Search Documents

To enable ammonium nitrate-fuel oil (AN-FO) to be used on an equal weight basis with nitroglycerine explosives, smaller diameter bore holes became necessary with consequent modifications to drill steel and burden on holes. Detonation of AN-FO in small diameter holes proved successful both with and without primer charges but some alterations were required to adapt anoloders to the smaller holes.Important factors in training all operators in the new charging method were the retention of improved fragmentation, avoidance of excessive overbreak and keeping wall rock dilution to an absolute minimum. The successful storage of ammonium nitrate in climatic conditions with daily temperature fluctuations above and below the critical 90°F has been achieved.INTRODUCTIONTechnical aspects of ammonium nitrate-fuel oil (AN-Fa) blasting agent are well covered in recent literature. This paper deals primarily with the manner of its introduction as the principal explosive underground at Great Boulder Gold Mines Ltd. and with the many problems encountered in the process. Following reasonably successful experimental firings in June 1962', using granular ammonium nitrate and an anoloder, permission was granted by theWestern Australian Mines Department to carry out test work in selected areas of the mine. The permit allowed for fuse firing only, and for a mixture of AN-Fa containing between 5t and 6 per cent fuel oil, with an adequate primer.The use of AN-Fa on an equal weight basis with nitroglycerine explosives, involved smaller diameter holes with alteration to ground burden and modification to drill steel.Initial tests indicated that it was apparent that AN-Fa could not replace gelignite on an equal weight basis if the...

Jan 1, 1965

By Rosie Moore, Harvey Keats, Kerry Sparkes, A. J. Naldrett

"Abstract-The Voisey’s Bay Ni-Cu-Co deposit was discovered in late 1994 as the result of prospecting initiated in the summer of 1993. By July 1995, proven mineable reserves were 31.7 x 106 tonnes grading 2.83% Ni, 1.68% Cu and 0.12% Co, and current total resources in all categories are quoted to be in the order of 150 X 106 tonnes. The deposit is associated with a body of troctolite belonging to the Nain Anorthosite (1.35 Ga - 1.29 Ga) suite, which was emplaced across the boundary between the Proterozoic "Rae" Province to the west and Archean "Nain" Province to the east.The deposit can be described in terms of three geological settings. The "Ovoid" is a 600 m long by 350 m wide by 100 m deep lens of massive sulfide, covered by 10 m to 20 m of glacial overburden, and separated from the underlying country rock quartz-plagioclase-biotite gneiss by a breccia of gneissic fragments in troctolite known as the Basal Breccia Sequence. To the west of the Ovoid lies the "Western Extension", comprising disseminated and massive sulfides in a north-dipping sheet of troctolite which ranges from upper unmineralized troctolite down through troctolite with increasing amounts of sulfide (up to 50%), to massive sulfide (in some places only), and then to Basal Breccia Sequence. East of the Ovoid, the troctolite sheet broadens out into a troctolite intrusion, within which occurs the "Eastern Deeps", a zone of massive and disseminated sulfide up to 100 m thick that is currently being explored. The mineralization of the Eastern Deeps lies along the line of intersection of a feeder sheet with the base of the intrusion. The current interpretation is that the three geological environments represent different erosional levels through a single mineralized intrusion. In this model, the deepest erosional level lies to the west and exposes the feeder to surface, whereas the Ovoid represents the base of the intrusion at surface, and the Eastern Deeps the base of the intrusion overlain by 600 m to 900 m of troctolite. Sulfides and gneissic fragments were brought up by magma flowing quickly through the feeder, and settled out where the flow rate decreased as the sulfide-bearing magma mixed with magma already emplaced in the intrusive body."

