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The kinetics of adsorption of gold di-cyanide onto activated carbon has been investigated extensively over the past two decades. These studies have demonstrated that both film and intra-particle mass transfer affect the kinetics. The dominant mechanism of intra-particle mass transfer has not yet been identified. In the work described, surface diffusion and pore diffusion are considered as possible rate-determining mechanisms of intra-particle mass transfer. Mathematical models are described that incorporate film mass transfer and the respective intra-particle mass transfer mechanism with equilibrium described by a Freundlich isotherm. Rate constants of film mass transfer and pore or surface diffusivities were estimated by the fitting of the respective models to experimental carbon adsorption data. The estimated pore diffusivities, after they had been corrected for the porosity and tortuosity of the carbon, were found in most instances to be higher than the molecular diffusivity of dilute gold di-cyanide in aqueous solution. This situation is not physically viable. The surface diffusion mechanism acting in parallel with the pore-diffusion mechanism is thus responsible for the intra-particle transportation of most of the gold.

Jan 1, 1996

By NONEn NA

1. Book reviews . Rudiments of mining practice, oy C.E. Gregory.Clausthal-Zellerfeld (West Germany), Trans Tech Publications.OS$24.Reviewer: A.N. BrownProfessor Gregory has had a wide experience of hardrockmetalliferous mining throughout the world, beinga well-known academic who has taught at many universitiesin the Western World. His basic training was obtainedin his native land of Australia. In this publication he identified the need for a basic, simple book on miningpractice to provide new students of mining with a backgroundto their studies. He also designed the book to providea background to persons operating on the fringesof the industry such as students of economics and journalists.The text extends to only some 120 pages, and containsa sufficient number of monochrome sketches, diagrams,and photographs. It is written in a straight-forward, easyto-read style. The book contains an index and elementarytable of conversion from imperial to SI (metric) units,and there is also a glossary of mining terms that mostreaders would find useful.The author has succeeded in keeping the contentssimple, as indicated by the title. However, after each chapter, there are references to further recommendedreading. The book could be useful in the South African context, although the coverage of coal and opencast mining operations is slender.

Jan 1, 1987

By C. L. E. Swartz, I. J. Barker, J. H. Schubert

A dynamic simulator of the leaching and adsorption cascades of a gold plant was developed and used to compare the effect of various disturbances on the overall efficiency of the plant. These comparisons show which disturbances most critically need to be controlled to optimize plant performance. The simulator was based on an existing gold plant. Dynamic and steady-state data were collected on the plant and were used in the modeling of the process. Simple dual-rate models are used to describe the leaching and adsorption processes. Mole-balances of various species take into account the changes of concentrations in the leach, and also the movement of pulp and carbon up and down the adsorption cascade. Fluctuations in the flow rate, density, and cyanide concentration of the feed to the leach have a negative effect on the efficiency of the leach, while carbon attrition was found to be an important factor in decreasing the efficiency of the carbon-in-pulp (GIP) section. Badly regulated transfers contribute towards the decreased efficiency of the GIP section, but overflows and carbon leakage have only a limited long-term effect. Various carbon profiles and transfer schemes were studied, and the results indicated that a slightly heavier loading at the bottom of the cascade is beneficial, while the type of transfer is relatively unimportant.

Jan 1, 1993

In August 1978, the National Productivity Institute invited entries for productivity awards, which it intended making as a recognition of firms and individuals who were contributing to the prosperity of South Africa by effecting outstanding improvements in productivity.

Jan 1, 1979

By D. Visser, P. D. Toens

The development of a continuous recording scintillation counter mounted on a cyclometer by P. D. Toens (Fellow) and D. Visser (Visitor) In order to facilitate ground radiometric surveys the Atomic Energy Board has developed a continuous recording device attached to a scintillation counter which is mounted on a cyclometer. Details concerning the construction are given.

