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By F. C. Grensing, W. R. Crib

Copper-15 Nickel-8 Tin alloy is a relatively modern material, having been discovered in the 1970’s. It has complexities with casting, hot working and interdependent solid state phase transformations. A key to the high reliability manufacture of wrought rods, bars, plates and tube is the casting technology, which limits segregation, promotes microstructural uniformity and enables hot working. The EquaCast® continuous casting process has enabled the production of a broadening variety of wrought forms with typical yield strengths ranging from 100 to 180 ksi (690 to 1241 MPa) depending on size, shape and temper. This paper reviews the characteristics of wrought Copper-15 Nickel-8 Tin products which have registration in AMS specifications (4596 and 4597) and MMPDS-04 (CN-1) for use in aircraft. The design limits, microstructures, fracture characteristics and tribological behavior will be examined. This alloy system is emerging as a material of choice for aircraft bearings, corrosion resistant oil and gas exploration components, machinery and demanding off-road equipment applications. ToughMet® 3 is an alternative or upgrade to conventional moderate and high strength aluminum bronze bearing alloys.

Jan 1, 2010

By J. Hamisch

Climate policy regarding perfluorocarbons (PFCs) may have a significant influence on investment decisions in the production of primary aluminum. This work demonstrates an integrated analysis of the effectiveness and likely economic consequences of different climate policy options. In our study we first compare atmospheric observations to the available estimates of PFC emissions for the baseline years 1990 and 1995. We then present projections for regional emissions of PFCs from the aluminum industry using the MIT Emissions Projection and Policy Analysis model under different policy scenarios. Abatement costs for emissions of PFCs and C02 are compared in the context of the Kyoto Protocol.

Jan 1, 1999

By Bora Derin, Sertac Yazici, M. Seref Sonmez

"In this study, the recycling conditions of waste liquor obtained after the production of tungsten boride powder from calcium tungstate by self-propagating high temperature synthesis (SHS) and the following hydrochloric acid leaching were investigated in detail. Environmentally unfriendly and extremely acidic (pH~ -0.3) liquor consisting of calcium, magnesium, and boron ions was treated with 1 M sodium carbonate solution to precipitate magnesium carbonate and calcium carbonate phases. The obtained amorphous precipitates were heated up to the temperature of 400°C for re-crystallization. As a result, MgO, CaC03 and CaMg(C03)z phases were obtained, while sodium, boron, chlorine ions were remain in the solution. The present study is still in progress.IntroductionSelf-propagating high temperature synthesis (SHS) is one of the techniques used in the production of a variety of advanced ceramics, inter-metallic, organic and inorganic compounds, oxygen free single crystals, and polymers [ 1, 2]. The reaction becomes selfsustaining and propagates in the reactant mixture, after initiation in SHS process. SHS products may contain the mixture of several unwanted compounds and elements. Therefore following acidic leaching process may be needed to purify the target product. In the previous study, calcium tungstate (Ca W04), magnesium (Mg) and boric acid (B20 3) mixture were reacted to produce tungsten boride powder by SHS process according to the Reaction 1. Then, magnesium and calcium containing byproducts (i.e. MgO, Mg3B206 and Ca3B206) found in the SHS product were leached out by using concentrated hydrochloric acid (HCl) solution to obtain pure tungsten boride powder [3].Ca W04 + 0.5B203 + 4.5Mg = WB + 4.5Mg0 + Cao (1)After the leaching, filtrate solution consisting of different amounts of magnesium, calcium, and boron requires additional treatment for the environmentally acceptable disposal.Several works were carried out about magnesium precipitation conditions and kinetics from brines. Rabadzhieva et al. investigated the precipitation of Mg(OH)z from brines by using NaOH as well as caustic soda [ 4]. Turek ve Gnot investigated the precipitation efficiency of Mg(OH)z for the temperature range between 10-40°C, while the reaction was kinetically experimented by Alamdiri et al [5, 6]. Homogeneous precipitation of nesquehonite (MgC03.3H20) by the reaction of MgCli with (NH4)2C03 in supersaturated solutions and factors that influence the precipitation of MgC03.3H20, such as reaction temperature, initial concentration, stirring speed, titration speed, equilibration time, have been studied by Wang et al [7]. The precipitation of Mg(OH)z by calcium hydroxide from aqueous solutions was studied by Baird et al. [8]. Stratful et al. focused on conditions influencing the precipitation of magnesium ammonium phosphate from wastewaters [9]. 1031"

Jan 1, 2011

By Thirumalai, K.

