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By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By J. D. Botsford

Westmin Resources Limited's H-W orebody on Vancouver Island is a copper/lead/zinc massive sulphide deposit that has been in production since 1985. The sulphur content of the ore averages 28% and in some stopes is as high as 53%. Several minor secondary sulphide dust explosions have occurred in development headings and cut and fill stopes, but as yet no known explosions have occurred in blasthole stopes. This pa:per reviews the history of sulphide dust explosions in the H-W Mine, factors contributing to the explosions and the preventative measures taken to control them.

May 11, 1988

By H. C. Gunning

In spite of the fact that mining has been more or less active in the northern part of Vancouver island since the late &apos;nineties&apos;, there seems to be a remarkable lack of information regarding the nature and development of the region. Recently the operations at the Old Sport mine of the Coast Copper Company, Limited, and spectacular copper discoveries in the vicinity of Nimpkish lake, have directed the attention of the mining fraternity to the district. The writer spent the summer of 1929 making a reconnaissance examination of the general geology and mining properties of the area between Quatsino sound and Nimpkish lake, and he feels that a short paper describing the nature and mining possibilities of the region should be of interest at this time. A more detailed account of the ?geology and of the mining properties will be published in the forth- coming Summary Report of the Geological Survey. A short paper dealing with the Nimpkish Lake district was presented at the Annual Meeting of the British Columbia Division, held recently in Vancouver.

Jan 1, 1930

By Fred W. Snow

THE mines of the Consolidated Copper and Sulphur Company, consisting of the Eust1s, the Albert, and the Capel mines, are situated w Ascot township, Quebec, about ten miles southeast of Sherbrooke, on the main line of the Quebec Central railway. Of these mines, only the Eustis is now producing, and it has been operated almost continuously for the past seventy years. Mining methods have been improved in recent years but are still old fashioned when compared with those employed in more modern and up-to-date mines. The ore is of milling grade and is mined for its copper and sulphur con-tent. Silver is present in small quantity, together with a trace of gold. The ore is mined by the shrinkage stope method. Pillars are frequently left as supports for the hanging-wall to prevent serious dilution of the ore and are sometimes recovered after the ore is drawn from the stope. Occasionally, small blacks of ore in close proximity to the shaft are mined by a cut-and-fill method. HISTORY ALBERT AND CAPEL MINES: The Albert and the Capel mines, originally known as the Capelton mine, were discovered in 1863 by George Capel (1). By the end of 1866 the Albert shaft had been sunk to a depth of 121 feet on an incline of about 30 degrees where a vein five feet thick was encountered. In 1879, these mines passed into the hands of G. H. Nichols and Company, by whom they were operated practically continuously until 1907. When mining operations ceased in that year, the shafts had reached depths on the incline of approximately 2,300 feet and 1,000 feet, respectively. These mines have been allowed to cave and fill with water and have been inaccessible for many years.

Jan 1, 1936

By S. Espley, G. Tan

"Inco&apos;s Little Stobie Mine is a low-grade nickel operation producing approximately 4()()() tons per day. Backfill has never been an economical option at the mine; therefore, the only viable type of mining in the upper zones has been by sub-level cave. This mining method allows for the draw-down of a rock cover into the empty stopes to provide stability to the over-all rock mass. In the lower areas of the mine, bulk blasthole mining methods have taken place, without rock fill, resulting in extremely large open stopes. As the mine reaches its final stage of recovery, it is inevitable that the hangingwall of the large voids will undergo tensile failure via spoiling.This paper deals with the collaborating efforts of Inco&apos;s Rock Mechanics group and the Little Stobie mining operations toward the successful recovery of the ore zone remnants such that the inevitable failure, and time of failure, of the rock mass is ""controlled"". Within the mining scheme, several key requirements had to be met to satisfy the operations: (1) production rates; (2) good blast fragmentation; and (3) secure pulling-horizons. A full-scale rock mechanics study was carried out involving: numerical modelling studies; pulling ellipse analyses; blast design, monitoring and analyses; laser profiling; and time domain rej7ectometry (TDR) instrumentation. The final recovery scheme, employing a controlled failure, involves recommendations on: (1) blasting techniques; (2) support systems; (3) mining sequences and scenarios; and (4) monitoring systems."

