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By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By T. C. Murphy, W. Taciuk

In 1966, the Iron Ore Company of Canada commissioned a wet magnetic scavanging plant for the recovery of fine magnetite values p.resent in spiral tailings discharged from a spiral gravity separation process. The plant includes dewatering, grinding, classification, thickening, mini-wedge screening, and primary, secondary and tertiary wet magnetic separation stages. The source of feed varies in quantity and quality, so the original design included variable operational procedures to deal with these conditions.

Jan 1, 1972

By Gwenaële Petit, Ulan Massimkhanov, Gilles Joubert

For its Zuuvch Ovoo uranium deposit in Mongolia, Badrakh Energy (partly owned by Orano Mining) is working on the prefeasibility study for exploitation by ISR (in situ recovery). As part of this project, Orano built a 2-cell (each cell is constituted of one producer well located in the center and surrounded by six injection wells in an hexagonal pattern) and a processing pilot plant that will be used to demonstrate the operability and economic viability of an ISR process. Another main objective of this pilot trial is to demonstrate the ability of Orano’s modeling tools to predict the ore behavior under given leaching conditions. To model uranium production by ISR, Orano uses HYTEC, a reactive transport computational software, which was adapted for its existing operation in Kazakhstan (Katco) to predict uranium recovery and reagent usage based on operating conditions. In order to perform similar simulations for this new deposit, Orano engaged in a comprehensive program including ore sampling, detailed characterization, and metallurgical testwork. The mineralogical conclusions were used to prepare a simplified geochemistry for the ore, in particular carbonate and reactive clay grades, uranium mineralization and penalizing elements such as pyrite. Then, bottle roll leach tests were used to characterize dissolution kinetics for smectite clays. Eventually, column leach test results such as pH, free acid, and uranium recovery were modeled on HYTEC to improve the fit of some of the dissolution kinetic parameters. Parameters fitted using metallurgical test work results will now be used as inputs for predictive model at the pilot scale, in order to anticipate operational results and help with operating decisions for production ramp up.

Jan 1, 2020

By A. J. McLaren

Introduction Gold holds an important place among the mineral products of Manitoba. In value, it ranks second only to copper, which in 1931 attained first place. The gold production increased from 23,189 fine ounces in 1930 to 102,969fine ounces in 1931. The production for 1930, worth $479,359, came almost entirely from the Central Manitoba mine. The production for 1931 was worth $2,128,558, of which $1,509,018 came from the Flin Flon mine, $528,951 from the Central Manitoba, and $83,497 from the Sherritt Gordon. The Gem Lake mine and some prospects produced $7,785. The total output of gold in Manitoba, from the first recorded production in 1917 to the end of 1931, is estimated at 178,669 fine ounces, valued at $3,693,332. The production for 1932 promises to reach a new high record, due chiefly to the stepping-up of tonnage at the Flin Flon plants and the coming into production of the San Antonio mill in May. History The Manitoba Act, constituting Manitoba a Province of the Dominion, was passed in 1870 and provided for the vesting in the Crown of all un-granted or waste lands of Manitoba, as well as for the administration of these lands by the Dominion of Canada for the purposes of the Dominion "subject to, and except and so far as the same may be affected by, the conditions and stipulations contained in the agreement for the surrender of Rupert's Land by the Hudson's Bay Company to the Crown". Included in these waste lands were large areas later prospected and staked out as mineral lands. Up to the year 1912, that vast territory extending from the 12th base line to the 60th parallel of latitude, and from the Saskatchewan boundary to Hudson bay, was part of the District of Keewatin. Although added to Manitoba in 1912, the administration of its mineral lands also remained vested in the Dominion, so that all mineral lands within the Province upon which deposits of gold ore have been found were disposed of and administered by the Mineral Lands Division, Department of the Interior, until the transfer of the natural resources to the Province of Manitoba, on July 15th, 1930.

