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By R. Hogg

"Particles play an important role in our environment and in many aspects of human activity. Much of the Earth's surface - sand, soil, rocks - consists of particles, as do clouds in the atmosphere, smoke from fires, and dust in our homes. Many of the foods we eat - cereals, flour, instant coffee - and everyday items such as pharmaceuticals, cosmetics, detergents and other cleaning products are encountered in the form of particles. Inks and paints consist of very fine particles dispersed in liquids. Modem agriculture uses huge quantities of fertilizers and pesticides, largely in particulate form. The list could be extended almost indefinitely; particle systems are obviously an important part of our daily lives. But what do we know about them? For most people, the answer is probably: not much.We are all familiar with the three common states of matter: gas, liquid and solid. In many respects, particle systems should be regarded as a distinct class of their own. The particles themselves may be solid but we all know that a heap of sand is quite different from a solid rock. A cloud of liquid droplets - fog - has much more in common with a cloud of solid particles - smoke - than it does with a bucket of water. There are certain characteristics and properties which are unique to the particulate state. The behavior of any particle system is determined not only by the material from which the particles are made, but also by interactions among the particles and with their environment. These interactions become increasingly important as the size of the particles decreases, and for exceedingly fine particles, smaller than about one micrometer (0.000001 meters or 0.00004 inches), these interactions dominate and we enter the realm of colloidal systems.Particle SystemsA system in which discrete entities - particles -are dispersed in a continuous medium can be regarded as a particulate system. The particles and the medium can consist of a solid, liquid or gas. The various combinations and some common examples are listed in Table 1. The properties and behavior of these systems depend on the characteristics of the particles, the nature of the medium, and the relative abundance of the two phases. In general, it is the latter which determines the kind of behavior exhibited by the system.As a general rule, the behavior of particle systems follows that of the dispersed phase (the particles) at high concentration, and that of the continuous phase (the medium) at low concentration. For example, both powders and smokes consist of solid particles in a gaseous medium. However, in a powder the solids typically occupy over one half of the total volume; in many respects powders behave like solids. In a smoke, on the other hand, the particles may take up only a few parts per million of volume, so that these systems generally behave like gases."

Jan 1, 1989

By Marilyn Biviano

This analysis was conducted in response to concerns raised by the Chairman of the Energy and Commerce Committee of the House of Representatives regarding the potential impacts on automobile production, GNP and employment resulting from embargoing south African supplies of the platinum-group metals, platinum and rhodium. This analysis should be considered an addendum to the recently released study in which the direct economic costs I of a U.S. embargo on selected South African strategic and critical materials are estimated. The estimated GNP and employment impacts result when a mineral shortage reduces domestic industrial production and are in addition to the direct costs estimated in the earlier study. The direct cost to this nation resulting from a decision to embargo six south African strategic and critical minerals was estimated at $1.85 billion per year during the 1988-1992 time frame of the study. The estimated direct costs include the costs to U.S. consumers resulting from higher strategic mineral prices, lower mineral consumption, and the cost of developing higher cost domestic mineral resources. A large proportion of the costs result from the shortage of the two metals: platinum and rhodium. The average direct annual cost of embargoing is estimated at about $1.4 billion for platinum and $384 million for rhodium.2

Jan 1, 1988

By R. R. Trengove

This paper is one of a series published by the Bureau of Mines on mining methods and operation practices. It describes the open-pit mining method and operations of the Kaiser Steel Corp. Eagle Mountain iron-ore mine, which is in the extreme southeastern part of California 175 miles east of Los Angeles in Riverside County. Nearest town to the mine is Indio, which is 60 miles away by an excellent highway (fig. 1). Elevations at the deposit vary from 1,400 to 3,000 feet. Figure 2 is a plan map of the Eagle Mountain iron mine. Kaiser Steel Corp. built a model camp at the mine, with all modern conveniences (fig. 3). The camp, comprising 145 homes, dormitories, mess hall, commissary, post office, and recreational facilities for 600 people, is at 1,390-foot elevation. The area has winter-resort weather between October and May, with occasional drops of temperature to 25° at night. From June to September temperatures sometimes rise to 1200 during the day. Rainfall is scant, approximately 2 inches a year, the majority of which comes as cloudbursts during the summer months.

