Search Documents

By S. R. B. Cooke, W. Philippoff, Donald E. Cadwell

[THE importance of contact angles in flotation has long been recognized, but little has been done to get quantitative relationships between the surface coverage of the mineral by the reagent, the length of the hydrocarbon chain, and the contact angle. It is well known that for a complete monolayer on the surface of a mineral the contact angle ? is determined only by the reagent&apos; and principally by the chain length of the hydrocarbon radical. Although for flotation the monolayer usually is regarded as being complete, early experiments of Wark and Cox2 showed that at very small concentrations of potassium ethyl xanthate the contact angle on galena changed in a continuous way from 0° to the equilibrium value of 60°. Further, Gaudin and Vincent&apos; showed a similar continuity using heptylic acid and sphalerite. This shows that with probably incomplete monolayers, ? varies with the degree of surface coverage. At the time these experiments were made it was impossible to measure the actual amount of surface coverage, especially since the decrease of the collector concentration in the liquor could be influenced by chemical side reactions. Through the use of the radioactive tracer method for the measurement of the amount of collector adsorbed on the surface of the mineral, Gaudin and Bloecher4 were able to determine accurately the actual surface coverage of dodecylamine acetate on quartz, but they did not measure any contact angles. It is believed that the relationship between the surface coverage and the contact angle is extremely important in flotation, especially as Gaudin and Bloecher showed that a 95 pct recovery is possible with a coverage of only 5 pct. Theoretical Considerations The work of adhesion W is the energy bound (in ergs per sq cm) when an interface is formed. It is determined by, the difference of the free surface energies (surface tensions) of the respective phases ?1 and ? 2 before contact and the interfacial free surface energy ?12 after contact. The definition of the contact angle permits the elimination of the unknown surface energy of the solid and hence the calculation5 of W from the surface tension of the liquid ? and the contact angle ?: [W = y (1 + cos ?)[1]] Consider a surface consisting of two components, identified as 2 and 3, 1 being the liquid. The amount of 2 in the composite surface is x, where 0 < x < 1. The respective contact angles with 1 and air are ? and ?3. The total work of adhesion of such a surface is the sum of the values of the components multiplied by their respective areas. A formal relation can be written: [W,,,=x•W2+ (1-x).WR[2] .] in which Wm is the work of adhesion of the composite surface. Eq 1 can be introduced into W2 and W3 but in the case of Wm some discussion is needed. If the two components are segregated, each component forming an integral part of the composite surface there is no physical meaning for a contact angle ?m, calculated from Wm, by using eq 1. If, on the other hand, the area of each patch of the components is small in comparison with, say, the diameter of the bubble used in measuring, it could be expected that ?m would have aphysical significance, because of the action of the surface tension of the liquid-gas interface tending to smooth out sharp corners. How small these patches would have to be is difficult to predict, but by using composite surfaces with microscopically]

Jan 1, 1952

By J. R. Thoenen

During 1928 questionnaires covering the calendar year 1927 were sent to over 1700 quarries: producing stone for purposes other thaw cutting to dimension. These inclined producers of stone for limn burning; cement manufacture, rip rag, and crushed stone. The various rinds of stone represented were limestone, trap rock, sandstone, granite, and marble. Replies received from limestone producers prior to November, 1928, were compiled into tables and published in February, 1925, as a preliminary report (Bureau of Mines Report of Investigation 2911).

Jan 1, 1930

By C. Cutts, K. Wheatley

The Dragon Lake Zone (uranium prospect) comprises a N160º trending vein that is approximately 110 m long, up to 5 m wide and from 1 to 40 m high. The zone is mostly within altered sandstone of the Fair Point Formation, the basal unit of the Paleoproterozoic Athabasca Group, but it also extends downward (up to 3.5 m) into basement rocks that occupy the northerly trending Maybelle River Shear Zone (MRSZ). This subvertical shear zone separates graphitic paragneiss and weakly deformed granitoid rocks to the east from non-graphitic paragneiss and foliated granitoid rocks to the west. The Dragon Lake Zone cuts across both the MRSZ and N060º-N070º-trending cross-faults that offset the shear zone but not the mineralized vein, which contains values up to 54.5% U over 50 cm core length. Strong chloritization occurs in graphitic paragneiss and sandstone adjacent to mineralization. Silica was depleted from the basement rocks and redeposited at the borders of the 5-15-m-wide alteration zone, as well as within overlying sandstone of the Manitou Falls Formation. There are minimal alteration effects in the overlying Lazenby Lake Formation. Geochemistry shows that the alteration zone in the Fair Point Formation is highly anomalous in metals, most notably in Ni, As, U, Pb, Co, and B. Clay within this zone is illitic and Fe-rich chlorite is also present. Brittle deformation is not as widespread or as well developed in the Fair Point Formation as it is in the overlying Manitou Falls Formation, which is extensively brecciated and contains some anomalous metal values.

