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By R. D. Schmidt, S. E. Follin

Introduction Mineral recovery from an in situ leaching operation is determined by the often complex interaction of hydrology, mass transport, and chemical kinetics. The operating conditions of many pilot and production scale uranium leaching operations involve heterogeneities in aquifer permeability. Differences in permeability may be naturally occurring, the result of differences in main size or cementation, or they may be induced by leaching activity. Variations in permeability directly affect the fluid flow streamline pattern, fluid flux, and so also leaching geochemistry and uranium recovery. An in situ leaching hydrology model (ISL) and a mass transport-oxidation rate model (ISLGC) have been developed for use in making site specific predictions of the leachability and productive potential of heterogeneous ore deposits, and for the optimal design of leachant injection and recovery operations. The two models are linked by output and input requirements. The ISL hydrology model generates a leachant flow streamline pattern between injection and recovery points in a flow domain incorporating regions of arbitrary permeability. The ISLGC transport model describes the changing solution concentrations of uranium and oxygen and the changing mineral concentrations of uranium and pyrite resulting from convection, longitudinal dispersion, and oxidation reactions. ISL hydrology model Basic equations The differential equation for steady-state two- dimensional flow in an isotropic porous medium is

Jan 1, 1988

By Peter C. Lighthal, Harvey N. McLeod, Iain G. Bruce

This paper describes the practical aspects of handling cyanide leach tailings. Alternative systems for cyanide destruction are briefly discussed. The provision of adequate retention time to allow natural degradation of cyanide during summer months is the most economical method of cyanide destruction. Cyanide in ground- water can frequently be both persistent and mobile, so that tailings basins should be designed to limit seepage. Common methods for limiting seepage are presented. Other aspects addressed are water balance, winter operation and abandonment of cyanide tailings systems. A case example of the Cheni Gold Mines Lawyers Creek Project tailings handling system is presented.

Jan 1, 1987

By Todor P. Stefanov

The thermal draught within ventilation networks of underground mines depends to a great extent on the shafts depths and degree of change of ventilating air density. When the topology and space orientation of a ventilation network are constant, the dynamics of thermal draught is determined mainly by the variations of the heat- and mass-transfer processes in the openings. This conclusion follows from the well known basic theoretical notions about the thermal draught-aerostatics and thermodynamics [1]. Quantitative evaluation about the influence of heat- and mass-transfer processes on dynamics of thermal draught could be made through: direct mine measurements, special experiments and with the aid of mathematical models. The first two methods produce sufficiently accurative results, however it is very difficult to perform such studies, particularly when these processes are evaluated within a large scope and multifactor aspects. Mathematical models of thermal draught allow to overcome easily these difficulties. The degree of accuracy of results, obtained by this method, depends to a great extent on the degree of approximation achieved by the model to the real heat- and mass-transfer processes. In this paper, with the aid of Bulgarian developed method, algorithm and computer program V WT-4 - for complex evaluation of ventilation parameters in active mine ventilation networks [2], the authors investigate some changes in the thermal draught. Basically, the method is an iterating evaluation of an open set of equations, which represents relationships between the following basic parameters of a mine ventilation network: [ ]

Jan 1, 1980

By Wolfgang Sand, Alex Schippers, Tilman Gehrke, Thore Rohwerder, Peter-Georg Jozsa

Metal sulfides are degraded via thiosulfate (pyrite) or via polysulfides and sulfur (sphalerite, galena, chalcopyrite) by leaching bacteria The attack on the crystal lattice is either effected by only iron(III) ions or by iron(III) ions and protons, respectively. Consequently, different endproducts are formed. For a control of ARD-processes, these reactions need to be hown to regulate them. Experiments in percolators up to 65 m3 with inorganic compounds like fluoride, concrete, or SDS resulted in differently lasting inhibition. Microcalorimetric measurements of microbial leach activity allow monitoring of these effects with respect to active bacterial cells, and, in addition, the amount or rate of dissolved metal sulfide allowing prediction of possible endangerment by ARD.

