Search Documents

By G. J. Feng

Based on detailed theoretical analysis of coarse floatation and three-phase froth, a laboratory system which contains a new type of froth floatation equipment is established. Through water experiment, the relationship among floatation dynamics parameters of the equipment is studied and the best work parameters are educed too. Based on all of above, Slurry test is carried out in a copper concentration plant. Granule between 0.28~0.45mm can be reclaimed successfully. The slurry test proves that to separate coarse minerals in froth floatation equipment is a kind of effective method, it is well worth to make a further study.

Jan 1, 2014

By F. C. Yi

Discontinuous and consecutive process was applied to probe into the Kinetics and adsorption theory for Cs+ adsorbed by Zeolites under the conditions of temperature, time and fixed-bed dynamic adsorption. It indicated that the sorption kinetics behavior of zeolite?s sorption on Cs+ is ac-cord with pseudo-secondary velocity equation, velocity constant k2=0.0005213 g?mg min-1, and equilibrium adsorptive capacity is 147.0588 mg?g-1; The equation can be expressed as: Y=0.0068X+0.0887; From the analyzing of diffusion coefficients on different temperatures and times, the coefficient of diffusion is not only related with the fabric of mineral and the character of ions but also the temperature and time; When the ambient temperature hoisted, the diffusion velocity augmented rapidly; Cs+ would get over a certain energy barrier when it enters into structure of zeo-lite; This energy is expressed by activation energy, and its value is E=131.668818 kJ?mol-1; There are two dominating adsorption mechanisms in the system of zeolite absorb Cs+: ionic interchange and surface coordinate adsorption.

Jan 1, 2014

By S. Kondratiev

Mechanism of the action of nonpolar physically adsorbed reactants in froth flotation is under discussion in the paper. It is shown that their basic influence on flotation includes removing of the kinetics restrictions of the flotation complex formation. Experimental data and practical evidence reported in the paper sustain the proposed mechanism. There are discussed potential dependence of the kinetics of dixanthogen formation on platinum and its influence on the induction time (IT).

Sep 1, 2012

By R. B. Shu

A moderate thermophilic microorganisms, has been isolated (45?) from a typical sulphide mine in the region of Mo Jiang located in the southwest of China. The culture has been used to extract copper from chalcopyrite concentrates obtained from De Xing copper mine. The majority of experiments were carried out in 300mL Erlenmeyer flasks containing 150mL volumes of mineral suspension. Effects of some variable parameters such as solids concentration, pH and the concentrations of inorganic nutrients on the bioleaching of chalcopyrite obtained from De Xing copper mine were investigated. For a given concentrate the most important factor affecting the fractional copper extraction was the size of the mineral particles. The overall rate of leaching was found to be limited by the area of mineral surface. The attack started in cracks and genetic defects and finally reached the whole chalcopyrite surface. As a consequence of this, the ore showed strongly cracks. The additive of ferrous sulfate increases the bacteria activity, but did not improve chalcopyrite bioleaching. The results indicate that the nature and relative proportions of the various minerals present have been shown to be important factors.

Jan 1, 2014

By Markus A. Reuter, Yongxiang Yang, Jim R. Post

In the upper part of an iron making blast furnace, sinter, coke and pellets are charged. While descending, the burden is heated and the iron oxides are reduced by the rising gases. The iron oxides start to soften and eventually melt. The melt and the remaining coke collect in the lower part of the blast furnace: the hearth. The remaining coke forms a porous bed: the dead man (see Figure 2). The melt flow through the dead man can affect substantially the hearth lining life, the furnace productivity and product (i.e. hot metal) quality. Physical characteristics like porosity and particle size distribution of the porous coke bed play a critical role. Because of the distributed nature of the coke properties, the bed packing structure and porosity will not be constant.

