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By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990's. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By J .. Carignan, Y. Dembele, J .. Guha, A. Fowler, A. Gobeil

The Barlow Lake stratigraphic section comprises the top of the Gilman Formation, the Blondeau Formation and the three sills of the Cummings Complex. Representative samples were analysed to allow characterization of the chemo-stratigraphic profile and geochemical affinity of the six rock facies found in the section. All the mineralized horizons are associated with sedimentary units. Geochemical signatures associated with the mineralizations are either very weak or very localized and shown by increases in K20 around the mineralizations and Fe203 near them. The mineralizations are stratiform, synvolcanic but resedimented and remobilized by regional metamorphism and possibly by hydrothermal activity initiated by the intrusion of the Cummings Complex. The evolution of the sedimentary basin with the decrease of its depth is confirmed by the chemo-stratigraphic profiles. Stratigraphic position in the section is important in order that the chemo-stratigraphy may serve as a guide for mining exploration in the distal facies of the Blondeau Formation.

Jan 1, 1984

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018

By R. Ghomashchi

Wear, fatigue and corrosion are the most widely encountered modes of failure in materials used in engineering applications, including aero-gas turbines. Although wear is distinctly classified as adhesive, abrasive, erosive, fretting and so on, there are usually more than one wear mechanism involved in the failure of components in service because there are many systems and materials variables active in materials wear that makes it more difficult to study. This is further complicated by the discrepancies between the results of laboratory tests and field data. The present investigation was set up to examine the wear characteristics of M50 and T1 high-speed steels at both room and elevated temperatures to draw a thorough understanding of the wear behavior of this class of high-speed steels. This article focuses on the mechanical and microstructural characterization of wear for T1 and M50 high-speed steels using a pin-on-disk wear machine.

Jan 1, 2005

By David C. Cook

The milling complex, situated just east of the Cassiar townsite, receives raw ore from the tramline and processes it into 105,000 tons per year of milled asbestos fibre. The ore is passed through a concentrator, where a barren rock fraction is removed. The concentrated ore, representing 70% of the feed, is dried, stored and then milled into nine separate fibre classifications. The finished product is packaged into 100-lb bags and loaded into trucks in one-ton units. New air-handling facilities were added in 1977to provide additional air for environmental control.

Jan 1, 1978

By Loui Geoffroy, Philippe Gaultier, Martin Piotte, Claude Coache, André Drouin

"Automatic driving at high speed of an underground truck was tested at Brunswick mine in September 1995. Modifications to the truck included: a remote interface to control actuators, front and back video cameras to follow a roof mounted optical guide and proportional hydraulic controls on the steering.The mathematical model of the hydraulic system was adjusted using least square regression. The steering data, used in calculating the regression parameters, were acquired from the moving truck. The automatic steering control used three measured variables: lateral deviation, angular deviation and steering angle. Lateral deviations are obtained using the cameras, which are in continuous view of the guide, while steering angles are acquired from an extensiometer placed at the articulation point of the vehicle. Gain scheduling was used to compensate for vehicle speed and available hydraulic flow. Non-linear characteristics of the modeled hydraulic system were offset using open loop compensation.Speeds up to 23 km/h in forward direction and 13 km/h in reverse were achieved deviaduring continuous testing along one of the mine’s production drifts. Proportional steering was essential in achieving high speeds, as it enabled more precise positioning of the vehicle’s steering direction while reducing the abuses on cylinder and cylinder pins via diminished oscillations about the optical guide at high speeds."

Jan 1, 1997

By R. Thierbach, W. Kahnt, Oberthür. T., D. Eisenburger, V. Gundelach

ABSTRACT: The ground penetrating radar (GPR) method was used in a platinum mine in Zimbabwe by members of the Federal Institute for Geosciences and Mineral Resources (BGR). The measurements were carried out in boreholes and drifts. Electromagnetic re?ections from a fault that consistently trends parallel to the mineralization zone permitted the mapping of the economically minable parts of the deposit. An introduction is given to the geology of the studied area and the application of the GPR method. The electrical parametres of the rocks are measured in situ, the GPR measurements are displayed with radargrams, and the visible structures are explained in illustrations.