Jan 1, 2000

By William E. Hole

The sand and gravel industry provides an enormous quantity of materials vital to the maintenance of low-cost construction. There has been little effort to conserve this valuable natural resource. In fact, existing regulations which affect sand and gravel operations act more to waste these materials than to conserve them. Another factor affecting the industry is new legislation requiring the reclamation of worked-out pits. Although such legislation creates many administrative headaches for a sand and gravel operator, there exists the possibility through such legislation of gaining some conservation measures that could be helpful to the industry.

Jan 1, 1974

By B. J. Arnold, F. F. Aplan, S. Chander

There is a broad range of chemical reagents of potential use to the coal preparation industry: flotation frothers, flotation collectors (for coal, ash minerals or pyrite) and collector-assisting (conditioning) agents, flotation depressants (for coal, ash minerals or pyrite), pH regulating agents, acid mine drainage treatment chemicals, flocculants, filtration aids, dispersants, dust suppressants (wetting agents and car-top or pile binders), freeze conditioning agents, water treatment chemicals (corrosion and scale inhibitors) and suspension stabilizing reagents (dispersants, stabilizers, biocides). The application of each of these types is discussed with particular attention paid to those of greatest importance: flotation frothers and collectors, pH regulators and acid mine drainage treatment chemicals, flocculants and freeze conditioning agents.

Jan 1, 1986

By D. M. Bodily, R. Jin, W. Hu

Four methods to assess the relative floatability of fine coal have been tested: flotation with frother only, salt flotation, timed-release analysis, and flotation with frother and collector. A practical and simple criterion that combines the separation efficiency (capacity factor) and kinetic rate constant (intensity factor) has been suggested. Five coal Samples from Utah were tested. Based on test results, it was concluded that the floatability test with collector and frother is closer to practice, and according to the suggested floatability criterion, coal fines can be classified into four categories of relative floatability: very easy, easy, moderate, and difficult.

