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By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By Raj K. Rajamani, Nikhil Dhawan

"Agglomeration has become common pre-treatment step to improve heap leach percolation thereby recovery, the fundamental understanding of the agglomeration process for crushed ores is still lacking. Agglomeration is required for ores which either contain excessive amounts of clay or an excessive quantity of fines generated during mining and crushing. Numerous experiments have been carried out in laboratory scale batch drums using different ores. It has been found out that experimental agglomerate size distributions exhibit self-preserving spectra. The self-preserving/ similarity distribution of the agglomerates is found to be independent of operating conditions and is uniquely determined by the size enlargement mechanism. An empirical model based on the absolute difference between moisture applied and optimum moisture was developed. This model uses self-preserving spectra in the form of a Rosin-Rammler distribution function to predict size distribution at different operating conditions. The empirical model was considerably easier to work with plant scale agglomeration drums. Also, a test known as dip test is developed which improves fundamental understanding of the agglomerate formation and growth mechanisms. This test also provides the progeny size distribution of each agglomerate size. The progeny size distribution was analyzed with a model that partitions the particles into a host and guest category. The ensuing partition coefficient identifies the behaviour of a particle as a host for other particles or a guest layering on other particles. This concept helps in identifying the type of agglomerate that would result for a specific feed size distribution. INTRODUCTIONHeap leaching is one of the hydrometallurgical processes that have served as a green and economically viable process for the treatment of low grade complex ores of copper, uranium, nickel, silver and gold (Dhawan et al., 2013). Heap leaching appears to be a favorable candidate for the least energy consuming process for low grade ores. In heap leach operations nowadays a pretreatment step known as crushed ore agglomeration has been implemented (Dhawan et al., 2013). A bed of agglomerates improves the uniform percolation of solution through the heaps of ore. Therefore, it was possible to treat wastes and mill tailings via agglomeration and heap leaching. Agglomeration pretreatment is required for ores which either contain excessive amounts of clay or an excessive quantity of fines generated during mining and crushing (Bouffard, 2005; Dhawan et al., 2013).While agglomeration has become common practice pretreatment step in heap leach operations, the fundamental understanding of the crushed ore agglomeration process is still lacking. The author reviewed publications up to 2012 on the crushed ore agglomeration process and did not come up with modeling studies on the topic (Dhawan et al., 2013). Some of the possible reasons can be the stochastic nature of the process, experimental difficulties, and lack of instrumentation for fundamental studies."

Jan 1, 2016

By L. Tafaghodi, S. Sarbishei

"Following the depletion of nickel sulfide ores, laterites are considered as one of the main sources for producing nickel and cobalt. One of the primary steps in pyrometallurgical extraction of nickel from laterites involves partial reduction of the ore at temperatures below 1000°C. Studying the kinetics of laterite reduction provides valuable information on reducibility of nickel laterites using coal as a reductant. The present study investigates the reduction behavior of a nickel laterite by thermal gravimetric analysis and differential scanning calorimetry. Non-isothermal reduction tests and X-ray diffraction analysis were performed to find the main reactions that occur during the process. The kinetic parameters were calculated by Coats-Redfern method. The general model of simple reaction f(a)=(1-a)n was used for calculating kinetic parameters.INTRODUCTION Nickel (Ni) naturally occurs in the form of sulfide and laterite ores. Laterite ores are mainly available in tropical regions. Weathering phenomena during millions of years has led to the formation of several layers with specific mineralogy (Butt & Cluzel, 2013). The three main layers downward are limonite, smectite, and saprolite (Crundwell et al., 2011). Although laterites are the most available nickel ore resource (70%), their share in the overall Ni production is limited to 40% (Crundwell et al., 2011). The main reasons for not materializing the full potential of laterites are as follows (Ray et al., 1985): •,Laterite ores contain high water content (free and combined) which in turn results in high energy consumption of the extraction process. •,As Ni is present in the form of solid solution in laterites, physical upgrading methods such as flotation are not effective in increasing the Ni content before the extraction process. •,Extracting Ni from sulfide ores involve exothermic reactions which are beneficial due to decreasing the overall energy requirement of the process, however there is not efficient release of energy in the process of extracting Ni from laterite ores."

