Search Documents

By Gaston Gingras

"IntroductionL'entretien de l'equipement minier dans les mines à ciel ouvert est une activité qui est aussi vieille que I'existence des mines et qui a progressé au cours des années pour suivre l'évolution des techniques d'exploitation. Lors de la mise en usage de s premières pelles à la va peur, celles-ci étaient généralement entretenues par I ‘équipe de quatre hommes qui était responsable de son opération. Pour les travaux plus compliqués ils utilisaient les services de machinistes qui eux savaient comment réparer Ie moteur à vapeur et couler des coussinets de ""babbit"". Les premières pelles diesel étaient entretenues de la même façon mais pour les réparations au moteur, on devait recourir au représentant du manufacturier qui était Ie seul à avoir les compétences nécessaires.Ce n'est vraiment qu ‘après la deuxième guerre mondiale que I ‘usage de l'équipement mobile s'est répandu dans les mines à ciel ouvert pour débuter les extractions selon les méthodes que I'on connaît aujourd'hui.L'entretien de l'équipement minier de façon organisée à débute avec I ‘usage de ces machines dans nos mines. Ces machines étaient un peu primitives, petites et pas très dispendieuses a I'achat. Même si la disponibilité était basse, elles fournissaient quand même un rendement qui en ces temps était acceptable. L’organisation de I ‘entretien de cet équipèrent était assez primitif et n'occupait qu'une place secondaire aux yeux de la direction de la mine."

Jan 1, 1988

By G. Barrasso

REACH was proposed by the EU Commission in October 2003 and stands for the Registration Evaluation, Authorisation and Restriction of Chemicals. It requires that all substances identified as persistent, bio-accumulative and toxic, whether the risk of those chemicals being released is real or perceived, require registration prior to them being allowed to be imported into the European Union. An internal investigation by the metals industry indicates that almost all primary raw materials streams would be classified as hazardous due to the potential health or environmental hazard properties of one or more of their ingredients. REACH uses a wide definition for chemicals and metals and as such its implications greatly impact the entire supply chain of the metals industry. The process of registration would require the producer/ importer to produce a dossier. Initiatives along the same lines as the EU REACH are also coming up in other parts of the world. REACH requires registration of at least four substances manufactured by the aluminium industry: aluminium metal, including powder, aluminium oxide, and aluminium hydroxide. The proposed legislation permits the affected companies to band together to form a consortium to develop certain aspects of the registration application. The aluminium industry has established a consortium and testing is currently underway.

Jan 1, 2006

Agenda 1.Energy consumption and energy costs ?focus and failings 2.Energy efficiency methodologies, people and supporting tools 3.Energy cost saving case studies from three minerals processing plants 4.The operations team and the supporting role of Operations IT 5.Conclusion: Reducing energy consumption and energy costs There are many good Energy Efficiency Methodologies ?Energy and GHG Emissions, Management Guidance Document, The Mining Association of Canada ?Energy Savings Toolbox ?An Energy Audit Manual and Tool, Canadian Industry Program for Energy Conservation (CIPEC) ?Lean and Energy Toolkit, Achieving Process Excellence Using Less Energy, www.epa.gov/lean ?Energy Efficiency Opportunities Assessment Handbook, www.energyefficiencyopportunities.gov.au

May 1, 2010

By O. Bernal

The Sociedad Minera Cerro Verde S.A.A, a subsidiary of Phelps Dodge Mining Company, operates a copper mining facility located in southern Peru. This "mine-forleach" operation currently produces 90,000 mtpy of copper cathode from secondary sulfide ore utilizing crushing, leaching, solvent extraction and electrowinning processes. The leach solution handling and application rates have undergone constant development over the years. This paper discusses the improvements in leach application designed to: 1) satisfy the needs of the "lixiviant request rate", which requires the use of application rates as low as 3.5 L/h/m2 and as high as 15 Llhlm2 with variable rest periods according to the leach kinetics, and 2) alleviate the poor solution distribution on the surface of the leach heaps inherent to drip emitters. Low application rates result in poor surface solution distribution and the formation of upside down cones of dry, non-leached material in the top meter of stacked ore, with heavy jarosite and iron salt precipitation; moreover, ferric iron is lost as insoluble precipitates. On the other hand, high unit flows associated with poor agglomerate quality can lead to uneven solution flow patterns within the heap leading to solution short-circuits, fines migration, and ponding with adverse effects on acid consumption and recovery.

