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By Michael G. Zabetakis, Aldo L. Furno, George H. Martindill

Hydrazine vapor is flammable in the absence of air at elevated temperatures and atmospheric pressure . The minimum concentrations of benzene , toluene , m- xylene , cumene , and n- heptane needed to inhibit flame propagation through vapor mixtures of hydrazine and hydrocarbon were determined at 125 ° C and atmospheric pressure . These concentrations can be correlated with either the heat of formation or the heat capacity of the hydrocarbon .

Jan 1, 1964

By Michael D. Fenton

Detailed comprehensive assessment of the performance of Afghanistan's mineral industry during 1987 is virtually impossible, owing to the paucity of reliable published information. It was evident, however, that the level of civil disorder, now in its eighth year since the arrival of significant numbers of Soviet troops, was in actuality little removed from open civil war. Insurgents controlled substantial areas of the country and imperiled any industrial activity in many places. Assistance programs by the U.S.S.R. and other Eastern European nations were directed at developing the country's meager mineral industry, but the economy was generally viewed as chaotic. The inflation rate was somewhere between 20% and 30%; major food shortages contributed to the discontent of the population, and numerous villages were devastated by Soviet and Afghan Government campaigns to destroy the insurgents and cut their supply routes. Moreover, proposals by the Soviets and the Kabul Government aimed at reducing tensions with the rebels and scaling down the warfare seemingly were taken by the opposition as signs of weakening by the Soviet-backed Government, and rather than reducing aggressions, seemed to heighten insurrectionist activities. Efforts to entice the substantial number of Afghans who have fled to nearby areas of Pakistan and Iran to return to their country seemingly were failures, and indications near yearend that the Soviet Union might soon begin withdrawal of its occupation force of nearly 120,000 did little if any to reduce disorder.

Jan 1, 1989

By Peter F. Steidl

As part of the Bureau of Mines methane control program, the Upper Free-port coalbed was studied in Fayette County, Pa., where this coalbed lies about 650 feet below the Pittsburgh coalbed and contains the largest remaining reserves of any coalbed in the county. Coal and overburden isopachs, structure and joint pattern maps, and a fence diagram were prepared using data from gas and oil exploration logs and coal outcrops. These maps will aid in deter-mining the need and/or feasibility of degasifying the Upper Freeport coalbed in the study area. Much of the coalbed in this area is under 600 to 1,400 feet of overburden. By correlation with data from the Pittsburgh coalbed, the gas content at depths of this order is estimated to be between 140 to 300 cf/ ton of coal, for a total of 190 to 400 billion cubic feet of methane in this coalbed in Fayette County.

Jan 1, 1977

By Joseph N. Harstead

This Bureau of Mines report provides information on the first 49 water-flood projects (or units) in Nebraska. All injection was in the ?D? or "J" Cretaceous sands of western Nebraska. Specific data presented include location, map, discovery and development, water supply and injection, oil and water production, estimates of oil in place, primary and secondary recoveries. The 49 projects studied) including four dual-zone projects, should recover about 126.5 million barrels of oil. Eighty-six percent of the estimated oil had been recovered by the end of 1966. Abundant water was found near most projects.

