Search Documents

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By V. Prasad, A. Afacan, K. Popli, S. Dubljevic

Froth flotation is one of the most common and widely used separation processes in the mineral processing industry; however, its complexity means that complete understanding of the process has not yet been achieved. A dynamic fundamental model is needed to enhance the understanding of the process and to improve process control. It is challenging to capture all the phenomena involved; hence, we propose a multiscale modeling approach with a framework ranging from macroscopic (equipment scale) to microscopic (attachment, detachment) models along with distribution models for ore particle sizes. Real-time froth properties are obtained using a vision-based sensing system. These measurements can be used for developing a soft sensor for grade using statistical methods such as PCR (principal component regression) and PLS (partial least squares) regression. The fundamental model is updated in real-time using extended Kalman filtering. Attachment dynamics are studied for different particle size distributions. The modeling and soft sensing is tested on batch flotation cell for the pure mineral galena with different particle size distributions using Xanthate and MIBC as collector and frother, respectively. The model, online measurements and soft sensor are useful in developing monitoring methods for froth flotation.

Jan 1, 2015

By B. K. Bhattacharyya, Morley. L. W.

"The primary purpose of conducting aeromagnetic surveys in mineral areas, and interpreting the data thus obtained, is to aid in the extrapolation of the geology from known to unknown areas-both in a horizontal and vertical direction. This paper describes one of the steps in the process of interpretation which has, in the past, been neglected-that of mathematically or quantitatively treating the data in two-dimensional map form. For this, several techniques are available.These techniques determine the downward and up-ward continuation fields, the second vertical derivatives and the fields reduced to the pole from the total magnetic field data. Second vertical derivatives and downward continuation fields increase the resolution and sharpness in the observed magnetic anomalies and tend to outline the surface traces of causative bodies with a reasonable amount of success in most cases. The 'reduction to the pole' is a mathematical process of calculating the field at the north pole from the observed field so that the un-desirable effects of the dip and declination of the earth's field and of rock magnetization are eliminated.New and accurate means of carrying out these calculations have been developed by the Geological Survey of Canada. In this paper are also presented the results of a method for obtaining the symbol and numerical map of the processed data with the help of the printer associated with the computer. The tedious work of digitizing magnetic field values in a map can be speeded up by the use of a semi-automatic coordinatograph, with the aid of which field values can be accurately transferred to punched cards."

Jan 1, 1966

By Christopher R. Davis

Resource modelling is the basis for any economic appraisal of a mining project and includes a number of steps from data acquisition and validation to resource reporting and classification. At each step in the modelling process it is necessary to define the specific objectives, the methodology proposed to achieve those objectives and to establish a set of checks and validation tools to assess the effectiveness of the proposed methodology. The data used has to be both reliable and relevant for the purpose of the modelling. QA/QC for database validation requires verification of sample location; including correct collar location, topographic modelling and down-hole surveying. Validation is also performed on assaying information such as checks for sampling bias and accuracy of core splits, proper use of pulp duplicates and standards, handling of calculated values, explicit/implicit absent data and data entry errors. The second step involves identifying the mineralized domains resulting from the mineralization process. This step requires a geometric interpretation of all relevant geological features that have influenced the spatial distribution of the mineralization including dykes, faults and alteration. In addition, a geologic reference system rather than a standard Cartesian system is established to measure distances between samples. Once the mineralized domains are established and the database has been validated, statistical and spatial description of the mineralized samples are examined in order to establish the histogram and the variogram of all variables of interest and their correlation. Results are also used to calibrate the global resource estimate within the mineralized domain and to establish the search strategy for grade interpolation. The mineral envelope is filled with polyhedral cells representing mining blocks. The average grade of these blocks is estimated using kriging techniques in order to eliminate global bias and to minimize the local error in the block grade estimate. Visual checks are made to validate the spatial trends in grade distribution while global bias and smoothing effect are assessed from the declustered sample statistics. When required, smoothing correction may be applied using ?change of support? techniques. Simulations are used to perform sensitivity analysis and the simulation models are used if severe smoothing of spatial variability makes the interpolated model inappropriate for mine planning. The keys to successful resource estimation are an integrated team of geologists, geophysicists, geostatisticians and mine engineers using the best available technology and reviews by independent auditors. The resource team is also responsible for performing a QA/QC program in order to measure the effectiveness of the methods in meeting the specific objectives at each step of the modelling process.