Jan 1, 2003

By P. Prakash

A dual-drive planetary mill, which has a rotating shaft that sweeps a circle of diameter 750 mm, has been designed. The planetary mill is powered by a 5 hp motor to rotate the main shaft and a 3 hp motor to rotate the jars. The charge dynamics inside the horizontal-axis planetary ball mill was established using three-dimensional DEM simulations. The simulation results provided data to determine the impact energy distribution and the effect of process parameters such as mill speed and filling. It has been observed that the mean impact energy per unit time increases with rotation-to-revolution ratio, whereas the average number of inter-particle impacts per unit time decreases. The mill was also used to synthesize a variety of powders. Here three case studies of reaction milling are briefly presented: (i) cementite and silicon carbide, (ii) oxide dispersed strengthened (ODS) steel, and (iii) magnetite from blue dust. In each case, the powder was produced by mixing and then milling the corresponding pure components. The phase evolution, particle size distribution, and morphology of particles during milling were studied for various samples collected at different milling times using laser size analyzer, SEM, TEM, and Mössbauerspectroscopy. The results established a convenient way to produce powders of high technological and commercial value.

Sep 1, 2012

By P. Somasundaran

Gangue minerals can often have severe adverse effects on selective value mineral separation. Such effects can be mediated through a variety of pathways or mechanisms. One popular mechanism is that of ?slime coating? or heterocoagulation, wherein the gangue mineral fines are believed to coat the value mineral surfaces and thereby reduce selectivity and floatability. Another pathway that has received relatively little attention is that mediated through the effect of gangue minerals on pulp rheology, and consequently selective separation. Our recent work in developing a scientific understanding of these effects has highlighted the prevalence and importance of this pathway. In this study, the impact of shape and morphology of serpentine gangue minerals on suspension rheology and selective Ni flotation from ultramafic ores was investigated. We found strong evidence for micro- and macro-network formation in the presence of acicular (needle-shaped) or fibrous minerals, which impacted pulp rheological properties. Results also supported the hypothesis that morphology has a greater role to play than mere shape. The size of the network ranged from 5 microns to 2 cm depending upon the amount and aspect ratio of fibrous minerals. These networks impede many flotation sub-processes, such as gas dispersion and bubble-particle interactions. Additionally, the small pore size of the networks prevents bubble penetration leading to a large transport of the gangue minerals to the concentrate via lifting of the entire network by bubble flux, which resulted in a significant grade dilution. Based on the scientific insights generated in this study various techniques have been developed to improve selective value mineral separation. Keywords: fibers, aspect ratio, microstructures, networks, pulp viscosity, gangue transport

Sep 1, 2012

By Z. H. Li

In connection with the features of characteristic waste water (containing cyanogen, arsenic and heavy metal) pollutants discharged by gold industry as well as the environmental features at the location of gold production enterprises, this paper briefly described the traditional method of treatment, and focused on the argument for technologies of clean production, advanced treatment and process control technology. Moreover, it clarified the future policies and development trend for treatment on characteristic waste water from gold industry.

Jan 1, 2014

By P. Holtzhausen, L. Auret, B. Lindner, A. Haasbroek

"Spiral concentrators offer a cost effective way to separate valuable minerals from gangue by displacing lighter materials to the outside, and heavier materials to the inside of the spiral. The separation can be seen as visible concentrate bands and splitters are set at the bottom of the spiral to effectively split the ore into various densities. As there are typically many spirals in a concentrator plant, it becomes ineffective to continually adjust the splitter positions manually. Vermaak et al. (2008) proposed to use image recognition to detect the concentrate bands, thereafter, creating a model predicting the positions under certain input conditions. This model could then be used for optimisation and/or control of splitter position or band position. In contrast an online concentrate band detection system would provide real time concentrate band positions without losing accuracy due to model generalisation. These systems are usually expensive and time consuming to develop, due to a lot of centralised features required (image capturing, image processing and/or feedback to a controller). This study took advantage of the recently developed Raspberry Pi minicomputer to perform rapid prototyping of an online image processing sensor. The Raspberry Pi, and accompanying camera module, offers a portable Linux environment which can natively run the required image processing algorithms. Furthermore, extensive use of OpenCV was made to reduce development time, by relying on existing and proven algorithms to detect the concentrate bands. The Raspberry Pi also incorporates generic input/output ports which can be used in future work to provide the signal to a controller. In conclusion, the Raspberry Pi was successfully used to perform real time concentrate band position detection on a spiral concentrator. This solution is more general than an experimentally identified input-output model and may be used for control or optimisation studies in a wide array of spiral concentrators."