Jan 1, 1932

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By J. D. Bosman, L. J. Gardner

"The Bushveld Complex is a large layered igneous intrusion, located in the northern parts of the Republic of South Africa. The complex hosts the largest known reserves of Platinum Group Metals in the world. On the western limb of the complex, mining of the Merensky economic horizon and UG2 chromitite layer has been conducted for many years by several mining companies, including Impala Platinum Limited. Over the past decade, Impala has planned a new generation of greenfield vertical shafts, commencing with comprehensive geological and geotechnical studies. As part of the geotechnical studies, numerous tests have been conducted to quantify the mechanical properties of the various near-reef rock types. These tests include point load tests conducted in the field, as well as uni-axial compressive strength, triaxial compressive strength, and Brazilian disc tensile strength tests conducted in specialist laboratories. The authors have compiled an extensive database containing a large number of tests for different rock types, ranging from felsic Anorthosite to mafic Pegmatoid. The database was analysed to quantify the mechanical properties and values for Mohr Coulomb and Hoek Brown failure criteria for each rock type typically exposed by mining. The paper will provide a data set of rock mechanical properties typically used in numerical modelling and other design processes. Using the significant number of tests available, data describing the variability of the various parameters will be included."

Jan 1, 2015

By M. R. KEYS

"The property is about 120 miles north of Red Lake in the Favourable Lake area, district of Kenora ( Patricia part) , Ontario. The original discovery was staked by K. Murray in December, 1927. The first development work was done by the Favourable Lake Mining and Exploration Company. In 1936 Newmont Mining Corporation acquired control of the property and developed it to production by September, 1939. Production to the end of 1945 had a value of $7,534,656 from 441,457 tons of ore, an average value of $17.04 a ton . This production was mainly from gold and silver, with lead and zinc of subordinate importance.The rocks in the vicinity of the mine trend in a north-south direction. From east to west the sequence is: (1) A dark-coloured, massive rock, presumably a flow, composed mainly of quartz and biotite. ( 2) A buff- coloured, scricitized rock locally containing quartz phenocrysts and black hornblende. This is an alteration product of the dark variety and is later than the folding. It occurs mainly within the dark rock. (3) A series of sediments comprising thin beds of greywacke, grit, quartzite, conglomerate, and iron formation. ( 4) A gabbro sill, now largely altered to amphibolite.With the exception of the buff type, these rocks dip 80°E. The buff rock has a very irregular outline in comparison with the other rocks and appears to dip somewhat more flatly east. Felsite and diorite dykes are also present. These have a general strike of S.60°E. and dip 65°S .W. A post-ore diorite dyke trending N.15°E. occurs about 2,000 feet east of the mine area."

Jan 1, 1954

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004

By P. Chryssanthakis

"The aim of this study is to give a better understanding for the behaviour of the composite material RRS and the synergy effect of its components while an excavation face advances during tunneling. The lower part of the Q-system scale (i.e. Q-values of 0.4 or less for a tunnel span of 10 m) is commonly used for tunnel applications in softer rock formations. This is implied in the updated Q-chart, where the dimensioning of rock support by using Reinforced Ribs of Shotcrete (RRS) comprises the use of fiber reinforced shotcrete, S(fr), rock bolts and shotcreted beams reinforced with steel rebars. The newest part of the lower part of the Q-chart gives more information on required support compared to older Q-system versions. The RRS can be described as a three part composite material with the 3rd component being the reinforced concrete beam (with no fibers) and with steel rebars that are placed in groups and sprayed with pneumatically applied shotcrete in layers. The RRS usually have a total thickness varying between 0.20 and 0.50 m and a width between 0.25 and 0.60 m respectively. They are placed at different distances along the tunnel axis depending on the rock mass quality.In this study, an effort has been made to simulate RRS in a numerical code and to study its behaviour in a real case study. A double tube, triple lane tunnel in weathered tuff has been chosen as reference material for testing RRS under changing load. This was done by writing a FISH subroutine which is implemented in the discontinuous numerical code Universal Distinct Element Code (UDEC) that takes into account the characteristics of the reinforced beam (height, width, number of steel rebars, and spacing) in the calculation process. A rather extensive parametric study has been run by using the same key input rock mass parameters and in situ stresses (?H/?v = 0.5), and changing only the RRS key input parameters in order to simulate the changing loads during the face excavation process in tunneling. The critical part of this numerical modelling work that is under investigation in this study, is the period just after the excavation: i.e 4 hours; 16 hours after excavation; and finally after the complete curing (28 days) of the cement based components. The RRS are installed in three consecutive steps as follows: a) the application of S(fr) on the rock surface in order to even it up for the RRS application; b) radial bolting; and c) installation of the reinforcing steel rebars, that form the reinforced beam.The results show that: a) the S(fr) is almost overloaded in the first 4 hours after application in both tunnels; b) on the S(fr) and steel rebars, the stresses, axial and shear loads, as well as moments are decreasing after 16 hours and 28 days; and c) the bolts loads are increasing with time. The observed reduction in stresses and loads in both the S(fr) and reinforced beam is surprising. A possible explanation is that tunnel arches are self-supported to a lesser extent as time progresses due to redistribution of stresses in the nearby rock mass through the radial bolts. The loads in radial bolts are increasing by almost 25%. This can be seen from the overall results as we observe an increase in maximum principal stresses, displacements, shear displacements along joints and hydraulic apertures compared to tunnel baseline that has no support of any kind."