Jan 1, 1988

By James Watson Baxter

Fluxes are used to promote pyrometallurgical processes that rely on adhesion (soldering or brazing) or fusion (gas and arc welding) to join metallic surfaces. In the adhesive processes, the metal surfaces to be joined are not melted; the join is formed using a filler metal with lower melting point than the base metal. Fusion welding involves use of heat in excess of the melting point of the base metal. The fused joint may be achieved either by simply fusing together metal surfaces brought in contact with each other or by introducing additional molten metal of similar composition to form a fused joint. ADHESIVE PROCESSES--SOLDERING AND BRAZING In order for molten filler metal, solder or braze, to spread in a manner that creates a successful join; the work surfaces on the base metal must be thoroughly cleansed. Fluxes remove stubborn oxide films and other surface contaminants, promote wetting of the work surfaces, add fluidity to the solder or braze, and enhance workability and ease of spreading. Brazing processes involve higher temperatures than those reached in soldering. Brazing fluxes, which must remain active and effective at the higher temperatures, differ from those employed in soldering. Some common fluxes used in adhesive processes are rosin for soldering tin and electrical connections, hydrochloric acid for use in soldering galvanized iron and other zinc surfaces, and borax for brazing. Soldering and brazing are similar processes, the primary difference being the temperature at which the joining operation is carried out. Soldered joints, produced with low-melting-point fillers (solders) that melt and flow at temperature less that 450°C (Althouse et al., 1988) can sustain loads of 1 to 1.7 MPa for extended periods of time (Anon., 1966). Brazing involves the use of filler materials with melting points commonly above 500°C and generally provides stronger joints than those obtained with solder. Both processes require local application of heat to melt and spread the filler so that the molten filler can wet (adhere to) the base metals by alloying and diffusion. Soldering Soldering is a means of joining metals by adhesion using a metallic bonding alloy as the filler, commonly a mixture of lead and tin. However, the adhesion of solder depends more on its ability to be keyed into minute surface irregularities than on alloying. The most familiar application is to provide and secure electrical connections. Soft solders can range from 1 to 70% tin with the remainder mostly lead. However, for general-purpose, soft-solder work, the alloy is commonly 50% lead-50% tin. Higher lead contents provide a wider range in the melting temperature and, for this reason, a 60% lead-40% tin alloy, which yields a mushy mixture, is used for wiped joints in lead sheet and pipe work. Conversely, 40% lead-60% tin alloys are used in soldering tin and other low- melting-point materials for which a narrower range of melting temperature is required. There are numerous other solder compositions such as tin-silver, 95% tin-5% silver and antimony-tin, 95% tin and 5% antimony (Carlin, Jr., 1992). Heat needed to melt and spread the solders is commonly provided by electrically heated, copper-tipped soldering irons or by means of torches; the solder is applied by hand, usually face-fed by means of wire. For wiped joints in plumbing and lead-cable splicing, the solder is manipulated with cloth pads. The molten solder wets the joint surfaces and is drawn, by surface tension, into minute fissures and capillary openings. Other applications involve use of induction heaters and furnaces with pre-shaped solder appropriately placed prior to fluxing and heating. In some processes, the joints are immersed in molten solder. Constituents and Role of Soldering Fluxes: Soldering fluxes generally fall into one of three categories: highly corrosive fluxes, intermediate fluxes, and noncorrosive fluxes. These same categories are sometimes designated inorganic, organic and rosin-based respectively (Althouse et al., 1988). Common constituents of each group are discussed briefly below. Corrosive Fluxes (Inorganic). Work with aluminum, magnesium, stainless steel, high alloy steel, aluminum bronzes, and silicon bronzes is carried out at temperatures in the upper portion of the range for solder operations. Soldering these materials requires use of highly active, corrosive fluxes to remove and prevent the formation of the especially stubborn, hard, oxide films that form on these materials upon exposure to the atmosphere. The corrosive fluxes consist of inorganic acids and salts that are applied either as pastes or dry. They are active at elevated temperatures and, since they remain active after the soldering is completed, must be completely removed. The main constituent of most corrosive fluxes is zinc chloride with a melting temperature well above the solidus temperature of most commercial tin-lead solders. It is made by the action of hydrochloric acid on zinc. When zinc chloride is used alone, un- melted particles of this corrosive salt get caught up in the joint and weaken it. For this reason, other inorganic salts such as ammonium chloride (NH4Cl) or sodium chloride (NaCl) may be added to lower the melting temperature. A mixture of zinc chloride and ammonium chloride is very effective because the excellent oxide reducing properties of ammonium chloride and the protective action of the molten zinc chloride combine to produce a fluxing action superior to that achieved when either is used alone. In addition to zinc chloride, ammonium chloride, and sodium chloride; common con-

Jan 1, 1994

By P. Somasundaran, C. C. Harris

The power consumption of stirred-media mills was studied using an approach developed from work on stirred reactors. Evaluated were the relationships of factors such as stirring speed and impeller and tank dimensions on the torque required to rotate disc and pin impellers immersed in dense particulate media. Data collected under carious experimental conditions were analyzed. The results were summarized and presented in the form of characteristic plots, general equations and dimensionless group correlations involving power and modified Reynolds numbers. Special attention was directed towards the rheological properties of the media, which was considered a non-Newtonian liquid, and hence the equation of power-law liquids was employed. A procedure for estimating the parameters of effective viscosity and scale-up guidelines (with respect to power consumption) are proposed.