Jan 1, 2007

By J. G. Peacey

"Canada has a special place in non-ferrous pyrometallurgy because it is the only country in the western world that is a significant producer of all the major non-ferrous metals; aluminum, copper, lead, magnesium, nickel and zinc. This large non-ferrous pyrometallurgy industry has developed because of Canada's abundant mineral wealth and energy resources. Table I summarizes the number of primary non-ferrous production facilities in Canada and their share of western world production.Production of non-ferrous metals is a mature, capital intensive business and its basic processes have been in use for many years. Nevertheless, these processes have continued to evolve in response to changing needs and external pressures; such as the energy crisis of the early seventies; historically low metal prices in the early eighties and the continuing pressure to reduce plant emissions and improve in-plant working conditions. Canada's major metallurgical companies: Alcan, Cominco, Falconbridge, Inco and Noranda have played a leading role in pioneering new process technology and continue to meet the difficult challenge of keeping their operations competitive in the global metals market. This paper will try to give an overview of the major developments in non-ferrous pyrometallurgy, largely from the Noranda and Canadian perspectives, highlighting the current status of process technology and possible future directions.AluminumCanada has the world's second largest aluminum smelting industry and its capacity has expanded rapidly in recent years with the completion of several large projects in Quebec. The location and capacity of the Canadian aluminum smelters are given in Table 2. All these plants use the Hall-Heroult process, that was invented over a century ago but over the last twenty years considerable improvements have been made to increase productivity, reduce power requirements and emissions.The developments in aluminum cell technology can be illustrated by the experience at Noranda Aluminum. In 1971, Noranda Aluminum started its first pot line using Kaiser's P69 prebake cell, which was considered, at that time, the best available technology. The P69 cell was designed primarily for high productivity, operating at 150 000 amps and high current density to produce just over tonne Al per cell-day. The P69 cell is a simple design, typically operating at about 88070 current efficiency and 15 800 kWh/tonne Al. When Noranda Aluminum decided to expand in 1980, the Alcoa 697 cell was selected as it then represented the most proven, stateof- the-art technology. This cell is similar to that installed at Alcan's new Grande Baie and Laterriere smelters and is designed to operate at 180000 amps and 93070 current efficiency, producing about 25070 more aluminum per pot-day than the P69 cell using about 15070 less power. The 697 cell has a much more sophisticated cell design, with very good balancing of the magnetic field giving a flat metal pad and allowing efficient operation at the higher amperage. Alumina is fed via point feeders that provide an almost continuous feed allowing close control of the alumina level in the bath and the use of low-ratio bath composition, giving much higher current efficiencies."

Jan 1, 1991

1.Overview of the Ministry of Energy, Mines and Petroleum Resources (MEMPR) 2.First Nations Perspective 3.Revenue Sharing Framework 4.Economic and Community Development Agreements (ECDA?s ) 5.Questions? The Ministry of Energy, Mines and Petroleum Resources (MEMPR) MEMPR manages the responsible development of British Columbia?s energy, mining and petroleum resource sectors. Through the promotion of teamwork and positive working relationships with our clients, MEMPR facilitates a climate for thriving, safe, environmentally responsible and competitive energy, mining and petroleum resource sectors. Works closely with others in Government (e.g.. Integrated Land Management Bureau) to engage First Nations in consultation processes as well as revenue sharing negotiations.

May 1, 2010

By J. R. Pronovost, P. M. Tiley, D. W. Watts

"In 1980, J.S. Redpath Limited were retained by Dickenson Mines Limited to increase hoisting capacity from 700 to 1000 tons per day. The hoisting capacity of the present skip-over-cage system could not be increased significantly through design modifications. The other constraint was a minimum of disruption to the current production. The Dickenson shaft was a three-compartment shaft from surface to the 8th level and four compartments before the 8th to the 23rd level. The solution to the problem was to remove the services from the shaft man-way compartment from the 8th level to surf ace by drilling a borehole close to the shaft and rerouting those services through the borehole to the 8th level. A service compartment would then be available from surf ace to the 23rd level.By providing a service hoist in this compartment, the skip hoist would then be free to produce the 1000-tons/day required production. This paper will describe the search for the required hoist and the friction hoist selected for the project, and trace the design modifications required to modify the hoist to suit the Dickenson application and satisfy the Department of Labour safety requirements.The paper has been co-authored by J.S. Redpath Limited and C.L. Tiley Associates, who participated in the design changes and eventual commissioning of the hoist.IntroductionIn the earl y part of 1980, J.S. Redpath Limited conducted an engineering study on the Dickenson Mines Limited No. 1 Shaft materials handling system. The object of the engineering study was to investigate the possibility of increasing the tonnage hoisted from the No. 1 Shaft complex by adding a service cage compartment and service hoist. This would permit utilization of the existing hoisting plant solely for production hoi sting. A further consideration of the engineering study was that any alterations had to be accomplished with little, or no, interruption to production."