Jan 1, 1994

By J. Olaf Sund

"The New Brunswick gypsum and an-hydrite deposits make up part of the Windsor group in the Upper Mississippian. The present deposits were formed by surface hydration of the underlying anhydrite beds. The sub-hydrate, hydrate, and di-hydrate stages of gypsum are formed from the anhydrite by this hydration. The anhydrite was precipitated from sea water in embayments that were separated from the sea by a reef or bay-mouth bar. The anhydrite is the original form of the calcium sulphate precipitate.One gypsum deposit near Plaster Rock in northern New Brunswick was precipitated from sea water directly as gypsum, which is its present form."

Jan 1, 1960

It?s a pleasure to be with you in Vancouver today to reinforce the good work you and your companies do to develop and operationalize new technology as a lever to improve operational performance and reduce our impact on the environment in absolute terms. Although I will use the work we do at Shell to reinforce this perspective, the principles apply to all of us in this industry regardless of whether you are a producer or supplier. I?d like to help demystify the future of Canada?s oil sands based on Shell?s view of global energy developments, including forecasted demand. One of the incontrovertible truths of this era of global energy defines change as an unchangeable law of progress. Another tells us that the art of progress is to preserve order amid change and to preserve change amid order. These axioms help frame the increasingly public debate about the future of Canada?s oil sands. I hope to illustrate how Shell?s commitment and investments create positive progress that embraces change amid order in the oil sands. I?m going to spend a little time today to focus the spotlight on the future of the oil sands to help demystify Canada?s hydrocarbon energy future. To do that, I?ll identify the features of our future energy security, including three hard truths about global energy that drive Shell?s business imperatives. Then, it?s instructive to examine Canadians? current consciousness about oil sands sustainability.

Oct 1, 2009

By Larson. William

What is Lunar In-Situ Resource Utilization (ISRU)? ISRU involves any hardware or operation that harnesses and utilizes ?in-situ? resources to create products and services for robotic and human exploration In-Situ Lunar Resources ???Natural? Lunar Resources ??Discarded Materials Lunar ISRU Products and Services ??Excavation, Site Preparation, and Outpost Deployment/Emplacement ??Mission Consumable Production ??Outpost Growth and Self-Sufficiency Benefits of ISRU ??Increased science and exploration hardware (instead of consumables) ??Increased safety, crew exploration time, and self-sufficiency ??Technology spin-in/spin-offs help recycling on Earth & space economy

May 1, 2009

By P. M. STILES

Acquired in 1957, the limestone quarry of Ideal Basic Industries on Texada Island north of Vancouver has become a major supplier of high purity limestone and construction stone. Crushed limestone products are shipped by barge to various destinations along the B.C. and northern U.S. coasts.

Jan 1, 1984

By M. Board, R. Pakalnis, S. Seldon, R. Brummer

The Kidd operation mines roughly 10 000 tpd of copper and zinc ore from underground and employs about 700 personnel. In the late summer and fall of 1997, major movements in the proximity of the east wall of the Kidd open pit had been observed. The Kidd pit had been mined from 1965 to 1977 to depths of 260 m (850 ft), followed by subsequent mining by underground methods to current depths in excess of 1830 m (6800 ft). The No. 1 Mine (2600 Level to pit bottom) is approximately 90% extracted, with most of the remaining reserve between 2000 and 2500 levels. Although initial concerns centred on the stability of the pit walls, the potential ramifications of the movements to the underground were recognized and measures were implemented to ensure the safety of personnel as well as to minimize the potential damage to existing operations. In late October, damage to underground operations was observed as deep as the 2000 Level. In the final assessment, the global mobilized mass was a “wedge”-shaped hangingwall block extending from surface to about 610 m (2000 ft) below surface. The “wedge” boundaries are defined by a fault and shear zone which have continuous lengths in excess of 1070 m (3500 ft); its base by shearing through the host rock mass; and its eastern face by deep tension cracks (Fig. 1). Mined and filled excavations at the western face of the “wedge” allowed mobilization of a mass in excess of 30 M tonnes. Movements in excess of 75 cm (30 in.) per day were recorded on the surface stations that preceded the complete shutdown of operations on October 29, 1997. The evaluations in the days following the shut-down were centred on mitigation of immediate and future possible negative impacts on infrastructure and mining of the remaining No. 1 Mine reserves while ensuring the safety of the operators. This effort required the rapid assessment of the potential damage of the block movement on underground infrastructure, stope access, drainage and ventilation, as well as airblast potential due to the falling of a large block into the pit near the ventilation intake at the base of the pit. These assessments were presented in a previous paper (Seldon et al., 1999). In total, the lateral movement of the block on the ground surface was over 4.3 m (14 ft). This paper describes the detailed studies performed to understand the failure mechanism and to assess the impacts on future mining in No. 1 Mine.