Jan 1, 2017

By Kazuhide Nakaniwa

In this research, we devised a measurement method using total stations (TSs) which have ?the Baum? which is a concentric circle reticle, as substitute for crosshairs. The Baum owes its name to the similarity between the concentric circles and trees (Baum in German). By setting one circle on both of edges of cylinders, operators can set their sights on points on the center line of the cylinders, and also can measure positional coordinates of the points. Also, by measuring two different points on the center line, operators can measure the position and tilt of the axes of the cylinders. Furthermore, we developed a pile driving navigation system. Foundation piles are used for various structures, and their forms are generally cylindrical. Especially, although it is difficult to drive tilted pile foundations, their usage are expected to expand due to their high earthquake resistance. Yet, a method to accurately measure the tilts of piles has not been established. However, we proved that operators can obtain adequate accuracy to control foundation piles through the measurement experiment using this system. Using this system, the information of the pile is measured using a TS, transferred to a PDA, and displayed from the operator?s view of the piling machine.

Aug 1, 2013

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

By J. W. Craig

CHROME ore, which is used in Canada in the production of ferro-alloys, in a variety of refractories, and indirectly in many chemical industries, is both commercially important and scientifically interesting. The sight of chromium metal is familiar to all of us in the home, the office, the automobile. Chromium is synonymous with armaments: it is understood to be one of several essential metals in tanks, which played an important role in the defeat of France in the spring of 1940. Chromium, in other forms, comes into our daily lives by way of paint and leather, of the familiar green ginger-ale and beer bottles, and more indirectly in every pound of steel produced in the .Dominion. Necessary to our civilization in peace and war, the ores of chromium occur in many corners of the earth. This paper attempts to describe the chemical constitution of chrome ores, their world distribution, and the various chrome products and their industrial applications in Canada.

Jan 1, 1940

"A 3-dimensional finite element model for stress/stability analysis of rock excavations in underground mines is presented. Developed for use on personal computer under OS/2 operating system, the model employs the 8-node isoparametric brick element and accounts for such loading conditions as in situ stresses and gravity loading of the rock mass. In addition, modelling of backfill in mine stopes as in situ stress-free material is incorporated. Material failure is assessed by Mohr-Coulomb or Hoek-Brown failure criterion. A mine design example is presented to illustrate the potential use of the model as a tool for stope design.IntroductionNumerical modelling of mine structures has become a vital tool for mine design in recent years. The need to maximize ore extraction ratio and to reach deeper mineral deposits underground has led the mining industry to employ numerical methods of analysis to undertake complex ground control studies in order to better understand the ground response to mining excavations and to evaluate the ground support requirements. Thanks to the rapid developments in computer technology, it is now possible to perform very comprehensive analyses including, but not limited to, 3-dimensional, elasto-plastic, or large deformation or time dependent nonlinear analyses on personal computer.During the past ten years or so, many researchers undertook 3-D finite element analyses of rock mechanics problems in mining engineering. The following is only a sample review. For example, Chan'!' used three-dimensional finite elements to study the mechanical response of jointed granite during shaft sinking at the Canadian Underground Research Laboratory. Wang et al.(2) performed 2-D and 3-D finite element analyses of room-and-pillar mining system with flat and rolling coal seams. Thatejatu used three-dimensional finite element method to examine the problem of branching tunnels. Dolezalovaw used three-dimensional finite elements for the analysis of tunnel-face advance with partial excavation as well as full-face excavation in combination with rein for cement of the face by long anchors. Peili (5) used three-dimensional finite elements for the simulation of rock-liner interaction near the tunnel face."

Jan 1, 1992

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004

By G. E. Rowan

"DURING the dark ages, the cherished dream of chemists was to find a process for converting base metal into gold. Many a wealthy-but-gullible patron lost a fortune in the search. Men who work with metals today are a bit more realistic. I haven't heard of a metallurgist who expects to develop any one alloy that will resist all corrosive media. In the field of stain-less steels, there are about forty different types of alloys that are used where corrosion is a •problem.A stainless product is ordinarily selected because it offers one or more of the following qualities:(1) Resistance to corrosion (2) Resistance to oxidation at high temperatures (3) Good mechanical properties at room temperature (4) Good mechanical properties at high or low temperature (5) Attractive appearance (6) Ease of maintenanceToday we are interested in discussing the stainless steel family of alloys because of their .ability to resist corrosion. We• will not try to explain the Theory of Corrosion. Let us assume that, when surface potential and oxide formations are properly controlled, iron will resist attack in various chemi.cal solutions. The addition of alloying elements to iron does this for stainless steels. The principal stainless alloys used by various Canadian industries are listed in the accompanying Table."

