

By W. L. Kerlie, J. H. Richards

The variation in hydrogen content of basic open-hearth steels during refining and the effect of changing from steam to air atomization were studied. The water content of the furnace atmosphere, the slag basicity, and the degree of oxidation of the slag-metal system largely control the hydrogen in the steel. SMALL amounts of hydrogen have an adverse effect on the ductility of steel and a wide range of hydrogen contents has an adverse effect on the internal soundness of both ferrous and nonferrous castings. This has been of major concern to the metal industry, both manufacturers and fabricators, for many years. As one of the results of continuing investigations of the hydrogen problem, much has been learned about methods of reducing the hydrogen content of liquid metals below the relatively high levels that are normally associated with such phenomena as rising ingots and excessive porosity in sand casting. However, it was not until a reliable and simple method for sampling and analyzing liquid metal was developed that much progress was possible in quantitatively evaluating the effect of steelmaking practice on hydrogen contents at levels below 6 to 8 ppm. Throughout all the work described in the following presentation the Geffner pintube technique was used to obtain samples of liquid metal1 * and the tin-fusion method, developed at Massachusetts Institute of Technology,2 was used to analyze the samples. Before attempting a systematic experimental program for minimizing the hydrogen content of open-hearth steels, it was necessary to determine the variation in hydrogen in the open-hearth bath during the normal processing of a heat. The logs of ten heats are illustrated in Figs. 1 through 7. The number at each point on the graphs refers to the number of pintube samples analyzed for hydrogen. An increase in the hydrogen content of the liquid metal during the early period of refining is apparent in all heats. There is evidence of a decrease in hydrogen later in the refining period, see Fig. 2, for example. Therefore, the existence of a maximum hydrogen content at some intermediate time during the refining period is anticipated. To test for the existence of a maximum, the data illustrated in Figs. 1 to 5 were grouped together so that they could be examined on a collectively comparable basis. The grouping was effected, as illustrated in Fig. 8, by superimposing Figs. 1 to 5 so that the apparent hydrogen maxima coincided at a fixed position, indicated by the zero on the time axis. Also, by vertical adjustment until the graphs appeared to the eye to be superimposed, the hydrogen scale was made to show the change in hydrogen content. That is, a standard amount was subtracted from the hydrogen values for each heat. Therefore, Fig. 8 represents a generalized presentation of the data and, for this reason, cannot be used to predict the actual hydrogen content of the bath during refining, but rather to show the probable rate of change in hydrogen during refining. Statistical examination of the grouped data in Fi.g. 8 shows that the apparent. increase and suhsequent decrease in hydrogen are real and confirms the existence of a maximum in general. The average increase In hydrogen during the early period of refining is between 0.8 and 1.3 ppm per hr, and the

Jan 1, 1958