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By G Richmond, J R. Glen

Western Metals Mt Gordon Operation is a copper mine and processing plant situated 120 kilometres north of Mt Isa. The unique Mt Gordon copper process utilises a whole of ore acid/ferric pressure leach to produce copper cathode from the Esperanza massive sulfide copper orebody. Esperanza ore contains chalcocite, covellite and minor chalcopyrite hosted in a massive pyrite matrix. These ore stocks will be depleted in late 2003. Recently the process circuit has been upgraded to allow the treatment of lower grade Mammoth ores. These include the installation of a ball mill to complement the existing SAG mill, a single stage rougher flotation circuit and a tailings thickener. The leach bleed neutralisation plant was also upgraded at this time. Commissioning of these new circuits occurred in March 2003 and involved all the challenges of ensuring current production levels were successfully maintained while new process steps were incorporated into the whole circuit. This paper explains the background flow sheet of the patented Mt Gordon process and the reasoning behind the enhancements required for an already successful copper leaching circuit. Included are discussion of the influences of the new ores on individual process components such as comminution, leach chemistry and solid/liquid separation. Longer term ore processing options are also discussed.

Jan 1, 2003

By T. Chmielewski

Unique mineralogical and petrological properties of black shale in the copper ore deposit of the Foresudetic Monocline (SW Poland) resulting from three lithological layers have been described in terms of its unfavorable behavior in the ore processing circuits. A concept of processing of a part of the black shale fraction from the flotation circuit of the concentrating plant by separating a by-product enriched in the shale matter was presented. This by-product represents the tailings of the first cleaning flotation and, as a hard-to-treat circulating middlings, overload the cleaning operation in the flotation circuit. It was found that the investigated by-product cannot be effectively up-graded using standard xanthate flotation. This is due to a fine dissemination of sulfide minerals in the dolomitic and clay shale particles significantly enriched in organic carbon. The content of the organic carbon is similar to that in the petrographically "pure" black shales. After a comprehensive examination of the shale by-product it was recognized that the investigated middlings can be regarded as a specific shale concentrate for individual processing. The effect of non-oxidative leaching of middlings with sulfuric acid on their further flotation was presented. It was shown that non-oxidative leaching is a selective process, in which calcium and magnesium carbonates decomposition leads to effective liberation of sulfide minerals which were finely disseminated in the hydrophilic carbonate gangue. Leaching of the flotation feed with sulfuric acid selectively decomposes carbonate minerals and consequently enhances flotation results. Saturation of leaching slurry with gaseous carbon dioxide favorably creates non-oxidative conditions and leads to a great decrease of the electrochemical potential of sulfide particles as well as hinders their solubilization. Partial carbonates leaching from middlings resulted in evident liberation of valuable minerals. Consequently, it resulted in an increase of both recovery and grade of concentrates obtained by flotation of shale by-product after non-oxidative leaching.

Jan 1, 2014

By Sidney Katell

This study presents the economics of the hot-carbonate purification process for removing C02. It considers three variations of the process in order to meet the design specifications, which call for a feed-gas flow of 10 million standard cubic feet per hour (std.c.f.h.) with C02 inlet concentrations of 10, 20, and 30 percent and exit C02 values of 5, 2, 1, 0.5, and 0.1 percent. Inlet pressure and temperature are 350 pounds per square inch [e] (p.s.i.g.) and 300° F., respectively. Estimated capital and operating costs are shown in the following to tabulations: [ ]