Jan 1, 2015

By Brien A. Perry, Art Wiebert

"Many organizations which have implemented Total Quality Management (TQM) are finding that the process has either stalled or is not working so well as originally envisioned. This can be particularly evident in an engineering environment where the uniqueness of engineers and their particular culture has not been adequately considered. Winning the commitment of a highly educated group ojprojemnnJJ1s to the TQM concepts, which are often initially 5W2 as too simplistic poses special challenges.Successful TQM implementations are found among technical groups where employees have significant input into creating the new work culture, feel empowered to make changes and are well trained in teamwork. A coach who is knowledgeable in implementation problems can, when working closely with the technical teams, help them circumvent obstacles and guide them successfully through the difficult early phases. The remaining key ingredient for success is supportive management which leads the change and is both informed and appreciative of the accomplishment being made.This Paper is based on first-hand experience with common problems and results encountered in implementing TQM in an engineering environment. Described in the paper are ways of avoiding these problems through awareness of the unique nature of engineering groups, implementation planning, just-in-time training and coaching people in the TQM process. The paper concludes with a focus on the opportunities and results from a successful implementation. These opportunities and results include the benefits each engineer can realize through process thinking, empowerment and teamwork."

Jan 1, 1995

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By S. P. Lowe

Flotation testing of Flin Flon ore was started in the Denver laboratory of Complex Ores Recoveries Co. in March, 1926. There had been a considerable amount of flotation testing previously which had shown possibilities of success, and it was felt that, with the increased knowledge of flotation and the comparatively new reagents then available, flotation held out the best prospects for a successful commercial treatment of this ore. There remained available for this experimental work a small amount of the rejects from a thorough sampling of the mine and some ore from the mine dump.

Jan 1, 1930

By L. Vinnett, T. Ledezma, F. Contreras, F. Díaz

"Mass balances in secondary grinding are subject to critical constraints mainly because of the unknown load distribution from the SAG mills, the uncertainties in the hydrocyclone split estimations and the lack of flowmeters in the key streams. In this paper, a methodology to support mass balances based on the use of radioactive tracer is presented. This approach was successfully implemented in two secondary grinding circuits of Minera Los Pelambres, which operate with ball mills of 21’ x 33.5’. The method allowed the load distribution of the SAG product (secondary grinding feed) to be determined. This load distribution was used as an input in the mass balance data reconciliation.The effective residence times of solid tracers were obtained in the secondary grinding equipment, where irradiated solid was used as a tracer. The residence times were obtained from the parametric deconvolution between the input and output tracer signals. The model fitting was performed to reconstruct the normalized output tracer concentration. Effective residence times of solid tracers in the ball mills ranged from 1.9 min to 9.5 min. The use of radioactive tracer measurement in grinding circuits is a powerful tool to consolidate mass balance results as well as to characterize grinding mills.INTRODUCTIONGrinding is the last stage of the comminution circuits. At this stage, the ore particles are reduced in size by a combination of impact and abrasion, either dry or wet (Austin & Concha, 1994). The grinding equipment mostly used in industrial operations correspond to horizontal tumbling mills (Wills & Napier- Munn, 2006). Tumbling mills employ steel balls or rods as grinding media. Ball mills, which are a type of tumbling mills, use steel grinding media with greater surface area per mass unit than SAG (semiautogenous grinding) mills or rod mills (primary grinding). Hence, the ball mills are suitable to obtain the particle size required in the next separation stages (Napier-Munn et al., 1996; Wills & Napier-Munn, 2006)."

