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By Meifeng Zhi, Yuqing Niu, Xixin Chang, Fengqi Zhao, Weimin Qiu, Hao Wang, Zhenqian Wen, Zujun Shu

An applicable Eluex process was developed for acid in-situ leaching (ISL) uranium mine in Bayanwula. In this process, uranium was adsorbed with strong base anion resin from the pregnant solution, then the loaded resin was eluted by sulfuric acid. After D2EHPA extraction, the concentrated eluate was enriched, and the loaded organic phase was stripped by sodium carbonate. The yellow cake was obtained by sodium hydroxide precipitation at last. The uranium concentration in the loaded strip solution was 52.8 g/L. Parameters of the process were determined, and the impact of the Eluex process in underground leaching was also investigated. In industrial design, 95% of raffinate went back to elution and 5% back to in-situ leaching. No significant effect on uranium leaching or resin adsorption was found.

Jan 1, 2020

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

By A. Klingberg, M. Svensson, N. Smolko Schwarzmayr

"Removal of silicates and carbonates from sedimentary phosphate ores by the use of new synthetic collector/formulations was investigated in a comparative study with traditionally used collector systems as references. In the direct carbonate flotation the new formulations showed higher efficiency, contributed to an improved balance of P2O5 recovery and P2O5 enrichment in the recovered material. Efficiency of the new formulations containing synthetic surfactants was 1.5–2 times better than potassium salt of fatty acid sulfonate based formulations that are traditionally used for that purpose. The new formulations also provided up to 7% increase in P2O5 recovery at the same P2O5 grade. The new synthetic collectors for removal of silicates showed extremely good selectivity towards silica bearing minerals. The selectivity factor for the flotation tests when new formulations were used was 32–52 and for the flotation tests with the traditional collectors: 20–32. The ratio between distribution of an amount of silicates (as SiO2) and distribution of phosphate in the froth (waste) is defined as the selectivity factor. The new formulations provided more than 2% decrease of the amount of SiO2 at the same P2O5 recovery.INTRODUCTIONPopulation growth and decrease of arable land are the main reasons for constant increase of consumption of apatite (phosphate ore) in the fertilization field (Lannefors, Gorochovceva, Klingberg, Lima, & Gustafsson, 2015). Fertilizers play a key role for farmers to produce more with less land. The phosphate component of the fertilizer is vital for producing healthy and large amount of crop. As a result the demand for phosphate rock is growing.The largest producers of phosphate rock are the Unites States, Morocco, Tunisia, China, Russia, and Brazil. The term “phosphate ore” includes all phosphate-bearing minerals and rocks, but only two of them are of industrial interest: apatite (igneous origin) and sedimentary phosphate (Peres, Araujo, El-Shall, Zhang, & Abdel-Khalek, 2007). The majority of the world’s phosphate deposits are of the sedimentary type. There are two different types of sedimentary phosphates: siliceous and carbonaceous which are categorized based on gangue minerals (such as quartz, carbonates, mica, and clay)."

Jan 1, 2016

By X. Xu, J. K. -W. Wong, J. -Y. Delenne, K. Soga

Hydraulic fracturing (HF) is a mulit-scale and multi-physics process which makes numerical modelling challenging. Conventional numerical models focus on multi-physics nature of HF but the multiscale nature is compromised by idealization of reservoir to be continuous, homogeneous and isotropic. However, natural fractures take a significant role in the success of HF for exploration of unconventional resources like Shale gas. Advancement in microseismic monitoring provides useful data for simulation in a much greater details. There is an urgent need to develop a suitable numerical tool for multi-scale threedimensional simulation to better understand the roles of discontinuities and heterogeneity in reservoir and its interaction with HF, especially to address the environmental concerns such as induced seismicity. In this paper, a simple discontinuum numerical method – Lattice Element Method (LEM) is proposed to model HF in a large scale three-dimensional model. A reservoir is modelled as a lattice network composed of 1D Hookean’s spring. Fracturing is modelled simply by removing lattices that meet a specified threshold as determined by the critical energy release rate of the rock. By introducing disorder in the model, mesh dependency in modelling fracture growth is minimized. Fluid flow is simplified as flow in pipe network and the permeability of pipe is related to fracture aperture by cubic flow law. Therefore, fracture flow and rock deformation are fully coupled. In this paper, four simulations of the same configuration except with different degrees of reservoir heterogeneity are presented. Fractures formed are diffusive and two groups of fracture are identified – connected fractures and isolated fracture without clear spatial correlation. The former forms a ‘fracture cloud’ and contributes to fluid flow and modeled by pipe network. The flow of fluid is highly tortuous and pipe network is sparely connected. The degree of reservoir heterogeneity controls the growth of ‘fracture cloud’ and pipe network. Microseismic monitoring often shows diffusive fracturing during HF on site and hence the outcome of the proposed model can be compared to such monitoring results.