Although the term "spalling" has long been known, Norton l first referred to its usage for the fracture or disintegration of materials subjected to rapid temperature changes. Spalling of ceramic materials at high temperatures has received attention in the past. Removal of the char formed during ablation in re-entry of space vehicles has been referred to as mechanical spalling. The first experiments to evaluate the process of rock fragmentation by thermal spalling were conducted by Stoces using a series of gasoline burners on the quartz veins of the Zinnwald deep mines in Germany. After the development of rocket-jet burners, the principles of 'thermal spalling combined with high fluid momentum found wide practical application in rocks. The well-known jet piercing process for drilling blastholes in taconite and for jet channeling in the quarrying of granite are among the more notable of these application^.

Jan 1, 1970

By A. J. Kraemer

For a number of years the Bureau of Mines has been conducting an investi-gation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from some oil fields of Louisiana are given in Bulletin 291. Analyses Of 26 representative crude oils from various producing formations of southern Louisiana are given in this report. These samples are from 14 fields in 10 parishes in the southern part of the State, usually designated as the "Louisiana Gulf Coast area."

Jan 1, 1934

By Florian Kongoli

Converters have been playing an important role in the extraction and processing of metals ever since the first type of converter was invented about 100 years ago. Historically their operation has been mainly based on the experience of talented operators rather than on strict control and optimization technologies. However, in the new realities of unavoidable necessity to increase productivity and in the conditions of diversification of primary materials from various geographical areas, improving control and optimization techniques have become indispensable. In this paper a review of the authors? previous work in terms of improving control and optimization of converter operational practices related to magnetite content and precipitation, slag and metal blows, problematic and dangerous elements such as As, Sb etc. has been described by highlighting the advantages that the new control and optimization methods and tools bring to everyday converter practices. Several examples are given and future work is underlined

Jan 1, 2005

By Mark Bauckman

Discussion Topics • Market Needs • Technology Developments & Best Practices • Industry & Government Developments • Future Possibilities & Your Role

Jan 1, 2006

By M. Gimpel, R. Galler, T. Antretter, H. Kargl, R. Tichy, W. Ecker, M. J. Mikl-Resch, G. Pittino

"A computational method based on a continuum-mechanical approach to simulate rock cutting is developed and evaluated. The aim is to obtain the local loading acting at the cutting pick during operation. The explicit FEM is chosen to model the pick-rock interaction. The presented method takes advantage of (i) an advanced material model (ii) a robust contact algorithm and (iii) fast calculations due to parallelization. A damage-plasticity law is chosen and modified with user-subroutines. A user integrated element deletion routine evades critical mesh distortions. Infinite elements at the model boundaries avoid unrealistic deformation wave reflection.INTRODUCTIONExcavation in mining and tunneling is a costly and complex process. Special equipment such as the roadheader (Figure 1) is employed to cut the rock in the excavation process but high material strengths limit their usability (Tockner 1999). Nowadays a challenge is to extend their field of application to harder and more abrasive rock materials. The forces on the pick (Figure 2) are of great importance and determine wear and especially the efficiency of the machine. Figure 2 shows the principle of cutting and the predominant forces. The variation of pick geometry, cutting depth or attack angle will result in an alteration of these forces and determine the efficiency of the process (Tockner 1999). The mechanisms of rock cutting follow the principle of indentation (Kou et al. 1999). Directly under the indenter a hydrostatic stress state evolves causing the material to fail only due to crushing and fragmentation mechanisms. In the close surroundings large strains emerge and tensile cracks are formed but in a further distance the material behaves elastically."

