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By Nelson R. Shaffer

Glamorous, burgeoning biotechnology and mundane industrial minerals would at first glance seem to share little in common, but in truth, modern biotechnology depends on many minerals. Biotechnical processes also can be used in industrial mineral extraction and processing. Biotechnology is broadly defined as the application of biological organisms, systems, or processes to manufacturing and service industries. Genetic engineering has reinvigorated one of mankind's oldest sciences, biotechnology, into a booming business. Many modern processes depend on microorganisms cultivated under very stringent conditions in bioreactors. Minerals from carbonate, sulfate, chloride, nitrate, phosphate, and silicate families are used to provide essential nutrients and to regulate growth conditions (such as pH) in order to assure optimal growth of organisms. Certain cells or enzymes perform better when immobilized upon or within solids, and minerals are often used to immobilize cells, especially in continuous process. Minerals are also used extensively in separating and purifying products of biotechnology. Diatomite, zeolites, and silica are especially useful in purification processes. Industrial minerals also are commonly used to clean up large volumes of process water that must be treated. Biotechnology can be employed in exploration, extraction, and processing of geologic materials and in reducing mining or other environmental problems through bioremediation. Microbes have been shown to solubilize certain elements and so promote extraction of heavy metals, phosphate, aluminum, potassium, and even rare earth elements. In a related technique, unwanted materials such as pyrite impurities can be leached microbially to produce cleaner products in sand and clay industries. Microbial actions can modify surface characteristics and so enhance certain ceramic properties. Certain organisms can accumulate useful elements from dilute sources; others can transform unusable chemical species to more useful forms. Deterioration of stone, concrete, and even glass or brick, can be accelerated by microorganisms. Control of such biodeterioration could improve long-term performance of industrial mineral products. Microbial processes have shown promise in improving several mine-related problems. Certain bacteria help remove clays from phosphate slimes and other suspensions. Others are used to degrade cyanide or other organic chemicals such as floatation aids. Cells immobilized on clays have been especially efficacious in bioremediation. Biotechnology industries, like the industrial minerals industries, encompass huge ranges of materials and processes. Costs of products from these industries range from pennies to thousands of dollars per unit, and their products are vital for maintaining modern life styles. Many biotechnical processes depend upon industrial minerals and certain biological processes can be harnessed to do useful tasks in the minerals field. The interplay of industrial minerals and biotechnology is important today, and as biotechnology advances, its interaction with the industrial minerals industry can only increase.

Jan 1, 1995

By J. P. Vandenhoeck

Sizing devices used commercially are unfortunately not 100% efficient, the splits that can be obtained are usually inferior to the results obtained in the laboratory. Often the capital and operating costs of equipment capable of high sizing efficiency cannot be justified by the economics or requirements of the process. To reconcile the desired sizing efficiency needed to obtain optimum process requirements with the sizing efficiency of equipment economically practical, it is often necessary or desirable to predict the gradation and weight splits of the products obtained based on the expectant efficiency of the contemplated sizing device or method. The less efficient the sizing device one must employ, the more important it is to know the results that may be expected for the establishment of the optimum flow sheet and the more difficult it becomes to estimate the results accurately. Air classification equipment which sizes materials by opposing the drag force created by an air stream acting on a particle with a combination of gravitational, inertial or centrifugal forces are substantially less efficient than, for example, a laboratory sieve analysis. Air classifiers allow oversize material to contaminate the fine fraction and leave undersize material in the coarse fraction. The techniques employed to predict the gradation and weight splits obtained from air classification outlined below are adaptable to other sizing devices less than 100% efficient such as screens, sifters and wet classifiers.

Jan 1, 1965

By Geoffrey Purcell

The flotation response to amine collector of quartz and the feldspars microcline and albite, of the pyroxenes augite and spodumene, and of olivine can be, explained by a physical adsorption model. Flotation decreases in the order given above, and the different behavior of the three groups is attributed to structural variations of the silicates, With sulfonate collector both chemical action and physical adsorption play their part in producing hydrophobic surfaces, and flotation increases in the order given.