May 1, 2001

By Peter Chmara

The measurement of dust concentration in Ontario mines since 1926 has been accomplished by konimetry, based on South African experience and methods. The introduction of a voluntary program of semi-annual surveys of air conditions at all operations throughout Ontario mines created a need for an instrument that would assess konimeter spots rapidly and accurately. The development of the Electronic Scanner, it is felt, answers this need. A program whereby all konimeter spot samples taken at Ontario mines will be counted at the MAP AO field offices in North Bay is described.

Jan 1, 1969

By B. R. Conard

Occupational epidemiology of the nickel-producing industry has found that inhalation exposures to certain nickel-containing substances are linked to respiratory cancers and to nonmalignant respiratory endpoints. Establishing such a linkage, however, is complicated by the fact that some diseases occur long after exposure to a causal agent (i.e., some diseases have long latencies). Furthermore, most chemical agents (especially nickel substances) vary significantly in their toxicological properties and their concentrations in workplace air have varied over processing history. Because of these complications, it is critical to understand historical exposures to specific nickel substances. To assist in this effort, the author focuses on the history of smelting and its related processes at Vale Canada’s (Inco’s) Ontario operations in the first half of the 20th century.

Jan 1, 2012

Cansolv® S02 Scrubbing Technology was described in a paper in Copper/Cobre 03. Four years on, the technology is operating at a full scale production facility.Hindustan Zinc Limited expanded their capacity by installing the AUSMELT process. The process proceeds through smelting, slag reduction, slag cleaning and holding stages sequentially in the same vessel, resulting in widely varying off gas characteristics. The off gas is suitable for treatment is a conventional acid plant for a modest proportion of the day, but at other times produces off gas too high in S02 to be discharged to atmosphere. Cansolv® S02 Scrubbing Technology was identified as a means of effectively removing the S02 down to low levels from the off gas during all stages of the pyrometallurgical process. Furthermore, the Cansolv® S02 Scrubbing System Technology produces high purity S02 that allowed for the captured S02 to be directed to an existing acid plant, avoiding the capital cost of new acid making capacity.

Jan 1, 2007

By A. A. Ruitenberg, G. Ruitenberg, J. Chandra

"The Caledonian Belt is mainly underlain by Late Precambrian and possibly Early Palaeozoic rocks, which are in part overlain by younger strata. Most of these rocks are weakly deformed, except for those in some linear . zones, which have been intensely deformed by cataclasis. Mineral deposits related to two distinct metallization episodes have been recognized. The earliest are zinccopper- lead sulphide deposits, which have been concentrated in the axial regions of late-stage cross-folds within the main cataclastic zone. The host rocks are andesitic and dacitic tuffs which show effects of intense talcose alteration, silicification and chloritization. Deposits related to the second episode are mainly composed of copper sulphides with locally abundant tennantite and tetrahedrite, which occur in brecciated and fractured carbonate-quartz veins. These veins postdate the late-stage cross-folds. VLF-EM and high-sensitivity magnetics proved to be very effective in delineating the geology of these deposits."

Jan 1, 1972

By Raymond Dallaire

The Humphrey's spiral is a static gravity separation device which cannot be adjusted to match short-term variations that occur in the feed. Any disturbance in the feed grade, per cent solids or flow rate affects substantially the recovery and grade of concentrate. Such variations must be minimized in order to maintain the desired rate of production and quality of the product for which the installation has been designed. A study has been performed in which the foregoing assertions were quantified. The feed grade, per cent solids, flow rate and particle size were varied independently. Ore from Carol Lake, Nfld., was used throughout the experiments. This consisted of specular hematite and magnetite in a silica gangue.

Jan 1, 1978

By R. R. Rogers

ABSTRACT The experiments described demonstrate that crude commercial lithium containing in the order of 0.5 per cent sodium can be refined, the resulting metal containing as low as 0.001 per cent sodium. During the process, the metal is vaporized and condensed at a gauge pressure of less than 0.04 micron. Considerable operating data and a detailed description of the experimental equipment are included. INTRODUCTION DUE TO THE unusual properties of lithium metal, its use is likely to increase considerably during the next few years (1, 2). This is of particular interest to Canadians because there are important deposits of lithium-containing minerals, especially spodumene, in Canada and it is hoped that lithium compounds and lithium metal will be produced from these deposits in the fairly near future. In order to assist in the development of this industry, the Mines Branch of the Department of Mines and Technical Surveys has initiated a programme of research in lithium metallurgy. In 1948, a paper (4) was published on methods of producing lithium metal and its alloys. Data on the corrosion resistance of some lithium alloys were included. In 1949, a paper (3) was published which showed that the addition of a small percentage of lithium to zinc anodes used for cathodic protection will improve their usefulness under certain circumstances.

