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By S. Frisch

Selenium (Se) in effluent waters has become a significant challenge for a number of industries. Toxicity studies and new reports of occurrence have certainly caused increased scrutiny and actions in the mining industry today (Sandy, DiSante, 2010). While initial activity in addressing selenium-laden waters were conducted in the coal mining industry, today a much broader range of mine types are beginning to search for solutions to selenium treatment of their mining waters, including both hard rock mining operations (gold, nickel, zinc, etc.) and soft rock mining (phosphate, uranium, etc.) Throughout North America, new regulations covering selenium discharge are either in place or being developed. While a number of physical/chemical approaches show promise in selenium treatment, when considering optimal cost and treatment efficacy issues, biological treatment ? particularly fixed-film biological treatment - is reported to be one of the most promising approaches to managing selenium-containing waters. Among biological treatment options, the fluidized bed reactor (FBR) has undergone extensive pilot testing for Se treatment in the last three years, including eight pilot programs, and the first FBR system is now operating at a coal mining site. In all tests, the FBR has been shown to be a highly cost-effective approach to selenium treatment based on its physical and performance characteristics. This is consistent with its history for reaching low levels of treatment in similar service for other oxyanions including perchlorate, nitrate and various metals. With the results from the most recent testing, the technology has been shown to be adaptable to an ever-broadening range of influent water conditions and flow rates, in varying terrains and weather conditions. Selenium occurs in various valence states from -2 to +6 (Sobolewski, 2005). The speciation of selenium plays a critical role in understanding the effectiveness of any approach for removal, especially to low levels. Elemental selenium is insoluble and has little effect on living organisms. Colloidal fractions are known to occur. In aqueous environments such as coal mining runoff, selenium is most often found as the oxygenated anions of selenite (SeO32-, Se4+) and selenate, (SeO42-, Se6+). Selenium is commonly found in mining waters in concentrations ranging from 3 to >12,000 µg/L. The U.S. National Primary Drinking Water Standard MCL is 50 µg/L for selenium (EU 10 µg/L; WHO 40 µg/L). The National Fresh Water Quality Standard is 5 µg/L for selenium. The U.S. Fish and Wildlife Service has recommended that the National Fresh Water Quality Standard be lowered to 2 µg/L to protect fish, waterfowl, and endangered aquatic species. Several states have followed with enforcement actions at these same low levels. In Canada, permits may require stakeholders to monitor levels in water or biota, or to comply with guidelines, at either the National or Provincial levels, which can be as low as 1 or 2 µg/L in surface waters. Treatment of selenium in all mining waters presents a series of challenges. It can be present in relatively dilute concentrations and in streams with variable and often high flow rates. It can be present in many soluble and particulate forms, which may affect process design and treatability. The conditions of influent selenium-containing waters can vary, with issues such as temperature, pH, total dissolved solids and other contaminants affecting the ability to remove selenium selectively and economically. Treatment of selenium often results in the generation of a concentrated by-product requiring disposal, and re-release from residuals can occur. Beyond these issues, the physical environment of a mining operation can offer challenges such as remoteness and harsh and/or cold weather. Currently available selenium treatment technology (Table 1) includes biological treatment and a number of physical-chemical processes ? such as ion exchange, membrane filtration and adsorption ? that vary widely in efficiency and cost. Most treatment options remain either too costly and/or unproven for selenium-containing streams for reasons that include poor removal efficiency, variability in volume and composition of influents, system sizing and logistics considerations, as well as operating requirements.

Feb 23, 2014

By B. C. Lewis

The mining industry has experienced a general trend toward an increasing number of longwall operations, an increasing percentage of underground coal being mined by longwalls, and increasing productivity from the longwalls. Longwall operators have not yet reached a state of mining euphoria. Competitiveness both within the industry and from alternate fuel sources is forcing continued pursuit of higher productivities and lower costs. The following graphics present trends in the industry. Longwall mines, as defined for this presentation, are those reportedly having longwall installations in each of the respective years. Production from both the continuous miner and longwall units is included in the longwall mines. Non-Longwall mines are all other underground mines. Productivity calculations are based on total employee-hours associated with the operation.

Jan 1, 1990

By B. R. Arvidson

Sharper separation and improved control of the top size increases the fine particle product yield. As the milling circuit recycle stream is reduced, the overall capacity is increased. In some cases, a doubling of throughput is realized, although 25 to 30% increase is more typical. Alternatively, the energy demand may be reduced, although the best economic improvement results from higher capacity. A comparison with a high-pressure roller mill circuit shows that an optimized ball mill circuit retrofitted with the new air classifier has lower energy consumption. The new air classifier features low energy demand and substantially lower maintenance compared to similar equipment. Design and operation of this recently patented classifier are discussed. Several industrial installations will be described.

