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By R. Stauber, B. Friedrich, S. Hilgendorf, G. Homm, C. Gellermann

Due to recent regulations limiting tolerated lead concentrations in copper alloys, new recycling strategies have to be considered. This study investigates the suitability of technical approaches in order to recycle leaded copper alloys exemplified by CuZn39Pb2 and produce an alloy in compliance with future lead regulations in the European Union. Three pyrometallurgical methods are considered to achieve this goal, namely vacuum distillation, intermetallic precipitation and fractional crystallisation. The impact of essential process parameters i.e. pressure, temperature, time, atmosphere and quantity of additives are identified using thermochemical and kinetic modelling. An experimental implementation reveals a general suitability of all three refining processes. However, the individual efficiency of the different methods strongly differs. Thus, a detailed assessment is carried out in order to provide an evaluation on the efficiencies of these methods from a technological, economical and environmental point of view. Taking a possible industrial realisation into account, the authors recommend the approach of vacuum distillation, although the energy demanded is comparatively high due to the enthalpy of evaporation for zinc, or rather, lead. However, required lead concentrations can be reached quickly without introducing an external element to the material. The prediction of selectivity and evaporation speed, which are immanent variables for a successful implementation, can be validated experimentally. INTRODUCTION In 2016 approximately 1 million tonnes of leaded copper alloy semi-finished goods with an average lead content of 2.1 Ma% have been produced in the European Union (EU). The global production in the same period exceeded 5.5 million tonnes, while the lead concentration has stayed constant at around 2.4 Ma% for the last 50 years. Up to 80 % of the current production volume is covered with end-of-life scraps, which are used for direct re-melting, depending on the alloy composition. Lead has been a popular alloying element in copper alloys in general, and in particular in brass due to its positive impact on various mechanical, physical and chemical properties, especially machinability. Health and environmental concerns were drivers for many governments to implement limitations on lead. In order to further utilise the resource potential of leaded copper scrap, it is inevitable to develop methods to efficiently eliminate lead from circulation as far as possible. (Glöser, Soulier, & Tercero Espinoza, 2013; Soulier, Glöser-Chahoud, Goldmann & Tercero Espinoza, 2018)

Jan 1, 2019

When selecting a method for monitoring crack growth in pipeline steel, the sensitivity or crack-size resolution plays a dominant role. Even though there are several visual and non-visual methods, the direct current potential drop (DCPD) method is very effective for monitoring crack growth because of its resolution. This method has been used for the past few decades and has gained increasingly wide acceptance in fracture research as one of the most accurate and efficient methods for monitoring the propagation of cracks. Furthermore, most R&D experience has proven that the electrical potential method can be used in most "aggressive" environments. For these reasons, the DCPD method was selected to design a testing machine to monitor corrosion fatigue crack growth. The use of finite-element modelling is shown to facilitate the application of the DCPD method for monitoring crack growth in steels. The 2D model calibration provided a good description of the test data and proved more accurate than the analytic Johnson's formula.

Jan 1, 2005

By M. H. Rana

"A survey of our knowledge in the field of rock mechanics is presented from the viewpoint of applications in the mining industry. Aspects of rock mechanics of special interest to the industry are enlarged upon, with emphasis on the avoidance of over-generalization. The relationship between fundamental and practical rock mechanics is discussed, and the need for cooperation between the university and industry to further our knowledge of -useful rock mechanics is emphasized. An attempt has been made to establish the scope of rock mechanics, as applied to problems in the mining industry. This is brought about by projecting rock mechanics as a tool to be intelligently used rather than magic, capable of producing ""miracles."" Continued education is important for individuals engaged in the application 0f rock mechanics in the mining industry. The scope of this education is discussed from a viewpoint of better communication between industry and the education and/or re-search establishments engaged in this work.Finally, the dangers of over-emphasis on rock mechanics are mentioned, but a justification of the in-vestment in rock mechanics programs in mines is also presented."