Jan 1, 1996

By J. W. Keyes

"The original grinding circuit at East Malartic consisted of two 8 by 8 C.A.C. mills in closed circuit with two 72 inch Akins Classifiers and an 8 by 10 secondary mill in closed circuit with two 48 inch duplex classifiers. With this circuit, we experienced a drastic drop in tonnage from one month to another, due to variations in the hardness of the ore. The first step to overcome this difficulty was made by increasing the critical speeds of the mills from 78% to 82%. This resulted in an increase in the secondary mill throughput; but, when the change was made on the primary mills no increase was obtained.The drastic drops in tonnage were still experienced and through working with Allis Chalmers the 8 by 10 mill was converted to a rod mill and the two 8 by 8 n1ills to secondary mills. This change eliminated the two 72 inch Atkins classifiers and the scoops on all the mills, since the 48 inch Akins classifiers sands could then be fed by gravity to the secondary mills through feed pipes.The rod mill and secondary mill discharges were fed to a common pump box using 5 by 5 S.R.L.'s running at 1085 R.P.M. with a twenty-five foot head. When this was done the pumping costs jumped from $105. 00 for 6 months to $1050. 00 in one month, or from 0. 0004 to 2. 75 cents a ton milled. Several factors contributed to this jump in pumping costs as follows:"

Jan 1, 1964

By Robert R. Stein

Using an automated drill test fooure, the U.S. Bureau of Mines measured the sound power levels produced by a small, pneumatic, rotary roof drill. A series of tests was conducted to determine (1) the relative effectiveness of several drill muffling schemes and (2) the relationship between drill sound power and pneumatic power supplied to the drill. The influence of rotation rate (i.e., airflow) and feed thrust on the penetration rate of the drill was also noted.

Jan 1, 1989

By Raymond L. Lowrie

Deregulation, as authorized by the Energy Policy Act of 1992 (PL102-486) allows free-market competition in the electric-utility industry. As the act unfolds, though, uncertainties abound about the type, degree and direction of impacts throughout the affected economy — from fuel suppliers to electricity generators and from power distributors to energy consumers. Instead of having a familiar base of captive customers and electricity prices fixed by negotiation with state public utility commissions, utility companies are preparing for open, free-market competition. They are looking at all areas, including fuel supply, to cut costs to remain competitive. Humorous anecdotes are told about utility companies shunning insiders for senior executive positions. Instead, they are opting for people from the telephone or other industries with deregulation experience. And there are light-hearted stories about a trend away from traditional electric-company names, such as the name of a city or state followed by Edison or Power and Light, to space-age names, such as Ameren, Entergy, Illinova or Unicom. No one wants to be left behind or be perceived to be left behind.

Jan 1, 1996

By W. W. Adams, T. D. Lawrence

"The National Safety Competition of 1938, the fourteenth of its kind conducted by the Bureau of Mines in which bronze trophies known as Sentinels of Safety are awarded to winning companies, has just been completed and the results are presented here.With 345 mines and quarries competing, more than in any previous year except 1931, the contest revealed low accident rates at many of the enrolled plants and, which is even more remarkable, it revealed 113 mines and quarries at which no lost-time accidents occurred during the contest year.The Sentinels of Safety trophies, provided by The Explosives Engineer magazine, were awarded to four underground mines, one open-pit mine, and one quarry. Each employee of the winning plant was awarded a Certificate of Honor by the Bureau of Mines in recognition of the employee's part in helping his company to win the trophy. In addition to the award of trophies, a Certificate of Honorable Mention was awarded to each of the mines and quarries in second, third, fourth, and fifth places in their respective contest groups and also to each mine and quarry that worked 30,000 or more man-hours without a lost-time accident. Ninety-two such certificates were awarded for 1938. Twenty-three other mines and quarries also operated without an accident but worked less than 30,000 man-hours, the minimum required by the contest rules for award of Certificates of Honorable Mention.Previous to 1938, five trophies were awarded annually in the National Safety Competition. For the 1938 contest a sixth trophy was provided by The Explosives Engineer so that open-pit mines and quarries, two classes of operations that previously had been included in one group in the competition, might have separate awards."