Jan 1, 1999

By R. S. Olsen

Intensely altered rock has had a large effect on slope stability as slopes increase in height at Island Copper mine. Traditionally used, fracture-controlled rock slope stability design techniques have been supplemented with analyses of failure modes which include failure along curved surfaces typical of soil materials. A rock mass rating (Pa) system has been developed that addresses the lower end of rock mass strengths. Rock masses are rated in terms of fabric integrity, alteration, fracturing intensity and gouge strength. Rock mass classes have been defined using statistical frequency distributions of rock mass rating values. Strength values have been assigned to the various classes from shear testing, back analyses of failures and engineering judgment.

Jan 1, 1987

A knowledge of airway friction factor (K-factor) is necessary to designing mine ventilation systems for least cost and optimum effectiveness. The friction factor used must be accurate and reliable to estimate correctly roadway resistances and pressure sources for required flows. Though the resistance to flow offered by mine airways has been an object of study over the last half century, no accurate relation has yet been established from which the prediction of the resistance of a projected airway can be made. In Kentucky, only limited and incomplete data on local K-factors are available. Therefore, there is a need for field investigations to determine these values in-situ for existing mining conditions. The author describes a study concerning K-factor that was carried out in ten coal mines, located in eastern and western Kentucky. The results of these investigations are presented in both tabular and graphical form.

Jan 1, 1991

By A. R. Negele

Kaolin-based pigments are the most widely used pigments in the paper industry. Several types are available and include standard hydrous, delaminated, calcined, chemically-structured, and most recently, composite pigments. Within each category, a spectrum of products is available to satisfy the application requirements of paper producers. The paper industry has a broad range of applications including fillers in woodfree and groundwood-containing papers, pigmented size press applications, ultra-lightweight and lightweight coated papers, coated merchant papers, cast coated papers and coated paperboard. Each application has its own set of performance criteria and suppliers must work with mills to identify appropriate product(s) to fulfill these requirements.

Jan 1, 1993

By A. A. Densmore

Telluric Current is that portion of the electric field observed at the surface of the earth which is of an alternating nature, and which is related to solar activity and events in the ionosphere. The primary electromotance which drives the telluric current is the result of the induction process associated with time variations in the earth's magnetic field. The relationship between the electric and magnetic components of this electromagnetic field depend upon the conductor. For our purposes, we are dealing with frequencies f in the range

Jan 1, 1972

By Richard M. Chamberlin

Perlite is an altered rhyolitic glass with 2 to 5 wt % water that expands or "pops" when heated quickly to plasticity while evolving steam to form lightweight, glass foam. Commercial perlite deposits in New Mexico are well-developed zones of chemical weathering (hydration) superimposed on highly permeable and thick glassy zones at the chilled upper surface and toes of high-silica-rhyolite lava flows and lava domes. The maximum tonnage of glass in these volcanoes was predetermined by their unique eruptive histories. New Mexico perlite production (80% of US production of 571,00 st) is mostly from the 3.9 Ma high-silica-rhyolite lava flows at the No Agua Peaks volcanic center. The primary vent at No Agua is defined by a 900 ft-high rubidium-rich composite lava dome, known as West Peak, that contains minor perlite reserves. Slightly less rubidium-rich lava squeezed out from under the west flank of the dome to form relatively thin (250 ft) but highly vesicular lobate flows that now consist of about 50 % recoverable perlite. Finally, rubidium-poor lavas were extruded from a radial dike on the northeast flank of the dome. These thicker (400 ft) flow lobes contain about 20 % recoverable perlite. The largest mass of lava does not always contain the most perlite. The thinner (west) flow at No Agua yields the largest perlite reserves rather than the large composite lava dome or thicker (east) flow.

Jan 1, 1994

By T. Negeri

Flotation is the most efficient and preferred solid-solid separation method in mineral processing. However, enhanced production of high-grade concentrates at sufficiently high recovery still poses technological challenges to-day. A novel flotation method to produce final-grade concentrates from finely-ground ores in a single step is being developed and tested by CANMET. For the complex sulphide ores tested, grades are superior while recovery is considerably improved. Furthermore, concentrate production rates, at similar recoveries, are faster than for the conventional rougher-scavenger-cleaner configuration. This paper discusses the physical operating parameters affecting Cu-Zn flotation metallurgy.