Jan 1, 1959

Bahuerachi Project Characteristics Why it?s nicer at Bahuerachi Mexico is a mining country Low political, regulatory and trade risk Low social/permitting risk Proximity to infrastructure Road Power grid (8 km) Rail line (25 km) High grade zones (skarns), CRD and near surface oxide component are sweet spots to the overall system. Size of low grade system points to potential long mine life?and numerous new targets developing. Timelines-2006? 90 to 100 combined RC and core holes to go! MAIN ZONE Drilling ? Goat ?Finish Mid April ? Main Zone, going North, depth of testing dependent, estimated for May ? North Lobe-May ? Commission independent resource estimate by May 06 for results of first pass drilling to date ?tonnesand grades ?Main Zone Milestone. ? Continue infill or expanded drilling to July (minimum) ? 1stpass RC scheduled until September OTHER Targets ? Begin drill testing North Skarn target Mid-April, minimum 5 drill holes, 1,000 meters. Ongoing expansion of target with surface work (mapping) ? Road to Colome(Skarnin north of Main Zone) as part of porphyry program ? Tule(southern) porphyry and skarn system-soils and mapping OUTSTANDING events Metallurgical report on floating and leaching tests (Sulphide/oxides).

May 1, 2006

By H. Dean

"Mine hoisting machinery, of which wire rope is an essential part, is developing, in Canada as well as in other parts of the North American continent, into highly sophisticated equipment. Heavier payloads are now required to be raised from steadily increasing depths at higher rates of speed and production. These hoisting conditions have, of necessity, brought about a major change in the production of steel roping wires and the wire ropes manufactured from them.Operators and designers of hoisting equipment are requesting a very much more efficient ratio of strength to weight in hoisting ropes, so that heavier loads may be raised from greater depths by ropes which will provide a predeterminable life span on which the operator may depend.The cost of wire rope to the operator is very low indeed, usually less than $0.01 per ton of payload, but the cost of unexpected shutdown periods, due to rope maintenance or change, can be extremely high -particularly in operations where a continuously high rate of production is an absolute necessity. Mine hoist ropes with a higher strength to weight ratio are now being made and used in some areas of Canadian mining, and a general understanding of the performance we may expect from them is required."

Jan 1, 1968

By Zhenyu Han, Dion Weatherley, Ruslan Puscasu

"This study aims to demonstrate the capacity of the Discrete Element Method (DEM) to model and simulate fracture in brittle rock, capture the crack propagation process and determine crack propagation rates for various levels of external loading. In the numerical experiments reported here, a macroscopically homogeneous body of brittle rock, containing a single pre-existing crack, was subjected to tensile stress loading. Simulations concerned with model I crack growth process in 3D were carried out. The process of fracture has been observed under various steady state and dynamic conditions. The numerical results obtained reproduce qualitatively and quantitatively a variety of observed fracture phenomena. Specifically, this study examined the onset of cracks, single dominant cracks that grow across the specimen, crack bifurcations and branching. The density of fractures that can be nucleated and grow to a significant size with and without arresting each other, crack growth speed and stress distribution, all have been consistently and systematically analyzed. Suggestions on potential future developments are made and discussed.INTRODUCTIONFracture and failure mechanics are very important in mining, manufacturing, materials processing, mineral processing, civil and mechanical engineering, and many other disciplines of science and engineering. Yet, due to the complexity of fracture phenomena, no theoretical models of broad applicability are currently available (Bieniawski 1967). The simulation of crack propagation is therefore considered an open question in numerical rock mechanics. Although, a significant body of experimental research on fracture of materials was carried out since the early days of fracture mechanics (circa 1940s) (Poncelet 1946, Mott 1948), often in parallel with the development of fracture mechanics theories as well as with the development of experimental and observational techniques themselves, the experimental results were often done on particular classes of material such as glasses and other very brittle materials. Indeed, a number of specific experimental observations on the behavior of growing cracks in brittle materials were made in the 1940s for which generally accepted explanations based on physical principles are still lacking. Likewise, quantitative numerical modeling, based on both continuum and discrete methods, as a basis for understanding dynamic crack growth is still in a preliminary stage."