Jan 1, 2013

By G. R. Peterson

To determine the availability of aluminum from world bauxite resources, the Bureau of Mines investigated 139 bauxite deposits worldwide and evaluated the potential production of aluminum based on the demonstrated resources of bauxite ore from 91 mines and deposits in 22 market economy countries. The demonstrated resources of the bauxite mines and deposits included in this study represent an in situ resource of 20.2 billion metric tons of bauxite. Total identified bauxite resources in market economy countries amount to roughly 31.9 billion tons. Of the demonstrated resource, some 18.8 billion tons of bauxite considered minable provide a production potential of 3.6 billion tons of primary aluminum. Given the wide geographic distribution of bauxite deposits, stable supplies of bauxite for aluminum production seem assured well into the next century. However, a tight market situation could develop during the 1990&apos;s unless the real price of aluminum increases enough to stimulate massive new investments in production capacity, particularly in refining and smelting. This study indicates that a real price of at least $0.85 per pound (in January 1980 dollars) would be necessary to stimulate the required investments and provide a sufficient rate of return on invested capital.

Jan 1, 1983

By Haldane J. S.

Discussion of a paper presented at the Institution of Mining Engineers' general meeting held in London on 8th June 1916 included oral contributions by Louis H., Mowat D.M., Lupton A., Bailey T.H., Blackett W.C. and Gerrard J., and written contributions by Collis E.L., Carlow C. and Wilson W.B., with the author's oral and brief written responses

Dec 1, 1916

By Hevina S. Dashwood

This paper proposes to build on my previous research (Dashwood 2012), which analyzed how and why the norm of sustainable development became institutionalized in the global collaborative corporate social responsibility (CSR) initiatives of major mining companies. Since the late 1990s, the majority of major global mining companies have employed the norm of sustainable development to frame their individual CSR policies and to inform industry collaboration at the global level through the International Council on Mining and Metals (ICMM). This paper proposal seeks to address lingering questions from that research, by developing an explanation for how the normative frame of sustainable development has translated into specific CSR standards adopted by the mining industry. Preliminary findings suggest that, although the global mining industry has reached broad consensus on the meaning of sustainable development in the context of mining, there remains considerable variation between mining companies in terms of which specific global standards they adopt. As members of the ICMM, major mining companies are required to report according to the Global Reporting Initiative (GRI) indicators relevant to mining, and there has been wide-spread up-take of the ISO 14,001 environmental management system standard. However, other global standards, such as the International Finance Corporation (IFC) Performance Standards and the Extractive Industry Transparency Initiative, have not been uniformly adopted by the mining industry. What explains this variation? The paper employs a three-level institutional framework (rational choice institutionalism, historical institutionalism and the ?new? institutionalism in organization theory) to explain the influences on the adoption of CSR standards in the global mining sector. Existing research confirms that institutional context is an important factor in explaining CSR adoption in the mining sector (Dashwood 2012). Are similar forces at work in explaining the variation in adoption of specific CSR standards? A three-level institutional analysis lends itself to uncovering influences both external to mining companies (such as pressures from stakeholders), as well as internal company dynamics (such as managerial discretion). Furthermore, the framework can incorporate dynamics operating at the global level (such as isomorphism), the national level (such as the regulatory regime) and the local level (such as community needs and environmental challenges). The theoretical significance of this framework is that the influences on CSR adoption are more complex than can be explained in a single approach (such as narrow rational choice/cost benefit explanations). On a practical level, insights into how global standards get interpreted and acted upon by individual companies could lead to the development of more appropriate and effective global standards.