Jan 1, 2010

By G. Vibert Douglas

"Gold occurs in Nova Scotia in three ways, saddle reefs, fissure veins, and fossil placers. Of these the saddle reefs are the commonest. They have been the source of most of the gold and have also been the subject of most of the literature on the gold occurrences.The Meguma or Gold-bearing series of Nova Scotia is a conformable succession of quartzite's and slates, possibly Precambrian in age, which have been folded into a number of anticlines and synclines that strike (Fig. 1) roughly east and west. This folding has been termed Acadian and is probably a westward continuation of the Caledonian revolution in Britain. It may have started in the Ordovician and continued through the Silurian and into the Lower Devonian. It was followed by the intrusion of the great Devonian granite batholiths. It is thought that the mineralization is connected with the late phases of the cooling of the granite. As the name saddle reef implies, the veins form on the crests and flanks of the anticlines, possibly in the synclinal troughs as well. The beds favoured by the solutions are the slates. The reason for this is apparent when it is realized that in order to fold over 30,000 feet of sediments (the thickness of the Meguma according to E. R. Faribault) through p radians of arc it is necessary to have a differential movement between the top and bottom beds of p times the thickness of the sediments. In the case of the Gold-bearing series, in which strong quartzite beds lie between incompetent slate beds, most of this differential movement was taken up in the slates. The evidence for this is the remarkably fine drag folding and the intense shearing and comminution of some of the beds of slate (Fig. 1). The quartzites exhibit some shearing and faulting, but there is little doubt that the greater permeability lay along the incompetent slate beds. The mineralizing solutions followed these beds and also passed from one slate bed to another through a joint or fault in the intervening bed of quartzite. These joining veins are called angulars in Nova Scotia. Within the veins the gold is in shoots and the real problem is to find out what controls the position and extent of the shoots."

Jan 1, 1954

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By Z. Gostynski

The paper is a historical cross-section through a 28-year period of operation of the direct-to-blister Flash Smelting Furnace in the KGHM Glogów Copper Plant. It presents the origin of the furnace as well as the path of numerous changes and modifications both in technology and process introduced in the furnace in response to the production and cost-reduction challenges. The authors provide justification of the statement that continuous improvement of the "Polish" Flash Smelting Furnace has ranked it among the most modem smelting units in the world.

Jan 1, 2007

By D. Pérez Escobar

Multiphase steels are quite sensitive to hydrogen embrittlement. Laboratory tests to evaluate this often use electrochemical, charging to introduce hydrogen into the sample, but damage purely caused by hydrogen charging has to be avoided. A ferrite-bainite steel, was charged using various conditions to identify when surface blisters occurred. Samples were also checked for internal, damage by electron microscopy. This study was repeated for three other multiphase steels and pure iron. An HSLA steel, was found to be more resistant whereas pure iron was quite susceptible to internal, hydrogen damage. For al, industrial, steels, cracks concentrated in the middle of the sample were attributed to inclusions and segregations, inherent to production.

Jan 1, 2010

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004

By S. Gößling-Reisemann

Most copper ores contain valuable co-products such as molybdenum, gold, silver, nickel, etc. Sulphuric acid and steam are valuable by-products, which are generated dur¬ing copper production. The environmental impacts from mining and refining therefore need to be shared between these by-products and co-products, an issue in Life Cycle As¬sessment (LCA) referred to as allocation. There are different, recognised methodologies for doing so: burdens can be allocated based on the market values of these commodities, they can be allocated by mass, volume, molar amount, functionality, or other physical, technical or economic factors. All of these methodologies have their respective merits and restrictions, and the choice is usually case specific. Nevertheless, the choice between alternative methodologies can have dramatic effects on the LCA results. Recycling in LCA has to be handled in a similar way, as it essentially constitutes a special case of co¬production. The existing standards (ISO 14040 ff.) allow different methods for imple¬menting recycling and allocation into metal LCAs (open loop, closed loop, value cor-rected substitution, etc.), which are still a subject of discussion in the scientific community. However, the methodology used can significantly influence the ecological profile of copper and copper products. We will present an overview of the different methodologies available for including recycling and allocation and give an analysis of how the meth¬odological choice affects the final LCA results. This work will be followed up by quantitative case studies.