Jan 1, 2015

By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

By Y. Luo

The rock breakage process in drilling is a main source of noise in roof bolting operations, especially when hard rocks are encountered. Proper control of drilling operation can provide an opportunity to improve energy efficiency of drilling and to reduce noise and heat generated from bit-rock friction. Drilling tests have been conducted in laboratory settings to confirm this noise-reduction strategy. Preliminary results show that the drilling parameters, penetration and rotational rates can be controlled to achieve in a desirable range in drilling medium hard rock. Based on the theoretical and experimental studies, rational drilling control strategy is developed for noise control while maintaining a safe and productive roof bolting operation. Applying this strategy in underground roof bolting operation, the noise exposure of roof bolter operators will be significantly reduced.

Aug 1, 2013

By Fabio Terzi

In this investigation some preliminary results are reported about the electrochemical oxidation of CO using goldbased encapsulated nanoparticles grafted on conducting substrate. The investigation has been planned in four steps: 1. production of Au(111) substrate and modification with self assembled monolayers; 2. synthesis and embedding of nanoparticles; 3. grafting of encapsulated nanoparticles on electrode substrates; 4. investigation of CO electroxidation on the modified electrode. The systems were characterized by means of various techniques (spectroscopic, microscopic, and electrochemical methods), obtaining information about SAM's structure and morphology, size and composition of nanoparticles and electrochemical behavior of modified electrodes.

Oct 1, 2003

By A. V. Tarasov

There are still a number of copper smelters in the world using the roasting and smelting process flow diagram for treating sulphide raw materials. The technical, economic and environmental performance indicators of such operations are inferior to the respective indicators of advanced processes. First of all with respect to copper and sulphur recovery: 95% and 75% as compared with 98% and over 90%, respectively. Based on the studies of the single-stage smelting process to produce white metal and blister copper conducted during recent years an analysis of the feasibility of roastingsmelting technology improvement was carried out in the Gintsvetmet Institute to substantially increase the copper and sulphur recoveries. On the basis of this analysis, it was proposed to modernize the technology and equipment within the framework of the existing process flow-sheet. The proposed modernization implies an increase in the roasting temperature; higher desulphurization degree in the process of roasting; a number of modifications in the roaster design depending on the particular conditions of a given operation; addition of lime flux to the feed charge to roasting; and transition to combined calcium-silicate smelting slags. The metallurgical and energy computations made have indicated that the proposed modifications of the technology will improve the copper and sulphur recovery up to 98% and 90%, respectively. The required capital investments have been estimated using as an example a particular copper smelter, the payback period determined taking into consideration additional output, fuel saving and a reduction in fines for sulphur emissions. For comparison, the capital cost of a smelter modernization is given for change-over to basically new autogenous Ausmelt, Outokumpu and V anyukov smelting technologies.

Jan 1, 2007

By R. Vergunst, E. A. Devuyst, G. Robbins

"INTRODUCTIONThe Inca process for continuous cyanide removal from industrial wastewaters was patented in 1984 by G.J. Borbely, et.al. (1). The process requires SO2, air, lime and a copper catalyst. Both free and complexed cyanide are oxidized to cyanate in the pH range 8 to 10. Cyanide bound to iron is removed by precipitation as a ferrocyanide insoluble salt and other base metals are removed as hydroxides.The process was piloted in 1982 on barren bleed solution at Campbell Red Lake Mines Ltd., Ontario (2). Since 1982, the Inca SO2-air cyanide removal technology has been applied in twelve commercial installations. The process has significant advantages over other commercial processes in the completeness of cyanide removal and lower reagent requirements and costs.COMMERCIAL INSTALLATIONSBy the end of 1988 Inca will have applied its patented cyanide removal technology to twelve commercial operations. Three of these, namely Scottie Gold Mines, Dupont of Canada Expl. Baker mill and Carolin, all in British Columbia, Canada, have ceased cyanidation operations but SO2-air cyanide destruction results were good for all mills, particularly so for over two years for the Scottie mill.Removal of cyanide from CIL slurry tailings is applied at Equity Silver (9,500 tpd) and Inca's new 1,200 tpd mill at Inca/Golden Knight. Detoxification of CIP tailings is carried out by Colosseum California (3,600 tpd) and Canamax's Ketza River operation (360 tpd). Repulped tailings from Merril-Crowe flowsheets are treated at Total Erickson's Mount Skukum mill (300 tpd) and Skyline's Johnny Mountain mill (200 tpd) and barren bleed at Inco/Queenston's McBean mill (500 tpd). Lynngold's MacLellan mill (1,800 tpd) treats pond supernatant water. Plating shop cyanide effluents are decyanized at Kuntz Electroplating in Kitchener, Ontario. Many of the above commercial operations were described in some detail in previous publications (3,4). Typical installations are described in this paper. A summary of operating results is given in Table 1."