Jan 1, 1960

By Leonardo Zuchi Guio

A ArcelorMittal Tubarão vem trabalhando nos últimos dois anos na implantação de um sistema automatizado de julgamento da qualidade da superfície de bobinas laminadas a quente, juntamente com a ArcelorMittal Global R&D. Tal sistema é denominado CGSIS – Coil Grading Surface Inspection System – e tem a função de interpretar as ocorrências de defeitos superficiais, identificados por um sistema de inspeção automático através de câmeras CCD auxiliado por técnicas de visão artificial, à luz da necessidade requerida pela aplicação final do material. Todas as ações sugeridas pelo sistema são baseadas em regras de aplicação e nas informações obtidas do sistema de inspeção automático, requerendo para isso taxas de acerto de classificação de defeitos adequadas para uma boa tomada de decisão. Para tanto, várias melhorias foram necessárias, envolvendo questões de ambiente, desempenho, confiabilidade, disponibilidade e treinamento do sistema, para se obter com isso melhores níveis de detecção e acerto. Outras questões envolvidas em tal processo concernem às mudanças aplicadas a políticas já estabelecidas de julgamento e comunicação do novo sistema com os sistemas já existentes. Vários benefícios da implantação do projeto já estão sendo percebidos provenientes das etapas de preparação para a instalação e espera-se que após a operacionalização um ganho superior a R$320k entre redução de custo com pessoal, aproveitamento de material e redução de reclamações de clientes seja alcançado.

Jul 30, 2018

By Ram V. Ramachandran

As an industry with major potential impacts (both good and bad) on water resources and due to the rising costs of process water, the mining and metallurgical processing industry has a key responsibility to contribute to the overall goal of preserving both the quantity and quality of water available within the watersheds they operate in. As we plan for new and existing mining and metallurgical projects, we need to consider a hierarchy of options to minimize our impact within the watersheds we operate; keeping clean water clean by diverting around our operations; reduction in the amount of water we use; reuse of water wherever possible, and improvements to water quality for recycling and/or release to environment. Technology is needed to treat water to improve its quality for reuse or release to the original watershed. While lime precipitation followed by sulfide polishing is effective for removal of most of the metals, it does little or nothing to remove ammonium ions and anions such as chloride, nitrate, molybdate, arsenate and selenite/selenite. Regulations on sulfate limits in treated discharge water has drawn close attention to the treatment of acid mine drainage (AMD). Management of brine and salt disposal is also posing a problem due to strict regulations and cost of disposal. This paper will: (a) address issues associated with managing water with the objective of maintaining water sheds—status quo-during and after operation (b) discuss potential technologies for advanced water treatment plants.

A kinetic model for leaching of various metals with different lixiviants in a batch system has been developed. Material balances for reactants and products at the solid/liquid interface were formulated and solutions to these balances were obtained in view of practical conditions. Special emphasis has been given to examine mixed controlled reaction systems where both heterogenous reaction and mass transfer play important role on the overall rate expression. The resulting kinetic expressions for either powder or rotating disc are discussed in light of experimental findings for various metals. Examples of the metal dissolution systems considered in this study include cobalt, nickel, copper and gold in acid, cyanide or ammoniacal solutions.

Jan 1, 1992

By H. J. McQueen

Pyro-reduction of ores to metal products developed markedly through the industrial revolution into the great depression. Nineteenth century resource and environmental sustainability were haphazardly improved by many process changes, although the motivation was primarily reduction in labor, feed stocks and fuel. Some notable achievements were coke and hot air for blast furnaces (later from waste heat stoves), puddling of wrought iron and steel ingot production with convertors advancing into oxygen use and continuous slab, billet and strip casting. Although advances in one sector were often counteracted by fall-backs in others, there was progress in that the resource consumption and pollution per unit of production was decreased. Improvements in the 2 decades following WW2 were mixed but popular notice of environmental hazards forced governments to legislate pollution controls and initiate steps in resource conservation. The energy crisis of the 1970’s saw an industrial energy-saving campaign and legislation of technology assessment procedures. Up until mid 18th Century, the training of iron masters depended on apprenticeship with some formalized knowledge from medieval books such as those of Biringuccio (1540) and Agricola (1556). The advances were very slow partly due to absence of scientific concepts of the smelting process. Nevertheless, some iron masters succeeded in improving the process and described procedures to instruct others. With the surge of steam power and the reverberatory puddling process for ductile wrought iron (WI), machinery changed from wood (iron strap reinforced) to WI machinery. With the clarification of the reduction and oxidation mechanisms by Cavendish and Lavoisier (~1780), productivity in iron production surged. The mechanical testing and microscopy of Kirkaldy (1862) spurred understanding of processing and properties of WI and steel. The various forms of C in steels were determined by chemists at the end of the 19th Century. It also became possible to control metal and slag chemistry in the open hearth furnace. But understanding of the transformations during heat treatment of steel only came in the first decades of the 20th Century.