Jan 1, 1956

By D. S. Kingery

The data obtained from this study cover test areas that are gassy to ultragassy and pillared areas of different sizes and degrees of tightness. The methods of controlling ventilation, applying bleeders, and supporting bleeder entries varied in the different test areas. It was not possible to study all conditions likely to be encountered in coal mines. Undoubtedly, there are areas where bleeder entries, even though properly planned and maintained, might prove unsatisfactory. However, on the basis of this study, the following observations were made: 1. Tests showed that each bleeder system studied provided some movement of air through the pillared area; the quantities of air delivered to the pillar line, ranged from 23 to 82 percent, depending mainly on the extent to which bleeder re-turns were used as main returns from the section. 2. Pressure measurements taken across pillared areas showed maximum pressure drops ranging from 0.05 inch of water for a shallow gob to 2.69 inches for a very deep gob. The pressure differentials varied with the size and tightness of the gob but proved adequate to induce airflow across worked-out areas or through fringes of the gob to the bleeder return system.

Jan 1, 1957

By Harold C. Pierce

"INTRODUCTION During the years 1941 to 1945, the United States produced less than one-half of one percent of all primary nickel, whereas the nation's consumption of the metal amounted to nearly three-fourths of the world's supply. Although postwar nickel consumption probably will be less than wartime consumption, trade- estimates for the next 10 years are well above the average established during the 1930-1940 decade. The greatest consumption is expected in nickel alloys, particularly nickel-alloy steels. 3/ The greater use of nickel cast irons and nickel-clad metals also signifies an expanding nickel market. In anticipation of the postwar demand for nickel, and realizing the seriousness of the ""have not"" position of the United States with respect to this metal, the Bureau of Mines, sent an engineer 4/ into the lower Copper River region of Alaska during the summer of 1944 to investigate the nickel deposits near the head of Canyon Creek. Samples from the Spirit Mountain nickel prospect were sufficiently encouraging to justify more intensive exploration. As a result, a program of surface trenching, systematic sampling, and detailed mapping of the property was adopted and directed by a Bureau of Mines engineer 5/ in the summer of 1945."

Aug 1, 1946

By S. P. Howell, M. W. Von Bernewitz

"Introduction. The first short—flame explosives were made in the United States during the year 1902, then the mount was 11,300 pounds. In 1902 they were designated ""permissible explosives"", and were required to meet specific tests. By 1912 the total consumption thereof had increased to 24,630,000 pounds, equal to 5 per cent of the total quantity of all kinds of explosives produced in this country; while in 1922 the total was 43,429,000 Pounds, or 10 per cent of the production, and 18 per cent of the explosives used for the mining of coal.Each year the Bureau compiles statistics of explosives, one important object of this being to show the extent to which permissible explosives are replacing other classes of explosives in coal—mining operations, and the influence of such replacement in reducing the number of accidents caused by explosives in this class of mines. The consumption of permissible since 1916 has considerably exceeded the quantity of high explosives (dynamites, etc.) used in coal mines. While the increase in use of permissible is good, the replacement of other explosives therewith is not nearly as good as with be, considering the known general efficacy and safety of permissibles."

Mar 1, 1924

By S. J. Pearce

The Bureau of Mines has prepared, as circumstances have dictated, a series of Schedules setting forth the minimum requirements that various types of equipment should meet to be considered safe and satisfactory for use in certain hazardous or unhealthful conditions. These Schedules cover a wide variety of devices ranging from explosives to electrically operated mine locomotives. This paper deals with those Bureau of Mines Schedules under which respiratory protective devices are tested and approved, and its purpose is to explain the function and operation of these Schedules. Provisions have been made for testing and approval of the following types of respiratory protective devices: Self-contained breathing apparatus,2/ supplied-air respirators,3/ gas masks,4/ dispersoid respirators,5/ and chemical cartridge respirators.6 These devices are tested at the Central Experiment Station of the Bureau of Mines in Pittsburgh, Pa. Self-contained breathing apparatus is tested by the Safety Branch, and the other types of respirators are tested by the Health Branch.