Jan 1, 1989

By P. -A. Bosse, J. Robitaille, P. Blatter

The LaRonde ore is a Cu-Zn-Pb ore with gold (3-4 g/t) and silver (60-100 g/t). The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation. Subsequent to a recent mill expansion, excessive gold was reporting to zinc concentrate with a concurrent decrease in gold to copper concentrate. Owing to the higher return obtained from the metal, the mill endeavors to recover additional gold and silver to the copper concentrate and minimize the placement of precious metals to the zinc concentrate. A gold deportment study showed that the gold occurs mainly as küstelite, with a moderate amount of electrum and a minor amount of native gold. It also showed that various sulfur-based Au-and/or Ag-bearing coatings on liberated küstelite and electrum were the major mineralogical factors that caused gold and silver to report to zinc concentrate. By frequency, such coatings were observed on 70-80% of total liberated gold particles reporting to the zinc concentrate. Based on the gold deportment and the chemistry of the coatings, the collector chemistry was reviewed and a new collector was added into the circuit which resulted in a significant increase in gold and silver recovery to the copper concentrate. The information obtained from the mineralogy confirmed and guided other process optimization. In this paper, the authors will describe the process mineralogy of the LaRonde ores, and in particular, the mineralogical evidence diagnosing the problem. Reference will also be made to the rationale behind how the problem was solved, the results achieved, and future steps in optimization.

Jan 1, 2005

By S. Kaiman

This paper describes flotation test work conducted over the past several years at the Mines Branch, Ottawa, on the radioactive quartz-pebble conglomerate ores of the Elliot Lake area of Ontario. The purpose of this work has been to produce a uranium flotation concentrate for sub-sequent leaching operations. The results of earlier investigations are summarized and correlated with the results of mineralogical studies of the ores and flotation products. The results of recent pilot-plant investigations by flotation, as well as by gravity concentration followed by flotation of the gravity tailings, are given. The principal collector used for uranium flotation was a tall oil fatty acid, and the indicated total cost of all reagents ranged from 21 to 31 cents per ton of ore treated.

Jan 1, 1966

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By Luino Jr. Dell'osso, Richard L. Every

The enormity of the methane-in-coal problem is discussed, with a brief summary of the state-of-the-art. Laboratory techniques and data on the desorption of methane from Pittsburgh seam coal are presented and discussed and include the effect of time, temperature and vacuum. Under laboratory conditions, it was possible to displace 90 per cent of the residual methane by flooding the coal samples with carbon dioxide. Carbon dioxide was found to be three times more effective than air and almost five times more effective than helium.

Jan 1, 1972

By H. R. Shakeri, R. Mayer, M. J. Worswick, A. Rahem

The current focus of research and development in transportation industry is to use lightweight materials such as aluminium alloys for more structural components. In this regard, maintaining safety of the passenger and vehicle is the most important; therefore crashworthiness of components made of lightweight materials must be evaluated prior to sizable application of these materials. The focus of the present study is to understand failure and damage mechanisms during the axial crushing of aluminium tubes made of A1Mg3.5Mn alloy of 2 and 3.5 mm thickness. Due mainly to complexity of the crushed tubes, a microstructural approach is considered. In this study optical, stereo as well as scanning electron microscopy techniques have been used to study damage and failure mechanisms in these types of tubes, which are essential energy absorbing components in passenger vehicles.