Jan 1, 1967

By X. Shi, N. S. Dala, V. Vallaythan

"Cellular damage induced by silica dust is known to be associated with increased fragility and destabilization or destruction of the cell membranes. The mechanism by which silica dust effects biological membranes is still unknown. Using the ESR spin-trap methodology, we find that hydroxyl radicals are generated in aqueous suspensions of freshly ground silica. The amount of the radicals generated depends on the extent of grinding and ""freshness"" of the dust. Using linoleic acid as a model lipid, we show that the silica dust causes lipid peroxidation via ·OH, 02-, or linoleic acid related radicals as intermediates. Catalase and superoxide dismutase inhibit the formation of these radicals. The results suggest that free radicals associated with freshly ground silica and the related lipid peroxidation of the memberanes may be the starting point of the silicotic processes.INTRODUCTIONDespite considerable-effort over the years, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrosis are still not fully understood (1,2). It is generally thought, nevertheless, that the interaction of the quartz particles with the cell membranes is the starting point of the silicotic process (3). We felt that the mechanism of the membrane damage by quartz might involve oxygenated free radicals because (a) a suspension of quartz particles in contact with alveolar macrophages has been reported.(4,5) to initiate an enhancement of lipid peroxidation, defined broadly as the ;oxidative deterioration of polyunsaturated components of lipids, and (b) hydroxyl (·OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (6) and initiating lipid peroxidation in lysosomal membranes (7). Moreover it is known that exposure of cell membranes, fatty acids and unsaturated food oils to ionizing radiation, which generates ·OH. radicals, causes rapid peroxidation (6). Earlier studies o~ the aqueous chemistry of quartz suspensions have reported detection of HzOz (8), implicating the formation of ·OH radicals as transient species, but, we are not aware of any report of the detection of ·OH radicals in quartz suspensions and this provided the motivation for the present undertaking. Since it is known that, because of their high reactivity (hence short life time) in aqueous media, the ·OH radicals cannot be detected via electron spin resonance (ESR) directly (9,10), we have used ESR combined with the spin-trap methodology (9) for studying the •OH formation."

Jan 1, 1988

By L. M. Demers, D. C. Kuhn

The alveolar macrophage (AM) responds to stimuli such as coal mine dust by releasing inflammatory mediators such as cytokines, growth factors. reactive oxygen species. and eicosanoids. Eicosanoids are synthesized by°AM through the action of cyclooxygenase and lipoxygenase enzymes and serve to modulate the proinflammatory function of this cell as part of the lungs' host defense mechanism. Reactive oxygen species can be generated by AM as a by-product in the biosynthetic pathway of the prostaglandins. AM produces primarily prostaglandin E2, thromboxane A2, and leukotriene B4 as part of the cellular response to an inflammatory stimulus. There is evidence to suggest that eicosanoid production by AM is functionally linked to both surface interaction with mine dust particles like silica and by the phagocytosis of the dust particle itself. In this report, we examined the effects of an antioxidant, vitamin E. on dust-induced synthesis of PGE2 and TXB2 in vitro and in vivo by AM obtained by bronchoalveolar lavage from rats. We also looked at the effects of the surface of silica particles on AM eicosanoid biosynthesis under conditions of calcination, a process that removes exposed hydroxyl groups from the surface of silica particles, thus reducing the likelihood of soluble hydroxyl radical formation. Treatment of AM with vitamin E in vivo and in vitro reduced the augmentation in eicosanoid production usually observed when AM are exposed to mine dusts. These results suggest that vitamin E may effectively reduce the inflammatory and fibrotic response produced by inhalation of mineral dust through an antioxidant mechanism. Silica that has been chemically altered by calcination was unable to activate AM eicosanoid production in vitro when compared to untreated, freshly fractured silica. These findings suggest that the mechanism by which dust particles can activate AM eicosanoid release may involve interaction of surface and/or soluble factors with the cell membrane. Taken together, these studies point to the involvement of AM eicosanoid production as part of the proinflammatory response of this cell to occupational inhalation of mineral dust. - Environ Health Perspect 102(Suppl 10):97-100 (1994)

Dec 1, 1995

By Ernesto Villaescusa, Andres Brzovic

Rock masses of the primary copper ore at the El Teniente Mine are very competent and massive. The rock mass contains almost no open discontinuities. Nevertheless, there is a high frequency network of small discontinuities coupled with widely spaced faults. A data collection campaign designed to characterize the rock structure was recently implemented. The results show that conventional analysis in terms of discontinuity frequency does not predict differences between two studied sectors. However, when an empirical definition of a weak discontinuity is applied, appreciable differences between the two sectors appear in terms of discontinuity frequency and predicted in situ block size distributions. These differences are in accordance with actual observations at the mine site. Due to the geological features of the primary copper ore, rock mass classification schemes cannot be readily applied to characterize these rock masses.