Jan 1, 1966

By Peter K. Weissenborn, Robert J. Pugh

The contrasting behaviour of electrolytes in inhibiting coalescence of bubbles was explained by the positive and negative distribution of anions and cations at the gadwater interface. Further, the efficiency of electrolytes which do inhibit coalescence of gas bubbles can be linked to a counter ion hydration mechanism and the effect of electrolyte concentration on gas solubility. A correlation was found between the transition concentration of electrolyte needed to prevent the coalescence of bubbles and the reduction in gas solubility. Hence, the inhibition of bubble coalescence in electrolyte solutions appears to be linked with the utilization of water molecules in the hydration of cations and a consequent reduction of water available for gas solubility.

Jan 1, 1995

By Michel L. Bilodeau

Mineral exploration is a sequential information gathering process. Primary exploration programs filter favorable areas through a series of geological, geochemical, and geophysical tests resulting in the discovery of mineral occurrences. The most favorable of these discoveries provides economic justification for a delineation drilling program. The purpose of delineation drilling is to provide information for estimating relevant physical characteristics of the mineral occurrence. These estimates are used to evaluate the exploration project and, eventually, the economics of mine development. Delineation drilling normally completes the exploration process. If the assessed economic characteristics of the delineated occurrence provide justification for mine development and production, an economic mineral deposit is the end result of the exploration process. Subsequently, a development drilling program is initiated to obtain the necessary data for detailed mine planning. The delineation drilling stage is in itself a sequential investment process. As delineation information accumulates, the reliability of geological estimates is improved and, thus, the uncertainty associated with the assessment of profitability criteria is reduced. Delineation drilling should continue as long as the marginal benefits, which result from improving the reliability of profitability criteria, exceed the marginal costs associated with the additional drilling.

Jan 1, 1979

By P. Chauvet

From a computational point of view calculating a variogram is a perfectly simple operation. For any particular study, we know which variable is to be studied. We also have a good idea of structural parameters which are likely to be important (the scale of the phenomenon, the probable direction of the anisotropy, etc.). Finally, we know the structure of the data file. So we can specify the parameters to be used to calculate the variogram (the distance classes, the angular classes, etc.). This allows us to decide which variogram program is most appropriate (1, 2 or 3 dimensional data, regularly or irregularly spaced, etc. ) . In general, the basic statistics (mean, variance, correlation? etc.) have been calculated beforehand, and so the distribution of the data is already known. Consequently, the choice of the parameter values fed into the variogram is by no means arbitrary. But it must nevertheless be made before the' variogram is calculated. If the resulting variogram is not satisfactory, the whole sequence of operations has to be repeated. Before going on to see how this can be avoided, it is worthwhile having a brief look at the common causes of "unsatisfactory" variograms.

Jan 1, 1982

By H. E. Rojas, G. T. Adel

The primary objective of most comminution operations is liberation; however, mill performance is generally quantified in terms of particle size. Only recently has the use of image analysis equipment made it possible to quantify mill performance on the basis of liberation. In this investigation, a series of tests were carried out to study the effect of mill operating parameters on the liberation of sphalerite from a sphalerite/dolomite ore. The parameters studied included mill rotational speed, mill loading and ball size. The results of this work appear to indicate that sphalerite liberation is improved under conditions that promote impact breakage, while dolomite breakage is enhanced under attrition conditions.

Jan 1, 1992

By H. M. Wells

The known high grade mineral re- sources in the United States are fast becoming exhausted; viable new deposits are more difficult to find and more expensive to develop; operating and capital costs have increased to meet more stringent regulatory standards. By contrast, international producers enjoy a cost advantage as a result of higher mining grades, improving technological competence, and more favorable government support. The domestic base minerals industry is finding it more and more difficult to compete in world markets. It has become essentially a marginal industry today. The current philosophy of taxation in the United States has evolved over the past century. The structure of the taxing system is based on the assumption that a firm must be able to pay its tax imposts out of profits. In principle, firms incapable of supporting the tax load should be replaced by others that can do so. This philosophy applies equally well to the mining industry, so long as it remains economically healthy. However, mineral resources are finite. The situation in the domestic base mineral industry has changed fundamentally in recent times. For the reasons given above, much of the industry now cannot continue to compete profitably in the open world market; and there are no known alternative domes- tic mineral resources more capable of doing so. Under these circumstances it is important to consider the effect of taxation not only on profitability, but also on survivability.

Jan 1, 1986

By R. J. Sweigard, R. V. Ramani

Productive and beneficial use of reclaimed surface-mined land is a concern of industry, government, and the general public. A process has been developed that will aid mine planners and public planners in the evaluation of postmining land use potential. This process involves the application of site planning principles to surface-mined land in a way that ensures productive end use of reclaimed land. The process consists of 10 basic components and is iterative in nature. Termination of the process depends on the amount of data collected and the evaluation requirements of each mining site. The analysis centers around the economic, environmental, and social impacts of the alternative land use plans.