Jan 1, 2015

By M. Gimpel, R. Galler, T. Antretter, H. Kargl, M. Mikl-Resch, R. Tichy, W. Ecker, G. Pittino

"A computational method based on a continuum-mechanical approach to simulate rock cutting is developed and evaluated. The aim is to obtain the local loading acting at the cutting pick during operation. The explicit FEM is chosen to model the pick-rock interaction. The presented method takes advantage of (i) an advanced material model (ii) a robust contact algorithm and (iii) fast calculations due to parallelization. A damage-plasticity law is chosen and modified with user-subroutines. A user integrated element deletion routine evades critical mesh distortions. Infinite elements at the model boundaries avoid unrealistic deformation wave reflection.INTRODUCTIONExcavation in mining and tunneling is a costly and complex process. Special equipment such as the roadheader (fig. 1) is employed to cut the rock in the excavation process but high material strengths limit their usability (Tockner 1999). Nowadays a challenge is to extend their field of application to harder and more abrasive rock materials. The forces on the pick (fig. 2) are of great importance and determine wear and especially the efficiency of the machine. Figure 2 shows the principle of cutting and the predominant forces. The variation of pick geometry, cutting depth or attack angle will result in an alteration of these forces and determine the efficiency of the process (Tockner 1999). The mechanisms of rock cutting follow the principle of indentation (Kou et al. 1999). Directly under the indenter a hydrostatic stress state evolves causing the material to fail only due to crushing and fragmentation mechanisms. In the close surroundings large strains emerge and tensile cracks are formed but in a further distance the material behaves elastically."

Jan 1, 2015

By Robert W. Geehan

"INTRODUCTION The Bureau of Mines, in cooperation with the Federal Geological Survey, explored the Crowell fluorite mine by core drilling in 1945. Claims investigated are in sec. 14, T. 12 S. R. 47 E., M. D. B. & M., in southern rye County, Nev., about 5 miles east of 'Beatty.The twelve holes drilled by the Bureau totaled 3,661 feet. During 1945 the mine operator drove extensive exploration drifts, in part to verify results of the Bureau's work. The drilling program was designed to test for extensions of ore bodies known in the mine.The Crowell mine has shipped Ore to steel plants on the west coast for the past 20 years. During the war this market called for all the fluorite the mine could produce, but previously there were periods when it was difficult to sell ore or concentrates.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Nines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.Special acknowledgment is due to Glenn Allen, district engineer;A. C. Johnson, chief, Reno Division, Mining Branch; S. R Zimmerley, chief, Salt Lake City Division, Metallurgical Branch; W. R. Thurston of the Federal Geological Survey for advice on geological problems; and J. Irving Crowell, Jr., operator of the property, for his cooperation."

Nov 1, 1946

By Menglong Bian, Xiaotong Dong

Thermal damage is an urgent problem faced by deep mining. High-temperature rock mass, hot water and electromechanical equipment are the sources of the thermal damage. The increase in air temperature in mine tunnel is the result of fluid–solid coupling heat transfer from various heat sources. This paper takes a roadway with hot water and a mine car as the research object. Based on the Fluent, Static Structural and Steady-State Thermal modules in ANSYS, the thermal-fluid–structure coupling analysis in the roadway is carried out. It is found that the hot water has a significant effect on the thermal environment of the mine. Under the experimental parameters, the maximum heat flux density and equivalent elastic strain at the interface between the hot water and the rock are 9789.3 W/m2 and 0.00054532 m/m, respectively. The heat flux distribution in the rock area near the mine car does not change much, and the equivalent elastic strain value in this area is high. After the air is heated in the hot water area, the temperature curve changes gradually and then rises steadily. By changing the inlet air temperature parameter, it is found that the lower the inlet air temperature, the better the cooling effect, and the change of the inlet air temperature can change the air temperature field in the roadway as a whole. By changing the parameter of inlet air speed, it is found that higher wind speed brings better cooling effect, but with the increase in wind speed, the cooling effect of roadway thermal environment is very limited. When the wind speed increases from 5 m/s to 10 m/s, the air temperature of most measuring points drops by more than 2℃; when the wind speed increases from 15 m/s to 20 m/s, the air temperature of most measuring points drops below 0.7℃. After the wind speed reaches a certain value, the cooling effect of ventilation is very limited.