Jan 1, 1951

By Jean-Louis Robert

Field work inaugurated in 1962 in the townships of Lemieux and Lesseps, in the Gaspe Peninsula of Quebec, has permitted the author to delineate the lithologic units of the area, to elucidate a few stratigraphic problems and to outline several zones of alteration. Certain features of these zones and the numerous mineralized showings in the area merit the attention of prospectors and exploration companies.

Jan 1, 1966

By D. M. Maijer, S. M. Mohseni, A. B. Phillion

The microstructure evolution kinetics of aluminum alloy B206 during artificial aging has been investigated using non-isothermal calorimetry. A combination of differential-scanning calorimetry (DSC) and tensile tests have been utilized to develop an Avrami model to predict the precipitation kinetics as a function of the thermal processing parameters. The Avrami coefficients, found based on a Kissinger analysis, compare well against those reported in the literature for aluminum-copper alloys. The rapid precipitation kinetics predicted by the Avrami model at temperatures higher than 200°C were assessed through a qualitative comparison against hardness measurement results. In contrast to the continuous hardening observed at 150°C, the material softens with continuing heat treatment at 250°C resulting in an overaged state. This can be attributed to the rapid precipitation kinetics at this temperature, leading to the termination of the precipitation-hardening effects at early stages of artificial aging.

Jan 1, 2015

The introduction consists of back-ground information, of an historical and statistical nature, relating to the Thompson mine. The geological presentation is based on illustrations that are intended to provide a progressively closer look at the ore occurrence. The illustrations consist of an index map, a geological map of a 15-by 85-mile area including the Thompson mine, a series of four maps dealing with the geophysics and geology of a 6-by 4\f.j-mile area at Thompson, a mine level plan and corresponding section, two sto11e 11lans and corresponding sections, and photo-graphs and photomicrogra11hs of the various one types. T HE Thompson mine is located about 400 miles due north of Winnipeg. The ore deposit was dis-covered in February, 1956. Five years later on March 25, 1961, the Thompson production facilities were officially dedicated with the shearing of the first nickel produced at the Thompson refinery. Full production, at an annual rate of more than 75,000,000 lbs. of refined nickel, was attained later in the year.

Jan 1, 1963

By N. C. Carter, Wm. H. White, J. E. Harakal

"Of twenty-one ore deposits in British Columbia which are either in production or advanced stages of exploration, five have potassium-argon ages in a range of 165-205 m.y., eight are in a range of 44-55 m.y. and the remainder are either ca. 140 m.y. or ca. 100 m.y. old. Deposits of the oldest group have generally similar geological environments and radiometrically indistinguishable ages of magmatic and hydrothermal minerals. Deposits of the youngest group also have similar geological environments, with successive magmatic and hydrothermal events closely intermingled in time and place. Such deposits find no comfortable home in existing classifications of ore deposits. 1t is suggested, therefore, that those epigenetic deposits which can be shown by radiometrie and/or geologie means to be coeval with genetically related magmatism be designated as ""paramagmatic deposits."""

Jan 1, 1968

By Barbara Kirby

Mining Industry Human Resource Council Who we are: National Sector Council for the Minerals and Metals Sector 18-person Board of Directors Over 100 Industry Volunteers PPP - Funded by HRSDC and industry What we do: Identify national HR challenges and opportunities for the Canadian mining industry Create national solutions through collaboration, partnerships and Synergy

Oct 1, 2010

By R. T. McAndrew

Introduction Drinnan is situated in the Prairie Creek coal area in the Foothills belt of Alberta. It lies on the main line of the Canadian National railway from Edmonton to Jasper. The exact location is shown on the map (Figure I). Interest in the field was aroused by several circumstances: Its proximity to Brule and Pocahontas on the southwest and to Coal-spur on the southeast led to the belief that coal might be economically produced here. There was already at Hinton a 3 ft. 9 in. coal seam being mined by Seabolt. The coal was of very good grade, being black and shiny in appearance with well defined cleavage and a heat value of 12,000 B. t.u. Outcrops of coal had also been noticed on the north side of the Athabaska river and Fish creek. These facts led the Jasper Coal Company to investigate the field. This Company considered taking over the Seabolt property at Hinton, but, owing to the size of the seam, this plan was abandoned and prospecting by diamond drills and test pits was started two years ago in the district east of Hinton. After prospecting had been completed, the most favourable district was found to be in township 51, ranges 24 and 25, west of the 5th meridian. The Company's lease includes all or parts of sections 18, 19, 20, and 28 in range 24, and sections 10, 11, 12, 13, and 14 in range 25. The approximate boundaries of the property are the Canadian National railway on the north, Happy creek on the west, and Cache Percotte creek on the east. The lease comprises 3,100 acres, and the total amount of coal in sight is estimated at 100,000,000 tons.