Aug 1, 2013

By Albert E. Long

During the summer and fall of 1948 the Bureau of Mines, in cooperation with the U. S. Geological Survey, conducted 6xperiments in diamond core drilling in the Phosphoria formation in southeastern Idaho and southwestern Wyoming. Nearly all of the diamond core drilling in the Phosphoria formation has been done by mining companies interested in finding and developing phosphate-bearing beds amenable to stripping. The recovery of sludge; and enough core (usually 30 to 60 percent) to identify certain marker beds produced by current drilling practices meets both the primary requirement of mining companies in determining depth of overburden and their secondary need to determine the phosphate content of relatively thick minable units whose general composition and nature are already fairly well established.

Jan 1, 1949

By G. G. Campbell

The Bureau of Mines in cooperation with Quaker State Refining Corp. conducted two underground-combustion oil-recovery experiments in the Venango Second sandstone in the Reno pool, Foster-Rena-Oil City field, Sugar Creek Township) Venango County, Pa.) to determine the applicability of the process for reservoirs producing Pennsylvania-grade paraffin-base crude oil. Tests were terminated when analyses of produced gas showed that a self-sustaining combustion front did not exist. It was thought that insufficient fuel had been deposited in the formation. Laboratory retort tests made after the second field test was concluded showed that crude oil from the Reno area would deposit enough fuel to support combustion if air flux, temperature, and time were maintained within defined limits.

Jan 1, 1967

By Alfred C. Lane

WE recently received from Professor A. C. Lane, Emeritus Professor of Geology and Mineralogy, Tufts College, Mass., and a Corresponding Member of this Institute, a very interesting account of some recent developments in radioactive methods of determining the age of minerals and, therefore, of the rocks in which they occur. It deals in particular with studies of the minerals of certain pegmatite dykes on the Huron claims and Bear claims in southeastern Manitoba, which, the results indicate, are among the oldest rocks of the earth&apos;s crust. The following article presents a non-mathematical summary of Professor Lane&apos;s paper . . It will be noted that he is anxious to obtain suitable samples of certain minerals and rocks for further age studies. We hope some o our members may be able to supply him with the material he needs. It may be well to explain briefly how the age determinations are made. Uranium is continually breaking down, or disintegrating in successive steps through radium, etc., to a final product which is lead (uranium-lead), and the rate at which this change takes place is known. Minerals containing uranium will therefore contain lead also, and the lead-uranium ratio mul-tiplied by a certain factor (approximately 7 ,600) will give the age of the mineral in millions of years. Thorium also disintegrates at a known rate to give lead (thorium-lead) as a final product, and the age of a mineral containing thorium can thus be calculated from the lead-thorium ratio. Thorium breaks down more slowly than uranium. In unit time, one gram of thorium produces about as much lead as 0.36 grams of uranium.-ED.

Jan 1, 1938

By P Ring, B Cooper, C Carr, G Laing

The Nova Ni-Cu-Co Operation, located in the Fraser Range of Western Australia, commenced commercial production in July 2017 only five years after discovery. Owned by Independence Group NL (IGO), the operation has successfully ramped up over an accelerated schedule and currently deploying leading technologies. This paper begins with a description of the Nova Operation, and its journey to achieve full production in such a short time frame. It includes discussions on development and production design, selection of fixed plant infrastructure, and the features challenges of running a low-pressure primary ventilation circuit. The paper also discusses key technologies that have improved overall safety for the underground workforce, and improved operational efficiencies. Investigations continue into the implementation of further technological applications for safety and productivity enhancements. This paper also discusses the findings from a study into transitioning from a diesel to an all-electric underground mining fleet, based on a review of Nova if it were to be developed today with the current EV offerings. The study indicates compelling savings will be available to future mines when considering development design, project schedule, capital outlay and operational savings, and the ‘next Nova’ is expected to be all electric.

Mar 15, 2021

This Bureau of Hines report on underground mine communications addresses methods and equipment to meet the communication requirements of working sections and places of coal and metal-nonmetal mines. A review of the status of trapped miner detection is also presented.