Jan 1, 2006

By V. Bazhko, V. Yahorava

The calcium sulphate waste stream of the wet phosphoric acid process, commonly called phosphogypsum (PG), contains the majority of rare earth elements (REE) initially present in the apatite feedstock. Mainly light and middle REE are present in PG and their total concentration ranges from 0.27% to 0.35% by mass. Worldwide, around 7 billion tonnes of PG have been produced to date at a current growth rate of 150-200 million tonnes per annum. In total, an estimated 21 million tonnes of REE are locked in PG waste dumps around the world. Due to the value of the REE contained in PG dumps a number of processes have been devised for their recovery. The majority of these processes applied complete or partial gypsum dissolution, but were deemed not viable due to high capital and operating costs. Mintek developed an alternative method for the recovery of REE from PG by applying Resin-in-Leach (RIL) technology. This technology was tested on PG sampled from dumps and current arisings from South African phosphoric acid production plants. The extensive testwork program included evaluation of various lixiviants and optimisation of lixiviant additions, optimisation of REE leach and adsorption conditions, batch equilibrium and kinetic adsorption tests, continuous RIL testwork and numerous variability tests. It was found that PG from different sources was highly variable, both in terms of REE recovery as well as physical properties of the material such as viscosity and filterability of the slurry. The recovery of REE varied from 15% to 80% depending on the origin of the samples. A high-level economic study indicated that at a price of >21 $/kg for mixed REE oxide product in conjunction with an overall REE recovery as low as 15% the economics of REE recovery from PG via RIL technology may already be favourable.

Jan 1, 2016

By Boris Yacksic, R. W. Bruce

"The flotation of a cassiterite ore with oleic acid will recover primary or rougher concentrates assaying over 10 per cent Sn, with a recovery of 80 to 90 per cent. These rougher concentrates cannot be up-graded to a marketable grade by normal reflotation. Experiments were conducted on low-grade tin ores, and a process was developed for up-grading the rougher flotation concentrates by a reverse flotation technique. The process was tested on a number of samples of ore from the Catavi mine in Bolivia. The results of these tests showed that a concentrate assaying 40 to 60 per cent Sn could be readily produced, with a recovery of 60 to 75 per cent of the tin in the ore."

Jan 1, 1967

By E. M. De Souza, J. F. Archibald

This paper examines aspects of Canadian mine backfilling operations that may be implemented to assist in reducing solid waste production, lowering energy costs, and restricting Greenhouse Gas emissions. Many Canadian underground mines use backfill to mitigate environmental effects associated with tailings disposal. Backfill production and disposal are energy intensive processes that require an average energy cost of 37.7 MJ/tonne of backfill to complete. Mine backfills, in engineering applications, also commonly make use of cement as a stabilizing agent. Cement requires an additional energy cost ranging between 4,637 and 6,600 MJ/tonne to produce. The large energy needs associated with mine backfilling and cement production operations create significant CO2 and Greenhouse Gas emissions. Approximately 1 tonne of CO2 and Greenhouse Gas is emitted for each tonne of Normal Portland Cement produced. For single mines producing 3,000 tonnes of backfill per day, considering both backfill and cement emission source terms, total emissions of CO2 ranging between 120.36 tonnes and 169.44 tonnes/day are anticipated. In Ontario, mining operations contribute 700,000 - 840,000 tonnes/year of CO2 and Greenhouse Gas emissions to satisfy backfill cement consumption needs alone. Potential reductions of cement in backfill would significantly reduce emission of these gases and lower their adverse environmental impacts. This paper identifies alternate, equally effective and lower cost binder agent strategies for cement in backfill that may lead to cement consumption reductions. Post-consumer glass represents one such potential alternative backfill binder. Over 950,000 tonnes of glass are disposed of annually in Canada, two-thirds of which exists in the form of easily recoverable glass packaging that is not currently recycled or reused. The partial replacement of cement by waste glass may address goals for reducing non-recyclable glass waste disposal; enhancing mine back filling operations; reducing total backfill energy costs; and ultimately reducing Greenhouse Gas emissions levels currently generated by the Canadian mining industry.