Jan 1, 1995

As mentioned in chapter 8, one of the objectives of the budget is to provide a mechanism for ongoing measurement and control of the production operation. The budget shows expected performance. Actual results are compared to this benchmark to evaluate past performance and to direct future activities. The variances between budgeted and actual results identify specific activities that did not perform as expected (whether negatively or positively). Managers who use variance analysis are essentially applying a management- by-exception philosophy. Individual organizations will determine variances that reflect their own processes and managerial interests, but these variances all follow the approach outlined here. Firms will also vary in the extent to which variances are reported. Some firms use a few variance measures for the overall production organization whereas others calculate variances for individual departments or even individual work areas. As mentioned in chapter 5, it is important to distinguish between controllable and noncontrollable costs when using budgets for control and evaluation.

Jan 1, 1999

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By M. D. Banghart

The Republic of South Africa is an outstanding example of the benefits to a new land by the application of individual enterprise, capital and know-how. While South Africa was colonized by European and Bantu people some 300 years ago, it was only 70 to 80 years agog when diamonds were discovered at Kimberley and gold on the Witswatersrand, that the mining, industrial and commercial potential of the country began to emerge. South Africa s national income rose from R1, 200 million in 1945 to over R4 billion in 1960 (1R = 10 shillings = $1.40 U. S.) The annual national income per head of population -- including all races -- is currently R254 (£127) This compares with £24 for India., £30 for Nigeria, and £50 for Ghana. Allowing for the increase in population, the increase in real income per head of population was about 40% during the past 15 years.

Jan 1, 1962

By X. P. Zheng, H. K. Lin

Barium fluorophlogopites were synthesized in the laboratory to investigate the effects of composition and crystal parameters on surface properties and floatability. The negative surface charge of mica is determined by the barium content, the crystal cell volume, the distance between the layer structure and the Ba-O bond length. The higher the barium content, the larger the cell volume and distance between the layer structure, and the longer the Ba-0 bond, the more negatively charged the surface is, and, hence, the more easily adsorbed are cationic collectors. When an anionic collector (sodium oleate) is used, barium oleate forms on the mica surface and hence chemical adsorption occurs.

Jan 1, 1995

By B. H. Kim

The use of a 25.4 mm diameter water-only hydrocyclone for separating fine-size (-150 µm), high-density (>4.5 g/cc) particles from similar-size, lower-density (2.65 glee) particles was investigated. It was found that a single-stage separation recovered nearly 90% of the heavy minerals (7.0 g/cc), while achieving a volume reduction of about 70%. The use of dense medium in a single stage improved volume reductions to 90% at similar heavy mineral recoveries. In addition, computer simulations of a three-stage circuit were performed, which showed that recoveries approaching 97% with volume reductions of 95% were possible.

Jan 1, 1998

By M. W. Harmer

Laboratory test work, pilot plant testing and plant experience with wet, fine mesh screens is discussed. High frequency, low amplitude, fine mesh, wet screens were installed on the 6th cleaner concentrate stream. These screens produce a 60% oversize recovery split of the molybdenite concentrate that is of leached equivalent quality. The undersize stream is leached with 'hot ferric chloride to remove Pb and Cu contaminates before roasting or shipment to sulfide customers. This plant modification is a good example of using existing technology in an unconventional flow sheet to yield significant cost savings.

Jan 1, 1990

By Dolf Vos

The balling section of the pelletizing plant at Hoogovens IJmuiden consists of 7 balling drums. Each with an average capacity of 100 tons of green pellets per hour. The balling drums are equipped with rotating scrapers and water-spraying systems. The scrapers are installed in order to restrict the growth of the race to a certain thickness. The spraying system is used to adjust the desired value of the moisture-content of the rewetted ground ore, the pellets and the race. The desired value is the value by which the balling- process is stable, good pellets are formed and surge occurs within certain limits. In October 1980 the construction of one of the balling drums has been modified. The rotating scraper was removed and the inner wall of the drum was supplied with a rubber-lining. In 1982 a second balling drum has been rubber- lined. At the same time the Tyler vibrating screen of this balling circuit has been replaced by a roller(bed)screen. By the end of 1983 all 7 balling circuits will be equipped with rubber-lined drums in combination with roller(bed)screens. The combination of these two modifications will improve the quality and the screen analysis of the green pellets, moreover resulting in savings on energy- and maintenance costs. This paper describes the influence of a rubber- lining on the balling process and the green pellet quality by carrying out in-plant testruns in November/December 1980. The testrun results have been compared with the results of a not modified balling drum.