May 5, 2022

Structural analyses of oriented bore core sections from the West Wallsend No.2 Colliery Holding together with investigations in adjac- ent collieries and on the surface delineated structural phenomena. The rocks examined are anisotropic due to strongly developed bedding planes and the presence of penetrative joint planes. Joints, in this context, are regarded as mechanical discontinuities, they are genetically identif- ied wherever possible and their spatial attit- udes are determined and geometrically related to the regional structure. Identifiable anisotropies in the roof- and floor-strata of the Borehole Seam render favour- able mining directions for longwall and bord and pillar layouts.

Jan 1, 1972

By L. Klatzel-Mudry, D. J. Nikols, J. D. Hughes

"The Geological Survey of Canada Paper 88-21, A Standardized Coal Resource/Reserve Reporting System for Canada, is referenced by National Instrument 43-101 for the preparation of resource and reserve estimates on coal deposits. However, for all disclosure of mineral resources or mineral reserves for coal, issuers are required by NI 43-101 to use the equivalent mineral resource or mineral reserve categories set out in the CIM Definition Standards and not the categories set out in Paper 88-21. “Because the framework is based on Canadian deposits and their tectonic regimes, the Canadian Securities Administrators believe it is not reasonable to apply Paper 88-21 to foreign coal properties. The “Resource Links” at the end of this volume provide website links to guidance documents for preparing coal resource and reserve estimates in Australia, South Africa, and the USA.”This report discusses definitions, concepts and parameters used to determine coal resource and reserve quantities, and provides a framework to facilitate consistent categorization of coal quantities found within various depositional and tectonic regimes in Canada.Coal deposits, or portions thereof, are first categorized in terms of their geological complexity <Geology Type), and probable recovery method (Deposit Type). Methods for determining quantification parameters including seam thickness, areal extent and bulk density are outlined for each geology/deposit category. Within each geology/deposit category, coal resources are further divided, based on their assurance of existence, into measured, indicated, inferred and speculative subdivisions and, according to their feasibility of exploitation, into immediate and future interest subdivisions. Coal reserves within each geology/deposit category are subdivided according to whether they are within or outside active mining areas, and may be reported on in place, recoverable and saleable bases.A wide cross-section of the coal industry in Canada contributed to the development of this reporting system. To ensure that the parameters and concepts expressed in the system continue to reflect technological and economic realities in the future, the Coal Association of Canada has established a committee to facilitate periodic reviews."

Jan 1, 2003

By J Benn, V Kuznetsov, G Timms, A Spain

Earthen covers are now widely used in the mining industry to control the generation rate and/or release rate of low quality drainage from piles of sulfidic minewastes. Covers are usually designed to reduce the water infiltration rate and in some cases may also reduce the oxygen flux to the underlying sulfides. Engineered covers have only been used since the 1980s, however, and there is very little field data on their performance in the longer term. This lack of information has implications for the degree of confidence that can be placed on the predictions of the environmental impacts of sulfidic minewastes, for the acceptance of close-out criteria by regulatory authorities and for the financial liability of the mining industry. Covers were placed on sulfidic waste rock dumps at the abandoned Rum Jungle uranium mine during 1984 - 1985. These covers were designed to reduce the water infiltration to less than five per cent of incident rainfall by both water shedding and storage-release mechanisms. Regular monitoring by the Australian Nuclear Science and Technology Organisation (ANSTO) demonstrated that the covers performed better than the design criterion for around ten years, but infiltration rates have subsequently increased. There is a 66 per cent probability that the infiltration rate now exceeds five per cent of incident rainfall. The cover on the largest pile, WhiteÆs heap, was sampled in pits dug at eight locations. Sampling was carried out at the end of the monsoonal wet season and again at the end of the ædryÆ season. This, together with laboratory testing, enabled cover performance to be assessed against five criteria: design, construction, cover material characteristics, physico-chemical characteristics and biological characteristics. We are of the opinion that the design of the cover was suitable to achieve the objectives of stability, water shedding, storage-release, and provision of a substrate for vegetation growth. Over most of the surface of the heap, the construction of the covers, drains and erosion prevention structures was in accordance with design specifications. However, several small and localised bare patches on the upper surface of WhiteÆs heap coincide with a reduced cover thickness, which is likely to have been due to poor construction in those patches. The construction of covers on minewastes is dependent on an adequate source of material meeting design specifications. From our limited examination, it appears that there was shortage of material for each of the three zones û a lower impervious clay layer, the moisture storage-release layer and the upper erosion-resistant layer for vegetative growth. An indication of this was that the upper layers in some areas were observed to be thinner than specified. We are of the opinion that this shortage of suitable material has been responsible for some of the changes observed ten years after emplacement. Physical and geotechnical testing indicated that the cover materials no longer meet the original specifications. In particular, the permeability at the 8 locations was found to be greater than specified, by up to several orders of magnitude. The higher permeability may explain the higher observed rainfall infiltration and moisture content of the waste rock. This increased permeability appears to be due to a combination of biological and physical processes û galleries formed by termites and ants and an extensive system of shrinkage/desiccation cracks formed by the development of a polygonal blocky structure involving the entire lower clay layer. The desiccation cracks may fill with coarser illuviated materials and form a conduit through which roots access the underlying waste rock. Measurements were made of oxygen flux into the heap as cover layers were excavated in the pits. They indicated that the full cover currently reduces the oxygen flux to 20 - 23 per cent of that into bare waste and that this reduction seems to be proportional to the cover thickness. It was also found that the oxygen flux into the cover is about four times higher at the end of the dry season than at the end of the wet season and that the difference is due primarily to the difference in moisture content of the cover. Recommendations are made for the design and construction of covers.