Jan 1, 1966

"RÉSUMÉOn discute les principales sources de dilution au cours d’une exploitation souterraine. Les différentes définitions de la dilution en usage sont analysées. Une nouvelle méthodologie de calcul simplifiée et facile à utiliser dans la pratique minière est présentée. Cette méthodologie permet de remplacer les différentes expressions analytiques en usage par les deux facteurs de dilution seulement : un «facteur de dilution planifiée» lié à la sélectivité d’abattage au niveau de la planification minière et un «facteur de dilution additionnelle » permettant de juger de l’efficacité du contrôle de terrain et de la dilution pendant l’exploitation souterraine. L’application de cette méthodologie donnerait un outil nécessaire aux niveaux de la planification, du suivi des travaux d’exploitation et d’éventuelles études comparatives des coûts entre les différentes situations minières.ABSTRACTThe principal sources of dilution during underground evaluation and mining are discussed, then definitions of ore dilution currently in use are analyzed. These definitions vary depending on the authors. A new ore dilution evaluation methodology is proposed, replacing the ten different analytical expressions by only two: the planned dilution factor related to the stoping selectivity, done at the mine planning level, and the additional dilution factor related to the efficiency of the dilution control measures during stoping operations. The conclusion shows that the use of this methodology would be a definitive asset in planning, in stoping operations follow-up, and in future costs comparison studies between mining operations."

Jan 1, 2001

By H. A. Kramer

The Flin Flon mine is at present hoisting 5,000 tons of ore daily. In 1943, a peak production of 6,188 tons daily was maintained. Before discussing secondary blasting, it is felt that a short review of stoping procedure will be of value. A list of papers dealing with various phases of the mining operation is appended. Stoping Practice Stopes vary in width from 30 to 150 feet, in length from 200 to 450 feet, and in height from 200 to 500 feet. A typical stope would be 300 feet long, 300 feet high, and 90 feet wide. The dip of the orebodies varies from 60° to vertical, with an average of 82°. The ore is heavy, having a specific gravity of 4. Both sub-level benching and radial drilling are practised. Blast-hole diamond drills are responsible for 85 per cent of the total production. Two sizes of hole are drilled at present, 11 7 6 -inch and 1%-inch. For bench drilling, the burden on the 1 7/16-inch hole is six feet, with holes on 8-foot staggered centres; in radial drilling, the burden is six feet, with nine feet between the toes. The burden on the l 5/8-inch hole is eight feet with holes on 11-foot centres, or 13 feet on the toe of fanned holes. Holes are blasted with two No. 8 instantaneous electric caps per hole, using 403 Polar Forcite. A powder charge of 0.15 pounds per ton is used, with a tonnage factor of 5 and 6.4 per foot drilled for the two sizes. Two rows of holes are blasted together. Fragmentation is satisfactory with the above drilling pattern and powder charge. However, some overbreak and fall-off locally results in oversize material. It is estimated that, after primary breaking, 75 per cent of the ore will pass through the grizzly openings and 15 per cent will pass the draw points, leaving 10 per cent that must be broken further to pass the draw points.

Jan 1, 1946

By R. J. A. Fricker

IT is the purpose of this essay to give a reasonably complete description of shaft sinking under a rock pentice in a small Northern Ontario gold property. Hallnor is in many ways an exceptional mine, but the sinking operations here described are but typical examples of the excellent practice for which Canadian mines and mining engineers are justly famous the world over. The worth of the subject lies, therefore, nor in its originality, but in its soundness; not in the spectacular, but in the economical and safe. Attention is particularly drawn to the excellent safety record and to the exceptionally low overall sinking cost. INTRODUCTION Prior to April, 1939, the Hallnor No. 1 shaft had been sunk vertically to a depth of 997 feet below the surface. It is a three-compartment shaft, 19 ft. 10 in. by 7ft. 7 in. outside the timbers (see Figure 1).

Jan 1, 1941

By Trang T. Tran-Valade

With continually increasing energy prices, the mining industry has been on the search for new energy optimization technologies. One area that is garnering great interest is Ventilation-On-Demand (VOD). Prior to selection and implementation of a VOD solution, it is important to fully understand the mine requirements as well as its existing infrastructure and the interaction with other automation in place at the site. With this information, a business case can be generated including a cost versus benefit comparison for various control strategies. To assist in the development of the business case, this paper will identify key areas for consideration and recommendations for an implementation plan.