Jan 1, 2007

By M. Brochu

In this paper, we present a computer-vision approach developed for wall-thickness measurements of corroded pipes inspected by double-wall radiography. The main objective of the work is to optimize data collection and film interpretation using computerized image analysis. To date, the system is able to identify the inner and outer contours of a pipe and perform wall thickness measurements at each pixel of a radiograph. This will be presented by analysing pipes having different dimensions. Another important feature of the system concerns the algorithms&apos; adaptability to pipe wall texture. In other words, image analysis is automatically refined around rough or corroded areas. This allows more precise thickness measurements and shape identification in critical sections as will be demonstrated with examples. Finally a brief overview of results exploitation will be given and compared with human interpretation. It will show the reliability of automated image analysis and the many possibilities offered by complete output analysis.

Jan 1, 2005

By D. Nie, M. Ren, T. Mo

This paper studied the phenomenon of room temperature creep deformation at crack tip and its effect on fatigue crack growth rate of a X-70 pipeline steel using compact-tension (CT) specimen on a MTS 810 testing machine. Time-dependent deformation at the crack tip under constant load was observed in this steel at room temperature and the amount of deformation produced was seen to depend on loading rate and the magnitude of stress intensity factor. It is found that there exists a critical stress intensity factor below which the deformation decreases with time when the applied load remains constant. It is also found that the occurrence of room temperature creep obviously affects the subsequent fatigue crack growth rate. The observed behavior was explained based on dislocation theory.

Jan 1, 2005

By Adam Jordens

Along with gravity separation and froth flotation, magnetic separation is one of the most common techniques for separating minerals. Minerals are separated by a magnetic force that is dependent on a combination of the applied magnetic field, the magnetic field gradient and the magnetic properties of the minerals themselves. Minerals may be classified as diamagnetic, paramagnetic or ferromagnetic based on the way they interact in a magnetic field. The magnetic susceptibility of a material may be determined by using a vibrating sample magnetometer to determine the magnetic moment of the material in an applied magnetic field and then converting this measured moment into the material?s magnetic susceptibility. In the case of rare earth minerals, magnetic separation is commonly used to remove ferromagnetic iron-bearing gangue minerals and to concentrate paramagnetic valuable minerals such as monazite and xenotime. These magnetic separation steps are frequently preceded by a gravity separation step as many iron oxides and rare earth minerals have specific gravities that are much larger than those of typical gangue minerals. By varying the magnetic field intensity it may be possible to use magnetic separation to selectively separate the paramagnetic and ferromagnetic minerals that report to the concentrate after gravity separation. Test work on a Canadian rare earth ore has shown that a gravity concentration step using a Knelson concentrator was able to selectively concentrate heavy magnetic minerals as evidenced by increased recoveries, relative to the Knelson tailings and fresh feed, after processing through a wet variable intensity magnetic separator. Mass pull to the Knelson concentrate was 4.5 % and the magnetic recovery of this concentrate, at 0.94 T, was approximately 40 % higher than the magnetic recovery from the Knelson tailings (70 % versus 30 %). The products of the wet high intensity magnetic separation were also analysed using a vibrating sample magnetometer to determine the magnetic susceptibilities of the various concentrate and tailings products.

Aug 1, 2013

By G. E. Bogin, C. Strebinger, J. F. Brune

"Evidence shows that methane gas emanates from the mined-out area or gob of a longwall coal mine and can travel towards the working face, posing an explosion risk. Since the gob consists of varying levels of compacted rock, many researchers have modeled fluid flow through the gob as a Darcy-type porous media with a specified porosity and permeability. When studying methane gas explosions near the gob fringe, the Darcy flow assumption may not be applicable to describe the methane flame interaction with the gob. Computational fluid dynamic studies were performed modeling methane flame propagation across a simulated gob which was modeled as both a Darcy porous medium and as discrete rock objects with varying sphericity. Modeling the gob as a Darcy porous medium results in unrealistic methane flame propagation since the porous media assumption does not consider any differences in rock size and/or distribution. Additionally, the porous media model does not allow for ignition within and subsequent flame propagation through the porous medium, which must be modeled to understand the potential for methane gas explosions in the gob area. Modeling the gob as discrete rock objects produces more realistic methane flame dynamics and agrees with experimental observations. Modeling results show flame propagation across circles, hexagons, and squares, meant to represent rock rubble in the gob, produce different levels of turbulence which affects methane flame propagation velocity. This research demonstrates that modeling methane gas explosions in a longwall coal mine environment, specifically near the gob area, requires modeling obstacles, such as rock rubble, as discrete physical objects to capture the complex coupling of fluid dynamics, thermodynamics, and heat transfer. INTRODUCTION Although there are methods to mitigating methane accumulations in a longwall coal mine, explosive gas zones (EGZs) of methane and air may exist and pose an explosion risk to nearby miners and equipment (Brune, 2014) (Karacan, Ruiz, Cote, & Phipps, 2011). In the event of an explosion, the resulting methane flame and pressure wave can be catastrophic as evidenced by the Upper Big Branch explosion in 2010 that killed 29 miners (Page, et al., 2011). Since the mining process is transient, it is difficult to determine exactly where these EGZs exist, but investigative reports show in many cases, these EGZs can be near the working face, behind the shields, or within the gob area (Brune, 2014) (McKinney, et al., 2001). Additionally, miners have recounted seeing flames moving back and forth within the gob and under the roof supports (McKinney, et al., 2001) and in other cases, anecdotal evidence of hearing small pressure pops deep within the gob area (Brune, 2014)."