Jan 1, 2014

By M. Saghaeian, R. Hejazi, H. Abedini, M. Zare

Water recovery in mineral processing plants is one of the most important subjects because water supply is a critical matter economically and environmentally, especially in desert areas. In this paper, the filtration behaviour of two iron ore tailing sample has been investigated using laboratory scale vacuum and pressure filtration units. These samples including tailing from Sirjan and Zarand concentrate production plants with the d80 of 94 and 41 micron, respectively. The results show that by using vacuum filtration the cake moisture content of Sirjan sample would be about 24%. But the filtration time is too long and vacuum belt filter cannot be used in industrial scale. Adding about 40 g/ton of flocculant would decrease the filtration time by about 30% and make the vacuum belt filter appropriate for dewatering of this sample. For Zarand tailing sample, the vacuum filtration would produce a wet cake by about 31% moisture content. Filtration time is too long and adding flocculant would not improve the results very much. So pressure filtration must be used for dewatering of this sample. The results of laboratory tests show that using pressure filter would reduce the cake moisture content to 21%. The filtration time is logical, so this process can be used for Zarand tailing dewatering.

Jan 1, 2014

By Ibrahim Alp, Duygu Dinç, Ersin Yazici, Adularya Energy and Electricity Generation and Mining Inc., Oktay Celep, Haci Deveci

Thiosulfate leaching as an environmentally benign alternative to cyanide leaching has received particular attention in recent years. Most studies have focused on thiosulfate leaching of free milling ores and, to some extent, pregrobbing ores. In this study, leaching of gold from the refractory Kaletas ore (in which gold/silver alloy is the only mode of occurrence detected) in ammoniacal thiosulfate solutions was studied. A two-level full factorial design (23) was adopted to investigate the effects of concentration of thiosulfate (0.2-1 M Na2S2O3), ammonia (0.5-1 M NH3) and copper (0.05-0.1 M CuSO4) on the extraction of gold from a ground ore (-38 µm) over a period of 24 h. Statistical analysis confirmed the leaching of gold improved with increasing concentrations of thiosulfate and ammonia. In contrast, increasing the concentration of copper in the range tested adversely affected the extraction of gold. The magnitude of effects of parameters on the gold extraction was in the order of Na2S2O3 > NH3 > CuSO4. The maximum extraction of gold (69.6%) was obtained in the presence of 1 M Na2S2O3, 1 M NH3 and 0.05 M CuSO4. The negative influence of copper on gold extraction is most likely attributed to the decomposition of thiosulfate catalyzed by copper. Concentration of thiosulfate was also identified to be statistically the most important parameter for its consumption.

Jan 1, 2014

By H. M. Yang

Structural alteration of pyrophyllite during mechanical activation in a planetary mill was investigated by X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) techniques. Mechanochemical effect markedly promotes the decrease in reflection intensities with increasing the grinding time. Prolonged grinding causes the pyrophyllite to become the amorphous structure. It can be indicated that pyrophyllite is very susceptible to alteration by grinding. Crystal size (d006) of pyrophyllite appears to be a limit after 2h grinding. IR spectroscopy analysis shows a little alteration in the bands of pyrophyllite after mechanical activation. The results indicate that the ordered structure of pyrophyllite is destroyed and lattice deformation occurs. Porous silica was then successfully prepared via leaching the mechanically activated pyrophyllite. Pyrophyllite was first ground for 6 h. Ground samples were subsequently leached with 4 M hy-drochloric acid at 80 °C for 2 h to produce porous silica with specific surface area of 188.1 m2/g, total pore volume of 0.18 mL/g and average pore size of 3.9 nm from N2 adsorption analysis. Otherwise, the porous silica obtained from direct leaching of the original pyrophyllite only has a specific surface area of 4.3 m adsorption analysis. 2/g and total pore volume of 0.03 mL/g. It is inferred that grinding is favorable for the formation of microstructure pores. It offers a simple and convenient route for the preparation of porous materials from natural minerals.