Jan 1, 1987

By R. D. Hansen, R. R. Klimpel

Previous papers by these authors on slurry rheology control grinding aids have emphasized the end-use results and application methodology involved. This paper emphasizes the chemical principles and the influence of various chemical structures behind slurry rheology control chemicals. Particular examples are shown which correlate chemical structure modifications to environmental factors involved in grinding such as pH, shear, ore type, water chemistry, and particle size.

Jan 1, 1990

By James P. Bowersox

Modem mineral processing plants handle large amounts of ore and produce large tailing streams. Plant performance can be optimized when the water is quickly recovered with a thickener. The caisson thickener was developed to overcome process and mechanical problems with the conventional traction and center column units. The caisson is a hollow center column that serves as a pump house. The rake arm structure is supported by a hydrostatic bearing which sits on top of the caisson. The caisson thickener with a hydrostatic bearing has operated for many years in several mineral processing applications.

Jan 1, 1981

By Emil O. Frind, David W. Blowes, K. Ulrich Mayer

The multicomponent reactive transport model MIN3P can be used to simulate the evolution of pore water, pore gas, and the mineralogical composition in mine waste environments. The model is formulated for variably-saturated conditions, considers transport of dissolved and gaseous species, and describes geochemical reactions based on a partial equilibrium formulation. Reaction processes included are complexation, oxidation-reduction, ion-exchange, mineral dissolution-precipitation and gas exsolution- dissolution reactions. An example application, describing the generation of acid mine drainage and subsequent reactive transport for a ID-vertical profile in a tailings impoundment near Elliot Lake, Ontario, is provided.

Jan 1, 2000

By Davidtz. John C.

INTRODUCTION The effectiveness of collector type on sulfide mineral flotation is generally determined by the amount and type of functional groups of collector molecules that interact with surface and water at the mineral/collector/water/gas interface. The final interfacial state when bubble contact takes place is preceded by chemical and physical reactions that involve these gas/liquid/solid interactions. These interactions differ not only for different minerals, solution and gas composition, but also for different collector molecules. The purpose of this paper is primarily to summarize the developments and status of short (C2-C6) and long (C12) chain, aliphatic collectors that contain three sulfur atoms in their polar function. These are trithiocarbonates (TT'Cs). For purposes of comparison, similarities in molecules containing 0, N and S are compared. Mostly short chain ionic collectors molecules of dithiocarbonates (DTCs) and TT'Cs were compared. The studies, largely bench scale flotation and plant testing, were carried out on ores containing Cu, Ni, Au, and PGM's. Studies of long chain 'ITC collectors are reported on Ni, PGM and auriferous pyrite ores containing uranium. Under starvation dosage conditions, surface activity coefficients of short chain collector molecules and interacting water were calculated. Based on the UNIFAC group contribution method of activity coefficient calculations, the Gibbs Excess Free Energy

Jan 1, 2005

A linear programming model with integer sequencing variables is developed to schedule limestone production for a quarry in Central Japan. The model is used to optimize raw material production from the quarry supplying limestone to cement, quick lime and aggregate plants. Typically, the mining in the quarry takes place in four to six different areas each area having 3 or 4 mining increments. Each mining increment contains different quality of limestone. The limestone production from the quarry is transported to the plants byway of 3 ore passes. Each plant requires a given quantity of limestone per period meeting certain quality constraints. This paper will describe development of the scheduling optimization model and how it is used to schedule production by period within the quarry to meet the capacity and blending requirements of the plants.

Jan 1, 2003

By R. V. Ramani, K. V. K. Prasad

Forecasting mined grade variability from exploration information is a challenging task in mine planning. For effective planning of activities, such as workplace scheduling, ore grade quality control, etc., development of realistic numerical simulation models of in situ variability from exploration information is an essential first step. Geostatistical conditional simulation (GCS) is one of the well known methods to develop such simulations. Recently, stochastic fractal models based on the assumptions of scale-invariance and self-similarity have been used for developing simulations of several natural phenomena. It has been suggested that these models might permit the generation of short-scale variability information from exploration data with greater fidelity when the data satisfies the attendant assumptions. In this paper, stochastic fractal models are reviewed, and their relationship to geostatistical variogram models is examined. A comparison of the two simulation techniques has been performed using coal sulfur data from a mined-out coal property. The results of this comparative analysis are also presented in the paper.