Jan 1, 2019

By Somasundaran P., M. Vasudevan, Z. Dai, D. R. Nagaraj, T. Bhambani, P. Patra

Historically, efficient beneficiation of ultramafic ores has been challenging, partly due to a lack of clear scientific understanding of the effects of Mg silicates, particularly fibrous serpentines, on selective Ni recovery. Recent research at Columbia-Cytec as a part of a Vale JDP project has led to new insights into the mechanistic aspects of the adverse effects of Mg silicates. Our research has provided strong evidence to support the hypothesis that the adverse effects of Mg silicates are mediated through their large influence on pulp rheological properties, far more than any other pathway. The severity of the effect of Mg silicates is predominantly dependent on the aspect ratios of Mg silicates. For example, the pulp viscosity increases dramatically with increase in the fibrous nature of the gangue mineral leading to poor Ni separation. Various ways by which the suspension rheology affects flotation sub-processes, with implications for remedy are discussed. The insights and results have served to develop (or construct) a phenomenological model to adequately explain all of the ore flotation data, particularly the Mg silicate transport to the froth phase and the concentrate.

Jan 1, 2011

Building block cave operations involves significant commitments to capital and time before arriving at completion or full scale production. The focus of the mine planners is habitually to minimize the upfront capital and achieve target development rates and construction dates. However, management of the construction of block cave projects requires understanding of the strategic/tactical decisions that the project planners can take to increase the value of the project and cope with schedule risks. As block cave projects involve development of vertical and lateral access to the underground footprint and ore body, more attention to uncertainties is required as most of those projects need to confront delays leading to a decrease in value. The standard process of development and construction scheduling is often not planned with provisions to realise uncertainties in the construction phase. Uncertainties and risks such as poor ground conditions and equipment breakdowns are the primary reasons for schedule slippage. As a result most of these projects experience delays. In order to mitigate risk to the project schedule, we centre our attention on increasing the value of the project by spending more money upfront and improving the schedule rather than focus on minimizing the upfront capital. Scenario-based simulations along with project appraisal methods hold great promise to address those challenges and enable mine planners to make better decision and enhancing project value. This paper will present a hybrid simulation based approach to model the process of development and construction based on discrete event (DES) and continuous based simulations (CBS). Such simulations will be conducted for scheduling multiple development headings (Apex, undercut, extraction, and haulage levels). Two scenarios are utilized to investigate the impact of risks on schedule and how flexibility in construction can be incorporated to minimize delays: (1) The bench mark scenario is created based on actual data from an existing case study. (2) The flexible scenario is an alternative way to use primary production infrastructure (Ore Handling System) including conveyer drifts, conveyer belt, and a gyratory crusher in the construction process and that requires the system to be in place before starting lateral development in the footprint. As a result, a truck-load system versus a conveying system will be studied to observe the gain in construction speed and to estimate the premium cost for mucking rock from headings and drawbells and transporting it to surface. Such strategic flexibility would be part of the original budget to make the tactical flexibility available during construction. Continuous cash flow models are used to evaluate and compare the scenarios. This study is an example of how new techniques in planning can be used to support decision-making processes in block cave design.

Aug 1, 2013

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005