Jan 1, 2003

By R. W. Stahl

Coal mining has been revolutionized by the continuous miner. This machine has replaced, or has combined into 1, 3 former operations: Cutting, blasting, and loading. During the 25-year period before this machine was introduced, advances had been made in transportation, but the actual "coal getting" remained virtually the same. As frequently occurs, the multiple-purpose continuous miner introduced a new hazard--more rapid liberation of methane. The coal output formerly obtained from 10 to 20 working places might now be obtained from 1. It is true that circulation of air was generally increased; but the bulk of this machine virtually precludes continuous flow of air across the face, where gas may accumulate. Apprehension about this possible hazard led the Bureau of Mines to test face atmospheres during operation; and Report of Investigations 5288, Methane Buildup During Cutting and Continuous Mining Operations (published in 1956), presents proof that real danger may be present in many otherwise well ventilated mines.

Jan 1, 1958

By Mustafa Kumral, Yuksel Asli Sari

Underground mining operations are sensitive to price fluctuations because they usually perform with a narrow profit margin compared to open-pit mining. Furthermore, the economic evaluations regarding operation are based on estimated or simulated grades rather than actual values. These bring a high degree of uncertainty to the viability of an operation. Hence, mine planning that accounts for uncertainty is crucial for underground mining operations. As an underground mining technique, sublevel stoping has geotechnical, curing time, seismicity, cost minimization, and production requirements. A new mixedinteger linear program is proposed that considers the uncertainty associated with net present value using chance-constrained programming. The net present value (NPV) maximization objective is transformed into a multi-objective maximization problem where one objective is to maximize the mean NPV, and the other objective is to maximize the negative standard deviation multiplied by a scalar called risk or reliability level. The balance between the two objectives was maintained by this scalar and was selected based on the reliability level of the project. A case study was conducted with varying reliability levels, and sequences were generated. It was shown that the expected net present value increased at higher reliability levels, and the overall value of the objective function decreased as the reliability level increased. In other words, the variance component penalized the value of the objective function. Moreover, it was observed from the case study that at lower reliability levels, stope grade order bears similarity to the extraction order.