Jan 1, 2015

By Min-Yuan Cheng

Heavy rainfall and typhoon oftentimes cause the collapse of hillslopes across mountain roads. Disastrous consequences of slope collapses necessitate the approach for predicting their occurrences. In practice, slope collapse prediction can be formulated as a deterministic classification problem with two class labels, namely ?collapse? and ?non-collapse?. Nevertheless, due to the criticality and the uncertainty of the problem, evaluating the collapse susceptibility of an area is a challenging task. This study proposes a novel Artificial Intelligence (AI) approach, named as K-Nearest Neighbor Based Bayesian Classifier (KNNBC), to deal with slope collapse assessment. In the proposed model, Bayesian inference is used as a framework to achieve probabilistic prediction of slope collapse. Meanwhile, K-Nearest Neighbor (K-NN) is employed as a density estimation technique. Equipped with probabilistic outputs, the K-NNBC is able to yield predictions with different levels of confidence and diminish misclassified cases. Experimental results point out that the proposed model is very helpful for decision-makers in slope collapse assessment and disaster prevention planning.

Aug 1, 2013

By Rodolfo Zanella

Au/TiO2 catalysts prepared by deposition-precipitation with NaOH (DPN) (~3 wt%) and urea (DPU) (~8 wt%) were tested in crotonaldehyde hydrogenation at atmospheric pressure. There is no differences in activity (mole.gAu -1 s-1) and selectivity between both DPU and DPN samples for a given activation treatment. This is due to the fact that DPU and DPN samples exhibit similar gold particle size distribution, although the gold loading in DPU is much higher that in DPN. The DPU samples were reduced under H2 at different temperatures (120-500 °C) or under air at 300 °C with various flow rates, to vary the average particle size within a large range, 1.7 to 8.7 nm. The selectivity to crotyl alcohol (selective hydrogenation of the carbonyl bond) is high, 60-70 %, and almost constant as a function of the particle size. The selectivity to crotyl alcohol is also constant for conversions between 10 and 50%. These results suggest that the adsorption mode of crotonaldehyde is of ?3 or ?4-type. In contrast, the TOF depends on the gold particle size, it drastically increases when the gold particle size is ~2 nm. Our results are in agreement with former studies that suggest that the gold atoms involved in the hydrogenation process are those of low coordination.

Oct 1, 2003

By B. Lafrance, C. J. Beaumont-Smith, L. R. Jones

"Abstract - The Burnt Timber gold deposit is located in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen, Manitoba. The deposit occurs along the Johnson shear zone, and is hosted by enriched and depleted tholeiitic volcanic arc basalts cut by feldspar porphyry dikes. The Johnson shear zone is a regional, belt-parallel structure characterized by the intensification of the regional S2 foliation. At the Burnt Timber deposit, S2 is folded by centimeter- to meter-scale, Z-shaped, F3 chevron folds that have an axial planar S3 crenulation cleavage. Within the 20 to 30 m-wide core zone of the shear zone, S2 and F3 are transposed parallel to S3 and the volcanic rocks are strongly sheared parallel to S3. The presence of a steeply plunging stretching lineation, together with dextral shear sense indicators along both S2 and S3 on horizontal surfaces, suggest that the Johnson shear zone is a dextral transpression zone. Gold was introduced in pyritic, biotitic, and carbonatized mafic volcanic rocks along the core of the shear zone. Mylonitic mafic volcanic rocks contain localized high-grade zones (=10 g/t Au) that differ from wider carbonatized, low-grade zones (<3 g/t Au) by the presence of deformed gold-bearing quartz-pyrite veins. High-grade zones are also associated with swarms of quartz-pyrite veins that cut across sericitized and carbonatized feldspar porphyry dikes, which acted as brittle, competent bodies during shearing. Gold deposition in the high-grade zones was controlled by the channeling of hydrothermal fluid along the core of the shear zone during shearing of the volcanic rocks, and brittle fracturing of the porphyry dikes. Sommaire - Le gîte aurifère de Burnt Timber est situé dans la ceinture de roches vertes Paléoprotérozoïque de Lynn Lake dans l’orogène Trans-Hudsonien, au Manitoba. Ce gîte est situé le long de la zone de cisaillement de Johnson et est encaissé dans des basaltes tholéiitiques d’arc enrichis et appauvris recoupés par des dykes porphyriques. La zone de cisaillement de Johnson est une structure régionale parallèle à la ceinture de Lynn Lake caractérisée par une intensité accrue de la foliation régionale S2. Au gîte de Burnt Timber, S2 est affectée par un plissement F3 en chevrons en Z d’échelle centimétrique à métrique associé à un clivage de crénulation de plan axial S3. Dans la zone centrale de 20 à 30 m de largeur au sein de la zone de cisaillement, S2 et F3 sont transposés parallèlement à S3 et les roches volcaniques sont fortement cisaillées le long de S3. La présence conjointe d’une linéation d’étirement à forte plongée et d’indicateurs cinématiques dextres sur les surfaces horizontales S2 et S3 suggère que la zone de cisaillement de Johnson est une zone transpressive dextre. L’or a été mis en place dans des volcanites mafiques altérées en pyrite, en biotite, et en carbonate au coeur de la zone de cisaillement. Les roches volcaniques mylonitiques présentent des zones aurifères locales à haute teneur (=10 g/t Au) qui diffèrent des zones à basse teneur (<3 g/t Au) par la présence de veines de quartz et de pyrite aurifère. Des zones à haute teneur associées à des essaims de veinules de quartz et de pyrite sont aussi notées dans des dykes porphyriques à plagioclase altérés en séricite et en carbonates; ces dykes se sont comportés comme des corps compétents durant le cisaillement. La déposition de l’or dans le zones à haute teneur a été contrôlée par la circulation du fluide hydrothermal au coeur de la zone de cisaillement durant la déformation des roches volcaniques et la fracturation des dykes porphyriques."