Aug 1, 1939

By Michael J. Beus

This Bureau of Mines report describes field investigations conducted in the Coeur d'Alene mining district of Idaho to obtain data on rock stress and physical properties. The resulting information has been utilized as input to detailed finite-element analyses to establish structural design criteria for deep-vein mine shafts. Measurement techniques include the Council for Scientific and Industrial Research biaxial and triaxial strain cells, the U.S. Geological Survey solid-inclusion probe, and the Colorado School of Mines dilatometer. Physical property testing was conducted in the laboratory on core obtained from each test site. Limited in situ physical property tests were also conducted. Reason-able success was obtained with the CSIR equipment, which was considered the most suitable for stress measurement in the study area. Test sites ranged in depth from 1,200 to 7,700 feet and are described in detail. The stress data were reduced by least-squares linear regression techniques to enable prediction of vertical and horizontal stresses to 7,500 feet. Ratios between the horizontal stresses as utilized for shaft design varied considerably, and a hydrostatic condition is the exception, based on Bureau measurements. Physical properties also varied widely, due to the complex geologic structure. Analyses of the data in terms of the tectonic history of the area show reasonable correlation. Data from previous rock mechanics investigations from the Coeur d'Alene district were also compiled and presented as part of this report to justify any generalizations regarding stress conditions and physical properties of the district as a whole.

Jan 1, 1980

By A. Robison, V. T. McLemore

"The San Juan Basin, New Mexico contains many heavy mineral beach-placer sandstone deposits of Cretaceous age. Beach-placer sandstone deposits are concentrations of heavy minerals that formed by mechanical concentrations (i.e. settling) of heavy minerals on beaches or in longshore bars in a marginal-marine environment. They have high concentrations of several elements, such as Ti, Zr, rare earth elements (REE), Sc, Y, U, Th, Nb, Ta and Fe. These elements are becoming increasingly more important to industry, because they are used in the manufacture of devices our society uses every day, i.e. cell phones, computers, and alternative energy devices, like solar panels. It is unlikely that any of the beach-placer sandstone deposits in the San Juan Basin will be mined in the near future because of small tonnage, low grades, high iron content, and distance to processing plants and markets. However, as the demand for some of these elements increases because of increased demand and short supplies, the dollar value per ton of ore rises, enhancing deposit economics. Current studies at the New Mexico Bureau of Geology and Mineral Resources are focused on the Apache Mesa (formerly Stinking Lake) deposit near Dulce, New Mexico. INTRODUCTION Beach-placer sandstone deposits are accumulations of heavy, resistant minerals (i.e. high specific gravity) that form on upper regions of beaches or in long-shore bars in a marginal-marine environment. They form by mechanical concentration (i.e. settling) of heavy minerals by the action of waves, currents, and winds (Fig. 1; Bryan et al., 2007). Modern examples are found along the Atlantic Coast, USA (Koch, 1986; Carpenter and Carpenter, 1991), southeastern Australia (Roy, 1999), and Andhra Pradesh, India (Rao et al., 2008), where they are mined for titanium, zircon, and monazite (a Ce-bearing rare earth, REE, mineral). Detrital heavy minerals comprise approximately 50-60% of these sandstones and typically consist of titanite, zircon, magnetite, ilmenite, monazite, apatite, rutile, xenotime, garnet, and allanite, among other minerals. Most of these minerals have a high specific gravity exceeding 4 and are dark colored, giving the sandstones a dark color, resulting in them being called black sandstones. Although beach-placer sandstone deposits are found in strata of all ages; the deposits in the San Juan Basin in New Mexico are restricted to Late Cretaceous rocks belonging to the Gallup, Dalton, Point Lookout, and Pictured Cliffs Sandstones (Fig. 2; Table 1; Chenoweth, 1957; Houston and Murphy, 1970, 1977). The beach-placer sandstones are black, dark gray, to olive-brown, resistant to erosion, and radioactive due to radioactive zircon, monazite, apatite, and thorium minerals. Anomalously high concentrations of Ti, Fe, Nb, Th, U, Zr, Sc, Y, and REE are characteristic of these deposits. Similar Upper Cretaceous heavy mineral, beach-placer sandstone deposits are found throughout Montana, Wyoming, Utah, Arizona, and Colorado (Dow and Batty, 1961; Houston and Murphy, 1970, 1977; Zech et al., 1994)."