Jan 1, 1982

By J. R. Pronovost, P. M. Tiley, D. W. Watts

"In 1980, J.S. Redpath Limited were retained by Dickenson Mines Limited to increase hoisting capacity from 700 to 1000 tons per day. The hoisting capacity of the present skip-over-cage system could not be increased significantly through design modifications. The other constraint was a minimum of disruption to the current production. The Dickenson shaft was a three-compartment shaft from surface to the 8th level and four compartments before the 8th to the 23rd level. The solution to the problem was to remove the services from the shaft man-way compartment from the 8th level to surf ace by drilling a borehole close to the shaft and rerouting those services through the borehole to the 8th level. A service compartment would then be available from surf ace to the 23rd level.By providing a service hoist in this compartment, the skip hoist would then be free to produce the 1000-tons/day required production. This paper will describe the search for the required hoist and the friction hoist selected for the project, and trace the design modifications required to modify the hoist to suit the Dickenson application and satisfy the Department of Labour safety requirements.The paper has been co-authored by J.S. Redpath Limited and C.L. Tiley Associates, who participated in the design changes and eventual commissioning of the hoist.IntroductionIn the earl y part of 1980, J.S. Redpath Limited conducted an engineering study on the Dickenson Mines Limited No. 1 Shaft materials handling system. The object of the engineering study was to investigate the possibility of increasing the tonnage hoisted from the No. 1 Shaft complex by adding a service cage compartment and service hoist. This would permit utilization of the existing hoisting plant solely for production hoi sting. A further consideration of the engineering study was that any alterations had to be accomplished with little, or no, interruption to production."

Jan 1, 1982

By K. Swedburg, M. Samuels

"The expansion of the concentrator at New Gold’s New Afton copper-gold mine in British Columbia, Canada, completed in 2015, included an increase in the required retention time of the cleaning circuit. On site pilot testing of a Woodgrove Staged Flotation Reactor (SFR) had shown that a high grade copper concentrate would be produced with excellent recovery. The SFR was selected rather than conventional tank cell technology based on the much smaller footprint (which rendered a separate and expensive building extension unnecessary), high concentrate grades demonstrated in testing, and the lower energy requirement. Three SFRs, each capable of taking a nominal feed of 700 cubic meters per hour were installed and commissioned 10 months after the receipt of order. The SFRs operate in series and all of the cells produce a final concentrate typically grading 32% Cu, while the overall SFR stage recovery averages 55%. The tailings from the SFRs are treated in the original conventional three-stage cleaner circuit where the remaining values are recovered in a concentrate grading 28% Cu. Design production was achieved within days of the initial start-up of the SFR circuit.INTRODUCTIONThe New Afton concentrator, located near Kamloops, British Columbia, Canada processes a copper-gold ore with a designed head grade of 0.96% Cu, 0.72 g/tonne Au, and 2.22 g/t Ag.The New Afton Mine is a block cave mining operation. Ore is undercut from the bottom up and removed at the extraction level from a grid of draw points. Ore is trammed to the ore passes by underground loader and dropped to a haulage level for transport by trucks to the gyratory crusher. From the crusher, the ore is conveyed to the mill via a 4.5 kilometre long conveyor system. Block caving was chosen for the New Afton deposit because the underground infrastructure could be built below the historical open pit of the Afton Mine (a previous operation of Teck Resources) and this method is favorable to large-scale low-cost mining.The New Afton deposit is a copper-gold, alkalic porphyry system. Hypogene mineralization is characterized by discontinuous copper sulphide veinlets and disseminations, principally chalcopyrite and minor bornite, along with pyrite as the second most dominant sulphide. Gold particles vary in size from 5 µm to 40 µm and occur as native gold and electrum, associated mostly with the chalcopyrite grains and never with the pyrite. In some instances, a second alteration phase has resulted in the copper sulphides being replaced by tennantite-tetrahedrite locally and along faults that transect the mineralized body. The design head grade of arsenic is 244 PPM, although the presence of tennantite is inconsistent and can vary from trace levels to 15% of the total copper. No arsenopyrite is present in the hypogene ores. Supergene mineralization, consisting of native copper with accessory chalcocite occurs in minor amounts along faults and highly oxidized near-surface portions of the deposit."