Jan 1, 2012

By William G. Pariseau, H. Douglas Dahl

Recent subsidence legislation indicates that mining engineers would be welt advised to be able to predict and control surface damage caused by mine subsidence. To date, such an ability is practically nonexistent. Model analysis is suggested as one of the alternative paths available which might yield fruitful results. Similitude requirements developed for a self-loaded body in static or quasi-static equilibrium indicate that complete similitude without centrifuging is an impracticability. However, a pilot experimental study which used a simplifying assumption to correctly model mine subsidence has produced results in qualitative agreement with field observations. The purpose of this paper is to present a discussion of the various approaches that can be taken in the study of mine subsidence phenomena. Particular attention is focused upon the rational selection and use of laboratory models. Broadly interpreted, mine subsidence is the deformation of the rock mass enclosing a mine. Depending upon a number of factors, the movement of the subsiding rock mass may disrupt gas and water lines or other buried utilities, damage surface structures such as buildings and bridges, dislocate streams, roads, and rail lines, aggravate acid mine drainage and fire problems, and generally mar the landscape. It is clearly a problem that no mine manager can safely ignore. It is also a problem that will grow with the general population increase. In the following discussion, a summary review of past and present approaches to subsidence studies is given. The possibilities of duplicating subsidence phenomena in laboratory models are examined, and an analysis of a particular type of model is presented. Some preliminary results obtained from a model of the particular type analyzed are then discussed. REVIEW OF PREVIOUS WORK Historically, subsidence investigations have been empirical studies in the field and laboratory or theoretical analyses of mathematically idealized media. Empirical and theoretical work in the United States has generally lagged behind investigations abroad. In the United States, field studies are mostly pre-World War 11. These are summarized in the Mining Engineer's Handbook. ' Field studies in Europe are more recent and more extensive. Those made in Great Britain are summarized in the Subsidence Engineers Handbook2 and represent observations made at 157 different collieries. Such studies by themselves are of limited usefulness as are all empirical studies. One can never be certain that conditions at one mine will be similar enough to those at another to warrant the drawing of like conclusions. European subsidence formulas rely heavily upon the "angle of draw" and "critical area" concepts. The angle of draw is defined as the angle between a vertical line through the face, and another line extending from the face to the surface at the point where movement is zero. The critical area is defined in relation to the least extraction necessary to produce maximum subsidence. Fig. 1 illustrates the angle of draw and critical area concepts. First and second "limits of influence" are also shown. The angle of draw and associated critical area concept are obviously not well defined, being dependent upon the accuracy of the surface survey. In Great Britain, the angle of draw has increased through the years from about 26 to 35°. In the United States, zero and negative angles of draw have been reported. In the authors' opinion, these purely geometrical concepts represent an oversimplification of subsidence phenomena and their use, in the United States at least, should be discouraged. Empirical observations of laboratory models containing layers of earth, sand, clay, and plaster were made by Fayol (cited by Peele) as early as 1885. An outgrowth of his work was the "dome theory," a verbal description of what is assumed to occur in subsiding rock masses. The dome theory has since fallen into disrepute. Theoretical analyses worthy of the name treat a subsiding rock mass as a deformable body. In these analyses, the actual rock mass is replaced by an idealized material that deforms according to a simple stress-strain relationship. The stress equations of equilibrium expressing the Newtonian laws of mechanical action and the geometry of strain furnish additional equations that must be satisfied. A loading criterion-generally understood, and in some cases stated explicitly-completes the theory.