Jan 1, 2000

By Saikat Chatterjee, Xintong (Brett) Liu, Kinnor Chattopadhyay

Magnesia carbon bricks are commonly used in BOFs and are generally pre-heated before the BOF goes into service. Owing to very stringent emission regulations, the BOF pre-heating process need to be controlled and optimized so that, the emission standards are met. One of the major concerns in organic emissions are its stringent limits on emission rates and total volatile emissions. In the present work, an attempt has been made to integrate CFD and Thermodynamic models to predict the emission rate of volatile organics during the pre-heating process. A one dimensional heat transfer model was developed using visual basic and then integrated with thermodynamics calculations using FactSage 6.4. The parameters that affected organic emissions were the pre heating procedure, gas composition of the burner, heating rate and type of the burner. Typical composition of MgO-C bricks and binder materials were obtained from literature and vendor data sheets. Chemical reactions between organic materials, refractory and burner gasses were considered. The model predictions indicated that certain burner conditions could destroy all organics before it exits the vessel while other conditions needed the use of an after burner at the mouth of the vessel. The model was also able to predict the organic emission rates based on the chosen pre-heating profile. This kind of predictive model will be very useful for the steel industry and enable them to justify permit limit applications and stick to the limits by fine tuning their pre-heating process.

Jan 1, 2015

By W. B. Burchall

Introduction In presenting this paper the author wishes to state that the opinions here given represent only his personal views. A general survey of the subject has been attempted, but such deductions as may have been drawn are not necessarily endorsed by the Company with which he is associated. The aeroplane as an instrument of transport is yet a novelty, for it is only twenty-five years since man first flew. This statement, by itself, may be very deceptive, for compared with the steam locomotive or even the auto-mobile, this infant in industry has made some remarkable showings. The &apos;actual performance&apos; speed-curve of aircraft plotted over a ten-year period is rising faster than the &apos;expectancy&apos; speed-curve of 1924 indicated, and it should be noted that, today, the possibilities of 600 miles per hour provoke less scepticism than did the prophecies of 400 miles per hour only a decade ago. Commencing with the remarkable achievement of raising one man into the air, aircraft with an all-up weight of 14 tons are now in daily use on the British airways, and recently a non-stop flight of 5,340 miles was accomplished in an aeroplane, without refuelling. More true than ever is the statement that the records of yesterday are commonplace tomorrow, for new ideas are today seized on and exploited to the utmost once the period of scepticism and doubt has been overcome. In fact, so many new ideas have been brought forward, during the past few years, and applied successfully in our economic life, that one may well ask if today we are not a little too impatient, too exacting in demands, forgetting that real worth-while progress -is attained by no short-cuts.

Jan 1, 1933

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By H. Oterdoom, S. Pilger, T. P. Bui, J. Rotarius

"Most FeNi furnaces used to rely on post-combustion and off-gas cooling inside the furnace to eliminate the produced CO gas, and control the off gas temperature. As furnace load, capacity, and thus gas volumes increased over the years, this led to increased instabilities that can cause problems in controlling the operation. Some of the large capacity furnaces nowadays work with partial or full combustion outside the furnace, more similar to the steel industry. Forced combustion with or without enriched air and other additions can support in controlling post-combustion, stabilizing and even reducing off gas amounts, and affecting composition. This paper presents some of the possibilities and advantages of having a specially designed post-combustion system for the FeNi laterite industry, but that could also be applied to other processes as well.Large Scale Furnaces In the FeNi industry, the Rotary Kiln Electric Furnace (RKEF) process is still going strong in spite of continuous hope that hydrometallurgical processes will one day make the RKEF plant obsolete. Within the pyrometallurgical plants there is a continuous trend for larger scale furnaces. The development for a number of furnaces that were started before 1985 and increased capacity by “natural growth” is given in Figure 1. Natural growth refers to the development of the plants that after having mastered a certain level of operation, were ready for a higher load that could be installed either with a new furnace on the same site, or during a revamp. The advantages of natural growth are numerous, for example: •,Deep knowledge of the ore and its’ behavior, no need for testing, and little risk of surprises. •,Mining, laboratory, equipment, etc. is all proven technology for the conditions on site. •,Starting a furnace with increased capacity is a re-start, not a green-field commissioning. •,Typically, when increasing the production capacity of an existing plant, not the entire plant is commissioned for the first time, but only a part. In the FeNi laterite industry for example, the kilns may already have had the capacity to provide enough material."