Jan 1, 2014

By D. Govender

Theoretical flotation models suggest that there is a positive relationship between bubble-particle collision rates and turbulent kinetic energy dissipation. Fine particle flotation performance is generally enhanced by increased collision frequency and hence higher energy dissipation. Contrarily, increased turbulence in the rotor-stator region is related to higher detachment frequency of the coarser size range. Therefore, the optimal modes of recovery for the ?fine? and ?coarse? size classes are diametrically opposed. Industrial applications have previously confirmed that applying greater power to flotation slurries yields significant improvements in fine particle recovery. However, recovery of the coarser size class favors a different flotation environment. An improvement in the kinetics of the fine and coarse size classes, provided there is no adverse metallurgical influence on the intermediate size ranges, is obviously beneficial to the overall recovery response. Managing the local turbulent kinetic energy dissipation, and hence the power imparted to the slurry, offers the benefit of targeting the particle size ranges exhibiting slower kinetics. FLSmidth recently introduced the practical implementation of this concept. In principle, it decouples flotation regimes where fine and coarse particles exhibit preferential recovery. In the case of naturally aspirated machines (Wemco®), it is referred to as Hybrid Energy Flotation? and incorporates at least three phases: ? Standard flotation machines (standard energy input, rpm, rotor size/type) at the beginning of the row, where flotation is typically froth phase limited and operational, and set-up parameters have a limited influence on the recovery. ? Higher-powered flotation machines (high rpm, high power rotor size/type) at the end of the row to improve fine particle recovery. ? Lower-powered flotation machines (low rpm, low power rotor size/type) to enhance coarse particle recovery. In evaluating the effect of turbulent kinetic energy on flotation performance, the spatial distribution and its effect on size denominated recovery needs to be evaluated. The mean energy dissipation rate is a measure of the bulk energy input, but CFD-based models offer a more introspective view of flotation sub-processes. A CFD-based flotation model is used to highlight the effect of turbulent dissipation energy on attachment and detachment rates. Preferential collection zones for ?fine? and ?coarse? particles are predicted for both forced air and naturally aspirated machines. Keywords: CFD-based model, attachment, detachment, energy dissipation, hybrid energy flotation?, forced air, naturally aspirated

Sep 1, 2012

By Tohru Kamo, Shigeyuki Katano, Hideki Nakagome, Maiko Adachi, Shingo Nakamura, Kaneshi Taniguchi, Zar Zar Hlaing, Takaaki Wajima

Tantalum capacitor is a small-sized and has large capacity, and is indispensable for electric equipment. The demand increases year by year, and a quite large number of used tantalum capacitors is generated. Recovery of tantalum from tantalum condenser is recently important since production of tantalum have not been stable for the price and the quality. However, recovery of tantalum from tantalum-condenser is difficult since tantalum parts strongly cover with the flame retardant resin made of halogenated compound (mold resin). This research investigated recovery of tantalum parts from tantalum condenser using steam gasification with mixed molten carbonate. Mixed molten carbonate (Na2CO3:K2CO3:Li2CO3 = 1:1:1) (3 g) put into the reactor, and heated with electric furnace while flowing nitrogen (160 mL/min) and steam (1 mL/min) warmed by heater. After heating to setting temperature (450 - 650 oC), tantalum condenser (3 g) was put into the reactor, heated for 5-10 min, and then cooled to room temperature to recover the reacted capacitor by filtration after treating with distilled water. At relatively low temperature (550 oC) heating for 10 min, mold resin can be decomposed by using steam gasification with mixed molten carbonate, in comparison with using pyrolysis and steam gasification without carbonate, and decomposition reaction occurred over 500 oC by using steam gasification with mixed carbonate. Recovery of tantalum parts from capacitor is successful using steam gasification with mixed molten carbonate at 530 oC for 5 min, due to the effective decomposition and removal of mold resin from capacitor. Furthermore, most halogen gas generated from decomposition of mold resin can be trapped in molten carbonate not to exhaust halogen gas. These results suggested that recovery process of tantalum parts from used condenser using steam gasification with mixed molten carbonate is expected as a feasible way to recycle the rare metal in electric equipment.