Jan 1, 1969

By S. Nakamura, M. Takaoka, Y. Mizuno, T. Kusakabe

"Mercury is produced as a byproduct from gold mines and, historically, has been transferred to recyclers and used for various industrial processes and products. However, under the Minamata Convention on Mercury, adopted in 2013,the intentional use of mercury in processes or products will be minimized in the world. Surplus elemental mercury should be treated as a hazardous waste and consequently, should be converted to a more stable chemical form for long-term storage or permanent disposal. A stabilization method has been developed to react mercury and sulfur using a planetary ball mill. The planetary ball mill can produce high-energy conditions and enable samples to react within a short period of time. A series of tests has been conducted to confirm that mercury sulfide can be produced using a bench scale machine with 2400 mL pot. Under a suitable experimental condition with 25 mm ball diameter, 30%of ball filling rate and 1.05 of molar ratio of S/Hg, a powdered mercury sulfide product was successfully obtained in 60 minutes. The leach ability and atmospheric emission from the product was extremely low. This stabilization method would contribute to an environmentally sound mercury management strategy for the gold industry.INTRODUCTIONDue to its unique physical and chemical properties, mercury has numerous applications, including in industry and medicine. However, mercury and its compounds are highly toxic. For example, in Japan, methyl mercury in waste water caused Minamata disease in the 1950s, which affected large numbers of people (Minamata Disease Municipal Museum, 2001). In recent years, environmental pollution caused by emissions and releases of mercury into the atmosphere, waterbody and land by various emission sources such as coal fire plants, artisanal and small-scale gold mining (ASGM), non-ferrous metal industries, waste incinerations etc. has also become a significant problem. To protect human health and the environment from anthropogenic emissions and releases of mercury and its compounds, the Minamata Convention on Mercury was adopted in 2013(UNEP, 2013)Because ground gold ore typically contains mercury at 0 to 100 ppm, mercury is often produced as a byproduct from gold mines (UNEP, 2016). In gold mining operations, mercury can be released from the ore by roasting or by leaching in cyanide solutions and recovery onto activated carbon. According to Yanget al. (2016), 85.1%of mercury in a concentrate was vaporized during a roasting process. Both processes finally discharge elemental mercury as a byproduct. In the USA, more than 100 ton of mercury was discharged from large-scale and industrial gold mining (Miller, 2004)."

Jan 1, 2017

By W. Z. Yin

With increasing of mining depth, many iron ores in Liaoning Province contain carbonates such as siderite and ankerite. The emergence of these carbonates in ores creates a fatal impact on the running producing process of anionic reverse flotation in Dong Anshan Sintering Plant, which leads to ?concentrate and tailing no separated?. And its reason is still unknown. Moreover, siderite, despite that its ferric theoretic grade is only 48.2%, however, do not affect the blast furnace utilization factor, therefore, can be used as raw materials in ironmaking. In order to solve the separate problem of iron ore containing carbonates, five pure minerals, martite, magnetite, quartz, siderite and ankerite, were selected for a series single flotation experiment. The aim was to discover the flotation difference of these minerals, furthermore, to explore a new flow sheet for the iron ore containing carbonates. The results of single mineral flotation experiment reveal that the combination regulators, starch and CaCl2, in different pH extent, can make these minerals taking on obvious flotation difference, which make it possible to process the iron ore containing carbonates. A new flow sheet, step-flotation, to process iron ore containing carbonates is explored, that is, first step, direct-flotation processing, is to eliminate the bad effect that the carbonates bring in flotation system by collecting carbonates under neutral condition; the second step, reverse?flotation processing, is to get qualified iron concentrate by collecting quartz under alkaline condition. Manual mixed ore sample were processed successfully through this new flowsheet under proper reagent system, which has absolute advantage compared with routine flowsheet. Actual ore sample of compound magnetic separation concentrate were processed successfully both open and closed circuit experiment through this new flowsheet. SEM and EDS were used to probe the reason why carbonates affect the regular processing. It is analyzed that moderate floatability of siderite and its coating on the surface of hematite and quartz make the phenomenon ?concentrate and tailing no separated?. This research provides a reasonable processing scheme for iron ores containing carbonates and can be used for reference in processing other complicated, refractory iron ore.