Jan 1, 2016

By Kousuke Takahata, Hirofumi Yoshimura, Jun Nakahigashi

Studies of a protium treatment for grain refinement of a + ß type titanium alloy are reviewed and recent experimental results are introduced. Protium treatment consists of the following three processes: (1) protium absorption, (2) martensitic transformation and hot working, and (3) final treatment for protium desorption and recrystallization. A combination of these processes results in the ultra-fine grains of 0.3 to 0.5 µm in diameter with high angle boundaries. The ultra-fine-grained material exhibits superplastic elongation of over 9000%. Superplastic forming was successfully used to fabricate a denture base. These materials may be widely applicable as biomaterials in various medical industries.

Jan 1, 2004

This paper generalizes open stopes into elliptical cross sections and applies the results of calculations based on the mathematical theory of elasticity to indicate stress distribution on the boundaries of such stopes. These show both compressive and tensile stresses and provide an ex-planation for the development of excessive dilution in shrinkage toping. Introduction T HE stress pattern around shrinkage stopes is identical with that around other stopes under the same physical conditions. However, a shrinkage stope ends as an unsupported open stope, and the method i limited to the stress range within which the rock is generally self-supporting. If it is acceptable to generalize the outline of a shrinkage stope into an elliptical cross section, then the graphs of Geldart & Udd (1) (see also Panek (2) and Denkhaus (3)) provide a good base for approximating the stress distribution as mining progresses. However, with failure conditions in the walls, the axis ratio, as cut

Jan 1, 1964

By Mei-Yan Yang, Ltd. Yunnan Yuntong Zinc Co., Yong-Xiang Li, Xing-Zheng Dai, Hong-Liang Wang, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"The removal of iron asgoethite from the high iron bearing solutions generated in zinc hydrometallurgy using a strong airflow device was investigated. The influence of oxygen flow, copper ion concentration, temperature and reaction time on iron precipitation as goethite was studied. The optimum conditions were: oxygen flow 0.2-0.35m3/h, copper ion concentration 0.25-0.5g/L, temperature 80-90oC, zinc oxide powder neutralizing agent and a reaction time of5to 7hours. Under the optimal conditions, the Fe2+concentration was reduced to 0.025g/L after iron precipitation, and the goethite residue contained 38.7wt.%Fe. The SEM and XRD analyses showed that the iron was present as well formed FeOOH crystals in the iron residue, and the amount of iron sulphate was very low. Production practice shows that, when the average iron concentration in the feed solution was 11.61g/L and 4.08g/L after precipitation, the weight of iron removed was 1,439kg/day. When the average iron concentration in the feed solution was 14.51g/L and 2.73g/L after precipitation, the weight of iron removed was 2,454kg/day. This represents a ~70 percent increase in iron removal.INTRODUCTIONThe objective of iron removal is to produce a small volume of iron residue, and our industrial goethite process meets this requirement. The high Fe(II) solution in our reactor isoxidized/hydrolyzed to precipitate goethite and the precipitate is sent to a pyro metallurgical furnace for final residue treatment. Some literature discusses (DengYong-guiet al., 2008;Meiguang-guiet al., 2001;Zhongzhu-qianet al., 1980) research on iron hydrolysis; one of the reported rate limiting parameters was the low availability of the oxidant when using air and another was the inhomogeneous air distribution. There are two iron hydrolysis-goethite precipitation methods; the Electrolytic Zinc process (EZ) and the Vieille Montagne process (VM) (Lei Xiang, 2006; Xuguo-qiang, 2007;ZhaoYonget al.,2005). The EZ method hydrolyzes the Fe3+directly to FeOOH. The weakness of the EZ process is the low recovery rate of the associated minor metals. The VM method reduces the iron to the ferrous state and then oxidizes the Fe(II)to Fe(III),with simultaneous hydrolysis/precipitation of the Fe(III) as FeOOH. Before iron hydrolysis, the minor metals, such as indium, could be selectively precipitated, because Fe(II)requires a high pH for hydrolysis. So the VM method has a high recovery rate for the minor metals. There levant goethite precipitation reaction is:"

Jan 1, 2016

By R. A. L. Drew, F. Jalilian, M. Jahazi

Joining of superalloy Inconel 61 7 with a foil interlayer using transient liquid phase bonding (TLP) technique was studied. Inconel 617 is a solid solution, Ni - Cr - Co- Mo alloy with an exceptional composition of high temperature strength, oxidation, carburization resistance and thermal stability. In this investigation, two bonding temperatures, 1065°C and 1150°C, and two interlayer thicknesses with joining times varying from 5 minutes to 24 hours were employed. Experiments were carried out using nickel base interlayer (A WS BNi-3) with boron as the melting point depressant (MPD) element. Joints were characterized using optical microscopy, SEM, FEG-SEM, EBSD, XRD and microhardness. The results indicated that the rate of elimination of the liquid phase with increasing the bonding temperature, holding time and decreasing the thickness of the interlayer increased. The main precipitates in the diffusion layer had platelike and blocky morphologies for both bonding temperatures and all holding times.