Jan 1, 2014

By Z. Kwela, A. Manhique, W. W. Focke, W. van der Merwe

"The main features of the de Wet improved alkali fusion process for the manufacture of AZST are: Fewer process are steps necessary; radioactivity is removed by leaching rather than by precipitation; fewer waste streams are generated; there is less waste to discard and alkali reagent is recovered in the form of a sodium silicate solution that is essentially free of radioactivity.Here we report on our efforts maximize the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated. The fusion products were characterized by infrared spectroscopy, X-ray diffraction and by wet chemical analysis.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since these compounds do not hydrolyze in water they limit the recovery of alkali in the sodium silicate product stream. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed."

Jan 1, 2003

By M. Evertsson, K. Bhadani, E. Hulthén, M. Bengtsson

"Modelling and simulations for mineral processing plants have been successful in replicating and predicting predefined scenarios of an operating plant. However, there is a need to explore and increase the potential of such simulations to make them attractive for users. One of the tools to increase the attractiveness of the simulations is through applying optimization schemes. Optimization schemes, applied on mineral processing simulations, can identify non-intuitive solutions for a given problem. The problem definition itself is subjective in nature and is dependent on the purpose of the operating plant. The scope of this paper is to demonstrate two optimization schemes: Multi-Objective Optimization (MOO) using a Genetic Algorithm (GA) and Multi-Disciplinary Optimization (MDO) using an Individual Discipline Feasible (IDF) approach. A two stage coarse comminution plant is used as a case plant to demonstrate the applicability of the two optimization schemes. The two schemes are compared based on the problem formulations, types of result and computation time. Results show that the two optimization schemes are suitable in generating solutions to a defined problem and both schemes can be used together to produce complementary results. INTRODUCTION The comminution process for a mineral processing plant consists of multiple crushing and classification stages and aims to produce fine material to liberate ore from the minerals. The modelling and simulation of such processes are well established using static process models (King, 2001; Napier-Munn et al., 1996). A recent development in the dynamic modelling for such processes has shown further increase in fidelity compared to the static process models (Asbjörnsson, 2015). The developed simulations can be utilized to design, operate and control mineral processing plants based on the requirements of users (Bhadani et al., 2017). Typically, the requirements in the operation of the comminution process are conflicting in nature, as for instance, reduction of power draw by process units, maximization of production of fine materials, and increasing utilization of the process units. These conflicting requirements leads to a Multi-Objective Optimization (MOO) problem to operate a mineral processing plant. The MOO problems are normally referred to as non-linear problems and its fundamental understanding with respect to process behaviour is difficult to achieve."

Jan 1, 2018

By R. J. Batterham

The science and practice of mineral processing has been driven for many years by the same set of challenges that shape the mining industry ? demand and supply, grades and their decline with time, mineralogy and the need to handle more complex ores, disposal and minimising of wastes and the availability of water, power, skilled labour and the like together with increasing expectations from the community, concerns on sustainability and safety and, as well, climate change forcing a more targeted approach on energy. In this paper, the author builds on previous reviews to the IMPC and suggests that while step changes are long overdue, the unprecedented demand mitigates against drastic changes. That said, the ?Mine of the Future? is already requiring some different approaches.