Jan 1, 2016

By George F. Crocker

Introduction The Helen mine and the Victoria mine of Algoma Ore Properties, Limited, in the Michipicoten district, Ontario, are 120 miles north of Sault Ste. Marie, on the north shore of lake Superior. They are on the Algoma Central railway between Hawk Junction and Michipicoten Harbour. Between them, these mines have produced 10,757,113 tons of iron ore. From 1900 to 1918, 2,823,369 gross tons of brown ore was shipped, and from 1939 to the end of 1949, 7,933,744 tons of siderite was produced from the open-pit operations and underground development. The finished product, known as 'Algoma sinter', is shipped to blast furnaces both in Canada and the United States. The iron-ore bodies are a part of a tabular shaped area of iron formation that extends over a length of more than 10,000 feet and has maximum width of 1,000 feet. The two siderite orebodies, known as the Helen and Victoria, are separated by two diabase dykes. The Helen orebody is 1,600 feet long with a maximum width of 250 feet and the Victoria is 1,200 feet long with a width comparable to the Helen. These orebodies are considered to be a replacement of the original rock by iron carbonate. The introduction of the iron-1bearing material probably occurred after the development of the major folded structures. The open-pit mining of siderite started in the Helen ore body in 1939 and continued until 1945. During this period, 3,853,395 tons of ore was mined. Open-pit mining started in the Victoria body in 1946 and is still being carried on. Underground development commenced in September, 1947. Diamond drilling and surface sampling had shown the Helen deposit to average 35.61 per cent Fe and 7.28 per cent SiO2, and the Vi.otoria deposit 33.73 per cent Fe and 10347 per cent SiO2?

Jan 1, 1950

Producing robust agglomerates with desirable structural properties is the key to success of the heap leaching of complex, low-grade nickel laterite ores. Mechanically strong but porous agglomerates with narrow size distribution (e.g., 5 ? 40 mm) are required to build permeable and perennially stable heaps of 4 ? 10 m height. The characterization of granules? microstructure is essential for greater understanding and correlation with the concomitant mechanical properties and robustness. In this study, we used non-destructive, computed X-Ray tomography analyses and scanning electron microscopy (SEM) in tandem with conventional compressive strength,and integrity/stability tests to draw links between nickel (Ni) laterite agglomerate strength/stability, internal microstructure (e.g.,porosity, inter-particle bridges) and binder type. It is shown that binder composition (e.g., tap water vs. 30% w/w H2SO4) and post-agglomeration drying both significantly impact on granules? physicochemical and microstructural properties. Acidic binder, in contrast with tap water, leads to significant incongruent leaching of different species from particles during ore-binder mixing and agglomeration. Upon wet agglomerate curing, solidified/recrystallized leached species form strong intra-granular solid bridges which, lead to greater compressive strength of dry agglomerates. Structural stability/integrity of cured agglomerates in acidic solution, however, decreases dramatically due to greater porosity and acid solubility of intra-granular solid bridges. These findings are useful in shedding more light on agglomerate structure characteristics and their optimization for enhanced column and heap leaching with concentrated sulphuric acid.

Sep 1, 2012

By J. Frederick Stampfer

Current certification testing of self-contained breathing apparatus includes tests with human subjects wearing the apparatus while exercising. During these tests, certain apparatus variables are measured during rest periods. Because of concerns that the present tests may not accurately simulate the stresses to which an apparatus is subjected in the field, the Bureau of Mines proposed new human subject tests. It was also felt that different measurement techniques would supply more reliable data on the apparatus response to these stresses. The Los Alamos National Laboratory was asked by the Bureau to evaluate the proposed tests and monitoring techniques. The major conclusions derived during this study are these: (1) The proposed tests are not too physically demanding. (2) As long as human test subjects are used, a minimum subject weight should be required for certification tests. (3) Important apparatus variables are the breathing resistance, temperature, and carbon dioxide and oxygen concentrations of the inhaled gas. (4) Continuous monitoring should be used, rather than monitoring only during rest periods. (5) New pass/fail criteria based on realistic estimates of the user's physiological requirements, as tempered by present and future engineering limitations, are needed. (6) When available, breathing machines, rather than human subjects, should be used for most certification testing. (7) A more realistic ergonomics test than that proposed is needed. (8) A gas leak test for the system and a facepiece leakage test are also needed.