Jan 1, 2004

By I. M. R. Duarte, J. A. Rodrigues-Carvalho, F. R. S. Rosa, A. B. Pinho

"This paper aims to contribute to the knowledge of the mechanical properties of the shales and greywackes which constitute the flysch-type deposits of the Baixo Alentejo Flysch Group, in the south of Portugal. These formations are flysch-type deposits constituted by sequences of usually thick greywacke beds alternating with thin shale beds, which include sometimes intercalations of conglomerate beds. All the sedimentation of these flysch formations was controlled by tectonics. At the same time, should have occurred along with the first Hercynian deformation phase, a low-grade metamorphic event (chlorite zone), that affected these flysch deposits. This study highlights the influence of anisotropy and heterogeneity of these flysch rocks on their physical and mechanical characteristics. The anisotropy verified in some physical properties and on mechanical properties, due to the foliation makes difficult the sample preparation for the laboratory tests. Besides, it induces a scattering of the properties values measured, as for example, the strength and the deformability. The heterogeneity is related to the main features of these geological formations, which are constituted mostly by thinly stratified greywackes and shale beds, which sometimes may affect the results of the laboratory tests making them less representative. The study is made by using both shales and greywackes that constitute these flysch-type deposits in order to evaluate their geotechnical properties, mainly of the shales. Samples of these two rock materials, are tested accordingly a laboratory testing programme, which includes which included mineralogical analysis (X-ray diffraction), physical tests (bulk density, porosity, and void index) and mechanical tests (uniaxial compression, and deformability tests). INTRODUCTIONOne of the factors that most influence the geomechanical behavior of rocks, as well as rock masses is the anisotropy. The word anisotropy comes from two Greek words ""anisos"" (meaning uneven) and ""tropos"" (meaning direction). A body or material is considered to be anisotropic, where the same property has different values depending in which direction it is measured, therefore, an anisotropic material is one whose magnitude of the properties depends on the direction in which these are studied or measured. Otherwise, it is about an isotropic material. However, the fully isotropic materials are quite rare in nature."

Jan 1, 2015

By E. Godin, M. Rigaud, S. C. Panigrahy, I. Malinsky

"RésuméDes boulettes de concentres d'hématite spéculaire à basse silice ont été produites en substituant la bentonite par de la tourbe, adéquatement traitée, additionnée d'une faible quantile de soude caustique durant le boulettage. La réductibilité de telles boulettes et leur gonflement pendant la réduction ont été évacues, en utilisant quatre mélanges gazeux différents, formes de H2 - CO - N2.L'influence du pouvoir réducteur du gaz utilise, sur le gonflement des boulettes, à été mis en évidence. Quelles que soient ces conditions réductrices, les propriétés mesurées sur les boulettes liées a la tourbe sont comparables aux propriétés obtenues avec des boulettes traditionnelles liées à la bentonite.ABSTRACTAdditions of peat moss and small quantities of NaOH during balling of low silica specular hematite concentrates have eliminated the need to use bentonite as a binder. The reducibility and swelling of such pellets have been evaluated using four different gas mixtures, consisting of H2 - CO -N2. The influence of the reducing power of the gases, on the swelling behaviour of pellets has been documented. Under the different reducing conditions, this new type of pellets exhibit properties similar to the ones obtained using bentonite."

Jan 1, 1987

By Andrea R. Gerson, Roger St. C. Smart, Russell Schumann, Joan E. Thomas, Warwick Stewart, Stuart Miller

Sequential Net Acid Generation (NAG) accelerated oxidation testing using peroxide was carried out on single sulfide mineral samples. The calculation of the nett acid production potential (NAPP) assumes that all the sulfide is present as pyrite and that dissolution results in a 2:1 ratio of H+:SO42-. NAPP as kg H2SO4/t is calculated as 30.6 x wt.% S present. To test whether this calculation is valid a NAPP* value was defined in which instead of using the wt.% S present for the calculation the wt.% S dissolved is used. Stoichiometric analysis of the dissolution products of the sulfide minerals as they would occur at pH 7 indicates, that in all cases, the ratio of H+:SO42- of 2:1 is viable. The NAG to pH 7 and NAPP* closely coincided for pyrite, bornite, chalcocite and covellite. For the three Cu-containing minerals, the NAG to pH 4.5 value was 0 as is predicted on the basis of the speciation likely to be present at pH 4.5. Acid generation is due to hydroxylation of the dissolved Cu between pH 4.5 and 7.0. The NAG to pH 7 and NAPP* values for chalcopyrite, arsenopyrite and pyrrhotite were in reasonable agreement but were not for either sphalerite or galena. Zn is not completely hydroxylated at pH 7 as is assumed by the calculation. For galena, surface analysis identified polysulfide formation on of the leach residue polysulfide. The formation of polysulfide is an acid consuming reaction. Therefore under conditions of accelerated oxidation the NAPP value is a reasonable estimate of the possible acid production in all cases except for sphalerite and galena. However, under conditions of less intense oxidation, for instance in columns, waste rock and tailings dumps, the formation of polysulfides is likely to be more widespread thus reducing the correlation between NAPP and the maximum possible acid production.

Jan 1, 2004