Jan 1, 2014

By Russell Frith

The entire subject area of micro-seismic events due to stored strain energy, as distinct from gas-driven coal outbursts, can be readily sub-divided into firstly events with their energy source from within the coal seam (termed “bursts”) and secondly, event with their energy source outside of the coal seam in either the overburden and/or floor strata. The reason for sub-dividing micro-seismic events in this manner is that if the causation mechanisms and associated geotechnical conditions are materially different, then effective pre-mining predictions and subsequent operational controls may also differ. Attempting to explain a multitude of micro-seismic event types without consideration of varying source mechanisms will inevitably lead to inadequate causal explanations and effective controls.

By M D. Uttarwar, R R. Yerpude

India is the world’s third-largest producer of coal and is endowed with the fifth-largest coal reserves in the world. Surface mining straddles the entire domain of the Indian coal mining industry, yielding over 88 per cent of production. With continually rising domestic demands, it has to shoulder the responsibility of sustaining the requisite increase in coal production and chasing commensurate stripping targets. Such an ambitious task calls for the deployment of smart technologies. In such a demanding situation, cast blasting of overburden has emerged as a promising alternative for enhancing production and productivity of dragline pits.The cast blasting technique reduces stripping costs significantly as it utilises the chemical energy of explosives in place of mechanical energy to move large volumes of overburden quickly. Proper application of cast blasting not only reduces overall mining costs but also increases coal production. This paper investigates and evaluates the potential of the cast blasting technique, with special reference to dragline pits employing the rehandle method of extended bench. The economic feasibility of the technique is also ensured under different scenarios so that considerable benefits would accrue to the individual surface coalmines. To underline the efficacy of the technique, different cast blasting models have been formulated under a range of operational and economic scenarios that resemble present day practices in India. In order to test for economic variability in the application of the technique, a risk analysis of all the formulated cast blasting models is performed using net present value.CITATION:Uttarwar, M D and Yerpude, R R, 2015. Potential of the overburden cast blasting technique in Indian surface coalmines – a modular approach and its financial implications, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 655–664 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By M. L. Brashears

Pine Point Mines is located in the Northwest Territories of Canada, about 500 miles north of Edmonton, Alberta (figure 1). Lead-zinc ore is found in numerous localized deposits along a generally east-west trending reef of Devonian dolomite, about 5 miles south of Great Slave Lake. A pumping-test program was carried out in 1968 to guide the design of dewatering systems for several open pits that are partially or wholly below the natural ground-water levels. The hydrogeologic conditions, methods employed and results obtained are discussed.

Jan 1, 1971

By N. P. Reddy

This paper describes an experimental setup for multiple-fan ventilation systems at the ventilation laboratory of the WVU Department of Mining Engineering. Housed in a 30 ft by 70 ft room, the experimental setup consists of three 18 in. variable-speed axial-flow fans, the 18 in. diameter fiberglass tubing and fittings for arranging networks, and the pitot tube measuring and data acquisition system. The fiberglass tubing and fans can be organized into the non-planner network of two fans or three-fans. It is mainly designed for studying the characteristic curves, operating points, and fan stall for the multiple-fan ventilation system.

Jan 1, 1992

By T. Tamenti

The purpose of the project was to conduct a feasibility study to determine if the current operating bottom dump trucks that haul coal should be replaced with rear dump trucks. The engineering availability of the bottom dump trucks was lower than targeted while the operating costs are the highest of all coal haulers within the Anglo Coal opencasts. To determine if it is feasible to replace the current bottom dump trucks with rear dump trucks, a production profile simulation was conducted to determine the number of rear dump trucks that would be required to meet the annual coal hauling requirements. The total capital and operating costs of these rear dump trucks were also determined using a total cost of ownership model. These were compared with the current costs of the bottom dump trucks to determine if it is financially feasible to replace the bottom dump trucks with rear dump trucks. Having considered the capital outlay that would be required to replace the bottom dump trucks with rear dump trucks as well as their respective operating costs, it was concluded that the current bottom dump trucks should be replaced with rear dump trucks. Other factors were considered in coming to this conclusion.