Jan 1, 1977

By S. D. Graham

"The extractive metallurgy of gold is largely controlled by mineralogical factors such as the presence of refractory gold, particle size, gangue mineral associations, presence of preg-robbers, oxygen and cyanide consumers, and locking characteristics in base metal sulphides. Light microscopy and automated mineralogy techniques are regularly used to characterise the effect of these variables on gold recovery. However, despite their widespread application there are a range of limitations when grades are low. Typically, the analysis of low-grade samples requires the preparation and analysis of numerous polished blocks. This is often costly and time consuming, with complexities regarding analysing statistically representative particle quantities and problems overcoming stereological bias. This is compounded by the “nugget” effect and high tenor nature of gold mineralisation. X-ray Microscopy techniques have the potential to overcome many of these problems, in particular the statistical representivity of analysis, removing stereological bias and effectively locating phases that are present in ultra-trace proportions. In this paper we outline the potential benefits of employing X-ray Microscopy (XRM) in characterising gold losses from a typical Cu-Au porphyry project, which were illusive in 2D based analysis. The talk will also outline additional application areas of XRM within the extractive value chain."

Jan 1, 2017

By Charles J. Stehlik

This report deals with the changing behavior of mine roof bolt and roof rock as a result of repetitious production blasting . Observations were made in the upper shale production headings at the White Pine Copper Co. room and pillar mine , White Pine , Mich . Roof bolt compression pads and a stratascope were used in the investigations , which were carried out in three separate test sites in which nearly identical procedure produced comparative , repetitive , and anomalous observations . Results indicate roof bolt tension change and roof quality deterioration anomalies were coincident with blasting . The hypothesized cause of the anomalies is a seismic shock generated by the blasts .

Jan 1, 1964

By Ruichen Ren, Xu Han, Caixia Li, Zengchuan Yue

In this paper, the size-density distribution of coarse middling coking coal (CMCC) with different grinding fineness and flotation concentrates was investigated. Then, the flotation behaviors and liberation characteristics of different size-density fractions in ground CMCC were analyzed, and the different size-density fractions were divided into five categories: mostbeneficial, secondary-beneficial, poorly liberated, insignificant-pollution, and serious-pollution. Based on the content of particles with different liberation characteristics, an evaluation index of the liberation characteristic of ground CMCC, namely, the liberation perfection index (LPI), was proposed. The results indicated that grinding changed the size-density composition of CMCC, which affected the flotation performance. Insufficient grinding and overgrinding were not beneficial to flotation. Insufficient grinding caused a higher content of poorly liberated particles and a lower content of most-beneficial particles. Overgrinding increased the content of serious-pollution particles and reduced the content of most-beneficial particles. The size order of the LPI values of different ground CMCC was consistent with the flotation efficiency, and the LPI values of the other two similar samples were overall positively correlated with their flotation performance, suggesting that the method is universal.

Feb 14, 2023

By K. Takahashi

Generally speaking, wastewater coming from the metallurgical process for recovering precious metal contains precious metals such as gold (Au), platinum (Pt), palladium (Pd), Silver (Ag), etc., which concentration is about 10 mg/L. In addition, there are other metals such as copper (Cu), iron (Fe), which concentration varies from several mg/L to more than 10,000 mg/L. It should be noted that the concentration of metals in wastewater is relatively high, considering the fact that these metals of similar concentration can be found in ores. However, most of these valuable metals are not treated, due to the high processing cost and technical problems. Within this frame, the authors put forward a new process that includes neutralization/reduction, precipitation and fusion. The idea is to recover and recycle Au, Ag, and Pd metals as well as protecting the environment by saving the resources. It was found that this new process was able to recover more than 90% of Au, Ag and Pd.

Jan 1, 2014

By D. W. Bacon

Plant process optimization programs are often costly, both in technical effort and loss of production. Evolutionary Operation or "EVOP" is a mode of plant operation consisting of controlled cyclical changes in process conditions by which information is provided concerning potential process improvements while both volume and quality uniformity in production are maintained. Its conceptual simplicity and low cost of utilization have led to successful adoption in a variety of industrial manufacturing operations. This paper is an expository account of basic EVOP theory, the problems encountered and the organization required in applying it to a processing plant. Illustrations are provided which indicate the payoff that can result.