Jan 1, 1951

By N. W. Lord

This volume contains the descriptions of the samples whose analy- ses are published in the preceding volume, Part I of this bulletin. The descriptions have been compiled from the notebooks of the per- sons who collected the samples, have been condensed from accounts given in published reports of the United States Geological Survey, or have been furnished by the collectors themselves. Inasmuch as the descriptions represent the work of many persons during a period of six years, and inasmuch as they were recorded under widely differing conditions, they necessarily vary in fullness of detail. The descriptions are published for two purposes: (1) To prosent such information regarding the character of the coal, the impurities in the beds sampled, and the nature of the roof and the floor of the beds as has a definite bearing on the significance of the analyses of the samples, and (2) to give any supplementary details such as the capacity or the output of a mine, the method of mining and prepar- ing the coal, and the chief uses to which it is put, that may be of assistance to Government engineers or purchasing agents, and to other persons, in preparing specifications and awarding contracts for fuel.

Jan 1, 1913

By Michael A. Trevits

Mine fires can be especially perilous because toxic products can quickly spread well beyond the fire zone thereby exposing all underground miners to dangerous and deadly conditions. Since November 1998, there have been six major underground coal mine fires or explosions in the United States (Willow Creek (twice), Sanborn Creek, Loveridge No. 22, West Elk and the Jim Walter Resources No. 5 Mine). In each case, the entire mine or specific areas of the mine had to be sealed due to the build-up of dangerous gases and the fear of uncontrolled spread of the fire. Effective placement of mine seals can deprive a mine fire of oxygen and is often followed by water flooding or injection of inert gas into the affected area. When access to the fire zone is impossible because of safety reasons, airtight mine seals can be constructed, in the area of the fire, remotely from the surface through vertical boreholes. Remotely constructed mine seals are commonly made from cementitious material. Since these mine seals are typically erected blindly, it is difficult to determine if mine roof-to-floor and rib-to-rib closure has been obtained. This paper provides a review of the available materials and technology used to remotely construct mine seals through vertical boreholes.

Jan 1, 2002

By H. B. Salisbury

The Bureau of Mines conducted research to determine if low-grade California chromite ores could be beneficiated to produce products suitable for commercial use. This research is part of a Bureau goal to provide technology capable of using low-grade domestic ores to meet emergency demands of the Nation for metals and minerals and in particular those minerals, such as chromite, which are considered critical. Two ores from California were ground and treated using gravity concentration and magnetic separation techniques. An are from Auburn in central California, assaying 2.5 pct Cr203, was treated by tabling and magnetic separation to yield a nonmagnetic product containing 44.7 pct Cr203 at a recovery of 36.4 pct. Core drilling samples from the Seiad Creek area of northern California, assaying about 6 pct Cr203, were upgraded by tabling to yield a concentrate containing nearly 50 pct Cr203 with a recovery of 50 pct. Both products are suitable for metallurgical and/or chemical use.

Jan 1, 1981

By Charles L. Kimbell

Available statistics on 1989 worldwide consumption of selected nonfuel minerals shown in table 5 show increases for 11 of 14 listed nonfuel mineral commodities with 1 unchanged from the 1988 level, a departure from the pattern of the past 2 years, in which each of the listed commodities registered gains. The 1989 results, however, were better than those for 1986 when only seven listed nonfuel mineral commodities recorded gains with one un- changed from 1985. Consumption of the two ferrous metal raw materials listed advanced as functions of increased output of pig iron and crude steel. The increase in iron ore consumption exceeded the increase in iron ore output, suggesting a slight drawdown of world iron ore inventories. The estimated in- crease in iron and steel scrap consumption was slightly greater than the minuscule increase in world steel production, but it is believed that there was little change in the ratio of iron ore to scrap in steel plant feed on a global basis.

Jan 1, 1992

Develop a training program to help mine workers effectively fight small fires in underground Goal mines. Training would enable miners to make rapid judgments on whether to attempt extinguishment, and how best to use the firefighting equipment on hand. Approach Fire reports were analyzed to define and delineate physical and behavioral variables which affect firefighting activities, and to determine effective procedures for extinguishing small fires. A course was then designed to train miners in such procedures. Finally, the course was reviewed by industry experts and administered to a group of miners to determine needed revisions and to validate the course. How It Works Analysis of fire data showed that six items should be emphasized in teaching proper fire response: 1. Alertness to fire potential. 2. Immediate power cutoff. 3. Internal, external communication. 4. Teamwork in fighting fires. 5. Role of ventilation and position of men inby the fresh air side. 6. Effective use of fire suppressant materials.