The 92nd Annual General Meeting of The South African Institute of Mining and Metallurgy was held on Wednesday, 16th August, 1989, at Kelvin House. Mr C.E. Fivaz (President) was in the Chair, and declared the meeting open at 16:05. Obituaries The President announced the deaths of the following members of the Institute:

Jan 1, 1989

By H. P. Coetzee, V. J. Solomon

As the price of gold increased, so did the viability of mining previously abandoned unpay areas of Stilfontein Mine. After an assessment to confirm the profitability of mining these areas, it was necessary to re-establish access-ways such as haulages, cross-cuts, and travelling ways. Openingup is a labour-intensive, relatively slow operation, and attempts were made to mechanizeand speed it up. Some of the techniques applied and the results achieved, whether successful or not, are discussed.

Jan 1, 1982

The possibility that type 430 stainless steel can become sensitized during annealing after hot-rolling was studied by simulated cycles of continuous-annealing heat treatments, and by calculation of the carbon solubility. It was found that the lower-carbon steel could be sensitized at lower annealing temperatures than the higher-carbon steel, which is in line with plant experience. The difference in sensitization behaviour is ascribed to the lower rate of recovery of the lower-carbon steel during cooling, since recovery is sensitive to the grain size. At practical heat-treatment temperatures, austenite formation does not play a role.

Jan 1, 1996

By F. L. D. Cloete

The Relix process is based on direct contact between an ion-exchange resin and undiluted pulp, thus avoiding prior solid-liquid separation. The resin particles float near the surface of the pulp, forming an inverted fluidized bed with the pulp flowing downwards. The basic idea was demonstrated on a full-scale pachuca tank at Stilfontein Gold Mine in 1970, followed by a small-scale demonstration run in a laboratory at the National Institute for Metallurgy. A pilot plant based on a throughput of 60 tons of ore per day was subsequently operated at West Driefontein Gold Mine for several periods over two years. Although the plant proved operable from a mechanical point of view, the metallurgical performance was not up to expectation. The basic cause of the poor metallurgical performace was shown to be backmixing of both the resin and the pulp between stages. The values obtained for resin losses were inconclusive. Further development of resin-in-pulp processes for the recovery of uranium should be focused on the performance of various techniques for the screening of resin from pulp.

Jan 1, 1981

The refractoriness of the gold in many of the pyritic ores from the eastern Transvaal is due mainly to the association between the gold and the sulphides, but it can be due to the presence of graphltlc carbonaceous material, which complicates the recovery of the gold by virtue of its adsorption activity. In an examination of the roasting characteristics of three flotation concentrates from the Barberton area, It was found that the gold in the concentrates occurred mostly in two forms: in very fine gold particles distributed within the arsenopyrite, and in a slightly coarser form loosely associated with the pyrite. Direct cyanidation of the concentrates gave gold extractions of from 16 to 30 per cent. After the concentrates had been roasted at temperatures of 650 to 700°C for 20 minutes with rabbling, the extractions varied from 86 to over 90 per cent. Examination of the residues after cyanidation indicated that gold was present in the porous calcines or in the calcined sulphide product. This observation, together with porosity measurements, suggests that physical encapsulation of the gold particles is the main reason for the refractory behaviour of the gold in the calcines.

Jan 1, 1988

By M. G. Adamson, B. D. H. Phillips

This paper describes a procedure that has been found successful in the planning and execution of practical trials of mechanized-mining equipment. The procedure is illustrated by reference to development trials of a rockslotting machine with pneumatic or hydraulic drills that were conducted on South African gold mines.

Jan 1, 1978

By G. T. C. Emere, E. C. Hunter

The use of cylindro-conical settlers for the clarification of underground water by E. C. HUNTER- (Associate) G. T. C. EMERE-, B.A. (Hons.) (Keele) (Visitor) This paper analyses the performance of conical settlers on Harmony Gold Mine from 1959 to the present time, and describes the investigation that was undertaken to substantiate and improve the use of conical settlers for a new pump chamber in another part of the mine.