Jan 1, 1967

By Volkan Arslan

This study aimed to remove the contaminants in quartz sand by using an eco-friendly method and to obtain high-purity quartz. For this purpose, ultrasound-assisted acid leaching was applied. Equal amounts of a mixture of diluted hydrochloric and oxalic acids were used as the solvent. Response surface methodology (RSM) was used for optimizing, modeling, and predicting the experimental parameters. The correlation coefficient ( R2) of the proposed quadratic model for the relationship between iron removal yield and test parameters was calculated as 0.9731 and it was determined that the predicted and actual values were compatible. Finally, optimization experiments were made and optimum experiment conditions were revised and determined as 83.38 °C of leaching temperature, 196.35 min of leaching time, 2.86 M of acid concentration, and 202.24 W of ultrasound power. Under the optimum conditions determined after optimization, the highest yield of iron removal was determined as 95.08%. Under the optimal parameters, the SiO2 content of the concentrates increased from 97.841 to 99.907% and the Fe2O3 content reduced from 0.225 to 0.011%.

Jul 12, 2021

By Weiran Zuo, Wanzhong Yin, Jin Yao, Keqiang Chen, Qiuyue Sheng, Liu Liu

It is important to investigate the liberation properties of gangue minerals and establish liberation models for low-grade iron ores to reject gangue early. In this study, three types of iron ores from different iron deposits were ground to different particle size distributions by locked-cycle grinding and batch grinding. The liberation distribution of quartz, the most dominant gangue mineral among the three types of iron ores, was tested by Mineral Liberation Analyzer (MLA). Afterward, the liberation distribution of the three types of quartz was fitted using the beta distribution function, and their shape parameters were related to particle sizes to develop the liberation model. MLA test results showed that the liberation distribution of quartz with different grinding methods was basically the same. The developed liberation model predicted the liberation distribution of quartz in low-grade iron ores from different iron deposits well, and its coefficient of determination (R2) was between 0.90 and 0.98. This study deepens the understanding of the liberation rules of quartz in low-grade iron ores from different iron deposits, and on this basis, a more efficient liberation model based on the beta distribution function is developed.

Oct 18, 2023

By B. Singh

The use of wire ropes has already been tried in a few countries for roof support In mines. But the use of scrap wire ropes, as a method of support on extensive scale has not been reported from anywhere except India. Extensive trials using freshly discarded wire ropes for roof support were undertaken both in the laboratory and field. In laboratory, model beams supported with different reinforcing techniques were tested to evaluate their comparative load bearing capacity vis-a-vis reinforcing factor. Among all the tests, the model supported with wire rope system at 60° angle in combination with two supplementary vertical bolts offered the best result 1.e. about 95% reinforcement. It also accepted post fracture loading of the beam. In statical analysis too, the best result could be obtained with the rope installed across the gallery at 60° angle. All these findings are in conformity with the field observations obtained during roof stitching practices in coal mines. Of late, roof stitching, an effective and economical method of roof support developed at CMRS, India in 1972, found wide application in over 200 coal mines. In this method, a freshly discarded wire rope is grouted across a gallery in two inclined drill holes supplemented with two middle vertical roof bolts at every 1.0 to 1.2 m interval along the gallery. It is tensioned against the roof using wooden sleepers and thus, the whole system functions like a roof truss.

Jan 1, 1990

By V Shrotri L Muhmood, P Gandhre

The current work deals with the measurement of some thermophysical properties of Ca(NO3)2 based ternary nitrate molten salts as HTF (heat transfer fluid) / TES (Thermal Energy Storage) material for CSP (Concentrating solar power) plants. The density and viscosity of different compositions of the ternary salt mixture containing Ca(NO3)2, NaNO3 and KNO3 close to the liquidus has been experimentally measured. An attempt has also been made to measure the melting point of the salt using the cooling curve technique as well as Differential Scanning Calorimetry (DSC). Thermogravimetric analysis has also been performed to estimate the peak operating temperature of the salt. Compatibility of suitable pipe material (SS304) with molten salt has also been discussed. The salt mixture proves to be a viable alternative to the already existing HTFs like Therminol VP-1 (organic oil) or Solar Salt® in regards to its lower melting point, wider operating range, low cost, nontoxicity, sufficiently high density and comparable viscosity.

Jun 19, 2024