Jan 1, 1931

By N. A. Duke, R. L. Carpenter

Abstract - The West Meliadine area is underlain by structurally interleaved panels of mafic and minor ultramafic metavolcanic rocks and metasedimentary rocks that occur along the northern margin of the Neoarchean Rankin Inlet greenstone belt. Three structural and metamorphic domains are recognized: (1) the easterly Wesmeg domain; (2) the central Barracuda-Ridge domain; and (3) the westerly Peter Lake domain. The Wesmeg domain is characterized by a series of southeast-trending, north-dipping, foliation-parallel panels of greenschist facies mafic metavolcanic and metasedimentary rocks. The Barracuda-Ridge domain is comprised of greenschist to amphibolite facies mafic metavolcanic rocks that define an east-northeast-trending structural grain. The Peter Lake domain consists of amphibolite facies mafic metavolcanic rocks and minor metasedimentary rocks intruded by a monzonite pluton. West Meliadine hosts the economically significant Wesmeg gold deposits, as well as other important gold showings across the Barracuda-Ridge and Peter Lake domains. The geological setting of the Wesmeg gold deposits resembles that of a break or fault zone. The Pyke Break is a major geophysical discontinuity (>65-km strike length) and is the first-order structural control on gold mineralization at West Meliadine. It is several kilometers wide and characterized by polyphase deformation and shear zone development accompanied by lode-gold mineralization. In general, gold concentration is related to quartz and iron-carbonate veining, iron sulfides (mainly arsenopyrite and pyrrhotite), and accompanying silicate alteration minerals that overprint favorable chemical and structural traps late in the history of deformation.

Jan 1, 2004

By H. W. Manley

SULPHUR, like the minerals of coal, iron and petroleum, is one of the essential materials in our modern expanding industrial civilization. Before discussing the salient features of the production of sulphur from the Canadian sour gas, it seems appropriate to outline the historical past and probable future utilization of sulphur. The ancient Greek writer Homer spoke of its "pest-averting sulphur" and the "divine purifying fumigation". Ancient alchemists found sulphur to be a fascinating and baffling material. The discovery of gun powder in the year of 1250, and its application to the art of war a, century later, made sulphur an important commodity in the progress of mankind. The initial manufacture of sulphuric acid in the year of 1736 by the Englishman Joshua Ward, established the basis of a chemical industry that today utilizes 80 per cent of the consumption of elemental sulphur. Commercial production of the chemical soda ash ( N a2C03) discovered in 1787 by the famous Leblanc Process, in-creased international demand for the element sulphur and marks the birthday of the Sicilian sulphur industry.

Jan 1, 1961

By W. T. Robson

Introduction Ground failure, violent or otherwise, is a problem to be contended with wherever underground operations are carried out. The character and extent of the failure, whether superficial or of more serious proportions, is determined by a number of factors, among which might be mentioned: the depth and dimensions of the underground workings; the types and distribution of wall rocks; structural features of the ore and enclosing rocks; the degree of metamorphism; the dip of the orebody; concentration of mining operations; the rate of mining; the history of the excavations made on the orebody in question. This last factor implies the consideration of such points as the arrangement and distribution of stoping both past and present, the current sequence of scoping, the type and effectiveness of the support used in old and current workings, and the amount and distribution of unmined parts of the lode. With such a variety of conditions, it is only natural that the situation at one place in a mine will not be the same as that obtaining in another part of the same mine and, more than likely, will be quite different in another property.

Jan 1, 1946

By W. H. Miller

Introduction In this paper we have endeavoured to present a general description of the electrical applications underground at Copper Mountain, including types of equipment used, problems encountered, and methods by which they were overcome. No attempt has been made to outline in detail the wiring of various circuits. Until recent years, the main use of electrical energy underground at Copper Mountain consisted of direct current for locomotives, trolley systems, .and signal and communication circuits. The prohibitive cost of equipment and distribution systems prevented any extensive use of a.c. beyond that commonly used for essential lighting purposes. However, in 1943 the shortage of manpower and the increased cost of labour and supplies necessitated a general mechanization programme.

Jan 1, 1951