Jan 1, 1996

By Jaime Lomelin

The brines from the sub-surface of the Laguna del Rey dry lake are pumped to Química del Rey, S. A. plant, where they are cooled in adiabatic crystallizers precipitating sodium sulphate decahydrate. This salt is dehydrated in multiple effect evaporators and dried in rotary kilns producing high purity anhydrous sodium sulphate. The spent brines from the sodium sulphate operation are concentrated in solar ponds, precipitating astrakanite and leaving a brine with a higher concentration of magnesium ions. This brine is treated with calcium chloride solution to eliminate the remainder of sulphates, leaving a solution of magnesium chloride ready for the manufacture of refractory grade magnesium oxide or periclase. The magnesium chloride is reacted with dolime to produce magnesium hidroxide which is washed, filtered, and calcined to produce soft burned magnesium oxide, which is briquetted and dead burned to produce the periclase.

Jan 1, 1984

By Patrick A. Ley

Maintaining, managing and manipulating large quantities of geologic data can be a very costly and time-consuming process. The use of computer-based methods can provide some relief to the problems of editing, displaying, and interpreting spatial geological data. ENCORE is a system designed specifically for coal orebody modeling and reserve esitmation where the geologic data is stored on a large mainframe computer and is accessed from a local work station for editing, manipulating, and producing various reports and high-quality engineering maps. The ENCORE system was designed for use by the geologist or mining engineer with little or no computer background and, additionally, it was designed to provide the geologist or mining engineer enough flexibility to be able to select the appropriate methodology for the orebody being analyzed. The various analysis tools incorporated into ENCORE can significantly increase the professional's productivity without burdening he or she with the need to understand the details of the internal computer language.

Jan 1, 1982

By Donald A. Dahlstrom, Wai-Ping Kam

The mineral industry and individual processing plants are large consumers of energy. While energy conservation has received some attention in the present Federal Administration National Energy Strategy proposal it is obvious that the mineral industry should also continue to emphasize energy consumption reduction for important economic savings alone. As indicated by other studies, comminution is the largest single consumer of energy in the mineral processing plant (1.3% of total electrical energy consumption in the U.S.A.).1 Fine grinding is the largest portion of this amazing statistic. While substantial energy savings have been demonstrated by new machine developments and improved control methods, undoubtedly there are additional areas in comminution where substantial progress can be made. Some time ago, the U.S. Department of Energy published a report on "Comminution and Energy Consumption" by a committee composed of experts in the field of comminution from industry and academia. They identified the following potential for energy savings by specific areas? Classification device design 9-13% Comminution device design 3-16% Control 9% Grinding additive 3-6% Materials 3% It is apparent that the classification device had the first or second highest savings potential. Obviously, serious research consideration must be given to this technology area. A series of three papers have previously been written on the subject of two stage classification research work for ball mill operation by the authors. Accordingly, a brief review will be made. Previous Research Results on Two Stage Classification The hydrocyclone was selected as the type of classification equipment for this study as it represents by far the majority of the devices used in ball milling. While four different hydrocyclone circuits have been proposed by others,3 only two were considered in this work as illustrated in Figure 1. Flowsheet A is truly counter-current in nature in that the product from the ball milling circuit is taken from the first stage overflow

Jan 1, 1992

By D. A. Newman

The purpose of this research is to examine the post-failure behavior of coal as a mass and examine the relationship between the results of this study and prior laboratory investigations of the post-failure behavior of coal as a material. Instrumentation to measure changes in stress and deformation was placed in a headgate yield pillar and will be monitored as the face passes the area. A battery powered, automated data acquisition system, capable of recording up to 9,000 data points, is currently used to remotely monitor changes in vertical and horizontal pillar stress.

Jan 1, 1988

By A. M. Marabini, G. Belardi, E. Spaziani

The objective of this research was to investigate the possible application of integrated circuits to the concentration of talc from the Valmalenco mine, located in northern Italy. The investigation was aimed at producing a high-grade product (low in impurities such as iron and carbonate) that would be suitable for industrial applications. Because of the presence of accessory minerals, the talc concentrate from this ore is not, at the present time, suitable for industrial applications.