Aug 4, 2023

By W. G. Davenport

The remainder of this book develops and uses mass and heat balances to describe steady"state flash smelting. Its objectives are to: a) describe the many ways a flash furnace operator can produce specified products, e,g. 65% eu matte, 35% SiOz slag, 1500 K (b) determine the oxygen, air, flux and hydrocarbon fuel requirements of each method (c) show how the flash furnace can be controlled to give specified products with varying feed compositions (d) suggest how the flash furnace operator can maximize profitability while producing specified products. This chapter develops the basiC heat and mass balance equations of steady-state ?flash smelting. It then adapts the equations to industrial feed materials .and products. Lastly it determines the amounts of oxygen and flux needed to produce molten matte and 35% SiOz slag from chalcopyrite concentrate in an Inco oxygen flash furnace,

Jan 1, 2001

By T. Sakaguehi

Some attempts were made to recover and remove of uranium that may be present in refining effluents, mine waste Water, and other waste sources by using microbial biomass. To establish which microorganisms accumulate the most uranium, 135 species of microorganisms (42 bacteria, 26 yeasts, 34 fungi and 33 actinomycetes) were screened. Of these 135 species of microorganisms tested, extremely high uranium absorbing ability was found in Pseudomonas stuzeri, Neurospora sitophila, Streptomyces albus and Streptomvces viridochromogenes. In addition to the research on uranium uptake, thorium recovery by using microorganisms was investigated. High abilities were found in Streptomyces levoris and Bacillus subtilis. The selective accumulation of heavy metal ions by various microorganisms has also been examined. Uranyl, mercury and lead ions were readily accumulated by almost all of the species of microorganisms tested. Actinomycetes and fungi differ from many bacteria and most yeasts in their selective accumulation of uranium, and mercury. The basic features of uranium uptake by Streptomyces viridochromogenes, a microorganisms with high uranium-uptake ability, were investigated systematically. Synthesizing these results, we suggested that the accumulation of uranium into these microbial cells is not directly mediated by any metabolic process:, but almost completely dependent upon physicochemical adsorption on the cell components. In addition to this fundamental research, uranium recovery was investigated in immobilized Streptomyces viridochromogenes. These immobilized cells adsorbed, uranium readily and selectively. The immobilized cells recovered uranium almost quantitatively and almost all uranium adsorbed was desorbed with 0.1 N Na2CO3, These results showed that microbial cells are more stable after Immobilization and can be used repeatedly for the process of uranium adsorption-desorption. These results suggested that these microbial cells can be used for the recovery and removal of nuclear fuel elements, such as uranium and thorium, from refining effluents and mine waste water.

Jan 1, 1991

By Ralph W. M. Lai

The liquid membrane separation process was first patented in 1968 for separating hydrocarbons.(1-4) This stimulated many researchers to join in the area of separating organic compounds. l Since then, its applications have been extended to the removal of contaminants from waste water,(12-33) encapsulation of enzymes and/or microorganisms for reaction and/or separation, (24-28) oxygenation of blood (artificial lung),(19) removal of toxins from blood (artificial kidney)(26,20) and metal extraction.(31-63) This paper discusses the possible process schemes for using liquid membranes to separate and concentrate copper ion from its acidic leaching solution.

Jan 1, 1982

By O. Forsén

A new cell construction was designed for the study of the electrochemical behaviour of additives in conditions that simulate real copper, electrorefining. The behaviour of gelatine and thiourea was studied by applying different electrochemical methods, i.e. polarization resistance and voltametric measurements. In this study, individual galvanostatic electrolysis experiments were carried out for 120 hours. The organic additives were introduced to the electrolyte at certain intervals and their concentration was varied in the range &om zero to four ppm. An optical microscope was applied for the examination of copper cathode deposit microstructures. The results show that gelatine has a polarizing effect on the deposition potential of copper whereas even small amounts of thiourea depolarize the electrodeposition of copper. The maximum inhibitor efficiency of gelatine was obtained at a gelatine concentration of slightly lower than two ppm. When both gelatine and thiourea were present in the electrolyte, the depolarizing effect of thiourea exceeded completely the polarizing effect of gelatine. If chloride ions were added to gelatine and thiourea containing electrolyte, the electrochemical behaviour of the system was altered drastically. Chloride ions resulted in the prevailing of polarization effect caused by gelatine while the depolarizing effect of thiourea disappeared in this system. The polarizing effect of gelatine increased until chloride ion concentration of 30 ppm was reached. Also, the above electrochemical phenomena could be detected in the optical examination of copper deposit microstructure.

Jan 1, 1995