Jan 5, 2007

By Robert L. Crosby

The Bureau of Mines investigated the substitution of cement copper powder for commercial copper powder in an Fe-7 pct Cu-l pct C powder metallurgy alloy. Copper powders from six different commercial cementation operations were separately upgraded by screening and hydrogen reduction. They were then mixed with commercial iron and graphite powders to form the Fe-7 pct Cu-l pct C alloy. Various chemical and physical properties were determined on the upgraded cement copper and the alloy powders. Mechanical, physical, and chemical properties were determined on green and sintered specimens made from the alloy powders. Mean tensile and bending strength of sintered specimens were significantly lower than the means from specimens made from commercial metal powders. The lower strengths are apparently related to poor sinterability.

Jan 1, 1970

To investigate mine ventilation problems which do not lend themselves to conventional anemometer and smoke study techniques by use of SF6 (sulfur hexafluoride) tracer gas. Approach SF6 tracer gas is released in-to the air at a given mine location. By collecting air samples at various other locations and analyzing these samples for SF6, the amount of air traveling from the release location to each sampling location can be quantitatively determined. Travel time between these locations can also be deter-mined. How It Works SF6 is ideal as a mine tracer gas. It is safe, odorless, chemically and thermally stable, and it generally has no background concentration. Furthermore, it is instrument detectable at concentrations as low as 10 parts per trillion. The SF6 is generally released from a pressurized lecture bottle, and air samples are taken in syringes or evacuated bottles. During the past several years, SF6 tracer gas has been employed to study a wide variety of mine ventilation problems such as: recirculation of return air into In-take airways, air leakage from adjacent mines and gob areas, air transit times through stoped areas, airflow patterns during a mine fire, leakage of gases from an underground oil shale retort into mine workings, face area ventilation patterns, methane flows in metal/nonmetal mines following a methane out-burst, and many other problem areas. Examples of some recent uses of SF6 follow.

Jan 1, 1982

By Rimas Pakalnis, Tom Brady, Lewis Martin

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate weak rock masses (such as are associated with operations in the Carlin Trend in Nevada) into existing design relationships. The original database that led to most of the empirical design relationships presently employed in hard-rock mining was derived from fair-to-good-quality rock. In this study, the relationship between weak rock quality and opening design (non-entry/entry methods) is being investigated. The common factor in all mines is a weak back or wall. This work attempts to provide tools that will enable a mine operator to make economic decisions that will also ensure a safe working environment. Tom Brady (for correspondence - E-mail- thb6@cdc.gov)and Lewis Martin are at the Spokane Research Laboratory, National Institute for Occupational Safety and Health, 315 East Montgomery Avenue, Spokane, WA 99207-2291, USA (E-mail• ljm8@cdcgov); Rimas Pakalnis is at the Mining Department, University of British Columbia, Vancouver, British Columbia, Canada (E-mail: rcp@mining.ubcca).

By Paul T. Allsman

THIS CHAPTER reviews the highlights of developments in mining technology during 1956 and presents a special report on the design of mine openings in stable ground. This special report is presented each year in an endeavor to stimulate use of the scientific approach to the solution of problems related to mining technology. Assuming that the literature on mining technology reflects trends in mining, it appears that two areas of activity were given most attention in 1956. One was research on mining technology,4 and the other was improvement of transportation, particularly trackless transportation, both at surface and underground mines.

Jan 1, 1958

By L. B. Pankratz

Low-temperature heat capacities, high-temperature enthalpy increments, and the enthalpy of formation at 298° K were determined calorimetrically for vanadium subnitride (VN0.465). The low-temperature investigation gave S°298.15 = 6.379 ±0.005 cal/deg mole, and a combustion calorimeter investiga¬tion provided ?Hf°298.15 = -31.80 ±0.60 kcal/mole. The two quantities were combined with the high-temperature data to give standard values of enthalpies of formation and free energies of formation above 298° K. These and related thermodynamic functions were tabulated to 1,800° K. Similar data are included in the range of 298° to 1,600° K for the mononitride, VN.

Jan 1, 1971

By Fred N. Kissell

A parachute-type stopping intended for changing the course of mine ventilation air during mine emergencies has been designed and tested. Some production uses are also visualized for metal mines. Preliminary tests in the laboratory and underground indicate that the parachute stopping is a workable concept, but further developmental research is required.