May 1, 2013

By R. E. Whitehead

"Abstract - Alkali-alumina and MgO-alumina plots are an effective instrument for displaying chemical and mineralogical compositions of altered and unaltered rhyolites and rhyodacites. They reveal that most supposedly unaltered rhyolites, apart from those of Cenozoic age, have undergone losses in Na2O and gains in K2O. The extreme loss of Na2O from highly altered rhyolites immediately adjacent to VMS deposits is strikingly illustrated by alkali-alumina plots. MgO/Al2O3 vs. K2O/Al2O3 diagrams display a strong negative correlation between MgO and K2O that results from the conversion of sericite to chlorite. A similar negative correlation between MgO and whole-rock d18O is apparent on plots of these two parameters. Alkali-alumina plots underscore problems in selecting appropriate precursor compositions required for mass-balance calculations. Molar ratio plots are a viable alternative to such calculations. Sommaire -Les diagrammes alcali-alumine et MgO-alumine constituent un instrument efficace pour la représentation des compositions chimiques et minéralogiques des rhyolites et rhyodacites altérées et fraîches.Ces diagrammes révèlent qu’à l'exception de celles d’âge Cénozoïque, la plupart des rhyolites qualifiées de fraîches ont subi une perte de Na2O et un gain de K2O. L’intense perte en Na2O que l’on note dans les rhyolites fortement altérées associées aux gîtes de type SMV est particulièrement bien mise en évidence par le diagramme alcali-alumine. Le diagramme MgO/Al2O3 vs. K2O/Al2O3 montre une forte corrélation inverse entre le MgO et le K2O due à la conversion de la séricite en chlorite. Une corrélation inverse analogue entre le MgO et le d18O de la roche totale s’observe sur un graphe comparant ces deux paramètres. L’usage du diagramme alcali-alumine fait ressortir combien il peut être difficile de choisir un précurseur de composition appropriée pour des calculs de balance de masse. Les diagrammes de rapport molaire constituent une alternative à de tels calculs."

Jan 1, 2006

By Maurice Morton

THE use of organic and inorganic stains has found wide application as a means of detection and estimation of organic fibres. Such stains have enabled the analyst to distinguish between organic fibres of different type and even between wood fibres produced by different processes. Among these stains, aqueous iodine solutions have figured prominently, as in the case of the well-known Sutermeister and Herzberg stains. At the Johns-Manville laboratories, the idea of applying a stain to asbestos fibres was first considered solely as a visual aid in the microscopic examination of such fibres. The staining medium used in this work consisted of a 1 per cent solution of iodine in C.P. glycerine, the latter being used extensively here as a dispersing and mounting liquid for asbestos fibre. This iodine solution was found to have distinct staining properties when used on the local chrysotile fibres, and to improve greatly their visibility under the microscope. It was soon revealed, however, that this staining is apparently limited to the chrysotile variety of asbestos, as against other varieties. It can be readily seen that, if such were the case, the staining test would become a very useful tool in differentiating between chrysotile fibre and the other mineral fibres, without recourse to a lengthy chemical analysis. Hence this investigation was launched, with the purpose of obtaining more information as to the selectivity of this stain as well as its mechanism. The only previous work of this nature that could be found in the literature was that of Van Winsen and Graham (1, 2, 3) on the adsorption of erioviolet dye by serpentine and related magnesia minerals. However, these authors did not refer to any specific behaviour of chrysotile as against other types of asbestos fibre.