Jan 1, 2016

By J. Coffin, M. Muinonen, D. Fragomeni, R. Multani, C. Deredin

"Rejection of pyrrhotite from pentlandite is of critical importance to the economics of nickel concentrate production and the main goal of the Strathcona milling operations. A joint team of XPS, Glencore Technology and Strathcona Mill personnel executed a comprehensive program of work to develop and implement strategies for increased Po rejection with focus on challenging ores containing high feed Po/Pn ratios (> 7) and significant hexagonal Po content (> 40% of total Po). This paper describes the team results including minerology, bench-scale flotation tests, and plant validation tests and modeling that have defined the path forward to improving the metallurgical performance and economics of the mill operation. Techniques to quantify hexagonal and monoclinic pyrrhotites were developed at XPS to assess the differences in their metallurgical behavior since their flotation responses are quite different. Mineralogical tools including QEMScan were extensively used to determine mineral liberation, associations, optimum grind size, and nickel deportment into pentlandite, pyrrhotite and non-sulphide gangue. Several reagents/strategies were evaluated during bench-scale flotation testing to significantly increase Po rejection. A significant shift in the Po-Pn selectivity and grade recovery curves was achieved using several strategies including the use of DETA and sodium metabisulfite, and regrind of the rougher concentrate and rougher cleaner/rougher tails.INTRODUCTION The Strathcona Mill is owned and operated by Glencore Nickel – Sudbury Integrated Nickel Operations and has been processing Ni-Cu ores from the Sudbury Basin since 1968 (valuable sulphides: pentlandite (Pn) – (Ni,Fe)9S8 and chalcopyrite (Cp) – CuFeS2). Currently Strathcona Mill receives ore mined from two main sources in the Sudbury area and produces two concentrate streams – a nickel-copper concentrate that is shipped to the Sudbury Smelter and a copper concentrate that is sent to the Fonderie Horne (Glencore Copper, Rouyn-Noranda). The general flowsheet currently used at Strathcona is displayed in Figure 1. It is highlighted by separate feed circuits for regular grade Ni ores and high grade copper ores. The copper circuit has a preflotation stage prior to a rougher-scavenger stage, a copper-nickel separation circuit, and a pyrrhotite (Po) rejection circuit."

Jan 1, 2018

This paper presents the results of research aimed at proposing new solutions in the area of belt conveyor elements. Many factors, such as energy consumption costs, and operating costs of belt conveyor elements, including belts, idlers and drives have an impact on the operational costs of conveyors. The paper presents special tests of new materials for the bottom cover of an energy-saving belt conveyor, which decrease rolling resistance. It also presents large-scale in-situ tests of a high-output belt conveyor for the purpose of simultaneous measurements of various types of conveyor belts (standard vs several energysaving types) under typical operating conditions of a lignite surface mine. Improvements in materials used for the bottom belt covers, supported by specially developed comprehensive tests of the new types of belts have provided valuable results of various proposed solutions. Since the tests of belts were done at exactly the same time and in the same operating conditions, direct comparison of the results is valid and should lead to a substantial decrease in the conveyors? drives? energy consumption, which will improve the effectiveness of belt transport and minimize its negative influence on the environment.

Aug 1, 2013

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By H. R. Taylor

The history and development of this property is more or less familiar to nearly everyone connected with the mining industry, so that only a brief outline of the more important facts will be given in this article. In 1916, a small pilot mill was constructed by the British Columbia Copper Company at Copper Mountain, and during 1916 and 1917 test work was conducted to determine the possibility of concentrating the ore and also to work out a suitable flow-sheet. In the spring of 1917, the location of a mill site at Allen by, which is about 8,% miles from Copper Mountain, and near the Similkameen river, was decided on, and the designing of a 2,000-ton plant was then worked out by Bradley, Bruff and Labarthe. Early in 1918, the actual construction of the concentrator began, and, after considerable labour difficulties, it was completed in 1920. During this period of construction, the West Kootenay Power Company ran a 60,000-volt power line over from Greenwood, a distance of 102 miles, and also built a sub-station at Allenby to take care of the mine and mill. The concentrator was started up on October 20th, 1920, and ran until December 11th, 1920, a total of 18,354 tons of ore being milled. The results of this short period of operation were encouraging, but, due to tlie prevailing low price of copper and high wages, it was necessary to shut down until a more favourable time. During the latter half of 1923, some work was done on remodelling the mill. This work continued until January 8th, 1924, when it was suspended.