Jan 1, 2014

By L. Muhr, Y. -T. Tang, M. -O. Simonnot, B. Laubie, R. -L. Qui, Z. Chour

"Agromining aims at recovering metals from different secondary resources with hyperaccumulating plants. These natural plants can selectively concentrate metals at very high level and can be transformed to produce commercial compounds. The classical strategy to recover metals from hyperaccumulator plants is based on hydrometallurgy. It consists of: i) burning the plant to obtain ash, which is a very rich bio-ore without organic matter, ii) transferring the target element(s) into aqueous solution by acid leaching and iii) purifying the leach liquor to obtain the target element(s) in the desired form. This method has enabled us to obtain nickel salts, nickel oxide, zinc and cadmium from different plants. However, it is not possible to apply this approach to recover rare earth elements (REEs) from the fern D. dichotoma, growing on mine tailings in South China. Actually, this plant is very rich in silicon: plant burning gives an amorphous ash, very stable despite severe leaching conditions. Therefore, the strategy has been changed and processes are currently developed to extract REEs by direct leaching of the biomass, without burning the plant. Several conditions (i.e. leaching solutions) have been investigated, showing that a good extraction yield was obtained with HNO3 0.5 N (around 84%). This yield was increased to 99% by adding a complexing resin into the leaching solution. After two-steps of elution, results have shown that is possible to recover 75% of the REEs at 81% purity.INTRODUCTION The demand of rare earth elements (REEs) (including 15 lanthanides, yttrium and scandium) has been growing sharply over the past years, because of their industrial applications. REEs are essential elements for emerging technologies, and are used for example in permanent magnets, lamp phosphors or rechargeable batteries. China is the main producer, and the market supply became tense in 2010 when this country decided to limit exports of these elements. Exploitable mineral resources, as well as REE separation capacity are concentrated in a few countries (e.g. USA, Australia, Malaysia, France), which increases the supply risk. Therefore, these elements are considered as critical raw materials (CRM) for many countries and especially for EU (Fortier and Gambogi, 2017)."

Jan 1, 2018

By V. A. Vorob'ev, A. N. Larionov, E. N. Ivanov, M. A. Ryazanov

The aim of the research is to increase the recoverable value of poor, difficult-to-digest complex mineral raw materials. In the Republic Belarus, universal centrifugal-shock devices have been created for crushing, grinding and classification of ore and non-metallic mineral raw materials in dry mode, which differ from foreign analogues by a higher level of resource saving (including electricity and materials). Dry-ore preparation technologies have been tested on a pilot scale: fine crushing (replacing grinding in rod mills), grinding (replacing wet grinding in ball mills) and pneumoclassification on different types of ores, - which made it possible to identify the criteria for the suitability and unsuitability of mineral raw materials for their use. The possibility of regulating the upper and lower limit of the size of the finished material is established, the possibility of reducing the yield of slimes (-0,020 mm) to 5 times is determined. A comparative analysis of the contrast degree of separation characteristics of ore a similar granulometric composition, crushed in wet and dry conditions, is performed. The achieved contrast degree of gravity properties after dry grinding - 104,3; after the wet - 60.2. When enriching on a centrifugal concentrator, gold recovery to the concentrate after dry grinding increased by 13.12% while improving the quality of the concentrate from 78.3 g/t gold to 90.75 g/t. When testing the gravity-flotation scheme for the enrichment of poor gold-quartz ore, the increment of gold extraction after dry grinding was 7.6% for gravity and 9.5% for flotation; the total increase in extraction is 17.1%. The possibility of flotation of a larger material after dry grinding has been proved, with an extraction gain of 1.5% compared to the flotation of thinner material after ball milling. The influence of dry technology on the efficiency of the leaching of gold and silver (an extraction gain of 5.5 to 10%) and heap leaching (extraction gain - up to 18.3%) was studied. The positive influence of dry ore preparation technologies on the efficiency of gold and silver heap leaching and heap leaching, thickening and filtration is proved. Lines of dry ore preparation technologies can be used in modular complexes for processing technogenic raw materials.

Jan 1, 2018

The status of utilization of copper ore resources, and the application and development of biohydrometallury technology in the world is reviewed. Based on the characterization of Zambia?s copper resources, biohydrometallurgy technology is shown to be a practical approach to extract and utilize the enormous low grade copper resource, such as ore tailings and low grade copper ore in this country. Through the cooperation of CSU, China and MMMD, Zambia, ?CNMC-CSU Demonstration Base of Biohydrometallurgy Technology in Zambia? was launched and several biohydrometallurgy plants are being constructed. This indicates that the biohdyrometallurgy technology would be applied soon in Zambia and in the whole Africa. Biohydrometallurgy technology stands as an efficient alternative to the traditional pyrometallurgy process and it can be the key to unlock mineral resources value. Keywords: biohydrometallurgy, low grade copper ore, Zambia, Central South University

Sep 1, 2012