Jan 1, 1941

By M. Pawlik, E. Arinaitwe, V. Ferrera

A series of flocculation tests were performed on dilute quartz suspensions with the use of five polyacrylamide-based flocculants of similar molecular weights but of different degrees of anionicity. The tests were performed as a function of ionic strength and pH. The macromolecular conformation of flocculants in solution was assessed through intrinsic viscosity measurements under the same physicochemical conditions as those of the flocculation tests. It was generally found that the flocculating efficiency of the polyacrylamides correlated with their ability to coil or stretch in solution. Polyacrylamides with the degrees of anionicity on the order of 10-18% showed the highest flocculating efficiency in terms of the settling rates of the flocculated solids and the residual turbidity of the resulting supernatant. At the same time, these most effective flocculants were also found to exhibit the greatest tendency to coil and stretch in solution. This result suggests that the flocculating power of a flocculant is determined not only by its ability to adsorb onto (and bridge) fine particles but also on its ability to conform to the size of the resulting floes.

Jan 1, 2009

By W. Abdellah

Underground mine developments, such as haulage drifts and cross cuts, play a vital role in providing access to ore extraction areas for mine production. The stability of mine developments is thus of crucial importance during the life of a mine plan. Many Canadian mines use longhole mining methods or one of its variants. These methods require access to the orebody through mine developments such as haulage drifts and cross cuts on multiple levels. This paper examines the stability of mine development access intersections with respect to the planned mining sequence. A case study, the #1 Shear East orebody at Vale?s Garson Mine in Sudbury, Ontario, is presented. A three-dimensional, elastoplastic, finite difference model (FLAC 3D) was created for a development intersection situated 1.5 km below ground surface. The stability, or performance of the intersection, is evaluated in terms of the strength-to-stress ratio. The ratio threshold is set at 1.4 for temporary openings. Unsatisfactory performance is defined as a strength-to-stress ratio less than this threshold value. The performance of the intersection stability is evaluated at various modelled mining stages and the probabilistic method of analysis is then invoked to study the probability of unsatisfactory performance of the intersection. The results are presented and categorized with respect to probability, instability, and mining stage.

Aug 1, 2013

By C. D. M. Chisholm

IN discussing stope filling, or backfilling, at the Sullivan mine, at Kimberley, B.C., a brief description of the problem will first be presented. The Sullivan orebody is a replacement in quartzite, with the ore con-forming, for the most part, with the bedding. The dip of the vein, apart from local irregularities, averages about 15 degrees near the outcrop in the southwest section of the mine, and steepens to almost 40 degrees at the northeast end of the mine. The thickness varies from a few feet to over 200 feet at the widest sections. The mineable length along the strike has averaged about 4,000 feet between the 4,600 and 3,900 levels-the section under discussion in this paper. To date, 28,000,000 tons of ore have been mined by the room-and-pillar method. Prior to 1930, all ground opened up had been supported by ore pillars, left during mining operations. From that time, the recovery of the ore from these pillars has been given serious consideration. Backfilling, as being carried on today, is the result of this study and is being done for two reasons: (1) to allow extraction of the ore pillars, and (2) to minimize subsidence of the hanging-wall rock, except where forced caving is found desirable. PRELIMINARY DEVELOPMENTS LEADING TO BACKFILLING When the Sullivan orebody was first opened up, early in the century, there appeared to be low-grade sections of the vein sufficient in extent to serve as permanent support for the roof. However, as mining extended into sections of the vein that showed continuous ore over greater areas, wooden cribs, filled with waste and low-grade ore, were erected. In some stopes, these cribs were as large as 40 ft. by 100 ft. in plan and from 50 ft. to 60 ft. in height, but it was soon realized that this method of support was inadequate. As mining progressed, it was found necessary to leave ore pillars, which eventually became the sole system of support. At first, these pillars were left at irregular intervals, but later they were laid out at definite locations on the mine plans, and these locations were adhered to as closely as mining would permit.

Jan 1, 1941

By L. M. Wang, G. P. Jiang, Y. Jiang, Liao. W. S.

ABSTRACT The authors measured porosities and permeabilities for cores from a low-permeability sandstone uranium deposit in Inner Mongolia. Features studied included fine pore structure, mineral composition, cation exchange capacity, granule appearance, and cementing features. In general, grading of the grains was relatively poor, which decreased the radii of the pore channels. The pore throat distribution was significantly heterogeneous. Pore channels ranged from small to large, but the lack of large pore channels led to low permeability. Cementation by calcite and clays, including montmorillonite, chlorite, and kaolinite, resulted in pore channel narrowing, further decreasing the permeability of the formation.