Jan 1, 1993

By Joseph F. Shirley

Introduction Inorganic depressants are chemicals added to the froth flotation process to maintain or produce hydrophylic surfaces on one or more minerals so they will remain in the pulp rather than attach to the air bubbles. Whether a depressant will be effective in depressing a given mineral depends on how it is used and the environment in which it is used. Some depressants must be added and conditioned into the pulp before the collector is added. Other depressants can be added in the presence of previously added collectors and effectively depress the desired minerals. Often the concentration of depressant relative to the collector concentration is critical to making an economic separation. It should be noted that some depressants will only work when specific collectors have been used. Some reagents such as sulfuric acid and hydrogen peroxide essentially act as depressants by altering the previously added collectors so that they are no longer effective. Some depressants such as sodium ferrocyanide are only effective in a very limited pH range and an essentially collector free environment. Major Depressants CaO Milk of Lime is by far the most used depressant both in tonnage and dollar value. Although it is most commonly listed as a pH modifier, it is also an important depressant for pyrite in copper and copper molybdenite flotation plants. Although a simple pH adjustment will often depress pyrite, there are times when grinding with fresh milk of lime is required to obtain optimum depression. Lime is also a molybdenite and gold depressant. NaSH Sodium hydrosulfide is by far the most commonly used reagent to depress copper and iron sulfide minerals in by-product molybdenite flotation plants. NaSH also depresses gold, silver sulfides and silver chloride. ZnSO4 Zinc sulfate is commonly used to depress sphalerite in lead-zinc and copper-lead- zinc flotation plants. It has also been used to effectively depress talc in by-product molybdenite circuits at a pH of 6.5.

Jan 1, 1986

A thermomechanistic model was developed for the thermal decomposition of the enargite contained in a copper concentrate at 650° to 750°C in a fluidized bed with an inert atmosphere. At the particle level, the model permits one to predict the thermal profile inside the reacting enargite particles, as well as their thermal cycle. At the macroscopic level, a population-based model coupled to the bubbling-bed fluidized bed model allows one to predict the fractional conversion (dearsenification) of an enargite-bearing copper concentrate.

Jan 1, 2002

By J. Andrew Leach, Robert T. Tape, Thomas G. Harper

A practical approach to elope stability design of heap leaches up to 90 m (300 ft) high is presented based on recent experiences with heaps throughout the Western U.S. Shear strength parameters for foundations, ore and liner systems are considered, with particular attention given to frictional contacts between geomembranes and clay or geotextiles. Stability of both ore and containment dikes is discussed including the effects of seismicity, staged dike construction, progressive heap development and in-heap solution levels. Design criteria and methods of analyses are presented along with techniques for improving stability.

Jan 1, 1987

By P. R. Shivdasan, R. D. Hagni

Cathodoluminescence microscopy (CLM) is uniquely applicable to the study of carbonatite-related fluorspar ore deposits. The mineralogy of the carbonatites, sodic and potassic fenites, marbles, quartzites and fluorite ores are readily determined and characterized. Calcite, dolomite, apatite and fluorite were deposited dominantly under high-temperature conditions, and they exhibit strong cathodoluminescence (CL). At the Okorusu, Namibia, carbonatite complex and fluorspar mines, three types of carbonatites have been recognized by field mapping and laboratory CLM. The main carbonatite intrusion is fine grained and consists mainly of calcite. A later phase of pegmatitic carbonatite consists of calcite, magnetite, Fe-rich pyroxene, apatite and pyrochlore. Pyroxene carbonatites were recognized mainly through their study by CLM.

Jan 1, 2002

By Sundar S. Saluja

Efficient and re1iable methods of fragmentation through blasting have been sought ever since the introduction of black powder in mining operations, but the pace of investigation became faster with the discovery of nitroglycerine. The development of modern measuring instruments and the need to blast more rock with the least damage has made the study of blasting mechanics and its application more important, particularly since the oil embargo. Investigations into the practical approach evolved by Daws (1909) and the work done to make it more useful is discussed. The work of several investigators is touched upon with particular reference to the development of computer programs to simulate and optimize blasting operations.

Jan 1, 1986