Jan 1, 1975

Lower noise exposure levels for operators and cleanup personnel working in portable nonmetallic mineral crushing and screening plants.

Jan 1, 1983

By R. E. Head, Virgil Miller

"INTRODUCTIONRecent investigations at the Intermountain Experiment Station of the Bureau of Mines at Salt Lake City indicate that metallurgists have given little attention to the occurrence of jarosite minerals in the oxidized ores of lead and silver. These investigations have also emphasized the importance of knowing when these minerals occur in the oxidized ores, especially those containing lead, silver, and gold, as their presence is a material factor in selecting a suitable kind of treatment. Since the question of the occurrence of jarosites in oxidized ores has come to the attention of the Bureau of Mines, investigation has indicated that plumbojarosite and argentojarosite are quite common. These two minerals appear to be widely distributed and probably escaped recognition by persons who had attempted to treat certain oxidized lead ores in which the jarosite minerals represented a material portion of the metal content.Consideration of the physical characteristics of the jarosites also indicates that in many cases failure to treat some of the oxidized lead ores with success has been directly due to the fact that the greater portion of their lead and silver content was present as plumbojarosite and argentojarosite. The data and the description of these minerals given in the body of this paper indi¬cate that attempts to recover lead and silver from ores in which appreciable amounts of the metals occur as plumbojarosite and argentojaeosite would be unsuccessful if confined to gravity methods of concentration. There are un-doubtedly considerable tonnages of oxidized lead ores in the various mining regions of this and other countries, and it is quite probable that in some of these ores the metal content of lead and silver may be largely anglesite (lead sulphate) and cerussite (lead carbonate) but that they will also contain cerargyrite (silver chloride), argentojarosite, and plumbojarosite. The treatment of such ores therefore presents an important problem, since a product is discarded from ores from which the recoveries of lead and silver have been below 70 per cent which is probably too low-grade to warrant aftertreatment by any process now in use."

Apr 1, 1928

By Arnold J. Farstad

The Location Group conversed in the Petroleum Room of the Green Center with the purpose of addressing the following list of topics in light of the Bureau of Mines' requirements for detecting and locating trapped miners by electromagnetic methods. These topics include: Noise, Sources, Antennas (transmit and receive), the Propagation Medium, Signal Processing, Optimum Frequency, Receivers, Pulse vs. CW Techniques, Passive Location Techniques, and Obstacles. Practical constraints such as equipment size, weight and power requirements, cost and intrinsic safety were kept in mind during these discussions. It was emphasized that in-mine equipment must be inexpensive, rugged, simple and lightweight. Otherwise, the mine operators probably would not buy it nor would the miners be able to effectively use it. Present techniques for experimentally detecting and locating trapped miners were discussed, along with techniques to improve their location accuracy. Analytical, numerical, and scale modelling methods were considered as a means of giving further insight into measurement, anomalies caused by terrain variations, conductivity contrasts, and obstacles. After discussion of these topics, conclusions were drawn and existing problem areas were identified. These problem areas were addressed in developing guidelines for future efforts. Following the discussion period, the Chairman gave a summary of the Location Group report and comments were solicited from the entire group. 2.0 GROUP DISCUSSION HIGHLIGHTS 2.1 Noise W. Bensema asked the group whether the noise data provided by NBS was adequate. It was determined that for location systems analysis, the most important form of noise data was the frequency spectra of vertical and horizontal magnetic fields on the surface, and the answer to his question was affirmative. Drs. Wait and Frischknecht pointed out the difficulty in accurately measuring the true vertical magnetic field since these measurements are heavily influenced by the loop setting and the local geology. Nevertheless, these measurements are important since the same perturbations would also affect a receiving loop oriented to receive the vertical magnetic field. Dr. Rankin pointed