Jan 1, 1983

By Nancy S. Raymon

The Bureau of Mines investigated the effect of controlled additions of selected metal oxides, as well as the adjustment of the calcia-to-silica ratio on the high-temperature strength of refractory-grade periclase. Increases in the hot flexural strength of some periclase materials in the range of threefold to fourfold were obtained with additions of Zr02 and by adjustment of the CaO:Si02 ratio to the 2.5 to 3.0 level. Results show that for each periclase refractory raw material, there exists a combination of level of Zr02 addition and an adjustment to the CaO:Si02 ratio that optimizes the hot flexural strength of each of these materials. Data also indicate that the improved hot strengths can be attributed to the high-temperature secondary phases formed between the different levels of periclase impurities and the additives, resulting in improved intergranular high-temperature bond strength.

Jan 1, 1982

By H. E. Powell

The mineral dressing research here reported is part of a continuing program by the Bureau of Mines to develop new or improved concentration processes for oxidized or partly oxidized lead and zinc ores. A sample of low-grade sulfide-oxide, lead-zinc ore from Jasper County, Mo., containing galena, cerussite, pyromorphite, hemimorphite, smithsonite, and sphalerite was concentrated by froth flotation and tabling to a grade of 66 percent lead. Because of the presence of a high content of slime-size values, the overall recovery of lead was limited to 64 percent at this grade. Tests to recover the zinc by froth flotation and by gravity concentration did not give satisfactory results. INTRODUCTION Since its establishment, the Rolla Metallurgy Research Center has con-ducted studies of base metals as a part of its overall program (1, 2, 3, 4, 5,6,7).3/ This research has been, and is, directed to beneficiating complex and submarginal ores, to retreating rejects from commercial installations, and to developing fundamental data.

Jan 1, 1960

By Oliver C. Ralston

OUTSTANDING TRENDS of the year included the following: 1. Concentration and beneficiation of iron ores to provide improved blast-furnace feed and extend ore reserves. 2. Successful development of pelletizing and sintering procedures for fine iron ores. 3. The realization that cyclone separation could replace existing classifiers in many grinding circuits. 4. The rapidly blossoming metallurgy of ultrapure silicon and improvements in zone melting. 5. The rapid increase in the use of liquid-liquid extraction and ion exchange in hydrometallurgy. 6. The industrial application of vacuum melting on the 100-ton scale. 7. The hope for developing a columbium (noibium) base alloy for high-temperature use. The technologic advancement in metallurgy that had the greatest effect on the American economy was the beneficiation of iron ores to give improved feed for blast furnaces and indirectly extend our ore reserves. This was not a sudden development but rather culmination of a decade of intensive effort.

Jan 1, 1958

The National Institute for Occupational Safety and Health (NIOSH) National Personal Protec-tive Technology Laboratory (NPPTL) and the Mine Safety and Health Administration (MSHA) conduct a Long Term Field Evaluation (LTFE) program to evaluate deployed self-contained self-rescuers (SCSRs). The objective of the program is to evaluate how well SCSRs endure the under-ground coal mining environment with regard to both physical damage and aging when they are deployed in accordance with Federal regulations (30 CFR 75.1714). This report presents ?ndings of the combined eighth and ninth phases of the LTFE. For these phases, over four hundred SCSRs were evaluated. The units tested include the CSE SR-100, Draeger Oxy K-Plus, MSA Life-saver 60, and the OCENCO EBA 6.5. The OCENCO M-20 was evaluated only in Phase 9. Testing was per-formed between December 2000 and April 2004. Results of the evaluation indicate that all SCSRs experience some performance degradation due to the mining environment. Observed degrada-tion varies from elevated levels of carbon dioxide, high breathing resistance, and reduced capacity. Mechanical degradation to the SCSR components included breathing hoses, chemical beds, outer cases and seals. The LTFE tests discussed in this report are different from tests performed for SCSR certi?cation to the requirements of 42 Code of Federal Regulations, Part 84 (42 CFR, Part 84). LTFE tests reported here are conducted to an end point, oxygen depletion, to enable comparison of the duration of new and deployed SCSRs. The method for obtaining deployed SCSRs for this evalua-tion was not a random selection from the deployed population of SCSRs. Although the results of these tests are useful for observing performance of the tested SCSRs, they are not representative of all deployed SCSRs. A new evaluation protocol, with revised sampling strategies, test methods, and reporting procedures, is currently being designed to enhance the generalizability of the results. This program will be implemented following completion of Phase 10 of the current LTFE protocol.