Jan 1, 2014

By Jerry Ran

Many large underground mines using the open stoping method have changed their primary applications of consolidated rock fill (CRF) to paste or consolidated hydraulic fill due to considerations of demand in infrastructure and equipment, system reliability, backfill capacity and material sources. However, some smaller or even large mines still use or consider using CRF for backfill purpose due to factors such as capital expenditure, availability or suitability of other fill types or in some cases local regulatory requirements. As demands on CRF applications diminish among major mining companies, there is a lack of recent literature on application of CRF to open stoping in design and operation. There are several methods being used for fill strength design. Results from these methods have been successfully applied to paste or hydraulic fill. However, the design strength for CRF is much higher than that determined by use of these widely accepted methods. In operation, CRF preparation and placement have significant impacts on the quality of placed CRF and therefore the mining performance. This paper reviews the current fill design methods and their applications to open stoping with presentation of the bench marking data, presents fill failure cases and various CRF preparation and placement arrangements and discusses quality assurance and control programs.

Jun 1, 2012

By Michael Cullen

The Quinsam Coal Mine is in the process of extracting a panel beneath the mine access road. To prevent damage to the road, and adjacent powerline, it was necessary to establish a ?protection zone? within which the extent of mining would be limited. The protection zone is analogous to the setback limit. For economic reasons it was desirable to make the protective zone as small as possible, and with the greatest extraction ratio possible. The size of the protective zone was established by determining the angle of critical deformation using the numerical model FLAC, coupled with field data on subsidence from the Mine. The angle of critical deformation (defined as the angle, measured from the vertical, at which intolerable damage is sustained by a structure) was determined to be between 0 and 5 degrees. The allowable extraction ratio in the protection zone was established using the ARMPS method of pillar design coupled with field data on pillar stability from the Mine. Excavations spans to prevent caving were determined by historical experience and field data on span stability from the Mine, coupled with numerical modeling. The minimum pillar size was determined to be 7.5m. The maximum pillar height was established at 2.5m. The maximum allowable excavation span was determined to be 8.5m. With these criteria, extraction ratios between 54 and 73% (measured in plan view) were determined to be appropriate for the protection zone.

May 1, 2001

By G. A. Vissac

In this paper we intend to deal particularly with the economic side of coal washing as it applies to our mines. We will then discuss why the dry-cleaning process has been selected, and give a brief description of our plant, dwelling only on its specific features and referring the reader to the numerous papers published on the subject for any details on the principles and machinery used in dry cleaning. ECONOMIC DISCUSSION The washery introduces an extra cost for depreciation, operation, and loss in treatment. A certain proportion of the coal, now being sold, and which the miners have been paid for. will have to be wasted. As a whole, the total increase in cost would be approximately 60 cents per ton. On the possibility of recovering this amount depends the success of the washery. There are two advantages to be expected from the washery, the first, which occurs at the mine and which will be certain; the second, more difficult to estimate, because it depends upon convincing our customers that they should pay more for a better product.

Jan 1, 1924

By J. Lee, K. B. Min, J. Rutqvist

Shear slip of fractures in fractured rock masses is a critical issue for many geological engineering applications, such as the design of underground nuclear waste repositories, enhanced geothermal systems (EGS), and geosequestration of CO2. This paper presents new development of the TOUGH-UDEC simulator for analysis of coupled thermal-hydraulic-mechanical (THM) processes in fractured porous media. As an alternative to developing a single coupled THM code in discontinuum, two existing wellestablished codes, namely TOUGH2 and UDEC, are coupled to cover coupled THM analysis of multiphase fluid flow, heat transfer, and deformation in fractured porous media. TOUGH2 is widely used for modeling heat transfer and multiphase, multicomponent fluid flow, and UDEC is a well-known discrete element code for rock mechanics, which have been verified and used by many groups all over the world. Although a sequential coupling of two codes is less efficient than having a single code in principal, a big advantage with coupling of TOUGH2 and UDEC is that both codes are well tested and widely applied in their respective fields. When linking two codes, the coupled equations cannot be solved simultaneously; they should be solved sequentially, with coupling parameters passed to each equation at specific intervals. After solving thermal-hydraulic equations through the TOUGH2 model, pressure (P) and temperature (T) information is delivered to UDEC model. Pressure information is directly stored at the center of each UDEC zone and domain, however, temperature information is interpolated from zone-centers to the corners nodes. After solving the mechanical equation through the UDEC model—considering new pressure and temperature—calculated fracture apertures are converted to equivalent permeability and porosity for TOUGH2 flow analysis. The solution was calculated by iteratively following an explicit sequence for numerical efficiency. Verification examples are presented to demonstrate the capabilities of the coupled TOUGH-UDEC simulator.