Jan 1, 2006

By Roy O. Ifill, W. Charle Cooper, Alan H. Clark

"Queen’s UniversityIn representative, run-of-mine samples from the Panel and New Quirke mines of the Elliot Lake uranium district, Ontario, brannerite, ametamict uranous titanate, occurs in microscopic grain-aggregates which display wide variations, both in textural habit and in the relative proportions of brannerite, titania polymorphs and/or “uraniferous titania”. As is widely documented, much of the brannerite occurs as trellis-like arrays of laths and needles pseudomorphing rutile oranatase. In some cases, the laths and needles are cemented by coffinite. Brannerite, with an average composition of (U0.629Th0.039Ca0.20)(Ti2.199Fe0.13)O69contains =3 wt% Th and is distinctly Ti-rich relative to the ideal composition, UTi2O6. Much of the Si reporting consistently in electron microprobe analyses (between 1 wt%and 5 wt%) is tentatively attributed to contamination by the quartz-sericite matrix, and a minor proportion is attributed to the presence of coffinite intergrowths. “Uraniferous titania” (average par-tial composition by weight: 10.8% U, 0.3% Th,32.9% Ti) is considered to represent an intermediate stage in the conversion of titania to brannerite.The leaching behaviour of brannerite in its different modes of occurrence was studied qualitatively by the rotating-disc (polished section) method in H2SO4and HCl solutions at 25° to70°C. Redox potential was not measured. The progress of the dissolution of the individual brannerite crystallites and grain-aggregates was monitored by optical and scanning electron microscopes. Regardless of its morphology and texture (laths or needles, reticulate or blocky),brannerite is not readily leachable. Regardless of the process conditions, the rate-controlling step appears to be the initial leach-pit formation. These pits expand radially through the aggregate as leaching proceeds. This dissolution mode is independent of the relative amounts of brannerite and titania, i.e. the type of grain-aggregate. Secondary coffinite intergrowths are readily leachable and enhance the overall leaching kinetics of brannerite by accelerating leach-pit formation. These data provide, for the first time, information on the controls on the leaching of the uraniferous phases which dominate the lower-grade ores in the Elliot Lake district."

Jan 1, 1996

By John Hughes

1. De Beers, Diamonds and Canada 1.1. De Beers was founded long ago (1888, the same time that Canada became a country) in a rural mining village in South Africa. Today, we employ 22,000 people across 19 countries and have 14 mines including open pits, shafts, beach-sands and seabed. 1.2. Last year our sales were US$5.7 billion and our total production amounted to 47 million carats which means a 40% global market share. For the Kyoto buffs in the audience, the company consumes 66 million cubic metres of water per annum, 210 million litres of hydrocarbon fuel and 1,600 GWh of electricity. Stats are good, but aren?t as expressive as a movie. This one is 2 minutes long, which is quicker than I could elaborate. (Video 1 - 2 minutes) 2. De Beers in Botswana is the leading source of diamonds 2.1 Today Botswana is the Jewell in the Crown. There are three big open pits that enjoy economies of scale that make them the lowest cost producers. Last year 60 million tonnes of overburden and 30 million tonnes of ore were moved in Botswana alone. Botswana produced 31 million carats, compared to 14 million carats in South Africa and 2 million very high quality carats inn Namibia. 3. Diamond Mines provide feedstock? ?.to jewellery stores