Jan 1, 2007

By J. A. Eisele, D. J. Bauer, D. E. Shanks

As part of its effort to produce cell - grade alumina from clay , the Bureau of Mines investigated the hydrogen chloride gas - sparging crystallization of aluminum chloride hexahydrate ( ACH ) from aluminum chloride liquor , to provide information for optimizing the crystallization operation . Four parameters important in controlling the crystallization of the aluminum chloride hexahydrate and the concentration of impurities , particularly phosphorus and magnesium , in ACH crystals are ( 1 ) aluminum chloride concentration in the feed solution to crystallization , ( 2 ) hydrogen chloride gas flow rate , ( 3 ) temperature , and ( 4 ) concentration of phosphorus and magnesium also in the feed solution . Parameters 1 , 2 , and 3 affect crystal formation . The combined effects are very important because the phosphorus and magnesium concentrate in the crystals during the early stages of crystal growth . Aluminum chloride hexahydrate of cell -grade purity was crystallized from saturated aluminum chloride solutions containing less than 0.003 wt - pct P205 and 0.010 wt - pct Mg0 . Crystallization temperatures less than 60° C decreased crystal purity .

Jan 1, 1965

By C. I. Basilio

The adsorption of dialkyl di-and mono-thio-phosphinates on gold, silver and gold-silver alloys has been studied in the present work. These reagents, which are selective collectors for sulfide flotation, have been found to improve precious metals recovery from ores. Voltammetric studies have indicated that dithiophosphinate adsorbs on gold at much higher potentials than on silver, while monothiophosphinate adsorbs only on silver. However, both adsorb on gold-silver alloys with the adsorption potential decreasing with increasing silver content. Using FTIR spectroscopic measurements, the surface species formed during the interactions of these collectors have been identified. The results of the electrochemical and spectroscopic measurements have been compared with the contact angle data obtained at controlled potential conditions.

Jan 1, 1992

By Constantin D. Pitis

?Demand-side measure" means a rate, measure, action or program undertaken to conserve energy or promote energy efficiency?? (BCUC, 1996) In actual economical environment, business sustainability requires high-efficiency technological processes. That is why the efficiency concept has to be present at all levels of industrial activities. Nowadays, some purchasing decisions are still driven predominately by the purchase price, in spite of the evidence that such price represents up to 5 % to 7 % of the total costs of ownership with full consequences of energy efficiency and the impact on total ownership costs. The paper presents essentials of converter types and basics of the Global Efficiency (GEff) Concept that has been promoted over the last few years in South African industries (Pitis et al., 2006/7). GEff concept is proven as a useful tool used on price-efficiency decisions. Theoretical and technical aspects of this concept were substantiated with case studies. First part presented in this paper will describe how GEff concept was used on price ? efficiency decisions when single input or direct converters and systems (considered as low value equipments) have been replaced. Besides the impact of energy savings and new innovative developments, the paper suggests general other benefits of: ? Technical and economical performance improvements and competitiveness of mining corporations to international standards; ? Defusing incipient energy crisis in the sector; ? Improving environmental conditions; ? Creating new job opportunities in mining sector. Proposed concept in this paper could be further developed as models of improving companies? corporate energy policies.