Jan 1, 1983

By Thomas M. Barczak

This U.S. Bureau of Mines report chronicles the historical development of longwall mining in the United States and speculates on future developments to the turn of the century. The involvement and contributions made by the Bureau during these developments are also discussed. Two major periods of history are analyzed: (1) from 1875 to 1950 when small advancing faces were operated manually, and (2) from 1950 to 1990 when mechanized extraction and powered roof supports provided a system to efficiently extract large coal panels. Five eras of technological development during the modern period are described and analyzed. These eras discuss the development of (1) mechanized extraction, (2) powered roof supports, (3) high-capacity roof supports, (4) shield supports, and (5) system automation. Current trends are analyzed in terms of longwall utilization, face production, support capacity, face widths, and new technological developments. From these analyses, the future of longwall mining to the year 2000 is speculated. It is concluded that longwall mining will continue to grow in importance during the next decade and that the next major technological milestone will be the realization of a fully automated longwall mining system.

Jan 1, 1992

By J. Bilant, B. Carlson, N. Gow

High Pressure Grinding Roll (HPGR) technology has been evaluated to replace tertiary cone crushing at Coeur Rochester operations (Coeur Rochester, Inc.) as an opportunity to improve silver recovery. In 2016 and 2017, onsite and third-party pilot programs were initiated to evaluate the impact of metallurgical recovery and heap leach performance of crushed product generated by an HPGR. In 2018, Forte Dynamics evaluated the HPGR laboratory metallurgical data from Coeur Rochester and all third parties to develop field-scale leach curves based on new crushing scenarios. The laboratory recovery test work data was consolidated and scaled to field conditions to determine projected heap leach performance. Based on the metallurgical testing conducted, the replacement of current tertiary cone crushers with HPGR technology has the potential to increase Coeur Rochester’s silver recovery rate by 8%, from 61% to 69%, and shorten the overall timing of silver recoveries from 20 years to just over two years. INTRODUCTION The Rochester mine, and associated valley fill heap leach facilities is an open-pit silver and gold mine located in Pershing County, Nevada, approximately 26 miles northeast of the city of Lovelock. In 2017, Rochester produced approximately 4.7M troy oz silver (Ag) and 51k troy oz gold (Au). Ore mined at Rochester is either fed directly to the primary X-Pit crusher, crushed at an in-pit crusher system, or placed directly onto a heap leach pad as run-of-mine (ROM). Both crushing circuits are comprised of three stages of crushing to produce a nominal 3/8” ore. Primary crushing consists of jaw crushing while secondary and tertiary crushing are composed of varying cone crushers. Historical recovery rates of crushed Rochester ore average 61.4% Ag and 95.9% Au over a period of 20 years [1]. These rates were derived from third party verification of in-house metallurgical test results, crusher production and heap leach production results from 1986 through 2004 in a private report for Rochester produced by KD Engineering Co., Inc. Recovery rates are regularly verified by compositing daily samples of ore delivered to each leach pad from the X-pit crusher, in-pit crusher, and/or ROM. A proportionate split of each sample is used to generate monthly composites for metallurgical analysis utilizing column leaching and bottle roll leaching. These tests are run in a manner analogous with production conditions and deliver test results that provide expected heap leach performance. As the Rochester oxide deposit has been mineralogically and metallurgically consistent, the gold and silver recovery trends have also been consistent over the life of the project. In 2016 and 2017, onsite and third-party pilot programs were initiated to evaluate the impact of HPGR technology to metallurgical recovery and heap leach performance of crushed product in an open circuit configuration, as a potential replacement for the currently in place tertiary cone crushers. During these years, HPGR was evaluated in three phases of test work.

Jan 1, 2019

By G. R. Strimbeck

This is a report on experimental work on development of a gasification process operating at near atmospheric pressures and using finely pulverized coal entrained in oxygen and steam. The gasifier was designed by The Babcock and Wilcox Co. in cooperation with engineers of the Bureau of Mines Morgantown station. The test work discussed in this report covers the first 34 tests made in the pilot plant in which a strongly coking Sewickley-bed coal, ground to either 70 or 90 percent through a 200-mesh screen, was used.