Jan 10, 2006

By M. J. Ferrante

New data on zirconium tetraiodide (ZrI4) have resulted from high-temperature enthalpy and X-ray powder diffraction studies conducted by the Bureau of Mines. These studies were undertaken as part of the Bureau's efforts to provide important thermodynamic data essential to the advancement of mineral resources technologies that can be employed with minimal energy requirements and minimal environmental degradation. Enthalpies were measured with a copper-block drop calorimeter. No transitions or other anomalies were found. Tabulated values are given from 298.15 to 772 K for relative enthalpy, heat capacity, entropy, and Gibbs energy function. Enthalpies are expressed in equation form and combined with data from the literature to calculate values of the standard enthalpy of formation and the Gibbs energy of formation. X-ray powder diffraction data indicate that ZrI4 is primitive cubic with a lattice parameter of 11.79 A and is isostructural with stannic iodide (SnI4).

Jan 1, 1980

By F. W. Smith

This paper is based largely on a study of experimental data obtained by the Bureau of Mines in its comprehensive 25-year survey of the carbonizing properties of American coals. Although the Bureau was interested in and conducted carbonization research-from time to time ever since it was organized in 1910 (1),4/ no systematic studies of the coke-, gas-, and byproduct-making properties of American coals were undertaken until 1927, when the American Gas Association appointed an advisory committee (2) to cooperate with the Bureau in developing equipment and techniques to obtain-data for the accurate assessment of the behavior of coals on carbonization. It was found, in general, that small-scale laboratory tests were unsuitable for the complete evaluation of the coking properties of coal; hence, larger pilot-plant-scale equipment was designed and used (3). It was decided that the scale of the test should be large enough to determine both the yield and quality of the products and yet small enough to maintain adequate control of the process variables (4). These considerations led to development of a carbonizing retort and furnace-of 80 to 200 pounds of coal capacity, suitable for operation at various temperatures up to 1,100° C. (2,0120 F.) and equipment for recovery and measurement of gas and byproducts. This apparatus and the standardized procedure for its operation became known as the Bureau of Mines-American Gas Association (EM-AGA) method or retort (5).

Jan 1, 1955

By C. E. Schmidt

Condensate waters from the Bureau of Mines Synthane process for coal gasification have been investigated by mass spectrometric methods to determine the organic contaminants. Waters from the gasification of six coals were extracted with methylene chloride, yielding 0.6 to 2.4 weight-percent extractable material. Using high-resolution mass spectrometry (HRMS), combined gas chromatography-mass spectrometry (GC-MS), and low-voltage mass spectrometry, 60 to 80 percent of the extract was found to be phenolic. About 20 organic contaminants have been identified and are present in the condensate waters from each coal gasified. The relative distribution of contaminants in the condensate water was nearly the same for the six coals gasified under various conditions; phenolic compounds were the most abundant in all cases.

Jan 1, 1974

By D. S. Colby, E. M. SEELEY

The total production capacity of the natural-gasoline industry increased to 27,212,000 gallons (647,905 barrels) daily on January 1, 1950, from 21,322,000 gallons (507,670 barrels) daily on January 1, 1948. The rate of growth during these 2 years averaged 13 percent per year, compared with 9 percent per year from 1946 to 1948 and 6 percent from 1944 to 1946. The total number of operable plants on January 1, 1950, was 554, 5 more than at the beginning of 1948. The number of absorption plants increased by 12, the number of cycling plants by 7, and the number of combination plants by 4. The number of compression plants and charcoal plants continued to decrease. Absorption plants accounted for 67 percent of the total capacity on January 1, 1950, compared with 62 percent 2 years previous. Eighty-two per- cent of the expansion in these 2 years was in absorption-plant capacity. Cycle plants accounted for 24 percent of the total industry capacity at the beginning of 1950, compared with 27 percent on January 1, 1948. The average daily capacity of absorption plants increased from 38,400 gallons at the beginning of 1948 to 50,600 gallons at the beginning of 1950. During the same period, the average daily capacity of cycle plants decreased from 150,200 gallons to 144,100 gallons. Texas showed the largest gain in number of plants 13 absorption, 4 compression, and 4 cycling plants. The State accounted for 67 percent of the gain in capacity and on January 1, 1950 had 50 percent total national capacity. Louisiana followed with 7 additional plants. Pennsylvania reported 14 and West Virginia reported 13 fewer plants than in 1948. Most of these reductions were in the number of compression plants.

Jul 1, 1950