Apr 1, 2005

By V. P. Mehrotra, D. W. Fuerstenau, A. -Z. M. Abouzeid

The use of pulverized coal for electric power generation results in the production of vast amounts of fly ash. One potential use for waste fly ash is the production of pellets for lightweight aggregates. This paper is concerned with the role of the physical and chemical characteristics of two different fly ashes in governing their agglomeration or pelletization behavior and their strength characteristics. In batch balling experiments, fly ash pellet growth was found to be extremely sensitive to the amount of moisture added. One ash (Mohave) exhibits marked pozzolanic activity whereas the other (Jim Bridger) does not. The pozzolanic activity has a very pronounced effect on pellet growth kinetics, moisture requirements, and the effect of various additives on growth kinetics. Slow drying under ambient conditions produces strong pellets from Mohave ash whereas Jim Bridger ash pellets lacking in pozzolanic activity are weak. Rapid drying at high temperatures results in weak pellets because water necessary for hardening is driven out of the pellet. Steam curing enhances pellet strength. Locked-cycle pelletizing experiments exhibit expected oscillation in pellet production rates and attendant fluctuations in pellet green strength.

Jan 1, 2004

By Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

At the present time of depletion of reserves of high grade rare earth deposits, it has become necessary to involve low grade raw materials in the production. Among the rare-earth deposits in Kazakhstan, the most advanced one is Kundybai. The mineralogical composition of ore is represented by the minerals: a-quartz SiO2, kaolinite Al2(Si2O5)(OH)4, muscovite KAl2(AlSi3)O10(OH, F)2, albite Na(AlSi3O8), rutile TiO2, and hematite Fe2O3. It contains: 59.1–68.5% SiO2, 19.1–28.4% Al2O3, 7.2–10.3% Fe2O3, 0.51–0.84% TiO2, 0.10–2.32% CaO, 0.39–2.10% MgO, and some other elements. Rare earths are located in the clay part (kaolinite, goethite) in the ion-adsorbing form, and they are represented by the main ore mineral churchite - YPO4·2H2O. In the ore the amount of rare-earth elements (total REEs) varies from 210 to 600 ppm. Elements of the cerium group predominate (La, Nd, Ce, Sm, Pr) and the yttrium group is represented by Y, Gd and Dy. Extremely thin intergrowth and accumulation of REEs in clay minerals cause difficulties in their recovery using flotation and gravitation beneficiating methods. The purpose of this work is the development of an extraction method for the main mineral components of ore with transfer of the total REEs into the solution with high extractive efficiency. Results of the experimental work into high-temperature processing (hereinafter referred to as sulphatization) of ore by sulphuric acid with subsequent dual-mode water leaching of the sulphate product (sinter) are presented in this manuscript. The influence on the ore sulphatization process of some physical and chemical parameters: liquid-to-solid (L/S) ratio (0.36–0.86 cm3/g), temperature (100 – 500°?), concentration of sulphuric acid (3.0–18.62 mol/L) and duration (0.5–2.5 h) was studied. Optimal technological parameters of the process were determined to be: L/S ratio 0.36–0.46 cm3/g; temperature 500°?; concentration of H2SO4 9.0 mol/L; soaking time 1.5 h. Under these conditions it is possible to obtain extractions of ~ 85% REE, as well as 58% aluminium and 10% iron. XRD and IR-spectroscopy analyses were used to determine the material constitution of sulphated cakes obtained under optimal conditions. It was found that the primary minerals are quartz and muscovite; however different sodium aluminium silicates and albite minerals are present as well. In the future, it is proposed that the leach residue cakes are processed into precipitated silica (“white soot”).

Jan 1, 2016

By A. M. Brown, P. V. Straznicky

Dimpling as a means of flush countersinking rivets is an old process predominantly used in secondary structures. The introduction of GLARE as an aerospace material has renewed interest in dimpling and its possible application in primary structures. The dimpling process is able to prevent the creation of a machined knife-edge in the thin aluminum plies of the GLARE sheets. In addition, dimpling eliminates the need to use reduced height rivets, such as the NAS 1097 rivet style. This investigation expands on an earlier study into dimpling of GLARE by Rans and Straznicky. In order to tailor the dimpling process to GLARE, FEM simulations were developed. After verification, a study was performed to find the best parameters for dimpling GLARE3-2/l. Coupon fatigue tests were carried out and the dimpled joints demonstrated increased fatigue lives over the conventional machine countersunk joints. Future wide panel fatigue tests are planned to confirm the usefulness of dimpling thin GLARE laminates.

Jan 1, 2006