Jan 1, 1983

By E. Martinez

A heavy mineral sand sample was tested containing 13% heavy mineral consisting of rutile, zircon, and ilmenite. Eleven tests were run at a mill site with a Mineral Deposit Limited MG 4 spiral to determine the effect of the addition 0; magnets to the spiral compared to conventional gravity separation. Different magnet configurations and field strengths were tested. Optimum results were obtained with the spiral retrofitted with magnets. The heavy mineral content of the concentrate was increased from 55.5% in the control to 64.2% with the magnets. The 8.7% improvement in heavy mineral recovery was due not only to the weakly-magnetic ilmenite, but also to increased recoveries if the non-magnetic zircon and rutile. The increased recoveries were achieved with no loss of concentrate grade.

Jan 1, 1992

By Dan Wang, Qiuju Li, Xiao Guo

The chemical states and ions interaction were significant interest to understanding columbite mineral/acid solution interface dissolution and reaction. The present research work was focus to explore the specific cations ( Nb5+, Fe2+, Fe3+) distribution near the ferrocolumbite mineral/acid solution interface, and determine these cations leaching sequence in sulfuric acid solution. X-ray photoelectron spectroscopy had the potential to provide detailed dissolution information by resolving chemical state and ion distribution of ferrocolumbite during sulfuric acid leaching process. The binding energy decreased in sequence as Nb5+- O < Fe2+- O < Fe3+- O, and increased in sequence as Fe3+- SO4 < Fe2+- SO4 < Nb5+- SO4 which revealed Nb in ferrocolumbite mineral more easily leached comparing to Fe. The ratio of Fe2+- O/Fe3+-O on leaching residue decreased, and Fe2+- SO4/Fe3+-SO4 ratio increased as sulfuric acid contraction increasing suggested that the Fe2+ oxidized to Fe3+ and released Nb from mineral and dissolved into leaching solution. The ratio of Nb/Fe was lower 0.07 with sulfuric acid contraction increasing which meant Nb dissolution promoted by oxidation of iron. The dissolution mechanism of Fe element in ferrocolumbite mineral was Fe2+- O broken and generated Fe2+. Fe2+ was oxidized to Fe3+ in concentrated sulfuric acid leaching solution. The dissolution mechanism of Nb in ferrocolumbite was that Nb5+- O was directly digested by H+, and the released Nb5+ complex with SO4 2− ion formed cation − anion pairs. The coordination of formation Nb5+- SO4 pairs and oxidation Fe2+ in mineral could promote ferrocolumbite dissolution.

Aug 5, 2023

By G. T. Adel, P. E. Richardson, R. Pazhianur

Cathodic protection using impressed current was employed to reduce mill wall wear during ball milling. Wear rates were determined from weight-loss measurements made on four 1-in.-diam mild steel coupons that were installed flush with the interior surface of the mill wall. Grinding tests were conducted on quartz, pyrite and quartz-pyrite mixtures at pH levels of 4.6, 7.1 and 9.2. Cathodic protection was shown to reduce mill wear by 30% to 60%. An examination of the coupon surfaces using scanning electron microscopy showed that cathodic protection greatly reduced pitting corrosion. The presence of a sulfide mineral, such as pyrite, was found to increase the wear rate significantly, possibly due to galvanic interactions. It was also found that the wear rate is significantly higher than the sum of abrasive wear and the corrosive wear, due to a synergistic effect.

Jan 1, 1998

By P. L. Stavenger

Principles of Operation and Mechanical Features General Mechanical Description Sieve-bend screens are high-capacity screening devices which utilize stationary, concave, wedge-bar screening surfaces. A complete sieve bend is comprised of a feed distribution chamber, a structure for holding the screen surface, and collection chambers or chutes for oversize and undersize materials. In devices used for metallurgical practice, provision is usually made for reversal of the direction of flow over the surface, either by rotating the surface or by changing the feed nozzle position. The size of the unit varies in height from 5 to 8 ft, and in width from 2 to 8 ft. The orientation of the wedge-bar surface is such that the slots between the wedge bars are perpendicular to the flow of feed material over the surface. The feed distribution means is arranged such that the flow of liquid suspension is distributed evenly and tangentially over the width of the screen surface. A variety of means are used including simple gravity weir feeds, long slotted nozzles, and a multiplicity of round nozzles. A typical gravity-fed weir type nozzle is shown in Fig. 18. Most sieve bends are fed with gravity feed in such

Jan 1, 1985