Jan 1, 2017

By J. E. Rowland

NIOCALITE is a new mineral species which has been identified in rock from the Oka district, Quebec. It occurs as prismatic crystals up to l 0 mm. in length and I mm. in width, in coarse, white, crystalline calcite with associated apatite, diopside, biotite, pyrochlore, and niobian perovskite. The crystals of niocalite are light yellow in col-our and have a vitreous lustre. The optical properties of niocalite (I) are as follows: Biaxial negative -2V = 56° a = 1.700, [ ] = 1.730 Birefringence y -a = 0.030 Optic orientation: X = b, Z/\c 12°, Y , /\a = 32° The specific gravity is 3.32 and the hardness is approximately 6 (Mohs scale). A detailed analysis performed on 2.4 gm. of hand-picked material reveals that niocalite is essentially a calcium niobium silicate. Table I gives the result of the analysis. Crystals of niocalite, apparently suitable for X-ray diffraction work, were selected, and single crystal photographs were obtained using both Weissenberg and Precession cameras. Initial difficulties were encountered in interpreting these films, and in correlating the crystal data with the optical data. The in-consistencies were explained by the fact that every grain examined was twinned to some extent.

Jan 1, 1957

By Paul B. Warrington

This paper presents a discussion of the factors affecting copper scrap markets, including such items as price levels, freight. grades of material, sources and packaging. Reference will also be made to the effective life and turn-around of the copper content of some products. Introduction IN TERMS OF SIZE, copper scrap is second only to ferrous scrap in tonnage recycled. However, in total value, it is second to none. For example, world scrap recovery during the preceding 4 years averaged just under 2,300,000 metric tons per annum, and at an average price of 70 ¢ a pound, this works out at a turnover of about $3.5 billion, which indicates that the copper scrap industry, or recycling as it is now becoming known , is a substantial one.

Jan 1, 1977

By Bryan Wilson

Background ?Nickel Rim South Mine started production ramp-up in Q2, 2009. ?The main dewatering pumps were put into use in August 2009. ?3 Feluwa?multisafe?positive displacement pumps ?1700m single lift pumping ?Reliability has been an issue due to the amount of slimes and fibers (from shotcrete) at the pumps. ?Critiqued internal dewatering system to solve some issues we were having with our sumps Findings 1.Much of the final dewatering system was not in place. a)Temporary pain. Difficult to say something is not working when the system was not yet in place as per design. b)Not enough capacity to handle slimes within the system. 2.Need to address issues with the final design: a)Ongoing costs: The end design has operating costs of $2.5 million b)Scoops in Sumps: The end design relies on scoops to be used for cleaning the sumps c)Slimes Recovery: The system mixes 3 different products in the sumps along with the fibers d)Pump repair costs: The existing Tsurumi pumps are too light duty for our slimes

Nov 1, 2011

By Anthony McDonald, Dominic Verhelst

"Hudson Bay Mining and Smelting Co. Ltd. (HBM&S) started up a zinc plant and smelter in late 1930, employing technology of that period. The zinc plant has since converted from a roast/leach operation to a two stage pressure leach operation to eliminate sulphur dioxide emissioms. The smelter, however, is still continuing with much of the original roaster/reverberatory furnace technology. This paper reviews the process flow of the copper smelter, with some comments on past and recent changes.Smelter FlowsheetPrior to July 1993, the HBM&S smelter operation consisted of seven areas, namely feed preparation, roasters, reverberatory furnace, converters, anode casting, fuming plant, and dust collection. A simplified smelter flowsheet is shown in Figure 1. The data for tonnage of materials moving through the circuit are presented in Tables I to 4, and are representative of the time period from July 1992 to June 1993. A change in the zinc plant technology in 1993 resulted in the elimination of a zinc-bearing sulphide leach residue from the smelter feed blend, thereby greatly reducing the zinc content of slag produced in the smelter. Consequently the fuming plant and ancillary equipment, such as the drying plant, were shut down. These areas will, however, be described. With the closure of the zinc fuming furnaces all the slag from the reverberatory furnace is now discarded to stockpile.The over-all smelter metal recoveries are 96% for Cu and rn.5010 for Au and Ag. Figures 2 and 4 indicate historical production numbers of copper, silver and gold, respectively. A review of the minor element distribution in the smelter can be found elsewhere."

Jan 1, 1994