May 1, 2010

By AIME AIME

Change of Meeting from Birmingham to Chattanooga. In consequence of the disturbed conditions attending a long¬continued labor strike in Alabama, the meeting of the Institute was changed from Birmingham, Ala., to Chattanooga, Tenn., where it will. begin on Thursday evening, Oct. 1, 1908. Information. of this change bad been sent to the newspapers through the Associated Press, and by circular to all members, when news was received of the sudden and unexpected termination of the strike referred to. It was, unfortunately, too late to change once more the arrangements for the meeting. But it is hoped that the cordial invitation of the citizens of ,Birmingham may be renewed and accepted at a future time, not too remote. Office Facilities for Visiting Members. A separate room in the suite occupied by the American Institute of Mining Engineers on the ninth floor of the United Engineering Society Building, has been equipped with furniture and telephone extension for the temporary use of members of the Institute or of sister societies, or visitors suitably accredited. Members of the Institute visiting New York for a short time, who need office facilities during their stay, or members residing in the city. who need temporary office accommodation, can arrange to have set apart for their exclusive use a room, equipped with office furniture, telephone, etc.,. in the suite of the Institute. It is not the intention to give possession of the room to any individual for an indefinite time, but to offer to members of the Institute an opportunity to acquire a well-located, well-equipped business headquarters to carry on transactions which

Jan 9, 1908

By B. Birol, M. N. Saridede

"Slag density is a significant factor in determining the process efficiency of the electroslag remelting (ESR) process, where calcium fluoride (CaF2)-based slag is formed synthetically to refine metal ingots. Although there are some former studies investigating the density of CaF2-containing slags, the prediction models focusing on them are applicable only to some specific systems. The present study aims to build a model to predict density for a wide range of CaF2-containing ESR slags. To investigate density for various slag compositions, CaF2-Al2O3-based and CaF2-Al2O3-CaO-based slag compositions were prepared. Additionally, some minor constituents like FeO, MgO and MnO were added to a 5:3:2 CaF2-Al2O3-CaO slag in order to investigate the effects of these constituents on the slag. The volumes of the prepared slags were measured in a tube furnace at 1450-1550 °C using the sessile drop technique, and their densities were calculated. The results showed that for the slags, density is related to optical basicity, and therefore a prediction model based on an Arrhenius equation was built. The model was tested with data from literature, and its limitations and validity are discussed.IntroductionThe electroslag remelting (ESR) process is a refining method in which a metal ingot is remelted under a synthetic slag. These synthetic ESR slags are mainly composed of calcium fluoride (CaF2), calcium oxide (CaO) and aluminum oxide (Al2O3). Other constituents like iron oxide (FeO), magnesium oxide (MgO), manganese oxide (MnO) and chromium oxide (Cr2O3) are added to this system in relatively low amounts, according to the type of steel ingot to be refined. The prediction of slag properties, such as electrical conductivity, viscosity and density, is crucial for the selection of the synthetic slag in order to obtain the required process parameters, like temperature, the passing time of the molten metal droplet through the slag, and metal-slag separation (Akbari, Reitz and Friedrich, 2009; Hara and Ogino, 1981; Mattar, El-Faramawy and Fathy, 2002; Mehrabi, Rahimipour and Shokuhfar, 2005; Presoly, Korp and Schneider, 2008).As slag density affects metal-slag separation in the ESR process, predicting the density of an ESR slag is important for appropriate refining and improved product quality. Although there are many studies investigating the density of slags (Akbari, Reitz and Friedrich, 2009; Aune, Hayashi and Sridhar, 2005; Hara and Ogino, 1981; Matsushita, 2011; Mills and Keene, 1987, 1981; Seetharaman et al., 2013; Shu, 2007; Shu and Chou, 2013; Sikora and Zielinski, 1974; Xu et al., 2012; Zhang and Chou, 2010), the prediction models built are generally valid for oxide-containing slags (Aune, Hayashi and Sridhar, 2005; Bottinga and Weill, 1970; Mills and Keene, 1987; Seetharaman et al., 2013; Shu, 2007; Xu et al., 2012; Zhang and Chou, 2010). These models were built on either the molar volumes of the constituents (Bottinga and Weill, 1970; Mills and Keene, 1987) or the thermodynamically calculated enthalpy or free energy of mixing, which can be applied to a system containing constituents sharing an ion, such as an O- ion for oxide systems (Aune, Hayashi and Sridhar, 2005; Hillert, 1980; Persson et al., 2007). Some recent studies modeled the density of some oxide slags on their optical basicity (Shu, 2007; Shu and Chou, 2013; Xu et al., 2012; Zhang and Chou, 2010)."

Jan 1, 2016