Jan 1, 1973

By W. C. Hudson

"The McLeod sand pits, on the northeast side of the Little Ocmulgee River in Wheeler County, Ga., opposite Lumber City in Telfair Co., were examined by the Bureau of Mines under its war program of Investigation of Critical and Essential Minerals. The pits are about a quarter of a mile above the bridge, which is half a mile above Lumber City. Mrs. A. T. McLeod of Lumber City owns the land, including the pits. The property was inspected by an engineer of the Bureau of nines on March 8, 1945, on recommendation of Capt. Garland Peyton, director, Division of nines, Mining, and Geology of Georgia.The Mcleod pits are at the northwestern extremity of a mile-long series of old pits that were worked from about 1900 until the 1920's. The burning of the spur railroad bridge connecting the pits with the Southern Railway at Lumber City stopped mining operations. The pits on the south-east, or opposite, side of the Glennwood Road from the McLeod pits were first worked by F. L. Hinson and later, in 1921, by Mrs. n. H. Mobley. The glass sand was shipped to Tallapoosa, Ga., and Chattanooga, Tenn., where it was used in the manufacture of bottles for soft drinks. Some of the sand was used as molding and construction material. The sand was mined by hand shoveling it into wheelbarrows, which were unloaded on freight cars. The pits were partly refilled with overburden, so that it is impossible to estimate even roughly the amount of sand excavated.Analyses of samples of glass sand made years age3/ and later in 19404/ roughly check those made by the Bureau of Mines laboratory, except that in the former the iron oxide content usually was greater, attaining a maximum of 0.72 percent.The sand pits are in a valley slightly more than a quarter of a mile wide that lies along the northeast side of the Little Ocmulgee River. The land is either flat or marked by ridges only a few feet high. . A rather thick growth of scrub trees covers most of the valley. The surrounding country consists of gently rolling farm lands. The altitude of the valley is not known, but, judging by its distance from the seashore, it probably is about 200 feet. In addition to the Glennwood highway, which crosses the valley, several old sand roads lead to the pits."

Apr 1, 1946

By Bill M. Stewart, Phil W. Patton, Curtis C. Clark

Back injuries from handling materials in underground mines continue to be a major safety problem. In spite of the ingenuity of many people and the development of numerous mechanized aids, the number of materials-handling injuries remains second only to the number of roof fall injuries in underground coalmines. Relocation and repositioning of electrical cable, conveyor belt parts, and roof bolt sup-plies in particular are the sources of significant numbers of back injuries. To help reduce such injuries, researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are examining Mine Safety and Health Administration accident data to determine correlations between materials-handling tasks and the number of back injuries. Also being investigated are new technologies used in underground mines in the United States. Equipment is being developed or modified that would replace the necessity of doing lifting tasks manually. A Coleman manipulator was tested, and modifications were made to make it more suitable for underground mine use. To reduce or eliminate the need to manually clean off materials that commonly plug grizzly openings, a track-guided pincher arm device was developed. Oversized rock can be broken with the pincher arms in the up position, and the arms can be lowered to grab and remove debris. The arm can also be used in a sweeping action to remove cohesive fines that may bridge grizzly openings.

By C. H. Elder

Coal degasification boreholes drilled from the surface have been success-fully hydraulically stimulated to increase the flow of gas from the coal. This Bureau of Mines report describes the hydraulic stimulation procedure for a coalbed, the equipment required, and design criteria for the treatment. Three examples of stimulation treatment show from fivefold to twentyfold increases in gas production. The tests were conducted in the Pocahontas No. 3 coalbed, Buchanan County, Va., the Pittsburgh coalbed, Washington County, Pa., and the Mary Lee coalbed, Jefferson County, Ala. Two sites where the coal was hydraulically stimulated and exposed by subsequent mining show no adverse effect on mining operations through the treated zones. The induced vertical partings were confined to the coalbed and did not in any way affect either roof or floor rock.

Jan 1, 1975

By J. M. Stuve

Calorimetric data for the dissolution of scandium sesquioxide and scandium trichloride in 4.360 molal hydrochloric acid were used to evaluate the standard heat of formation of ScCl3(c). The heat of reaction for Sc(c) + 1.5Cl2(g) = ScCl3(c) at 298.15° K was computed as -225,440 ±340 cal/mole.

Jan 1, 1965