Jan 1, 2015

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

By Gordon L. Kidd

The object of this paper is to show the relations of the East Coulee coal area to the near-by Willow Creek, Wayne, Rosedale, and Drumheller areas, all being parts of the Drumheller field. The word ?area? is here used in a more local sense than that employed by Dr. J. A. Allan, whose. 'area' is rather comparable with the 'mining division' in British Columbia. I have drawn freely from the published information, particularly from Dr. Allan's report on the "Geology of Drumheller Coat Field, Alberta", and from Dr. E. Stansfield's paper on " A Chemical Survey of Alberta Coals", to whom thanks are due. The Drumheller field is served by branch lines of the two principal Canadian railways. The C.N.R. traverses the district by its Goose Lake line from Calgary to Saskatoon; and the C.P.R. by a line from Calgary to Acme and then southeasterly to Drumheller, where it effects a junction with the C.N.R., over which the C.P.R. has running rights as far as Rosedale. From Rosedale, a joint line built during the summer of 1928 extends about forty miles down the Red Deer river to the mouth of Bull Pond creek. From that point the C.P .R. turns more southerly to connect with the Bassano-Empress line. The C.N.R., it is expected, will eventually proceed eastward to connect with a transcontinental line. The joint line from Rosedale down the Red Deer river opened up the Willow Creek and East Coulee areas.

Jan 1, 1929

By X. Xu, J. K. -W. Wong, J. -Y. Delenne, K. Soga

Hydraulic fracturing (HF) is a mulit-scale and multi-physics process which makes numerical modelling challenging. Conventional numerical models focus on multi-physics nature of HF but the multiscale nature is compromised by idealization of reservoir to be continuous, homogeneous and isotropic. However, natural fractures take a significant role in the success of HF for exploration of unconventional resources like Shale gas. Advancement in microseismic monitoring provides useful data for simulation in a much greater details. There is an urgent need to develop a suitable numerical tool for multi-scale threedimensional simulation to better understand the roles of discontinuities and heterogeneity in reservoir and its interaction with HF, especially to address the environmental concerns such as induced seismicity. In this paper, a simple discontinuum numerical method – Lattice Element Method (LEM) is proposed to model HF in a large scale three-dimensional model. A reservoir is modelled as a lattice network composed of 1D Hookean’s spring. Fracturing is modelled simply by removing lattices that meet a specified threshold as determined by the critical energy release rate of the rock. By introducing disorder in the model, mesh dependency in modelling fracture growth is minimized. Fluid flow is simplified as flow in pipe network and the permeability of pipe is related to fracture aperture by cubic flow law. Therefore, fracture flow and rock deformation are fully coupled. In this paper, four simulations of the same configuration except with different degrees of reservoir heterogeneity are presented. Fractures formed are diffusive and two groups of fracture are identified – connected fractures and isolated fracture without clear spatial correlation. The former forms a ‘fracture cloud’ and contributes to fluid flow and modeled by pipe network. The flow of fluid is highly tortuous and pipe network is sparely connected. The degree of reservoir heterogeneity controls the growth of ‘fracture cloud’ and pipe network. Microseismic monitoring often shows diffusive fracturing during HF on site and hence the outcome of the proposed model can be compared to such monitoring results.

Jan 1, 2015