Jan 1, 2006

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016

By Dieter Birk

"The Atlantic Coal Institute illustrates the potential for high technology employment in Maritime Canada, by using local talent and the latest equipment to address a national market. Since I983, contract research for industry and government has generated 31 man-years of high-tech employment, added $2.3 million to the local economy and contributed new technology for Canadian coal. Industry now has access to new procedures for coal minerals analysis, pyrolysis, and geochemistry applied to industrial problems of exploration, beneficiation, conversion and combustion.Research at the Institute is market-driven, based on cost recoveries from contracts. The financial performance to date exceeds that of similar industrial research institutes in major cities and demonstrates that small isolated laboratories are cost-effective. Economic renewal of Canada's resource industries will require increased R&D which in turn can be a source of local employment and pride. Small research teams are more efficient but require an enlightened policy of contracting-out by big business and big government."

Jan 1, 1987

By H. Staton, V. Suontaka, E. Sharifi

"Flotation circuits are typically controlled using on-line elemental assays obtained from the slurry lines. In base metal applications, X-ray fluorescence (XRF) analyzers are the most common instruments for elemental analysis of the slurries. Eagle Mine has been utilizing a Courier XRF Analyzer since 2014. Typically, in XRF analysis, the sampling rate is 10-25 minutes which is good enough for manual process control. In 2018, Eagle Mine upgraded the Courier XRF analyzer with the Rapid Measurement module that is based on reflectance spectroscopy. This option reduces the sampling rate to 10-15 seconds, while maintaining the superior accuracy of the XRF analyzer. This paper presents the results from implementation of Rapid Measurement at Eagle Mine.INTRODUCTION Eagle mine is an underground mine producing nickel and copper concentrates. Eagle Mine is owned by Lundin mining and located in the Upper Peninsula of Michigan, USA. The Humboldt Mill, previously an iron ore processing facility, was refurbished in 2014 and is used to process the ore and produce separate nickel and copper concentrates. Approximately 2,000 metric tonnes of ore is milled per day. Ore is processed using a conventional crushing followed by single stage ball mill and flotation. Nickel and copper concentrate are transported to facilities in North America via rail car. A bulk copper-nickel concentrate is produced by separating the copper and nickel minerals from gangue material by flotation. The copper-nickel bulk concentrate is reground, followed by one stage of cleaning to reject further gangue minerals. The bulk cleaner concentrate is then subjected to a final flotation stage where the copper and nickel minerals are separated from one another through the addition of lime. Final concentrate grades are 14% Ni and 2% Cu in the nickel concentrate and 31% Cu and 0.8% Ni in copper concentrate."

Jan 1, 2019

Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005

By O. A. Ojo, N. Esmaeili

"The effects of brazing and use of composite powder mixture as interlayer material on hot corrosion resistance of brazed IN738 superalloy were studied. Brazing was observed to result in significant reduction in the hot corrosion resistance of the superalloy. However, application of composite powder mixture, which consists of additive superalloy powder, enhanced the hot corrosion resistance of brazed samples. It is also found that although the use of composite powder mixture increased hot corrosion resistance of brazed alloy, if the additive powder completely melts, which is possible during brazing, it can significantly reduce the hot corrosion resistance of the brazed joint. Elemental micro-segregation during solidification of the joint with completely melted powder mixture produces chromium depleted zones and consequently reduces hot corrosion resistance, since a uniform distribution and adequate chromium concentration is necessary to combat hot corrosion. This has not been previously reported in the literature and it is crucial to the use of composite powder mixture for enhancing the properties of brazed superalloys.INTRODUCTION Superalloys have been developed in response to the increasing demand for materials with higher resistance to corrosion and creep and also with higher mechanical strength at higher temperatures (Smith, 1981). Ni-base superalloys are predominantly used in manufacturing hot sections of gas turbine engine components. This is due to their high strength and corrosion resistance in extremely high temperature service environments which is typical for hot sections of gas turbine engines (Miglietti, 2009). The continuous demand for higher efficiency and output has resulted in the use of higher operating temperatures and gas pressure in modern gas turbine engines (Jahnke & Demny, 1983). Consequently, this has caused thermal and mechanical stresses which result in severe degradation and damage of gas turbine engine components due to creep, fatigue and hot corrosion (Zhang, Feng, & He, 2006). The decision to replace or repair damaged parts depends on the overall repair cost and expected life of the repaired components (Jahnke & Demny, 1983). However, in most cases, it is more cost effective to repair damaged parts rather than use a full replacement."

Jan 1, 2017

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016