Jan 5, 1977

By P. J. Kinver

The paper presents details of the costs and outputs being achieved by South African mechanized tunneling and stoping drillings. The information was gathered from various hard-rock mining and tunneling operations ranging from deep-level gold mines to shallow base-metal mines. The survey included older pneumatic rigs and the newer electro-hydraulic rigs, but excluded shaft drilling and the stope drillings that were developed recently for narrow reefs. The information presented is intended as a guide to those having to decide whether to use mechanized drillings and, if so, what type and quantity

Jan 1, 1990

By H. M. Friede, R. H. Steel

Tin mining and smelting in the Transvaal during the Iron Age by H. M. FRIEDE*. Ph.D. and R. H. STEEL* (Visitors) This paper reviews the historical, archaeological, and metallurgical evidence on Iron Age tin mining and tin smelting in Southern Africa. The results of the analysis of twenty samples of tin ore, tin slag, and tin ingots found associated with Iron Age materials in the Transvaal (mostly in the Rooiberg area) are reported and discussed. The types of ingots preserved in local collections are described. A small experimental tin-smelting furnace was constructed and worked according to traditional African Iron Age technology. Qualitative and quantitative results of this experiment are reported.

Jan 7, 1976

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar, J. M. A. Geldenhuis

The successful application of solid electrolytes in electrochemical cells for high-temperature thermodynamic studies depends to a large extent on an accurate knowledge of the P. value of the electrolyte (the oxygen partial pressure at which the ionic conductivity and n-type electronic conductivity of the electrolyte are equal). Consequently, the P. value of an electrolyte must be determined prior to its use in electrochemical cells. This paper describes the successful application of a coulometric titration technique in the quantitative assessment of the P. values of a commercially available ytria-stabilized zirconia electrolyte that has been used extensively by local investigators. The experimentally determined P. values of the electrolyte are reported and compared with P. values reported in the literature for a similar electrolyte.

Jan 1, 1988

By M. Splaine, W. Davidson, D. C. Atkinson

Since 1964, Nchanga Consolidated Copper Mines, Ltd., has been developing and using production scheduling methods for optimizing its metallurgical operations in the short term (up to one year). Medium-range metallurgical planning has been possible only by successive evaluations of a single-year LP. A modified version of Rosenbrock's direct search technique has now been developed to allow multi-year optimization of both mining and metallurgy for medium-range planning. The modifications to the search technique have produced a marked increase in computational efficiency for this heavily constrained problem in many variables and the system is a usable planning tool, given a reasonably powerful computer. The plans are 'optimum' in the sense that they yield the maximum present value of the operations. Each of the resulting five-yearly mine plans forms the basis for further detailed metallurgical evaluation by the established production scheduling system.

By R. M. Lamya

A semi-empirical kinetic model was developed for the atmospheric leaching of a Ni-Cu matte in copper sulphate-sulphuric acid solution. Kinetics of the leaching process was studied as a function of initial copper ion concentration, initial acid concentration, temperature, stirring rate and particle size distribution. The kinetic model was developed on the basis of the leaching mechanism and chemical reactions of the leaching system investigated, and was evaluated by comparing the model predictions to experimental data. The model was found to satisfactorily fit the trends in the leaching of the metals, namely copper, nickel, cobalt and iron.

Jan 1, 2009

By P. J. D. Lloyd, Jill Urban, M. R. Urban

The adsorption of gold from cyanide solutions onto constituents of the reef, and its role in reducing the efficiency of the gold-recovery process by M. R. URBAN. M.Sc. (Chem. Eng.) Rand (Visitor). JILL URBAN. B.Sc. (Chem. Eng.) Rand (Visitor) and P. J. D. LLOYD. Ph.D. (Cape Town) (Fellow) Evidence for the adsorption or re-precipitation of gold from cyanide solutions onto gangue minerals of the Witwatersrand reefs has been gathered over a number of years by various investigators. The evidence from tests using radioactive tracers is conclusive and indicates thlt adsorption contributes about 0,1 g/t to the total gold loss from conventional reduction works. The loss is a function of the alkalinity and cyanide concentration of the solution, and it appears to be affected by the extent of time between milling and cyanidation. The heavy minerals appear to be the strongest adsorbers, and the clay minerals somewhat less strong adsorbers. A sensitive qualitative test based on thin-layer chromatography permits the extent of adsorption and desorption to be readily determined.

Mr K.C. Owen started his mining career as a learner official after matriculating at the Parktown Boys' High School, Johannesburg in 1967.

Jan 1, 1991

A very successful banquet was held in the Ballroom of the Carlton Hotel on 7th March, 1986. The Institute thanks the Organizing Committee and the sponsors (listed on this page), without whose generous support the banquet would not have been possible.

Jan 1, 1986