Jan 1, 1996

By J. M. Rotter, R. A. Lohnes, J. Y. Ooi

Reliable prediction of wall pressures in a coal silo demands careful characterization of the stress-strain properties of the coal. This paper describes the results of triaxial compression tests on a typical fine-ground coal used in power generation and describes the fitting of several different constitutive models to the data. The fitted parameters for the constitutive models are well suited to application infinite element analyses. The different models are used to give the reader flexibility in choosing a model and to show the shortcomings of some models. To explore the quality of the fitting process, the fitted results are compared with finite element predictions of the triaxial test itself.

Jan 1, 1998

By J. L. Post, L. Borer

Small seams of fibrous tremolite and actinolite commonly occur in many California counties. A number of larger seams of this fibrous material were mined from 1882 until about 1955. The fibers from these mines were used for making acid filters, battery cases and fire-resistant paint. With increasing population, new residential areas are being developed in the foothill regions, leading to increased contact with seams of fibrous amphiboles. These forms of asbestos can be particularly dangerous to human health. Thus, it is necessary to determine the locations of these mines and adjacent veins and to identify the specific amphibole minerals present.

Jan 1, 2003

By D. A. Stanley, B. J. Scheiner, P. M. Brown

The Bureau of Mines (USBM), US Department of the Interior, has developed a method of dewatering clay slurries based on flocculation by high-molecular-weight polymers and water removal from the formed flocs using a trommel or hydrosieve. The exchange ion on the clays affects their dewaterability. Metal ions in solution and on the exchange sites of smectite clays are known to act as Lewis acids. Recent work has determined that these ions can be titrated with high-molecular-weight polymers. The relative acidity of the exchange ion and the basicity of the polymer determined by the new method give insight into the dewatering mechanism.

Jan 1, 1990

By A. Redfern, B. G. D. Smart

The ultimate objective of the development work presented in the paper is to devise an appropriate method for relating powered support specification to geological conditions and mining practice, thus enabling the longwall method of coalmining to be successfully implemented throughout the varied coalfields of the world. The paper begins with a review of various methods previously used to determine support rating, each method being analysed with regard to its source, the logic and theory which constitute the method, and subsequent recommendations. An alternative approach is then proposed, the Powered supports being considered to be one of three foundations, sharing load with coal ahead of the faceline which acts as another foundation, and the waste behind the supports which acts as the remaining foundation. The load/deflection characteristics of the coal and waste, which in turn are related to geological conditions and mining practice, are shown to affect the load transfer on to and hence the specification of the powered support. In particular the characteristic of the waste foundation is shown to be affected by the caving mechanism, an alternative form to that mechanism accepted for British conditions being proposed and designated "parting-plane-controlled" caving. A finite element solution for a beam on elastic foundations was used to translate the above concepts into numerical results, these results being compared with data from Indian and Chinese operating conditions. The Indian case study examines the effect of using a conventional chock type of support in a one-web back mode when mining towards a roof break generated ahead of the face, while the Chinese case study compares measured subsidence over a longwall with "blocky" roof conditions with the model results. The comparisons are encouraging, suggesting that the approach used is worthy of further development.

Jan 1, 1986

By R. J. Pruett, J. Yuan

Kaolin clays from five different commercial deposits in Georgia were studied to understand the variations of zeta potential and related fundamental properties. The results suggest that higher negative zeta potential is related to exchangeable or soluble calcium ions in the clays.

Jan 1, 1999

By Jerry Demchuk, Allan Flemming, Stephan Day

Luscar Ltd. is currently developing open pit mining plans for the Telkwa Coal Project. Most waste rock is predicted to be non-acid generating but a proportion (less than 20%) is potentially acid generating. The waste management plan includes in-pit and ex-pit disposal of blended and till-capped waste rock, segregation and in-pit encapsulation of strongly potentially acid generating materials, and in-pit underwater disposal of coarse and fine tailings. The paper will present the steps used to design the waste management plan including the development of geochemical design criteria using various tests and theoretical and practical knowledge of waste behaviour.

Jan 1, 2000