Jan 1, 1954

By Curt D. Jr. Edgerton

This study was made to determine trends in fresh water usage by California petroleum refineries, to Forecast fresh water requirements to 1975, and to evaluate water conservation practices. Statistical data used in the study were obtained largely from published sources and from records of selected companies. An adequate sampling of the State's refining capacity was obtained, and the data were extrapolated to the total California refining capacity. A breakdown of the data was then made on the basis of the following refining regions: (1) the Los Angeles Basin and Southern Coastal region, (2) the Southern San Joaquin Valley, and (3) the San Francisco Bay area. An unpublished forecast of crude oil input to refineries by a major oil company operating on the West Coast was used as a basis for predicting fresh-water usage. The 1963 fresh water intake by California petroleum refineries was 84 million gallons per day. This is expected to increase to 128 million gallons per day by 1975. The fresh-water to crude-oil ratio is increasing in all regions except the Southern San Joaquin Valley. At present, the supply of fresh water available to almost all of the State's petroleum refineries, mostly from surface sources and company-owned wells, is adequate, although shortages may develop within the foreseeable future. Present conservation methods are centered around the following four objectives: (1) minimum intake of fresh water of the lowest possible quality commensurate with sound technologic practice; (2) optimum recirculation (3) proper treatment before discharge; and (4) substitution of air cooling for water cooling.

Jan 1, 1965

By David R. Jessey

This volume contains the detailed mine site reports written by the WAPORA, Inc. and KETRON, Inc. staffs. It is a companion Appendix Volume to Control of Water Pollution from Surface Mining Operations. Copies of this report are maintained on Open File at the U.S. Bureau of Mines Research Center, Spokane, Washington.

Jan 1, 1981

By K. B. Le Bron, T. van Aard

The empirical pillar strength formulae have been widely, and in most cases successfully, applied to design underground pillars for mines in the Bushveld Igneous Complex (BIC). This paper presents the case for combining the empirical method with numerical modelling when it comes to crush pillar stability analyses. The benefits include an understanding of potential failure mechanisms, which may then be accounted for in the designs. In addition, the impact of weak layers, such as shear zones, the impact of the dip of the orebody, differences in layouts, such as holing widths and the presence of advanced strike gulleys (ASGs) immediately adjacent to the crush pillars, and stress regime (k-ratio) may be studied using numerical modelling, as it is not accounted for in the empirical method.

Mar 5, 2025

By M. L. Skow

Large tonnages of the manganese ores found in Aroostook County, Maine, are refractory to conventional mineral-dressing techniques and to the common chemical- extraction procedures. The Maple Mountain-Hovey Mountain ores are typical of this type. Because the most promising method of recovering the manganese from these ores has been a chloridizing roast in which the ground ore is in contact with gaseous hydrogen chloride, preliminary batch tests were made with a fluidized bed. On the basis of these tests, it was concluded that fluidization, with careful control of operating conditions, could be employed for this cloridization and warrants further study. Selective volatilization of the iron at 600° C. was unsuccessful. An operating temperature of approximately 950° C. was necessary for a practicable rate of volatilization of manganese chloride. Hydrogen chloride contents of 10 to 100 percent of the fluidized gas gave essentially equivalent manganese recoveries with an 80- minute retention time, For shorter periods reaction was more complete with the higher hydrogen chloride concentrations. At the 80-minute retention period the lower hydrogen chloride concentrations volatilized somewhat less iron and also improved the physical operation of the process. Fluidization gave results superior to comparable tests on chloridization in a fixed bed.