Jan 1, 1929

By Karina Forster

Open stope design depends on the ore body geometry, loading conditions and rock mass properties to estimate stope dilution and ground support requirements. Rock mass conditions for design primarily rely upon estimates of well established rock classification systems. Many sources of data exist for obtaining estimates for these rock mass classification values which include core logging, geotechnical mapping, geological mapping as well as linking one classification system to another through the use of empirically derived equations. The extent of mapping coverage can also vary significantly based on the data collection technique. This paper proposes an approach where individual components of rock mass classification systems are collected by the different available data collection techniques. Data from different rock types are also considered separately based on their alteration characteristics and general observation products. Data from the Cameco Corporation Eagle Point Mine is presented and an approach is outlined for obtaining average representative classification values for stope hanging wall characterization. The effectiveness of this approach is demonstrated through the analysis of a data base of hanging wall dilution information.

Jun 1, 2012

By James H. C. Martens

Among the many interesting problems of the pre-Cambrian of the Canadian Shield is that of the origin of certain types of gneisses which are intimately associated with the granites on the one hand and with the metamorphic rocks of known sedimentary origin on the other. The observations recorded in this paper on the structure and composition of these ancient rocks found in a small part of northern Quebec may help to lead to a clearer understanding of the way in which they were formed and also constitute a contribution to the regional geology and petrography of a district for which little detailed information is available. The area considered is located near the Ashuapmuchuan, or Chamuchuan, river about 180 miles north-northwest of the city of Quebec, and therefore well within the Canadian Shield. Although most attention was devoted to the rocks along this river from the 57th to the 70th mile above its entrance into Lake St. John, a few observations on other localities to the north and northwest of that lake will be included. The field work was done in the summer of 1924 in cooperation with L. W. MacNaughton, E. S. Roberts, and B. M. Shaub, all of Cornell University. The party ascended the Ashuapmuchuan river by canoe and spent about a month near the mouth of Stacker, or Brochet, river, the outlet of the lake of the same name, returning by way of Mikoasas river. The writer wishes to express his obligation to his associates for their co-operation in the field and for their permission to publish the results. He is especially indebted to B. M. Shaub for the photographs of rock outcrops. Professor A. C. Gill g:ive many suggestions which were helpful in the laboratory study of specimens and in the preparation of this paper.

Jan 1, 1927

By John R. Hayes, Kebbi A. Hughes, John Rowson, Peter E. R. Blanchard, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm

Uranium ore bodies contain elements within mineral phases that need to be disposed of responsibly. Solid waste can be placed in a tailings management facility (TMF) to contain the waste elements and limit interactions with the environment. It is important to understand how the chemistry of the tailings evolves throughout the lifetime of the operations that feed the TMF and after the site has been decommissioned. The objective of our collaboration with Orano Canada was to study how the tailings from the TMF located at McClean Lake, Saskatchewan change over time. This manuscript discusses our use of X-ray absorption spectroscopy (XAS) and X-ray microprobe to study the fate of Mo and Ca in the tailings. Mo is considered an element of concern (EOC) and it is necessary to determine if a stable solid Mo-bearing species forms. Thermodynamic modeling suggested that aqueous Mo would precipitate over time as powellite (CaMoO4). Comparing Mo K-edge XAS spectra from the solid tailings to the aqueous Mo concentration in the pore water showed that powellite did form and that this did result in a decrease in the aqueous Mo concentration over time. Further, it has been proposed that Ca2+(aq) can react with bicarbonate ions in the pore water and precipitate as calcium carbonate (e.g., CaCO3). This reaction would limit the aqueous bicarbonate present in the tailings that could react with uranyl ions to form soluble uranyl-carbonate complexes. We have identified several trace Ca-bearing species, including carbonates, in the tailings using XAS and X-ray microprobe.

Jan 1, 2020