Jan 1, 1956

By Carl L. Shapiro, Jerome and Strauss

This is a critical examination of the theory that the amount of carbon necessary to form the iron-carbon (carbide) eutectoid is lowered by the addition of any carbide-forming element. Although this theory has been built up over a long period of years, it appears, in the light of recent published investigations upon the ternary constitutional diagrams of iron with carbon and other alloying elements, to be no longer tenable. A survey of these new results, summarized below, shows that (as is known) some metals lower the carbon content of the iron-carbon (carbide) eutectoid, whereas others raise it, but (as not heretofore clearly set forth) some first move the eutectoid in one direction and then, at higher concentrations, shift it in the opposite direction. Moreover, these differences in behavior exist even among the common alloying metals classed as carbide formers. PART I Influence of Body-centered Cubic Elements The effects of the various body-centered cubic metals (chromium, tungsten, molybdenum, vanadium, columbium and tan. talum) are reviewed individually. Iron-carbon-chromium System.—In the monograph on Alloys of Iron and Chromium, Kinzel and Crafts1 concluded that the carbon content of the eutectoid is lowered by increasing the chromium content. The quantitative influence of chromium on the eutectoid point of iron-carbon alloys was shown by Monypenny2 (Fig. I) and no data have been forthcoming to refute his findings. Iron-carbon-tungsten System.—Gregg,3 in the monograph on Alloys of Iron and Tungsten, accepted the data showing that tungsten decreases the amount of carbon required to form the eutectoid. The influence of tungsten on the eutectoid percentage of carbon as determined by Oberhoffer and Daeves4 is shown in Fig. 2; these results have received general approval. , I ron-carbon-molybdenum System.—In the monograph on Alloys of Iron and Molybdenum, Gregg5 reviewed the work of Guillet,6 Swinden,7 and ReedI8 all showing that molybdenum lowered the carbon content of the eutectoid, whereas Takei9 contradicted this conclusion. Svetchnikoff and Alferova,10 a little later, showed that large additions of molybdenum shift the eutectoid to the right. These last-named investigators found that molybdenum, up to 1.2 per cent, shifts the pearlite point and the point of maximum solubility of cementite in the gamma phase only slightly in the direction of lower carbon content; on the other hand, increasing amounts of molyb-S

Jan 1, 1944

By Jerome and Strauss, Carl L. Shapiro

This is a critical examination of the theory that the amount of carbon necessary to form the iron-carbon (carbide) eutectoid is lowered by the addition of any carbide-forming element. Although this theory has been built up over a long period of years, it appears, in the light of recent published investigations upon the ternary constitutional diagrams of iron with carbon and other alloying elements, to be no longer tenable. A survey of these new results, summarized below, shows that (as is known) some metals lower the carbon content of the iron-carbon (carbide) eutectoid, whereas others raise it, but (as not heretofore clearly set forth) some first move the eutectoid in one direction and then, at higher concentrations, shift it in the opposite direction. Moreover, these differences in behavior exist even among the common alloying metals classed as carbide formers. PART I Influence of Body-centered Cubic Elements The effects of the various body-centered cubic metals (chromium, tungsten, molybdenum, vanadium, columbium and tan. talum) are reviewed individually. Iron-carbon-chromium System.—In the monograph on Alloys of Iron and Chromium, Kinzel and Crafts1 concluded that the carbon content of the eutectoid is lowered by increasing the chromium content. The quantitative influence of chromium on the eutectoid point of iron-carbon alloys was shown by Monypenny2 (Fig. I) and no data have been forthcoming to refute his findings. Iron-carbon-tungsten System.—Gregg,3 in the monograph on Alloys of Iron and Tungsten, accepted the data showing that tungsten decreases the amount of carbon required to form the eutectoid. The influence of tungsten on the eutectoid percentage of carbon as determined by Oberhoffer and Daeves4 is shown in Fig. 2; these results have received general approval. , I ron-carbon-molybdenum System.—In the monograph on Alloys of Iron and Molybdenum, Gregg5 reviewed the work of Guillet,6 Swinden,7 and ReedI8 all showing that molybdenum lowered the carbon content of the eutectoid, whereas Takei9 contradicted this conclusion. Svetchnikoff and Alferova,10 a little later, showed that large additions of molybdenum shift the eutectoid to the right. These last-named investigators found that molybdenum, up to 1.2 per cent, shifts the pearlite point and the point of maximum solubility of cementite in the gamma phase only slightly in the direction of lower carbon content; on the other hand, increasing amounts of molyb-S

Jan 1, 1944